Static Solutions FS-3500 User Manual

Safety Data Sheet
Issue Date: 22-Jul-1996
Revision Date: 03-Apr-2015 Version 2
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Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1. Product Identifier
SDS #
DYNI-008-EU
Product Name
FS-3500
1.2. Relevant Identified Uses of the Substance or Mixture and Uses Advised Against
Recommended Use
Floor stripper
1.3. Details of the Supplier of the Safety Data Sheet
Supplier
Static Solutions, Inc. 43 Broad Street Hudson, MA 01749
For further information, please contact
Contact Point
Static Solutions, Inc.
Email Address
contactus@staticsolutions.com
1.4. Emergency telephone number
Emergency Telephone (24 hr)
INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America)
Section 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Regulation (EC) No 1272/2008
Skin corrosion/irritation
Category 1 Sub-category C
Serious eye damage/eye irritation
Category 1
Classification according to 67/548/EEC
Full text of R-phrases: see section 16
Hazard Symbols
Xi - Irritant
R-code(s)
Xi;R36/38
2.2. Label Elements
Labeling according to Regulation (EC) No. 1272/2008 [CLP].
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Signal Word
Danger
Hazard Statements
H314 - Causes severe skin burns and eye damage
Precautionary Statements - EU (§28, 1272/2008)
P280 - Wear protective gloves/protective clothing/eye protection/face protection P260 - Do not breathe dust/fume/gas/mist/vapors/spray P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P280 - Wear eye protection/ face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician
2.3. Other Hazards
General Hazards
None known
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
Chemical Name
EC No
CAS No
Weight-%
Classification
according to
67/548/EEC
Classification
according to
Regulation (EC) No.
1272/2008 [CLP]
REACH Registration
Number
Monoethanolamine
Present
141-43-5
<5
Xn; R20/21/22
C; R34
Acute Tox. 4 (H302) Acute Tox. 4 (H312) Acute Tox. 4 (H332)
Skin Corr. 1B (H314)
Not determined
Ethylene Glycol
Monobutyl Ether
Present
111-76-2
<5
Xn; R20/21/22
Xi; R36/38
Acute Tox. 4 (H302) Acute Tox. 4 (H312) Acute Tox. 4 (H332)
Skin Irrit. 2 (H315)
Eye Irrit. 2 (H319)
Not determined
Sodium metasilicate
Present
6834-92-0
<5
C; R34
Xi; R37
Skin Corr. 1B (H314)
STOT SE 3 (H335)
Not determined
Alcohols, C9-11
ethoxylated
-
68439-46-3
<2
Xi;R41
(self-classification)
Not determined
Not determined
Full text of R-phrases: see section 16
Full text of H- and EUH-phrases: see section 16
Section 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
General Advice
Provide this SDS to medical personnel for treatment.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediately call a poison center or doctor/physician.
Skin Contact
Wash off immediately with plenty of water. If skin irritation persists, call a physician.
Inhalation
Remove to fresh air. Call a physician or poison control center immediately.
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Ingestion
Do not induce vomiting. Drink promptly a large quantity of milk, egg whites, gelatin solution; or if they are not available, drink large quantities of water. Immediately call a poison center or doctor/physician.
4.2. Most Important Symptoms and Effects, Both Acute and Delayed
Symptoms
Causes severe skin burns and eye damage. Ingestion may cause severe burns to mouth, throat or stomach.
4.3. Indication of any Immediate Medical Attention and Special Treatment Needed
Notes to Physician
Treat symptomatically.
Section 5: FIRE-FIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media
Water spray (fog). Carbon dioxide (CO2). Dry chemical. Foam.
Unsuitable Extinguishing Media
Not determined.
5.2. Special Hazards Arising from the Substance or Mixture
Material is corrosive.
Hazardous Combustion Products
Under fire conditions, toxic and irritating fumes may be emitted. Carbon oxides.
5.3. Advice for Firefighters
Wear self-contained breathing apparatus and protective suit. Use personal protective equipment as required.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
Personal Precautions
Use personal protective equipment as required.
For Emergency Responders
Use personal protection recommended in Section 8.
6.2. Environmental Precautions
Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS.
6.3. Methods and Material for Containment and Cleaning Up
Methods for Containment
Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up
Mop up or otherwise absorb with an inert material and place in an appropriate waste disposal container for disposal. Clean up in accordance with all applicable regulations.
6.4. Reference to Other Sections
See Section 13: DISPOSAL CONSIDERATIONS.
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Section 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Advice on Safe Handling
Handle in accordance with good industrial hygiene and safety practice. Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Do not breathe vapors or spray mist. Wash face, hands, and any exposed skin thoroughly after handling. Wash contaminated clothing before reuse.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling.
7.2. Conditions for Safe Storage, Including any Incompatibilities
Storage Conditions
Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep locked up and out of reach of children.
7.3. Specific End Use(s)
Specific Use(s)
Floor stripper.
Risk Management Methods (RMM)
The information required is contained in this Safety Data Sheet.
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
Exposure Limits
.
Chemical Name
European Union
United Kingdom
France
Spain
Germany
Monoethanolamine
141-43-5
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
STEL: 3 ppm
STEL: 7.6 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
S*
STEL: 3 ppm
STEL: 7.5 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
TWA: 2 ppm
TWA: 5.1 mg/m3
Ceiling / Peak: 4 ppm
Ceiling / Peak: 10.2
mg/m3
Ethylene Glycol Monobutyl
Ether
111-76-2
S*
TWA 20 ppm
TWA 98 mg/m3
STEL 50 ppm
STEL 246 mg/m3
STEL: 50 ppm
STEL: 246 mg/m3
TWA: 25 ppm
TWA: 123 mg/m3
Skin
TWA: 10 ppm
TWA: 49 mg/m3
STEL: 50 ppm
STEL: 246 mg/m3
S*
STEL: 50 ppm
STEL: 245 mg/m3
TWA: 20 ppm
TWA: 98 mg/m3
TWA: 10 ppm
TWA: 49 mg/m3
Ceiling / Peak: 20 ppm
Ceiling / Peak: 98
mg/m3
Skin
Component
Italy
Portugal
Netherlands
Finland
Denmark
Monoethanolamine
141-43-5 ( <5 )
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
Skin
STEL: 3 ppm
STEL: 7.6 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
STEL: 7.6 mg/m3
TWA: 2.5 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
Skin
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
Ethylene Glycol Monobutyl
Ether
111-76-2 ( <5 )
TWA: 20 ppm
TWA: 98 mg/m3
STEL: 50 ppm
STEL: 246 mg/m3
Skin
STEL: 50 ppm
STEL: 246 mg/m3
TWA: 20 ppm
TWA: 98 mg/m3
Skin
STEL: 246 mg/m3
TWA: 100 mg/m3
TWA: 20 ppm
TWA: 98 mg/m3
STEL: 50 ppm
STEL: 250 mg/m3
Skin
TWA: 20 ppm
TWA: 98 mg/m3
Skin
Chemical Name
Austria
Switzerland
Poland
Norway
Ireland
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Monoethanolamine
141-43-5
Skin
STEL 3 ppm
STEL 7.6 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 4 ppm
STEL: 10 mg/m3
TWA: 2 ppm
TWA: 5 mg/m3
STEL: 7.5 mg/m3
TWA: 2.5 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
Skin
STEL: 3 ppm
STEL: 5 mg/m3
TWA: 1 ppm
TWA: 2.5 mg/m3
STEL: 3 ppm
STEL: 7.6 mg/m3
Skin
Ethylene Glycol Monobutyl
Ether
111-76-2
Skin
STEL 40 ppm
STEL 200 mg/m3
TWA: 20 ppm
TWA: 98 mg/m3
Skin
STEL: 20 ppm
STEL: 98 mg/m3
TWA: 10 ppm
TWA: 49 mg/m3
STEL: 200 mg/m3
TWA: 98 mg/m3
TWA: 10 ppm
TWA: 50 mg/m3
Skin
STEL: 20 ppm
STEL: 75 mg/m3
TWA: 20 ppm
TWA: 98 mg/m3
STEL: 50 ppm
STEL: 246 mg/m3
Skin
8.2. Exposure Controls
Engineering Controls
Apply technical measures to comply with the occupational exposure limits. Ensure adequate ventilation, especially in confined areas. Showers. Eyewash stations.
Personal Protective Equipment
Eye/Face Protection
Recommended for general protection.
Hand Protection
Gloves are recommended.
Skin and Body Protection
Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory Protection
Under normal conditions, respirator is not normally required.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State
Liquid
Appearance
Clear Thin red liquid
Odor
Slight solvent
Color
Clear red
Odor Threshold
Not determined
Property
Values
Remarks • Method
pH
10.9-11.9
Melting Point/Freezing Point
Not determined
Boiling Point/Boiling Range
100 °C / 212 °F
Flash Point
None to boiling
Evaporation Rate
Equal to water
Flammability (Solid, Gas)
Liquid- Not Applicable
Flammability Limits in Air
Upper Flammability Limits
Not determined
Lower Flammability Limit
Not determined
Vapor Pressure
Equal to water
Vapor Density
Equal to water
Relative Density
1.050
Water Solubility
Completely soluble
Solubility(ies)
Not determined
Partition Coefficient
Not determined
Auto-ignition Temperature
Not determined
Decomposition Temperature
Not determined
Kinematic Viscosity
Not determined
Dynamic Viscosity
Not determined
Explosive Properties
Not determined
Oxidizing Properties
Not determined
Section 10: STABILITY AND REACTIVITY
10.1. Reactivity
Not reactive under normal conditions.
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10.2. Chemical stability
Stable.
10.3. Possibility of Hazardous Reactions
Hazardous Polymerization
Hazardous polymerization does not occur.
Possibility of Hazardous Reactions
None under normal processing.
10.4. Conditions to Avoid
See Sec. 7 Handling & Storage.
10.5. Incompatible Materials
Strong acids. Strong oxidizers.
10.6. Hazardous Decomposition Products
Burning produces irritating and toxic fumes. Oxides of carbon.
Section 11: TOXICOLOGICAL INFORMATION
11.1. Information on Toxicological Effects
Acute Toxicity
Product Information
.
Eye Contact
Causes severe eye damage.
Skin Contact
Causes severe skin burns.
Inhalation
Avoid breathing vapors or mists.
Ingestion
Do not ingest.
Unknown Acute Toxicity
0.91% of the mixture consists of ingredient(s) of unknown toxicity.
The following values are calculated based on chapter 3.1 of the GHS document:
Oral LD50
5,918.00
Units
mg/kg
Dermal LD50
13,409.00
Units
mg/kg
Inhalation
Gas
99,999.00
Units
mg/L
Mist
18.50
Units
mg/L
Vapor
2,206.00
Units
mg/L
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Component Information
Chemical Name
Oral LD50
Dermal LD50
Inhalation LC50
Ethylene Glycol Monobutyl Ether
= 470 mg/kg ( Rat )
= 99 mg/kg ( Rabbit )
= 450 ppm ( Rat ) 4 h
Monoethanolamine
= 1720 mg/kg ( Rat )
= 1 mL/kg ( Rabbit ) = 1000 mg/kg
( Rabbit )
Sodium metasilicate
= 600 mg/kg ( Rat )
Alcohols, C9-11 ethoxylated
= 1400 mg/kg ( Rat ) = 1378 mg/kg
( Rat )
> 2 g/kg ( Rabbit )
Tetrasodium EDTA
= 1658 mg/kg ( Rat ) = 10 g/kg (
Rat )
Skin corrosion/irritation
Causes severe skin burns.
Serious eye damage/eye irritation
Causes severe eye damage.
Sensitization
Not classified.
Germ cell mutagenicity
Not classified.
Carcinogenicity
None known based on information supplied.
Reproductive toxicity
Not classified.
STOT - single exposure
Not classified.
STOT - repeated exposure
Not classified.
Aspiration hazard
Not classified.
Symptoms
Please see section 4 of this SDS for symptoms.
Section 12: ECOLOGICAL INFORMATION
12.1. Toxicity
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.
Chemical Name
Algae/aquatic plants
Fish
Crustacea
Monoethanolamine
15: 72 h Desmodesmus subspicatus
mg/L EC50
200: 96 h Oncorhynchus mykiss
mg/L LC50 flow-through 114 - 196:
96 h Oncorhynchus mykiss mg/L
LC50 static 3684: 96 h Brachydanio
rerio mg/L LC50 static 300 - 1000:
96 h Lepomis macrochirus mg/L LC50 static 227: 96 h Pimephales promelas mg/L LC50 flow-through
65: 48 h Daphnia magna mg/L
EC50
Ethylene Glycol Monobutyl Ether
1490: 96 h Lepomis macrochirus
mg/L LC50 static 2950: 96 h
Lepomis macrochirus mg/L LC50
1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia
magna mg/L EC50
Sodium metasilicate
210: 96 h Brachydanio rerio mg/L
LC50 semi-static 210: 96 h
Brachydanio rerio mg/L LC50
216: 96 h Daphnia magna mg/L
EC50
12.2. Persistence and Degradability
Not determined.
12.3. Bioaccumulative Potential
Chemical Name
Partition Coefficient
Monoethanolamine
-1.91
Ethylene Glycol Monobutyl Ether
0.81
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12.4. Mobility in Soil
Mobility
Not determined.
12.5. Results of PBT and vPvB Assessment
Not determined.
12.6. Other Adverse Effects
Not determined.
Section 13: DISPOSAL CONSIDERATIONS
13.1. Waste Treatment Methods
Waste from Residues / Unused Products
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated Packaging
Improper disposal or reuse of this container may be dangerous and illegal.
Section 14: TRANSPORT INFORMATION
IMDG
14.1 UN/ID No
UN1760
14.2 Proper Shipping Name
Corrosive liquids, n.o.s. (Monoethanolamine, Sodium Metasilicate)
14.3 Hazard Class
8
14.4 Packing Group
III
RID
14.1 UN/ID No
UN1760
14.2 Proper Shipping Name
Corrosive liquids, n.o.s. (Monoethanolamine, Sodium Metasilicate)
14.3 Hazard Class
8
14.4 Packing Group
III
ADR
14.1 UN/ID No
UN1760
14.2 Proper Shipping Name
Corrosive liquids, n.o.s. (Monoethanolamine, Sodium Metasilicate)
14.3 Hazard Class
8
14.4 Packing Group
III
ICAO (air)
14.1 UN/ID No
UN1760
14.2 Proper Shipping Name
Corrosive liquids, n.o.s. (Monoethanolamine, Sodium Metasilicate)
14.3 Hazard Class
8
14.4 Packing Group
III
IATA
14.1 UN/ID No
UN1760
14.2 Proper Shipping Name
Corrosive liquids, n.o.s. (Monoethanolamine, Sodium Metasilicate)
14.3 Hazard Class
8
14.4 Packing Group
III
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Section 15: REGULATORY INFORMATION
15.1. Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture
National Regulations
Occupational Illnesses (R-463-3, France)
Chemical Name
French RG number
Title
Monoethanolamine
141-43-5
RG 49,RG 49bis
Ethylene Glycol Monobutyl Ether
111-76-2
RG 84
European Union
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents at work .
International Inventories
TSCA
All components in this product are listed or exempt from listing
EINECS/ELINCS
-
DSL/NDSL
-
PICCS
-
ENCS
-
IECSC
-
AICS
-
KECL
-
Legend
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
PICCS - Philippines Inventory of Chemicals and Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
AICS - Australian Inventory of Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
15.2. Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
Section 16: OTHER INFORMATION
Full text of R-phrases referred to under sections 2 and 3
R34 - Causes burns R37 - Irritating to respiratory system R41 – Risk of serious damage to eyes
R36/38 - Irritating to eyes and skin R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed
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Full text of H-Statements referred to under sections 2 and 3
H302 - Harmful if swallowed H312 - Harmful in contact with skin H332 - Harmful if inhaled H314 - Causes severe skin burns and eye damage H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H370 - Causes damage to organs
Classification Procedure
Calculation method
Issue Date:
22-Jul-1996
Revision Date:
03-Apr-2015
Revision Note:
New format.
This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006, as amended by Regulation (EU) No. 453/2010
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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