Material Sa f ety Data Sheet (MSDS) Report MSDS Number: SDS201912172578
Applicant: Shanghai Xinleina Baby Cars Accessories Co., Ltd.
No. 1090-1, Liu Qiao Village, Lv Xiang Tow n, Jinshan District, Shanghai, 201517, China.
Sample Description:
Product Name : Valve Regulated Sealed Lead-Acid Rechargeable Battery
Data Reviewed : Jul 15, 2020
Shanghai Ruifu Co., Ltd. did not test, certify, or approve the product described in this Material Safety Data Sheet
(MSDS), and all information in this MSDS was provided by the supplier or was reproduced from publically available
regulatory data sources. Shanghai Ruifu Co., Ltd. makes no representations or warranties regarding the
completeness or accuracy of the information in this MSDS and disclaims all liability in connection with the use of this
information or the product described in this MSDS. This MSDS was generated in accordance with requirements of
China GB standards(GB/T 16483-2008 & GB30000-2013), for more details please refer to the following attached
pages.
This report shall not be reproduced except in full, without the written approval of Shanghai Ruifu Co., Ltd.
Shanghai Ruifu Co.,Ltd.
Rm 22106, BLDG #1, NO.888 Huanhu Xi’Er Road, Pudong Dis trict, Shanghai, 201306, China
Tel: +86 21 67795598 E-mail: MSDS@vip.163.com Website: www.msds-china.com
Approved By:
Pingo Zhang, Manager
On behalf of Shanghai Ruifu Co., Ltd.
MATERIAL SAFETY DATA SHEET
Page: 1
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Product Name
:
Valve Regulated Sealed Lead-Acid Rechargeable Battery
Battery Model
:
2-FM-4 3-FM-4 3-FM-4.5 3-FM-5 3-FM-7 3-FM-10 6-FM-7
42 12-FM-5 12-FM-7 12-FM-10 12-FM-12
Identified use
:
Electronic scale, toy buggy power supply, light ing
Details of the supplier of the safe ty data
Emergency telephone number
Corrosive to Metals
:
Category 1
Skin corrosion
:
Category 1
Serious eye damage
:
Category 1
Reproductive toxicity
:
Category 1A
Specific target organ
:
Category 1 (Central nervous system, Kidney, Blood)
Specific target organ
exposure (Inhalation)
:
Category 1 (Central nervous system, Kidney, Blood)
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
6-FM-10 6-QA-4 6-FM-4 6-FM-4.5 6-FM-12 6-FM-14 6FM-15 6-FM-20 6-FM-24 6-DZM-12 6-DZM-20 6-DZM-
Recommended use of the chemical and restrictions on use
sheet
Shanghai Xinleina Baby Cars Accessories Co.,
Ltd.
No. 1090-1, Liu Qiao Village, Lv Xiang Town,
Jinshan District, Shangha i, 201517,
China.
SECTION
2. HAZARDS IDENTIFICATION
The following information is provided for the scenario that exposure occurred during battery
production or container breakage or under extreme heat conditions such as fire, however, under
normal conditions of battery use, internal ingredients/compone nts will not present any physical, health
and environmental hazard.
The following GHS hazardous classification are derived based on the internal ingredients under
extreme exposure scenarios, such as breakage, leakage or being abused.
GHS-Classification- China standards(GB30000-2013)
Tel: +86-21-57375252, contact your local
emergency telephone number
Product Information
Tel: +86-21-57375252
E-mail: 574230353@qq.com
systemic toxicity - repeated
exposure (Oral)
systemic toxicity - repeated
GHS-Labelling- China standards(GB30000-2013)
1 / 11
MATERIAL SAFETY DATA SHEET
Page: 2
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Hazard pictograms
:
Signal Word
:
Danger
Hazard Statements
:
May be corrosive to metals.
Precautionary Statements
:
Prevention:
Causes severe skin burns and eye damage.
Causes serious eye damage.
May damage fertility or the unborn child.
Causes damage to organs (Central nervous system, Kidney,
Blood) through prolonged or repeated exposure if swallowed.
Causes damage to organs (Central nervous system, Kidney,
Blood) through prolonged or repeated exposure if inhaled.
Obtain special instructions befor e us e.
Do not handle until all safety precautions have been read and
understood.
Keep only in original container.
Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response:
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER or doctor/
physician.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON C ENT ER or doc to r/
physician.
IF exposed or concerned: Get medical advice/ attention.
Wash contaminated clothing before reuse.
Absorb spillage to prevent material damage.
Storage:
Store locked up.
Store in corrosive resistant stainless steel container with a
resistant inner liner.
Disposal:
Dispose of contents/ container to an approved waste disposal
plant.
Other hazards
No further available information.
2 / 11
MATERIAL SAFETY DATA SHEET
Page: 3
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Product type
:
Manufactured article/solid
Chemical Name
CAS-No.
Classification
Concentration (%)
Lead
7439-92-1
Repr. 1A; H360
30-43
Lead dioxide
1309-60-0
Acute Tox. 4; H302/H332
15-22
Sulfuric acid
7664-93-9
Met. Corr. 1; H290
10-15
ABS resin
9003-56-9
Not classified
5-9
Tin
7440-31-5
Not classified
3-4
Manganese powder
7439-96-5
Not classified
2-3
Calcium
7440-70-2
Not classified
1-2
General advice
:
Move out of dangerous area.
If inhaled
:
Move to fresh air.
In case of skin contact
:
If on skin, rinse well with water.
In case of eye contact
:
In the case of contact with eyes, rinse immediately with plenty
If swallowed
:
Get medical attention immediately.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components
STOT RE 1; H372
Repr. 1A; H360
STOT RE 2; H373
Aquatic Acute 1; H400/H410
Skin Corr. 1; H314
Eye Dam. 1; H318
SECTION
4. FIRST AID MEASURES
Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If breathed in, move person into fresh air.
If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
Wash contaminated clothing before re-use.
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
3 / 11
MATERIAL SAFETY DATA SHEET
Page: 4
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Do NOT induce vomiting.
Most important symptoms
:
Causes serious eye damage.
Notes to physician
:
No hazards which require special first aid measures.
Suitable extinguishing media
:
Use extinguishing measures that are appropriate to local
Unsuitable extinguishing
media
:
High volume water jet.
Specific hazards during
:
Highly flammable hydrogen gas is generated during charging
Hazardous combustion
:
Toxic fumes, corrosive vapors and sulfur oxides.
Specific extinguishing
methods
:
Product is compatible with standard fire -fighting agents.
Further information
:
Fire residues and contaminated fire extinguishing water must
Special protective equipment
for firefighters
:
In the event of fire, wear self-contained breathing apparatus.
Personal precautions,
:
Stop flow of material, contain/absorb small spills with dry
Rinse mouth with water.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
and effects, both acute and
delayed
SECTION
firefighting
products
5. FIREFIGHTING MEASURES
May damage fertility or the unborn child.
Causes damage to organs through prolonged or repeated
exposure if swallowed or inhaled.
Causes severe burns.
circumstances and the surrounding environment.
Foam/Carbon dioxide (CO2)/Dry chemical
and operation of batteries.
To avoid risk of fire or explosion, keep sparks or other sources
of ignition away from batteries.
Do not allow metallic materials to simultaneously contact
negative and positive terminals of cells and batteries.
be disposed of in accordance with local regulations.
SECTION 6. ACCIDENTAL RELEASE MEASURES
protective equipment and
emergency procedures
sand, earth, and vermiculite.
Do not use combustible materials.
If possible, carefully neutralize spilled electrolyte with soda
ash, sodium bicarbonate, lime, etc.
Wear acid-resistant clothing, boots, gloves, and face shield.
Do not allow discharge of unneutralized acid to sewer.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
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MATERIAL SAFETY DATA SHEET
Page: 5
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Environmental precautions
:
Prevent product from entering drains.
Methods and materials for
:
If possible, carefully neutralize spilled electrolyte with soda
Other information
:
Comply with all applicable federal, state, and local regulations.
Advice on safe handling
:
Do not drop battery, puncture, or attempt to open battery
Conditions for safe storage
:
Store batteries under roof in cool, dry, well-ventilated areas
Engineering measures
:
Store sealed lead acid batteries at ambient temperature.
Avoid conditions that could cause arcing between terminals.
Respiratory protection
:
None required for normal handling of the finished poroduct.
Hand protection
:
None required for normal handling of the finished poroduct.
Eye protection
:
None required for normal handling of the finished poroduct.
If necessary to handle damage product where exposure to the
containment and cleaning up
SECTION 7. HANDLING AND STORAGE
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
ash, sodium bicarbonate, lime, etc.
case.
Avoid contact with the internal components of a battery.
Do not subject product to open flame or fire and avoid
situations that could cause arcing between terminals.
Do not smoke.
Keep away from combustible materials, organic chemicals,
reducing substances, metals, strong oxidizers.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
SECTION 8. EXPOSURE CONTROLS/PER SONAL PROTECTION
Components with workplace control parameters
Airborne exposures to hazardous substances are not expected when the cells or batteries are used
for their intended purposes.
Exposure standards are not applicable to the sealed articles.
Personal protective equipment
separated from incompatible materials and from activities that
may create flames, spark, or heat.
Observe label precautions.
Never recharge batteries in an unventilated, enclosed space.
Do not subject product to open flame or fire.
When concentrations of sulfuric acid mist are known to
exceed PEL, use approved respiratory protection.
5 / 11
MATERIAL SAFETY DATA SHEET
Page: 6
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
organic electrolyte is a possibility, chemical splash goggles
Skin and body protection
:
None required for normal handling of the finished poroduct.
Hygiene measures
:
Wash hands before breaks and at the end of workday.
When using do not smoke.
Physical state
:
Manufactured article
Color
:
Black
Odor
:
No odor/odorless(product)
Odor Threshold
:
No data available
pH :
No data available
Melting point/freezing point
:
327.4 ℃(lead)
Boiling point/boiling range
:
1740℃ (lead)
Flash point
:
No data available
Evaporation rate
:
No data available
Flammability (solid, gas)
:
Non-flammable under normal use conditions
Upper explosion limit
:
Non-explosive
Lower explosion limit
:
Non-explosive
Vapour pressure
:
No data available
Relative vapour density
:
No data available
Relative density
:
No data available
Density
:
11.35 g/cm³(lead)
Water solubility
:
0.15mg/l (lead)
and a face shield are recommended.
If battery case is damaged, use rubber or plastic acid-resistant
gloves with elbow-length gauntlet, acid-resist ant apr o n,
clothing and boots.
When using do not eat or drink.
Ensure that eyewash stations and safety showers are close to
the workstation location.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Sharp, penetrating, pungent odor(electrolyte)
6 / 11
MATERIAL SAFETY DATA SHEET
Page: 7
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Solubility in other solvents
:
No data available
Partition coefficient: noctanol/water
:
No data available
Thermal decomposition
:
No data available
Viscosity, dynamic
:
No data available
Viscosity, kinematic
:
No data available
Oxidizing properties
:
Not an oxidizer
Reactivity
:
No decomposition if stored and appli ed as direct e d.
Chemical stability
:
Stable under recommended storage conditions.
Possibility of hazardous
reactions
:
Product will not undergo hazardous poly mer iz ati on.
Incompatible materials
:
Contact with combustibles and organic materials may cause
Hazardous decompositio n
Electrolyte: Sulfur trioxide, carbon monoxide, sulfuric acid
sulphur oxides, toxic fumes.
Acute oral toxicity
:
LD L0 (Human): 155 mg/kg
Acute inhalation toxicity
:
LC Lo (Human): 271 mg/m 3
Acute oral toxicity
:
LD 50 (Rat): 2,140 mg/kg
Result: Repeated exposure may cause skin dryness or cracking.
Remarks: Causes severe skin burns and eye damage.
SECTION 10. STABILITY AND REACTIVITY
products
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Not classified based on available information.
LEAD:
SULFURIC ACID:
The sealed battery is considered stable.
fire and explosion.
Reacts violently with strong reducing agents, metals, sulfur
trioxide gas, strong oxidizers, and water.
mist, sulfur dioxide, hydrogen sulfide, corrosive vapors,
Skin corrosion/irritation
Causes severe burns.
LEAD:
7 / 11
MATERIAL SAFETY DATA SHEET
Page: 8
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Result: Not irritating to skin
Result: Corrosive to skin
Remarks: May cause irreversible eye damage.
Result: Slightly irritating to eyes
Result: Corrosive to eyes
Reproductive toxicity -
:
Positive evidence of adverse effects on sexual function and
Exposure routes: Ingestion
Exposure routes: Inhalation
SULFURIC ACID:
Serious eye damage/eye irritation
Causes serious eye damage.
LEAD:
SULFURIC ACID:
Respiratory or skin sensitisation
Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
May damage fertility or the unborn child.
LEAD:
Assessment
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Causes damage to organs (Central nervous system, Kidney, Blood) through prolonged or repeated
exposure if swallowed.
LEAD:
Target Organs: Central nervous system, Kidney, Blood
Assessment: Causes damage to organs through prolonged or repeated exposure.
Target Organs: Central nervous system, Kidney, Blood
Assessment: Causes damage to organs through prolonged or repeated exposure.
Aspiration toxicity
Not classified based on available information.
fertility from human epidemiological studies.
Positive evidence of adverse effects on development from
human epidemiological studies.
8 / 11
MATERIAL SAFETY DATA SHEET
Page: 9
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
M-Factor (Acute aquatic
toxicity)
:
10
Acute aquatic toxicity
:
Very toxic to aquatic life.
Chronic aquatic toxicity
:
Very toxic to aquatic life with long lasting effects.
Toxicity to fish
:
LC 50 (Lepomis macrochirus (Bluegill sunfish)): > 28 mg/l
LC 50 (Lepomis macrochirus (Bluegill sunfish)): 16 - 28 mg/l
Toxicity to daphnia and other
:
EC 50 (Daphnia magna (Water flea)): > 100 mg/l
Toxicity to algae
:
EC50 (Desmodesmus subspicatus (green algae)): > 100 mg/l
General advice
:
Lead-acid batteries are completely recyclable.
federal regulations.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
LEAD:
Ecotoxicology Assessment
SULFURIC ACID:
Exposure time: 96 h
Method: Static
Remarks: Mortality
Exposure time: 96 h
Method: Static
Remarks: Mortality
aquatic invertebrates
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Exposure time: 48 h
Method: Static
Exposure time: 72 h
Dispose of in accordance with all applicable local, state and
SECTION 14. TRANSPORT INFORMATION
International transport regulations
9 / 11
MATERIAL SAFETY DATA SHEET
Page: 10
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
LAND TRANSPORT (China road, JT/T 617-2018)
UN Number: UN2800
Proper Shipping Name: BATTERIES, WET, NONSPILLABLE,electric storage
Hazard classes: 8
Packaging group: Not applicable
SEA TRANSPORT/INTERNATIONAL MARITIME DANGEROUS GOODS(IMDG, 39-18)
UN Number: UN2800
Proper Shipping Name: BATTERIES, WET, NONSPILLABLE,electric storage
Hazard classes: 8
Packaging group: Not applicable
Special provision: 29, 238
LQ: 1L
EQ: E0
EmS No.: F-A,S-B
Marine pollutant: No
AIR TRANSPORT/INTERNATIONAL AIR TRANSPORT ASSOCIATION(IATA DGR, 61th edition)
UN Number: UN2800
Proper Shipping Name: BATTERIES, WET, NONSPILLABLE,electric storage
Hazard classes: 8
Packaging group: Not applicable
Packaging group: Not applicable
EQ: E0
Packing code(passenger): 872
Packing code(cargo): 872
Special provision: A48、A67、A164、A183
ERG code: 8L
10 / 11
MATERIAL SAFETY DATA SHEET
Page: 11
Revision Date: 15/07/2020
SDS Number: SDS201912172578
Valve Regulated Sealed Lead-Acid Rechargeable
Battery
Version: 1.3
Regulations on the Control over Safety of Dangerous Chemicals (Decree No. 591 of the State
Classification and code of dangerous goods （GB6944-2005）
This battery is not subject to DG regulations and is not a dangerous goods.
AIR TRANSPORT - IATA/ICAO(2019-2020 Edition of the ICAO Technical Instruction for the Safe
Transport of Dangerous Goods by Air (Technical Instructions) and the 61th Edition of the IATA
Dangerous Goods Regulations (DGR)):
This valve regulated lead-acid battery is exempt from DG regulation and classif ied as “non-spillable
battery”, so this battery is not subject to DG regulations, since it meets the requirement of packing
instructions 872 of special provision A67.
This valve regulated lead-acid battery is securely packaged, protected from short circuits and labeled
“non-spillable”, they are good for transportation on either passenger or cargo aircraft.
MARINE TRANSPORT – IMDG(IMDG Code 201 8(39-18)):
This valve regulated lead-acid battery is non-spillable battery and meet the requirements of special
provision 238, so it is not subject to the provision of IMDG code.
SECTION 15. REGULATORY INFORMATION
Council of the People's Republic of China)
General rules for preparation of chemical safety data sheet （GB16483-2008）
Rules for classification and labelling of chemicals(GB30000-2013)
Classification and labels of dangerous chemical substances commonly used （GB13690-2009）
List of dangerous goods GB12268-2012
SECTION 16. OTHER INFORMATION
Further information
Revision Date: 15/07/2020
Disclaimer:
This SDS is intended to provide a brief summary of our knowledge and guidance regarding the use of
this material. The information contained here has been compiled from sources considered by us to be
dependable and is accurate to the best of our knowledge. It is not meant to be an all-inclusive
document on worldwide hazard communication regulations.
This information is offered in good faith. Each user of this material needs to evaluate the
conditions of use and design the appropriate protective mechanisms to prevent employee
exposures, property damage or release to the environment. We assumed no responsibility for
injury to the recipient or third persons, or for any damage to any property resulting from misuse of
the product.
**End of Material Safety Data Sheet***
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