Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet (MSDS)
For
Shenzhen Lumin Technology Co., Ltd
Room D906, Tianhui Building, Yousong Road, Longhua Didstrict, Shenzhen, 518100
and for their product
Li-ion battery
Model/type reference ...................... : 18650
Trademark ....................................... :N/A
Material Safety Data Sheet
Nominal Voltage…………………….: 3.7V
Typical Capacity…….......………….: 2600mAh, 9.62Wh
Weight…….......…….............…….: 46.28g
Shape and Physical Dimension
(mm)………………………………..:
Version number…………………….: V3.0
Preparation Date……………..…….: Jan. 02, 2018
Revision date………………………..: N/A.
Laboratory ....................................... :
Address ........................................... :
H: 68.4mm
D: 18.3mm
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Compiled by (name+ signature) .. :
Ivan Ni
Approved by (name+ signature) .. :
Report No.:STR17119191S Page 1 of 10
Davis Yang
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Identifier
Product name: Li-ion battery
Model: 18650
Other means of identification
Synonyms:none
Recommended use of the chemical and restrictions on use
Recommended Use:Used in portable electronic equipments;
Uses advidsed against:
a) Do not dismantle, open or shred secondary cells or batteries.
b) Do not expose cells or batteries to heat or fire. Avoid storage in direct sunlight.
c) Do not short-circuit a cell or a battery. Do not store cells or batteries haphazardly in a box or
drawer where they may short-circuit each other or be short-circuited by other metal objects.
d) Do not remove a cell or battery from its original packaging until required for use.
e) Do not subject cells or batteries to mechanical shock.
f) In the event of a cell leaking, do not allow the liquid to come in contact with the skin or eyes. If
contact has been made, wash the affected area with copious amounts of water and seek medical
advice.
g) Do not use any charger other than that specifically provided for use with the equipment.
h) Observe the plus (+) and minus (–) marks on the cell, battery and equipment and ensure correct
use.
i) Do not use any cell or battery which is not designed for use with the equipment.
j) Do not mix cells of different manufacturer, capacity, size or type within a device.
k) Battery usage by children should be supervised.
l) Seek medical advice immediately if a cell or a battery has been swallowed.
m) Always purchase the battery recommended by the device manufacturer for the equipment.
n) Keep cells and batteries clean and dry.
o) Wipe the cell or battery terminals with a clean dry cloth if they become dirty.
p) Secondary cells and batteries need to be charged before use. Always use the correct charger an d
refer to the manufacturer’s instructions or equipment manual for proper cha rging instructions.
q) Do not leave a battery on prolonged charge when not in use.
r) After extended periods of storage, it may be necessary to charge and discharge the cells or
batteries several times to obtain maximum performance.
s) Retain the original product literature for future reference.
t) Use only the cell or battery in the application for which it was intended.
u) When possible, remove the battery from the equipment when not in use.
v) Dispose of properly.
Details of the supplier of the safety data sheet:
Supplier Name: Shenzhen Lumin Technology Co., Ltd
Address: Room D906, Tianhui Building, Yousong Road, Longhua Didstrict, Shenzhen, 518100
Telephone number of the supplier: 0086-0755-23769382
Emergency Telephone No.(24h): 0086-0755-23769382
Fax: 0086-0755-23769382
Report No.:STR17119191S Page 2 of 10
Postcode: 518000
E-mail address: sunny@liuminltd.com
Emergency telephone number
Company Emergency Phone Number: 0086-0755-23769382
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet
2. HAZARDS IDENTIFICATION
Classification
No harm at the normal use. If contact the Electrolyte liquid in the Li-ion battery, reference as follows:
Classification of the substance or mixture
Classification according to GHS
Acute Toxicity, Oral(Hazard category 4)
Acute Toxicity, Dermal(Hazard category 3)
Skin, irritate(Cagegory 1B)
Eye Irritate (Hazard category 1)
GHS Label elements, including precautionary statements:
GHS02 GHS05 GHS06
Signal word: Warning
Hazard statement(s):
H242:Heating may cause a fire;
H311: Toxic in contact with skin;
H314:Causes severe skin burns and eye damage;
H302:Harmful if swallowed;
precautionary statements:
Prevention:
P264 Wash thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response:
P312:Call a Poison center or doctor/physician if you feel unwell.
P302+P350-IF ON SKIN: Gently wash with plenty of soap and water
P301+P330+P331-IF SWALLOWED: rise mouth. Do NOT induce vomiting
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
Storage:
None
Disposal
P501: Dispose of contents/container in accordance with local/national regulations
Hazards not otherwise classified (HNOC)
Not Applicable
Other information
Report No.:STR17119191S Page 3 of 10
No information available.
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterixation: Mixtures
Description:
Product: Consisting of the following components.
Common Chemical Name
Lithium Cobalt Oxide (LiCoO2) 25~50 12190-79-3 235-362-0
Aluminum Foil (Al) 5~15 7429-90-5 231-072-3
Poly Vnylidene Fluoride PVDF(-[-CH2-CF2-]-n) 0~5 24937-79-9 ---Aluminum 2~10 7429-90-5 231-072-3
Polyethylene 5~15 9002-88-4 200-815-3
Concentration
(%)
CAS
Number
EC No.
Polypropylene 2~3 9003-07-0 ---Carbon 10~30 7440-44-0 231-153-3
Organic Solution 10~20 N/A ---Nickel 0.5~5 7440-02-0 231-111-4
Note: CAS number is Chemical Abstract Service Registry Number.
N/A=Not apply.
4. FIRST-AID MEASURES
First aid measures
Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call
a physician.
Skin Contact Remove contaminated clothing and shoes. Wash skin with soap and water. In the
case of skin irritation or allergic reactions see a physician.
Inhalation Move to fresh air. If symptoms persist, call a physician.
Ingestion Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.
Most important symptoms and effects, both acute and delayed
Swallowing Do not induce vomiting. Get medical attention.
Most Important Symptoms/Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically
No information available.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Report No.:STR17119191S Page 4 of 10
CO2, dry chemical powder, water spray.
Unsuitable Extinguishing Media:No information available.
Specific Hazards Arising from the Chemical
Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Carbon monoxide(CO)
Carbon dioxide
Other irritating and toxic gases.
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact No
Sensitivity to Static Discharge No
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved
or equivalent) and full protective gear. For example: Wear self-contained respiratory protective
device. Wear suitable protective clothing and eye/face protection.
Special hazards arising from the substance or mixture:
Battery may burst and release hazardus decomposition products when exposed to a fire situation.
Lithium ion batteries contain flammable electrolyte that may vent, ignite and produce sparks when
subjected to high temperature(>150℃), When damaged or abused(e.g. mechanical dam age or
electrical overcharging); may burn rapidly with flare-burning effect; may ignite other batteries in
clothes proximity.
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Avoid contact with eyes.
Refer to section 8 for personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.
Evacuate personnel to safe areas.
Environmental precautions
Environmental Precautions Refer to protective measures listed in Sections 7 and 8.
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Cleaning up Use personal protective equipment. Dam up. Cover liquid spill with
sand, earth or other Non combustible absorbent material. Pick up and transfer to properly labeled
containers. Clean contaminated surface thoroughly.
7. HANDLING AND STORAGE
Precautions for safe handling
Report No.:STR17119191S Page 5 of 10
Handling Handle in accordance with good industri al hygiene and safety practice. Avoid contact with
skin, eyes and clothing. Wear personal protective equipment.
Wash thoroughly after handling. Use this material with adequate ventilation.
The product is not explosive.
Conditions for safe storage, including any incompatibilities
If the Li-ion battery is subject to storage for such a long term as more than 3 months, it is
recommended to recharge the Li-ion battery periodically.
3 months: -10℃~+40℃, 45 to 85%RH
And recommended at 0℃~+35℃ for long period storage.
The capacity recovery rate in the delivery state (50% capacity of fully charged) after storage is
assumed to be 80% or more.
The voltage for a long time storage shall be 3.0V~4.2V range.
Do not storage Li-ion battery haphazardly in a box or drawer where they may short-circuit each other
or be short-circuited by other metal objects.
Keep out of reach of children.
Do not expose Li-ion battery to heat or fire. Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic materials.
Keep ignition sources away- Do not smoke.
Store in cool, dry and well-ventilated place.
Incompatible Products
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
None known.
Material Safety Data Sheet
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION
Control parameters
Ingredients with limit values that require monitoring at the workplace:
12190-79-3 Lithium Cobalt Oxide
TLV (USA) 0.02mg/m3
MAK (Germany) 0.1mg/m3
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in
AFL-CIO v. OSHA, 965 F.2d 962(11th Cir., 1992).
Appropriate engineering controls
Engineering Measures Showers
Eyewash stations
Ventilation systems
Use adequate general or local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Ensure adequate ventilation.
Individual protection measures, such as personal protective equipment
Eye/Face Protection:
Tightly sealed goggles
Body protection:
Protective work clothing.
Report No.:STR17119191S Page 6 of 10
Skin protection:
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet
Protective gloves
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
Penetration time of glove material:
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
Respiratory Protection No protective equipment is needed under normal use conditions. If
exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be
required.
Hygiene Measures Handle in accordance with good in dustrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: Cylindrical
Physical
State
Change in condition:
pH, with indication of the concentration Not determined.
Melting point/freezing point Not determined.
Initial boiling point and Boiling range: Not determined.
Flash Point Not determined.
Evaporation rate Not determined.
Flammability (solid, gas) Not determined.
Upper/lower flammability or explosive limits Not determined.
Vapor Pressure:
Vapor Density:
Color: Silver
Odour: Odourless
Odor Threshold: No information available
Not determined.
Not determined.
relative density: Not determined.
Solubility in Water: Not determined.
Solubility in other solvents Not determined.
n-octanol/water partition coefficient Not determined.
Auto-ignition temperature Product is not self-igniting.
Report No.:STR17119191S Page 7 of 10
Decomposition temperature Not determined.
Odout threshold Not determined.
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet
Evaporation rate
Viscosity Not determined.
Other Information No further relevant information available.
Not determined.
10. STABILITY AND REACTIVITY
Reactivity: Stable under recommended storage and handling conditions (see section 7, Handling
and storage).
Chemical stability:
Thermal decomposition/conditions to be avoided: No decomposition if used according to
specifications.
Possibility of Hazardous Reactions:
Hazardous Polymerization:
Conditions to avoid:
Incompatible materials:
Hazardous Decomposition Products:
Stable under normal conditions of use, storage and transport.
None under normal processing.
Hazardous polymerization does not occur.
Strong heating, fire, Incompatible materials.
Strong oxidizing agents. Strong acids.Base metals.
Carbon oxides, Other irritating and toxic gases.
11. TOXICOLOGICAL INFORMATION
Acute toxiciy: No data available.
LD/LC50 values relevant for classification:
Not available.
Skin corrosion/irritation: No irritant effect.
Serious eye damage/irritation: Cause serious eye irritation.
Respiratory or skin sensitization: No sensitizing effects known.
Specific target organ system toxicity: No information available.
CMR effects(carcinogenity, mutagenicity and toxicity for reproduction): No information
available.
12. Ecological Information
Toxicity:
Acquatic toxicity:
No further relevant information available.
Persistence and degradability: No further relevant information available.
Bioaccumulative potential:
Mobility in soil:
Results of PBT and vPvB assessment
Report No.:STR17119191S Page 8 of 10
No further relevant information available.
No further relevant information available.
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects:
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
No information available.
Material Safety Data Sheet
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation: Must not be disposed together with household garbage.
Do not allow product to reach sewage system
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
14. TRANSPORT INFORMATION
The Li-ion battery had been tested according to the requirements of the UN manual of tests and
Criteria, Part III, subsection 38.3;
The Li-ion battery with a Watt-hour rating not exceeding 100Wh or the cell with a Watt-hour rating in
not exceeding of 20Wh, The lithium ion batteries according to Section II/Section IB of PACKING
INSTRUCTION 965, or of PACKING INSTRUCTION 966～967 of the 2018 Dangerous Goods
regulations 59th Edition may be transported.
The packaging shall be adequate to avoid mechanical damage during tran sport, handling and
stacking. The materials and pack design shall be chosen so as to prevent the development of
unintentional electrical conduction, corrosion of the terminals and ingress of moisture.
According to the Packing Instruction of IATA DGR 59th Edition for transportation.
Meets requirements of International Maritime Dangerous Goods(IMDG)-2016 Special Provision 188
to be transported as non-dangerous goods;
Meets the requirements of 49CFR173.185 to be transported as non-dangerous goods for road, rail,
air, and vessel.
Meets the requirements of TDG special provision 34 to be transported as non-dangerous goods.
The package must be handled with care and that a flammability hazard exists if the package is
damaged;
UN number of lithium battery: UN3480 or UN3481;
UN Proper shipping name/Description (technical name): Lithium ion batteries or Lithium ion batteries
contained in equipment or Lithium ion batteries packed with equipment;
UN Classification (Transport hazard class): Non dangerous;
15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation:
Authorisations: No information available.
Restrictions on use: No information available.
Regulatory information
Report No.:STR17119191S Page 9 of 10
Shenzhen SEM.Test Technology Co., Ltd.
1/F, Building A, Hongwei Industrial Park, Liuxian 2nd
Road, Bao'an District, Shenzhen, P.R.C. (518101)
Material Safety Data Sheet
CAS No. EU
(EINECS)
12190-79-3 Listed Not listed Not listed NDSL Not listed Not listed Not listed
7429-90-5 Listed Listed Listed DSL Listed Listed Listed
24937-79-9 Listed Listed Listed DSL Listed Listed Listed
7429-90-5 Not listed Listed Not listed DSL Listed Listed Listed
9002-88-4 Not listed Listed Not listed DSL Listed Listed Listed
9003-07-0 Listed Listed Listed DSL Listed Listed Listed
7440-44-0 Listed Not listed Not listed Not listed Not listed Not listed Listed
7440-02-0 Listed Listed Listed DSL Listed Listed Listed
Chemical safety assessment A Chemical Safety Assessment has not been carried out.
US
(TSCA)
Japan
(ENCS)
Canada
(DSL/
NDSL)
Austrlia
(AICS)
Korea
(ECL)
China
(IECSC)
16. OTHER INFORMATION
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
Relevant phrases:
R20/22: Harmful by inhalation and if swallowed.
R36: Irritating to eyes.
H302: Harmful if swallowed.
H332: Harmful if inhaled.
******************End of MSDS******************
Report No.:STR17119191S Page 10 of 10
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