Sprayon S00353000 User Manual

MR™353 Foaming Citrus Mold Cleaner Aerosol

Not available.
Aerosol.

US / Canada: [phone]
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year

SAFETY DATA SHEET

Product name

Other means of
identification

Product type

Emergency telephone
number of the company

Section 1. Identification

:

:
:

:

Manufacturer

:

Sprayon Products Group
101 W. Prospect Avenue,
Cleveland, Ohio 44115

Relevant identified uses of the substance or mixture and uses advised against

Not applicable.

S00353000

S00353000

Product code

:

Product Information
Telephone Number

:

US / Canada: [phone]
Mexico: Not Available

Regulatory Information
Telephone Number

:

US / Canada: [phone]
Mexico: Not Available

Transportation Emergency
Telephone Number

:

US / Canada: [phone]
Mexico: SETIQ 01-800-00-214-00 / (52) 55-5559-1588 24 hours / 365 days a year

Section 2. Hazards identification

GASES UNDER PRESSURE - Compressed gas
SKIN CORROSION/IRRITATION - Category 2
SKIN SENSITIZATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) ­Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
ASPIRATION HAZARD - Category 1

Classification of the
substance or mixture

:

Signal word

:

Danger

Hazard pictograms

:

GHS label elements

Percentage of the mixture consisting of ingredient(s) of unknown oral toxicity: 6%
Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 6%
Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 19.
9%

OSHA/HCS status

:

This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).

Date of issue/Date of revision

:

7/3/2018

Date of previous issue

:

2/1/2018

Version

:61/14

S00353000

MR™353 Foaming Citrus Mold Cleaner Aerosol

SHW-85-NA-GHS-US

Section 2. Hazards identification

Precautionary statements

Prevention

:

Wear protective gloves. Use only outdoors or in a well-ventilated area. Do not breathe
dust or mist. Wash hands thoroughly after handling. Contaminated work clothing must
not be allowed out of the workplace.

Response

:

Get medical attention if you feel unwell. IF INHALED: Remove person to fresh air and
keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell.
IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
vomiting. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated
clothing before reuse. If skin irritation or rash occurs: Get medical attention.

Storage

:

Store locked up. Protect from sunlight. Store in a well-ventilated place.

Disposal

Dispose of contents and container in accordance with all local, regional, national and
international regulations.

Hazards not otherwise
classified

:

None known.

Contains gas under pressure; may explode if heated.
Causes skin irritation.
May cause an allergic skin reaction.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
May cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.

:

Hazard statements

Please refer to the SDS for additional information. Keep out of reach of children. Keep
upright in a cool, dry place. Do not discard empty can in trash compactor.

Supplemental label
elements

DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which
can cause permanent brain and nervous system damage. Intentional misuse by
deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING:
This product contains chemicals known to the State of California to cause cancer and
birth defects or other reproductive harm. FOR INDUSTRIAL USE ONLY.

:

Section 3. Composition/information on ingredients

d-Limonene

≥10 - ≤25

5989-27-5

Butane

≤5

106-97-8

2-Propanol

<5

67-63-0

2-Butoxyethanol

<5

111-76-2

Propane

≤3

74-98-6

Ingredient name

CAS number

% by weight

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health and hence require reporting in this section.

Other means of
identification

:

Not available.

Substance/mixture

CAS number/other identifiers

:

Occupational exposure limits, if available, are listed in Section 8.

Mixture

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.

Section 4. First aid measures

Eye contact

:

Description of necessary first aid measures

Date of issue/Date of revision

:

7/3/2018

Date of previous issue

:

2/1/2018

Version

:62/14

S00353000

MR™353 Foaming Citrus Mold Cleaner Aerosol

SHW-85-NA-GHS-US

Section 4. First aid measures

Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.

Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.

Skin contact

Inhalation

Ingestion

:

:

:

Notes to physician

:

Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.

Specific treatments

:

No specific treatment.

Most important symptoms/effects, acute and delayed

Inhalation

:

Can cause central nervous system (CNS) depression. May cause drowsiness or
dizziness. May cause respiratory irritation.

Can cause central nervous system (CNS) depression. May be fatal if swallowed and
enters airways.

:

Ingestion
Skin contact

:

Causes skin irritation. May cause an allergic skin reaction.

No known significant effects or critical hazards.

:

Eye contact

Over-exposure signs/symptoms

Skin contact
Ingestion

Inhalation

Adverse symptoms may include the following:
respiratory tract irritation
coughing
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo
unconsciousness

Adverse symptoms may include the following:
nausea or vomiting

Adverse symptoms may include the following:
irritation
redness

:

:

:

Eye contact

:

Adverse symptoms may include the following:
pain or irritation
watering
redness

Potential acute health effects

Indication of immediate medical attention and special treatment needed, if necessary

Date of issue/Date of revision

:

7/3/2018

Date of previous issue

:

2/1/2018

Version

:63/14

S00353000

MR™353 Foaming Citrus Mold Cleaner Aerosol

SHW-85-NA-GHS-US

Section 4. First aid measures

Protection of first-aiders

:

No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.

Hazardous thermal
decomposition products

Specific hazards arising
from the chemical

Decomposition products may include the following materials:
carbon dioxide
carbon monoxide

In a fire or if heated, a pressure increase will occur and the container may burst.
Bursting aerosol containers may be propelled from a fire at high speed.

Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Special protective
equipment for fire-fighters

Use an extinguishing agent suitable for the surrounding fire.

Extinguishing media

:::

None known.

Suitable extinguishing
media

:

Unsuitable extinguishing
media

:

Special protective actions
for fire-fighters

:

Section 6. Accidental release measures

Environmental precautions

Personal precautions, protective equipment and emergency procedures

:

:

No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. In the case of aerosols being ruptured, care should be taken due to the rapid
escape of the pressurized contents and propellant. If a large number of containers are
ruptured, treat as a bulk material spillage according to the instructions in the clean-up
section. Do not touch or walk through spilled material. Avoid breathing vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.

Small spill

:

Methods and materials for containment and cleaning up

For non-emergency
personnel

For emergency responders

:

If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non­emergency personnel".

Date of issue/Date of revision

:

7/3/2018

Date of previous issue

:

2/1/2018

Version

:64/14

S00353000

MR™353 Foaming Citrus Mold Cleaner Aerosol

SHW-85-NA-GHS-US

Section 6. Accidental release measures

Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.

Large spill

:

Section 7. Handling and storage

Advice on general
occupational hygiene

Conditions for safe storage,
including any
incompatibilities

Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Store in accordance with local regulations. Store away from direct sunlight in a dry, cool
and well-ventilated area, away from incompatible materials (see Section 10) and food
and drink. Protect from sunlight. Store locked up. Use appropriate containment to
avoid environmental contamination. See Section 10 for incompatible materials before
handling or use.

:

:

Protective measures

Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems should not be employed in any process in which
this product is used. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not get in
eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid
breathing gas. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Empty containers retain product residue and can be
hazardous.

:

Precautions for safe handling

d-Limonene

None.

Butane

NIOSH REL (United States, 10/2016).

TWA: 800 ppm 10 hours.
TWA: 1900 mg/m³ 10 hours.

ACGIH TLV (United States, 3/2017).

STEL: 1000 ppm 15 minutes.

2-Propanol

ACGIH TLV (United States, 3/2017).

TWA: 200 ppm 8 hours.
STEL: 400 ppm 15 minutes.

NIOSH REL (United States, 10/2016).

TWA: 400 ppm 10 hours.
TWA: 980 mg/m³ 10 hours.
STEL: 500 ppm 15 minutes.
STEL: 1225 mg/m³ 15 minutes.

OSHA PEL (United States, 6/2016).

TWA: 400 ppm 8 hours.
TWA: 980 mg/m³ 8 hours.

2-Butoxyethanol

ACGIH TLV (United States, 3/2017).

TWA: 20 ppm 8 hours.

NIOSH REL (United States, 10/2016).
Absorbed through skin.

TWA: 5 ppm 10 hours.
TWA: 24 mg/m³ 10 hours.

OSHA PEL (United States, 6/2016).

Section 8. Exposure controls/personal protection

Ingredient name

Exposure limits

Control parameters

Occupational exposure limits (OSHA United States)

Date of issue/Date of revision

:

7/3/2018

Date of previous issue

:

2/1/2018

Version

:65/14

S00353000

MR™353 Foaming Citrus Mold Cleaner Aerosol

SHW-85-NA-GHS-US