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SAFETY DATA SHEET
1. Identification
Product identifier: ORANGE CITRUS CRAZY CLEAN
Other means of identification
SDS number:
RE1000007495
Recommended restrictions
Product Use: Cleaner
Restrictions on use: Not known.
Manufacturer/Importer/Distributor Information
Manufacturer
Company Name:
Sprayway, Inc.
Address:
1000 INTEGRAM DR.
Pacific, MO 63069
Telephone:
1-630-628-3000
Fax:
Emergency telephone number: 1-866-836-8855
2. Hazard(s) identification
Hazard Classification
Physical Hazards
Flammable aerosol
Category 1
Health Hazards
Serious Eye Damage/Eye Irritation
Category 2A
Skin sensitizer
Category 1
Environmental Hazards
Acute hazards to the aquatic
environment
Category 2
Chronic hazards to the aquatic
environment
Category 2
Hazard Symbol:
Signal Word:
Danger
Label Elements
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Hazard Statement:
Extremely flammable aerosol.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Precautionary
Statements
Prevention:
Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Wash thoroughly after
handling. Wear protective gloves/protective clothing/eye protection/face
protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated
work clothing should not be allowed out of the workplace. Avoid release to
the environment.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of
water If skin irritation or rash occurs: Get medical advice/attention. Specific
treatment (see on this label). Wash contaminated clothing before reuse.
Collect spillage.
Storage:
Protect from sunlight. Do not expose to temperatures exceeding
50°C/122°F.
Disposal:
Dispose of contents/container to an appropriate treatment and disposal
facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.
Hazard(s) not otherwise
classified (HNOC):
None.
3. Composition/information on ingredients
Mixtures
Chemical Identity
CAS number
Content in percent (%)*
Cyclohexene, 1-methyl-4-(1methylethenyl)-, (4R)-
5989-27-5
1 - <5%
Propane
74-98-6
1 - <5%
Butane
106-97-8
1 - <5%
Proprietary
1 - <3%
1,2,3-Propanetriol
56-81-5
0.1 - <1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Ingestion:
Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Inhalation:
Move to fresh air.
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Skin Contact:
If skin irritation occurs: Get medical advice/attention. Destroy or thoroughly
clean contaminated shoes. Immediately remove contaminated clothing and
shoes and wash skin with soap and plenty of water. If skin irritation or an
allergic skin reaction develops, get medical attention.
Eye contact:
Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.
Most important symptoms/effects, acute and delayed
Symptoms:
No data available.
Hazards:
No data available.
Indication of immediate medical attention and special treatment needed
Treatment:
No data available.
5. Fire-fighting measures
General Fire Hazards:
Use water spray to keep fire-exposed containers cool. Fight fire from a
protected location. Move containers from fire area if you can do so without
risk.
Suitable (and unsuitable) extinguishing media
Suitable extinguishing
media:
Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
media:
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical:
Vapors may travel considerable distance to a source of ignition and flash
back.
Special protective equipment and precautions for firefighters
Special firefighting
procedures:
No data available.
Special protective equipment
for fire-fighters:
Firefighters must use standard protective equipment including flame
retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures:
Ventilate closed spaces before entering them. ELIMINATE all ignition
sources (no smoking, flares, sparks or flames in immediate area). Keep
upwind. See Section 8 of the SDS for Personal Protective Equipment. Do
not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Keep unauthorized personnel away.
Methods and material for
containment and cleaning
up:
Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste.
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Notification Procedures:
Prevent entry into waterways, sewer, basements or confined areas. Stop
the flow of material, if this is without risk. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Stop leak if you
can do so without risk.
Environmental Precautions:
Avoid release to the environment. Prevent further leakage or spillage if safe
to do so. Do not contaminate water sources or sewer.
7. Handling and storage
Precautions for safe handling:
Avoid contact with eyes. Wash hands thoroughly after handling. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Do not
pierce or burn, even after use. Avoid contact with eyes, skin, and clothing.
Conditions for safe storage,
including any
incompatibilities:
Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use.
Aerosol Level 1
8. Exposure controls/personal protection
Control Parameters
Occupational Exposure Limits
Chemical Identity
Type
Exposure Limit Values
Source
Propane
REL
1,000 ppm
1,800 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL
1,000 ppm
1,800 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA
1,000 ppm
1,800 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Butane
REL
800 ppm
1,900 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
STEL
1,000 ppm
US. ACGIH Threshold Limit Values (03 2018)
TWA
800 ppm
1,900 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
1,2,3-Propanetriol - Total
dust.
PEL 15 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 10 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
1,2,3-Propanetriol Respirable fraction.
TWA 5 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
PEL 5 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Appropriate Engineering
Controls
No data available.
Individual protection measures, such as personal protective equipment
General information:
Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level. If exposure limits have not been established, maintain airborne levels
to an acceptable level.
Eye/face protection:
Wear safety glasses with side shields (or goggles).
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Skin Protection
Hand Protection:
No data available.
Other:
Wear chemical-resistant gloves, footwear, and protective clothing
appropriate for the risk of exposure. Contact health and safety professional
or manufacturer for specific information.
Respiratory Protection:
In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.
Hygiene measures:
Avoid contact with eyes. Observe good industrial hygiene practices. When
using do not smoke. Contaminated work clothing should not be allowed out
of the workplace. Avoid contact with skin.
9. Physical and chemical properties
Appearance
Physical state:
liquid
Form:
Spray Aerosol
Color:
No data available.
Odor:
No data available.
Odor threshold:
No data available.
pH:
No data available.
Melting point/freezing point:
No data available.
Initial boiling point and boiling range:
No data available.
Flash Point:
-104.44 °C
Evaporation rate:
No data available.
Flammability (solid, gas):
No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%):
No data available.
Flammability limit - lower (%):
No data available.
Explosive limit - upper (%):
No data available.
Explosive limit - lower (%):
No data available.
Vapor pressure:
3,972.1165 - 5,171.068 hPa (20 °C)
Vapor density:
No data available.
Density:
No data available.
Relative density:
No data available.
Solubility(ies)
Solubility in water:
No data available.
Solubility (other):
No data available.
Partition coefficient (n-octanol/water):
No data available.
Auto-ignition temperature:
No data available.
Decomposition temperature:
No data available.
Viscosity:
No data available.
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10. Stability and reactivity
Reactivity:
No data available.
Chemical Stability:
Material is stable under normal conditions.
Possibility of hazardous
reactions:
No data available.
Conditions to avoid:
Avoid heat or contamination.
Incompatible Materials:
No data available.
Hazardous Decomposition
Products:
No data available.
11. Toxicological information
Information on likely routes of exposure
Inhalation:
No data available.
Skin Contact:
No data available.
Eye contact:
No data available.
Ingestion:
No data available.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation:
No data available.
Skin Contact:
No data available.
Eye contact:
No data available.
Ingestion:
No data available.
Information on toxicological effects
Acute toxicity (list all possible routes of exposure)
Oral
Product:
ATEmix: 160,256.41 mg/kg
Dermal
Product:
Not classified for acute toxicity based on available data.
Inhalation
Product:
Not classified for acute toxicity based on available data.
Repeated dose toxicity
Product:
No data available.
Skin Corrosion/Irritation
Product:
No data available.
Serious Eye Damage/Eye Irritation
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Product:
No data available.
Respiratory or Skin Sensitization
Product:
No data available.
Carcinogenicity
Product:
No data available.
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:
No carcinogenic components identified
US. National Toxicology Program (NTP) Report on Carcinogens:
No carcinogenic components identified
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):
No carcinogenic components identified
Germ Cell Mutagenicity
In vitro
Product:
No data available.
In vivo
Product:
No data available.
Reproductive toxicity
Product:
No data available.
Specific Target Organ Toxicity - Single Exposure
Product:
No data available.
Specific Target Organ Toxicity - Repeated Exposure
Product:
No data available.
Aspiration Hazard
Product:
No data available.
Other effects:
No data available.
12. Ecological information
Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Product:
No data available.
Aquatic Invertebrates
Product:
No data available.
Chronic hazards to the aquatic environment:
Fish
Product:
NOEC : Estimated < 1 mg/l
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Aquatic Invertebrates
Product:
No data available.
Toxicity to Aquatic Plants
Product:
No data available.
Persistence and Degradability
Biodegradation
Product:
60 % (28 d) Readily biodegradable
BOD/COD Ratio
Product:
No data available.
Bioaccumulative potential
Bioconcentration Factor (BCF)
Product:
No data available.
Partition Coefficient n-octanol / water (log Kow)
Product:
No data available.
Mobility in soil:
No data available.
Known or predicted distribution to environmental compartments
Cyclohexene, 1-methyl-4(1-methylethenyl)-, (4R)-
No data available.
Propane
No data available.
Butane
No data available.
Proprietary
No data available.
1,2,3-Propanetriol
No data available.
Other adverse effects:
Toxic to aquatic life with long lasting effects.
13. Disposal considerations
Disposal instructions:
Discharge, treatment, or disposal may be subject to national, state, or local
laws.
Contaminated Packaging:
No data available.
14. Transport information
DOT
UN Number:
UN 1950
UN Proper Shipping Name:
Aerosols, flammable
Transport Hazard Class(es)
Class:
2.1
Label(s):
–
Packing Group:
II
Marine Pollutant:
No Environmental Hazards:
No
Marine Pollutant
No Special precautions for user:
Not regulated.
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IMDG
UN Number:
UN 1950
UN Proper Shipping Name:
Aerosols, flammable
Transport Hazard Class(es)
Class:
2
Label(s):
–
EmS No.:
F-D, S-U
Packing Group:
– Environmental Hazards:
Yes
Marine Pollutant
No Special precautions for user:
Not regulated.
IATA
UN Number:
UN 1950
Proper Shipping Name:
Aerosols, flammable
Transport Hazard Class(es):
Class:
2.1
Label(s):
–
Packing Group:
–
Environmental Hazards:
Yes
Marine Pollutant
No Special precautions for user:
Not regulated.
Cargo aircraft only:
Allowed.
15. Regulatory information
US Federal Regulations
Restrictions on use: Not known.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
None present or none present in regulated quantities.
CERCLA Hazardous Substance List (40 CFR 302.4):
Chemical Identity
Reportable quantity
Propane
lbs. 100
Butane
lbs. 100
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Fire Hazard
Immediate (Acute) Health Hazards
Flammable aerosol
Serious Eye Damage/Eye Irritation
Skin sensitizer
SARA 302 Extremely Hazardous Substance
None present or none present in regulated quantities.
SARA 304 Emergency Release Notification
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Chemical Identity
Reportable quantity
Propane
lbs. 100
Butane
lbs. 100
SARA 311/312 Hazardous Chemical
Chemical Identity
Threshold Planning Quantity
Cyclohexene, 1-methyl-4(1-methylethenyl)-, (4R)-
10000 lbs
Propane
10000 lbs
Butane
10000 lbs
Proprietary
10000 lbs
1,2,3-Propanetriol
10000 lbs
SARA 313 (TRI Reporting)
None present or none present in regulated quantities.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations
US. California Proposition 65
No ingredient requiring a warning under CA Prop 65.
US. New Jersey Worker and Community Right-to-Know Act
Chemical Identity
Cyclohexene, 1-methyl-4-(1-methylethenyl)-, (4R)-
Propane
Butane
US. Massachusetts RTK - Substance List
No ingredient regulated by MA Right-to-Know Law present.
US. Pennsylvania RTK - Hazardous Substances
Chemical Identity
Propane
Butane
US. Rhode Island RTK
No ingredient regulated by RI Right-to-Know Law present.
International regulations
Montreal protocol
Not applicable
Stockholm convention
Not applicable
Rotterdam convention
Not applicable
Kyoto protocol
Not applicable
Inventory Status:
Australia AICS:
Not in compliance with the inventory.
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Canada DSL Inventory List:
Not in compliance with the inventory.
EINECS, ELINCS or NLP:
Not in compliance with the inventory.
Japan (ENCS) List:
Not in compliance with the inventory.
China Inv. Existing Chemical Substances:
Not in compliance with the inventory.
Korea Existing Chemicals Inv. (KECI):
Not in compliance with the inventory.
Canada NDSL Inventory:
Not in compliance with the inventory.
Philippines PICCS:
Not in compliance with the inventory.
US TSCA Inventory:
On or in compliance with the inventory
New Zealand Inventory of Chemicals:
Not in compliance with the inventory.
Japan ISHL Listing:
Not in compliance with the inventory.
Japan Pharmacopoeia Listing:
Not in compliance with the inventory.
Mexico INSQ:
Not in compliance with the inventory.
Ontario Inventory:
Not in compliance with the inventory.
Taiwan Chemical Substance Inventory:
Not in compliance with the inventory.
16.Other information, including date of preparation or last revision
Issue Date:
09/22/2019
Revision Information:
No data available.
Version #:
1.0
Further Information:
No data available.
Disclaimer:
This information is provided without warranty. The information is believed to
be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.
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