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SAFETY DATA SHEET
1. Identification
Product identifier: CRAZY CLEAN ALL PURPOSE CLEANER
Other means of identification
SDS number:
RE1000008685
Recommended restrictions
Product Use: Cleaner
Restrictions on use: Not known.
Manufacturer/Importer/Distributor Information
Manufacturer
Company Name:
Sprayway, Inc.
Address:
1000 INTEGRAM DR.
Pacific, MO 63069
Telephone:
1-630-628-3000
Fax:
Emergency telephone number: 1-866-836-8855
2. Hazard(s) identification
Hazard Classification
Physical Hazards
Gases under pressure
Compressed gas
Health Hazards
Serious Eye Damage/Eye Irritation
Category 2A
Environmental Hazards
Acute hazards to the aquatic
environment
Category 2
Hazard Symbol:
Signal Word:
Warning
Label Elements
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Hazard Statement:
Contains gas under pressure; may explode if heated.
Causes serious eye irritation.
Toxic to aquatic life.
Precautionary
Statements
Prevention:
Wash thoroughly after handling. Wear protective gloves/protective
clothing/eye protection/face protection. Avoid release to the environment.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention.
Storage:
Protect from sunlight. Store in a well-ventilated place.
Disposal:
Dispose of contents/container to an appropriate treatment and disposal
facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.
Hazard(s) not otherwise
classified (HNOC):
None.
3. Composition/information on ingredients
Mixtures
Chemical Identity
CAS number
Content in percent (%)*
Ethanol, 2-butoxy-
111-76-2
1 - <5%
Alcohols, C9-11, ethoxylated
68439-46-3
1 - <3%
Butane
106-97-8
1 - <5%
Propane
74-98-6
0.1 - <1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
4. First-aid measures
Ingestion:
Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
Inhalation:
Move to fresh air.
Skin Contact:
Wash skin thoroughly with soap and water. If skin irritation occurs: Get
medical advice/attention.
Eye contact:
Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.
Most important symptoms/effects, acute and delayed
Symptoms:
No data available.
Hazards:
No data available.
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Indication of immediate medical attention and special treatment needed
Treatment:
No data available.
5. Fire-fighting measures
General Fire Hazards:
Use water spray to keep fire-exposed containers cool. Fight fire from a
protected location. Move containers from fire area if you can do so without
risk.
Suitable (and unsuitable) extinguishing media
Suitable extinguishing
media:
Use fire-extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
media:
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical:
Vapors may travel considerable distance to a source of ignition and flash
back.
Special protective equipment and precautions for firefighters
Special fire fighting
procedures:
No data available.
Special protective equipment
for fire-fighters:
Firefighters must use standard protective equipment including flame
retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures:
Ventilate closed spaces before entering them. ELIMINATE all ignition
sources (no smoking, flares, sparks or flames in immediate area). Keep
upwind.
Methods and material for
containment and cleaning
up:
Absorb spill with vermiculite or other inert material, then place in a container
for chemical waste.
Notification Procedures:
Prevent entry into waterways, sewer, basements or confined areas. Stop
the flow of material, if this is without risk. ELIMINATE all ignition sources
(no smoking, flares, sparks or flames in immediate area). Stop leak if you
can do so without risk.
Environmental Precautions:
Avoid release to the environment. Prevent further leakage or spillage if safe
to do so. Do not contaminate water sources or sewer.
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7. Handling and storage
Precautions for safe handling:
Avoid contact with eyes. Wash hands thoroughly after handling. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Do not
pierce or burn, even after use.
Conditions for safe storage,
including any
incompatibilities:
Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use.
Aerosol Level 1
8. Exposure controls/personal protection
Control Parameters
Occupational Exposure Limits
Chemical Identity
Type
Exposure Limit Values
Source
Ethanol, 2-butoxy-
TWA
20 ppm
US. ACGIH Threshold Limit Values (2008)
TWA
25 ppm
120 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
REL
5 ppm
24 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL
50 ppm
240 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Butane
REL
800 ppm
1,900 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
STEL
1,000 ppm
US. ACGIH Threshold Limit Values (03 2018)
TWA
800 ppm
1,900 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Propane
REL
1,000 ppm
1,800 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL
1,000 ppm
1,800 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA
1,000 ppm
1,800 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Ammonium hydroxide
((NH4)(OH))
STEL
35 ppm
US. ACGIH Threshold Limit Values (2008)
TWA
25 ppm
US. ACGIH Threshold Limit Values (2008)
STEL
35 ppm
27 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
STEL
35 ppm
27 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
REL
25 ppm
18 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL
50 ppm
35 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Acetic acid, phenylmethyl
ester
TWA
10 ppm
US. ACGIH Threshold Limit Values (2008)
Sodium hydroxide (Na(OH))
Ceiling 2 mg/m3
US. ACGIH Threshold Limit Values (2008)
Ceiling 2 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Ceil_Time
2 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 2 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Benzene, 1,1'-oxybis- Vapor.
STEL
2 ppm
US. ACGIH Threshold Limit Values (03 2018)
TWA
1 ppm
US. ACGIH Threshold Limit Values (03 2018)
PEL
1 ppm
7 mg/m3
US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
REL
1 ppm
7 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
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TWA
1 ppm
7 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Phenol, 2,6-bis(1,1dimethylethyl)-4-methyl-
TWA 10 mg/m3
US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Phenol, 2,6-bis(1,1dimethylethyl)-4-methyl- Inhalable fraction and vapor.
TWA 2 mg/m3
US. ACGIH Threshold Limit Values (2008)
Phenol, 2,6-bis(1,1dimethylethyl)-4-methyl-
REL 10 mg/m3
US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
Biological Limit Values
Chemical Identity
Exposure Limit Values
Source
Ethanol, 2-butoxy(Butoxyacetic acid (BAA),
with hydrolysis: Sampling
time: End of shift.)
200 mg/g (Creatinine in urine)
ACGIH BEL (03 2013)
Appropriate Engineering
Controls
No data available.
Individual protection measures, such as personal protective equipment
General information:
Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level. If exposure limits have not been established, maintain airborne levels
to an acceptable level.
Eye/face protection:
Wear safety glasses with side shields (or goggles).
Skin Protection
Hand Protection:
No data available.
Other:
No data available.
Respiratory Protection:
In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.
Hygiene measures:
Avoid contact with eyes. Observe good industrial hygiene practices. When
using do not smoke.
9. Physical and chemical properties
Appearance
Physical state:
liquid
Form:
Spray Aerosol
Color:
No data available.
Odor:
No data available.
Odor threshold:
No data available.
pH:
No data available.
Melting point/freezing point:
No data available.
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Initial boiling point and boiling range:
No data available.
Flash Point:
-104.44 °C
Evaporation rate:
No data available.
Flammability (solid, gas):
No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%):
No data available.
Flammability limit - lower (%):
No data available.
Explosive limit - upper (%):
No data available.
Explosive limit - lower (%):
No data available.
Vapor pressure:
2,757.9029 - 4,136.8543 hPa (20 °C)
Vapor density:
No data available.
Density:
No data available.
Relative density:
No data available.
Solubility(ies)
Solubility in water:
No data available.
Solubility (other):
No data available.
Partition coefficient (n-octanol/water):
No data available.
Auto-ignition temperature:
No data available.
Decomposition temperature:
No data available.
Viscosity:
No data available.
10. Stability and reactivity
Reactivity:
No data available.
Chemical Stability:
Material is stable under normal conditions.
Possibility of hazardous
reactions:
No data available.
Conditions to avoid:
Avoid heat or contamination.
Incompatible Materials:
No data available.
Hazardous Decomposition
Products:
No data available.
11. Toxicological information
Information on likely routes of exposure
Inhalation:
No data available.
Skin Contact:
No data available.
Eye contact:
No data available.
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Ingestion:
No data available.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation:
No data available.
Skin Contact:
No data available.
Eye contact:
No data available.
Ingestion:
No data available.
Information on toxicological effects
Acute toxicity (list all possible routes of exposure)
Oral
Product:
ATEmix: 46,153.85 mg/kg
Dermal
Product:
ATEmix: 17,631.51 mg/kg
Inhalation
Product:
ATEmix: 528.68 mg/l
ATEmix : 132.17 mg/l
Repeated dose toxicity
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
NOAEL (Rabbit(Female, Male), Dermal, 90 d): > 150 mg/kg Dermal
Experimental result, Key study
NOAEL (Rat(Female), Oral, 90 d): < 82 mg/kg Oral Experimental result, Key
study
NOAEL (Rat(Female), Inhalation, 2 yr): < 31 ppm(m) Inhalation
Experimental result, Key study
Alcohols, C9-11,
ethoxylated
NOAEL (Rat(Female, Male), Oral, 90 d): >= 500 mg/kg Oral Read-across
based on grouping of substances (category approach), Key study
Butane
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
Propane
NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
Skin Corrosion/Irritation
Product:
No data available.
Specified substance(s):
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Ethanol, 2-butoxy-
in vivo (Rabbit): Irritating Experimental result, Key study
Alcohols, C9-11,
ethoxylated
in vivo (Rabbit): Not irritant Read-across based on grouping of substances
(category approach), Weight of Evidence study
Serious Eye Damage/Eye Irritation
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
Rabbit, 24 - 72 hrs: Irritating
Respiratory or Skin Sensitization
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
Skin sensitization:, in vivo (Guinea pig): Non sensitising
Carcinogenicity
Product:
No data available.
IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:
No carcinogenic components identified
US. National Toxicology Program (NTP) Report on Carcinogens:
No carcinogenic components identified
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):
No carcinogenic components identified
Germ Cell Mutagenicity
In vitro
Product:
No data available.
In vivo
Product:
No data available.
Reproductive toxicity
Product:
No data available.
Specific Target Organ Toxicity - Single Exposure
Product:
No data available.
Specific Target Organ Toxicity - Repeated Exposure
Product:
No data available.
Aspiration Hazard
Product:
No data available.
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Other effects:
No data available.
12. Ecological information
Ecotoxicity:
Acute hazards to the aquatic environment:
Fish
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
LC 50 (Oncorhynchus mykiss, 96 h): 1,474 mg/l Experimental result, Key
study
Alcohols, C9-11,
ethoxylated
LC 50 (96 h): 0.9 mg/l
LC 50 (Oncorhynchus mykiss, 96 h): 5 - 7 mg/l Experimental result, Key
study
Butane
LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study
Propane
LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study
Aquatic Invertebrates
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
EC 50 (Daphnia magna, 48 h): 1,550 mg/l Experimental result, Key study
Alcohols, C9-11,
ethoxylated
EC 50 (Daphnia magna, 48 h): 2.5 mg/l Experimental result, Key study
Butane
LC 50 (Daphnia sp., 48 h): 69.43 mg/l QSAR QSAR, Key study
Chronic hazards to the aquatic environment:
Fish
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
NOAEL (Danio rerio): > 100 mg/l Experimental result, Key study
Alcohols, C9-11,
ethoxylated
NOAEL (Pimephales promelas): 0.16 mg/l Read-across based on grouping
of substances (category approach), Weight of Evidence study
Aquatic Invertebrates
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
EC 50 (Daphnia magna): 297 mg/l Experimental result, Key study
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EC 10 (Daphnia magna): 134 mg/l Experimental result, Key study
Alcohols, C9-11,
ethoxylated
NOAEL (Daphnia magna): 1.75 mg/l Read-across based on grouping of
substances (category approach), Weight of Evidence study
Toxicity to Aquatic Plants
Product:
No data available.
Persistence and Degradability
Biodegradation
Product:
No data available.
Specified substance(s):
Ethanol, 2-butoxy-
90.4 % Detected in water. Experimental result, Key study
Alcohols, C9-11,
ethoxylated
100 % (28 d) Detected in water. Read-across based on grouping of
substances (category approach), Weight of Evidence study
Butane
100 % (385.5 h) Detected in water. Experimental result, Key study
Propane
100 % (385.5 h) Detected in water. Experimental result, Key study
50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study
BOD/COD Ratio
Product:
No data available.
Bioaccumulative potential
Bioconcentration Factor (BCF)
Product:
No data available.
Specified substance(s):
Alcohols, C9-11,
ethoxylated
Pimephales promelas, Bioconcentration Factor (BCF): 237 Aquatic sediment
Read-across from supporting substance (structural analogue or surrogate),
Key study
Partition Coefficient n-octanol / water (log Kow)
Product:
No data available.
Specified substance(s):
Alcohols, C9-11,
ethoxylated
Log Kow: 3.3 - 3.73 Yes QSAR, Weight of Evidence study
Mobility in soil:
No data available.
Known or predicted distribution to environmental compartments
Ethanol, 2-butoxy-
No data available.
Alcohols, C9-11,
ethoxylated
No data available.
Butane
No data available.
Propane
No data available.
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Other adverse effects:
Toxic to aquatic organisms.
13. Disposal considerations
Disposal instructions:
Discharge, treatment, or disposal may be subject to national, state, or local
laws.
Contaminated Packaging:
No data available.
14. Transport information
DOT
UN Number:
UN 1950
UN Proper Shipping Name:
Aerosols, non-flammable
Transport Hazard Class(es)
Class:
2.2
Label(s):
–
Packing Group:
II
Marine Pollutant:
No Environmental Hazards:
No
Marine Pollutant
No Special precautions for user:
Not regulated.
IMDG
UN Number:
UN 1950
UN Proper Shipping Name:
Aerosols, non-flammable
Transport Hazard Class(es)
Class:
2
Label(s):
–
EmS No.:
F-D, S-U
Packing Group:
– Environmental Hazards
No
Marine Pollutant
Yes
Special precautions for user:
Not regulated.
IATA
UN Number:
UN 1950
Proper Shipping Name:
Aerosols, non-flammable
Transport Hazard Class(es):
Class:
2.2
Label(s):
–
Packing Group:
– Environmental Hazards
No
Marine Pollutant
Yes
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Special precautions for user:
Not regulated.
Cargo aircraft only:
Allowed.
15. Regulatory information
US Federal Regulations
Restrictions on use: Not known.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
None present or none present in regulated quantities.
CERCLA Hazardous Substance List (40 CFR 302.4):
Chemical Identity
Reportable quantity
Butane
lbs. 100
Propane
lbs. 100
Ammonium hydroxide
((NH4)(OH))
lbs. 1000
Sodium hydroxide
(Na(OH))
lbs. 1000
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Fire Hazard
Sudden Release of Pressure
Immediate (Acute) Health Hazards
Flammable aerosol
Gases under pressure
Serious Eye Damage/Eye Irritation
SARA 302 Extremely Hazardous Substance
None present or none present in regulated quantities.
SARA 304 Emergency Release Notification
Chemical Identity
Reportable quantity
Ethanol, 2-butoxy-
Butane
lbs. 100
Propane
lbs. 100
Ammonium hydroxide
((NH4)(OH))
lbs. 1000
Sodium hydroxide
(Na(OH))
lbs. 1000
Cedrene
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SARA 311/312 Hazardous Chemical
Chemical Identity
Threshold Planning Quantity
Ethanol, 2-butoxy-
10000 lbs
Alcohols, C9-11,
ethoxylated
10000 lbs
Butane
10000 lbs
Propane
10000 lbs
Ammonium hydroxide
((NH4)(OH))
10000 lbs
Acetic acid, phenylmethyl
ester
10000 lbs
Sodium hydroxide
(Na(OH))
10000 lbs
Benzene, 1,1'-oxybis-
10000 lbs
Phenol, 2,6-bis(1,1dimethylethyl)-4-methyl-
10000 lbs
SARA 313 (TRI Reporting)
Chemical Identity
Reporting
threshold for
other users
Reporting threshold for
manufacturing and
processing
Ethanol, 2-butoxy-
N230 lbs
N230 lbs.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations
US. California Proposition 65
No ingredient requiring a warning under CA Prop 65.
US. New Jersey Worker and Community Right-to-Know Act
Chemical Identity
Ethanol, 2-butoxy-
Butane
US. Massachusetts RTK - Substance List
Chemical Identity
Glycine, N,N-bis(carboxymethyl)-, sodium salt (1:3)
US. Pennsylvania RTK - Hazardous Substances
Chemical Identity
Ethanol, 2-butoxy-
Butane
US. Rhode Island RTK
No ingredient regulated by RI Right-to-Know Law present.
International regulations
Montreal protocol
Not applicable
Stockholm convention
Not applicable
Rotterdam convention
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Not applicable
Kyoto protocol
Not applicable
Inventory Status:
Canada DSL Inventory List:
On or in compliance with the inventory
EINECS, ELINCS or NLP:
Not in compliance with the inventory.
Japan (ENCS) List:
Not in compliance with the inventory.
Korea Existing Chemicals Inv. (KECI):
Not in compliance with the inventory.
Canada NDSL Inventory:
Not in compliance with the inventory.
US TSCA Inventory:
On or in compliance with the inventory
New Zealand Inventory of Chemicals:
Not in compliance with the inventory.
Japan ISHL Listing:
Not in compliance with the inventory.
Japan Pharmacopoeia Listing:
Not in compliance with the inventory.
Mexico INSQ:
Not in compliance with the inventory.
Australia AICS:
On or in compliance with the inventory
China Inv. Existing Chemical Substances:
On or in compliance with the inventory
Philippines PICCS:
On or in compliance with the inventory
Ontario Inventory:
On or in compliance with the inventory
Taiwan Chemical Substance Inventory:
On or in compliance with the inventory
16.Other information, including date of preparation or last revision
Issue Date:
11/05/2019
Revision Information:
No data available.
Version #:
1.1
Further Information:
No data available.
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Disclaimer:
This information is provided without warranty. The information is believed to
be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.
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