P 262 : Do not get in eyes, on skin, or on clothing.
P 271 + P
P 304, P
P302, P
CGA-PG02 : Protect from sunlight when ambient temperature exceeds
Press. Gas
H 280 : Contains gas under pressure; may explode if heated.
H01
HG01
P 202 Do not handle until all safety precautions have been read
403
340, P 313
336, P 315
: Gases under pressure
(Liquefied gas)
: May displace oxygen and cause rapid suffocation.
: May cause frostbite.
and understood.
: Use only outdoors or in a well-ventilated area. Store in a
well-ventilated place.
: IF INHALED: Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Get medical
advice /attention.
: IF ON SKIN: Thaw frosted parts with lukewarm water.
Do not rub affected area. Get immediate medical
advice/attention.
Page 2 of 14
52 oC (125oF).
CGA-PG05 : Use a back flow preventive device in the piping.
CGA-PG06 : Close valve after each use and when empty.
CGA-PG27 : Read and follow the Safety Data Sheet (SDS) before use.
OSHA-
PG01
Contact with liquid or cold vapor can cause frostbite.
Other Hazards
Low acute toxicity.
High exposures may cause an abnormal heart rhythm and prove suddenly
fatal.
Very high concentrations may cause anesthetic affects and asphyxiation.
Contains fluorinated greenhouse gases covered by the Kyoto Protocol.
: DO NOT REMOVE THIS PRODUCT LABEL (or
equivalent wording).
3. COMPOSITION/INFORMATION ON INGREDIENTS
Common Name
R134a
*Contains no other components or impurities which influence the classification of the product.
Ingredient
1,1,1,2-
tetrafluoroethane
CAS Number Specification
811-97-2 100% (w/w) None established.
OSHA-PEL
Page 3 of 14
4. FIRST AID MEASURES
Eye Contact
Ingestion
Contact with liquid or cold vapor can cause frostbite.
Immediately flush with water for at least 15 minutes, opening
eyelids to ensure flushing.
Get medical attention if symptoms occur.
Inhalation
Skin Contact
Victims should be assisted to an uncontaminated area is most
important.
Move exposed person to fresh air.
If not breathing, provide artificial respiration or oxygen by
trained personnel.
In the event of cardiac arrest apply external cardiac massage.
Further treatment should be symptomatic and supportive.
Keep victim warm and quiet.
PROMPT MEDICAL ATTENTION IS MANDAROTY IN
ALL CASES OF OVEREXPOSURE.
RESCUE PERSONNEL SHOULD BE EQUIPPED WITH
SELF-CONTAINED BREATHING APPARATUS.
Take off the contaminated clothing / shoes immediately.
Flush the affected area with lukewarm water not exceeds 105oF
(40oC) immediately.
Get medical attention if symptoms occur.
Unlikely route of exposure.
Do not include vomiting.
Provided the patient is conscious, wash out mouth with water
and give 200-300ml of water to drink.
Get medical attention if symptoms occur.
Page 4 of 14
important symptoms and effects,
xtinguishing media
Unsuitable extinguishing media
None known
hazards arising from the
Most
both acute and delayed
5. FIRE FIGHTING MEASURES
Suitable e
Special
chemical
High concentrations may cause asphyxiation.
Symptoms may include loss of mobility/ consciousness.
Victim may not be aware of asphyxiation.
As asphyxiation progresses, nausea, vomiting, prostration, and
loss of consciousness may result, eventually leading to
convulsions, coma, and death.
Use an extinguishing agent suitable for the surrounding fire.
Exposure to fire may cause containers to rupture/explode.
R134a does not support life. It act as a simple asphyxiant.
Special protective equipment and
precautions for fire fighters
In case of fire: Stop leak if safe to do so.
Continue water spray from protected position until container
stays cool.
In confined space use self-contained breathing apparatus (opencircuit positive pressure compressed air type) in combination
with fire kit.
Thermal decomposition will evolve very toxic and corrosive
vapors (hydrogen fluoride).
HFC 134a is not flammable in air under ambient condition of
temperature and pressure.
Certain mixtures of HFC 134a and air when under pressure
maybe flammable.
Certain mixtures of HFCs and chlorine may be flammable or
reactive under certain conditions.
Safety gloves and shoes, or boots, should be worn when
handling cylinders.
Page 5 of 14
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