Page 1/7
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.04.2019 Revision: 09.04.2019Version number 7
SECTION 1: Identification of the substance/mixture and of the company/undertaking
·
1.1 Product identifier
·
Trade name: Lötwasser Nr.1/V
·
1.2 Relevant identified uses of the substance or mixture and uses advised against
·
Technical function
·
Application of the substance / the mixture
·
1.3 Details of the supplier of the safety data sheet
·
Manufacturer/Supplier:
Stannol GmbH & Co. KG
Haberstrasse 24
D-42551 Velbert
+49 (0) 2051 3120 332
sdb@stannol.de
·
Further information obtainable from:
·
1.4 Emergency telephone number:
soldering
Soldering flux
Product Safety Department
8:00 am - 5:00 pm (CET) +49 (0) 2051 3120 332
SECTION 2: Hazards identification
·
2.1 Classification of the substance or mixture
·
Classification according to Regulation (EC) No 1272/2008
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
STOT SE 3 H335 May cause respiratory irritation.
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
·
2.2 Label elements
·
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
·
Hazard pictograms
d~
GHS05
·
Signal word
·
Hazard-determining components of labelling:
zinc chloride
·
Hazard statements
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H411 Toxic to aquatic life with long lasting effects.
·
Precautionary statements
P102 Keep out of reach of children.
P260 Do not breathe mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
P310 Immediately call a doctor.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
·
2.3 Other hazards
Flux / flux gels:
Inhalation of vapors released during the soldering process should be avoided. Flux vapors irritate the nose, throat, and
respiratory tract, and can lead to allergic reactions (asthma) after prolonged or repeated contact. Therefore, an active
suction is recommended.
d~
GHS07
Danger
d~
GHS09
easy to do. Continue rinsing.
(Contd. on page 2)
GB
49.0.2
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.04.2019 Revision: 09.04.2019Version number 7
Trade name: Lötwasser Nr.1/V
Page 2/7
After working with the product and before eating, drinking or smoking, wash your hands with soap and water.
Keep out of the reach of children.
·
Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
Not applicable.
SECTION 3: Composition/information on ingredients
·
3.2 Mixtures
·
Description:
·
Dangerous components:
CAS: 7646-85-7
EINECS: 231-592-0
Mixture of substances listed below with nonhazardous additions.
zinc chloride
Skin Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4,
H302; STOT SE 3, H335
·
Additional information:
For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
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4.1 Description of first aid measures
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General information:
·
After inhalation:
·
After skin contact:
·
After eye contact:
·
After swallowing:
·
4.2 Most important symptoms and effects, both acute and delayed
·
4.3 Indication of any immediate medical attention and special treatment needed
Immediately remove any clothing soiled by the product.
In case of unconsciousness place patient stably in side position for transportation.
Immediately wash with water and soap and rinse thoroughly.
Rinse opened eye for several minutes under running water. Then consult a doctor.
Drink plenty of water and provide fresh air. Call for a doctor immediately.
No further relevant information available.
No further relevant information available.
(Contd. of page 1)
2.5-15%
SECTION 5: Firefighting measures
·
5.1 Extinguishing media
·
Suitable extinguishing agents:
·
5.2 Special hazards arising from the substance or mixture
Use fire extinguishing methods suitable to surrounding conditions.
During heating or in case of fire poisonous gases are produced.
·
5.3 Advice for firefighters
·
Protective equipment:
Mouth respiratory protective device.
SECTION 6: Accidental release measures
·
6.1 Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation
Wear protective clothing.
·
6.2 Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
·
6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralising agent.
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
·
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
(Contd. on page 3)
GB
49.0.2
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.04.2019 Revision: 09.04.2019Version number 7
Trade name: Lötwasser Nr.1/V
Page 3/7
See Section 13 for disposal information.
SECTION 7: Handling and storage
·
7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
·
Information about fire - and explosion protection:
·
7.2 Conditions for safe storage, including any incompatibilities
·
Storage:
·
Requirements to be met by storerooms and receptacles:
·
Information about storage in one common storage facility:
·
Further information about storage conditions:
·
7.3 Specific end use(s)
SECTION 8: Exposure controls/personal protection
·
Additional information about design of technical facilities:
·
8.1 Control parameters
·
Ingredients with limit values that require monitoring at the workplace:
CAS: 7646-85-7 zinc chloride
WEL (Great Britain) Short-term value: 2 mg/m³
·
Additional information:
·
8.2 Exposure controls
·
Personal protective equipment:
·
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes and skin.
·
Respiratory protection:
Not necessary if room is well-ventilated.
Use suitable respiratory protective device in case of insufficient ventilation.
·
Protection of hands:
No further relevant information available.
Long-term value: 1 mg/m³
The lists valid during the making were used as basis.
Keep respiratory protective device available.
No special requirements.
Not required.
Keep container tightly sealed.
No further data; see item 7.
(Contd. of page 2)
_S
Protective gloves
Rubber gloves
Synthetic rubber gloves
To avoid skin problems reduce the wearing of gloves to the required minimum.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
·
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the
glove material can not be calculated in advance and has therefore to be checked prior to the application.
·
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
49.0.2
(Contd. on page 4)
GB
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.04.2019 Revision: 09.04.2019Version number 7
Trade name: Lötwasser Nr.1/V
Page 4/7
·
Eye protection:
Safety glasses
SECTION 9: Physical and chemical properties
·
9.1 Information on basic physical and chemical properties
·
General Information
·
Appearance:
Form:
Colour:
·
Odour:
·
Odour threshold:
·
pH-value:
·
Change in condition
Melting point/freezing point:
Initial boiling point and boiling range:
·
Flash point:
·
Flammability (solid, gas):
·
Decomposition temperature:
·
Auto-ignition temperature:
·
Explosive properties:
·
Explosion limits:
Lower:
Upper:
·
Vapour pressure:
·
Density at 20 °C:
·
Relative density
·
Vapour density
·
Evaporation rate
·
Solubility in / Miscibility with
water:
·
Partition coefficient: n-octanol/water:
·
Viscosity:
Dynamic:
Kinematic:
·
Solvent content:
Water:
·
9.2 Other information
Fluid
Clear
Characteristic
Not determined.
Not determined.
Undetermined.
100 °C
Not applicable.
Not applicable.
Not determined.
Product is not selfigniting.
Product does not present an explosion hazard.
Not determined.
Not determined.
Not determined.
1.09 g/cm³
Not determined.
Not determined.
Not determined.
Not miscible or difficult to mix.
Not determined.
Not determined.
Not determined.
89.5 %
No further relevant information available.
(Contd. of page 3)
SECTION 10: Stability and reactivity
·
10.1 Reactivity
·
10.2 Chemical stability
·
Thermal decomposition / conditions to be avoided:
·
10.3 Possibility of hazardous reactions
·
10.4 Conditions to avoid
·
10.5 Incompatible materials:
·
10.6 Hazardous decomposition products:
49.0.2
No further relevant information available.
No decomposition if used according to specifications.
No dangerous reactions known.
No further relevant information available.
No further relevant information available.
No dangerous decomposition products known.
GB
(Contd. on page 5)
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.04.2019 Revision: 09.04.2019Version number 7
Trade name: Lötwasser Nr.1/V
SECTION 11: Toxicological information
·
11.1 Information on toxicological effects
·
Acute toxicity
·
LD/LC50 values relevant for classification:
CAS: 7646-85-7 zinc chloride
Oral LD50 350 mg/kg (rat)
·
Primary irritant effect:
·
Skin corrosion/irritation
Causes severe skin burns and eye damage.
·
Serious eye damage/irritation
Causes severe skin burns and eye damage.
·
Respiratory or skin sensitisation
·
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
·
Germ cell mutagenicity
·
Carcinogenicity
·
Reproductive toxicity
·
STOT-single exposure
May cause respiratory irritation.
·
STOT-repeated exposure
·
Aspiration hazard
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Page 5/7
(Contd. of page 4)
SECTION 12: Ecological information
·
12.1 Toxicity
·
Aquatic toxicity:
·
12.2 Persistence and degradability
·
12.3 Bioaccumulative potential
·
12.4 Mobility in soil
·
Ecotoxical effects:
·
Remark:
·
Additional ecological information:
·
General notes:
Toxic for fish
No further relevant information available.
No further relevant information available.
No further relevant information available.
No further relevant information available.
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
·
12.5 Results of PBT and vPvB assessment
·
PBT:
Not applicable.
·
vPvB:
·
Not applicable.
12.6 Other adverse effects
No further relevant information available.
SECTION 13: Disposal considerations
·
13.1 Waste treatment methods
·
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
·
European waste catalogue
11 05 04* spent flux
15 01 10* packaging containing residues of or contaminated by hazardous substances
(Contd. on page 6)
GB
49.0.2
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.04.2019 Revision: 09.04.2019Version number 7
Trade name: Lötwasser Nr.1/V
·
Uncleaned packaging:
·
Recommendation:
SECTION 14: Transport information
·
14.1 UN-Number
·
ADR, IMDG, IATA
·
14.2 UN proper shipping name
·
ADR
·
IMDG
·
IATA
·
14.3 Transport hazard class(es)
·
ADR, IMDG
Disposal must be made according to official regulations.
UN1840
1 8 4 0 Z I N C C H LO R I DE SO L UT I O N m i xt u r e,
ENVIRONMENTALLY HAZARDOUS
Z I N C CHL O R I D E SO L U T I O N mi xt u r e , MA R I N E
POLLUTANT
ZINC CHLORIDE SOLUTION mixture
Page 6/7
(Contd. of page 5)
dc`oa}dâ´
·
Class
·
Label
·
IATA
dc`oa}
·
Class
·
Label
·
14.4 Packing group
·
ADR, IMDG, IATA
·
14.5 Environmental hazards:
·
Marine pollutant:
·
Special marking (ADR):
·
14.6 Special precautions for user
·
Danger code (Kemler):
·
EMS Number:
·
Segregation groups
·
Stowage Category
·
14.7 Transport in bulk according to Annex II of Marpol
and the IBC Code
·
Transport/Additional information:
·
ADR
·
Limited quantities (LQ)
·
Excepted quantities (EQ)
·
Transport category
8 Corrosive substances.
8
8 Corrosive substances.
8
III
Product contains environmentally hazardous substances:
zinc chloride
Symbol (fish and tree)
Symbol (fish and tree)
Warning: Corrosive substances.
80
F-A,S-B
Ac i ds, heav y metals an d their salts (in c l u ding the i r
organometallic compounds)
A
Not applicable.
5L
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
3
(Contd. on page 7)
GB
49.0.2
Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 09.04.2019 Revision: 09.04.2019Version number 7
Trade name: Lötwasser Nr.1/V
·
Tunnel restriction code
·
IMDG
·
Limited quantities (LQ)
·
Excepted quantities (EQ)
·
UN "Model Regulation":
SECTION 15: Regulatory information
·
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
·
Directive 2012/18/EU
·
Named dangerous substances - ANNEX I
·
Seveso category
·
Qualifying quantity (tonnes) for the application of lower-tier requirements
·
Qualifying quantity (tonnes) for the application of upper-tier requirements
·
REGULATION (EC) No 1907/2006 ANNEX XVII
·
15.2 Chemical safety assessment:
E2 Hazardous to the Aquatic Environment
None of the ingredients is listed.
Conditions of restriction: 3
A Chemical Safety Assessment has not been carried out.
E
5L
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN 1840 ZINC CHLORIDE SOLUTION MIXTURE, 8, III,
ENVIRONMENTALLY HAZARDOUS
200 t
500 t
Page 7/7
(Contd. of page 6)
SECTION 16: Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
·
Relevant phrases
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
·
Department issuing SDS:
·
Contact:
·
Abbreviations and acronyms:
ADR: A ccor d europ éen sur le transport des ma rchandises dangereuses par Route (European Agreement concer ning t he International C arri age of
Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity – Category 4
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
Hr. Dörr
Product Safety Department
GB
49.0.2
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