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SAFETY DATA SHEET
Revision Date 22-Apr-2015
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
Company Phone Number
24 Hour Emergency Phone Number
Spray Nine® 32 fl.oz
26810
None
Disinfectant Cleaning
No information available
Distributor
ITW Permatex Canada
35 Brownridge Road, Unit 1
Halton Hills, ON Canada L7G 0C6
Telephone: (800) 924-6994
1-87-Permatex
(877) 376-2839
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
Version 1
E-mail address
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Label elements
Emergency Overview
The product contains no substances which at their given concentration, are considered to be hazardous to health
Odor CitrusAppearance Clear Physical state Liquid
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
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Not applicable
3. COMPOSITION/INFORMATION ON INGREDIENTS
substance(s)
Chemical Name CAS No Weight-% Trade Secret
WATER 7732-18-5 60 - 100 *
ETHOXYLATED C9-C11 ALCOHOLS 68439-46-3 1 - 5 *
DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 1 - 5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
Skin contact
Inhalation
Ingestion
Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
Use personal protective equipment as required. Avoid contact with skin, eyes or clothing.
See section 2 for more information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
None.
Specific hazards arising from the chemical
None in particular.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
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6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevention of secondary hazards
Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required.
See Section 12 for additional ecological information.
Prevent further leakage or spillage if safe to do so.
Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth
or other non-combustible absorbent material. Take up mechanically, placing in appropriate
containers for disposal. Clean contaminated surface thoroughly.
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Conditions for safe storage, including any incompatibilities
Storage Conditions
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials
Strong oxidizing agents
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Appropriate engineering controls
Engineering Controls
Individual protection measures, such as personal protective equipment
Eye/face protection
Skin and body protection
Respiratory protection
General Hygiene Considerations
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.
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Showers
Eyewash stations
Ventilation systems
Wear safety glasses with side shields (or goggles).
Wear protective gloves and protective clothing.
Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as
appropriate.
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Liquid
Clear
Citrus
No information available
Values
No information available
No information available
100 °C / 212 °F
> 93 °C / > 200 °F
< 1
No information available
No information available
No information available
18 mm Hg
>1
1.02 g/ml
Soluble in water
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
Remarks • Method
Tag Closed Cup
Butyl acetate = 1
Air = 1
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
No information available
No information available
<0.5%
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Excessive heat.
Incompatible materials
Strong oxidizing agents
Hazardous Decomposition Products
Carbon oxides
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
WATER
7732-18-5
ETHOXYLATED C9-C11
ALCOHOLS
68439-46-3
DIPROPYLENE GLYCOL
MONONBUTYL ETHER
29911-28-2
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis.
Ingestion may cause irritation to mucous membranes.
> 90 mL/kg ( Rat ) - -
= 1378 mg/kg ( Rat ) = 1400 mg/kg
( Rat )
= 1620 µL/kg ( Rat ) = 5860 µL/kg ( Rabbit ) = 42.1 ppm ( Rat ) 4 h
> 2 g/kg ( Rabbit ) -
Information on toxicological effects
Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Germ cell mutagenicity
Carcinogenicity
No information available.
No information available.
This product contains one or more substances which are classified by IARC as
carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly
carcinogenic to humans (Group 2B).
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
39421 mg/kg
76980 mg/kg
12. ECOLOGICAL INFORMATION
Ecotoxicity
3.17% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
DIPROPYLENE GLYCOL
MONONBUTYL ETHER
29911-28-2
- 841: 96 h Poecilia reticulata mg/L
LC50 static
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS
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Waste treatment methods
Disposal of wastes
Contaminated packaging
US EPA Waste Number
DOT
Proper shipping name:
IATA
Proper shipping name:
IMDG
Proper shipping name:
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Do not reuse container.
Not applicable
14. TRANSPORT INFORMATION
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
Complies
Complies
Not determined
Not Listed.
Complies
Not determined
Not determined
Not determined
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Yes
No
No
No
No
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CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals
Chemical Name California Proposition 65
ETHANOL - 64-17-5 Carcinogen
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
SODIUM HYDROXIDE
1310-73-2
ETHANOL
64-17-5
X X X
X X X
U.S. EPA Label Information
EPA Pesticide Registration Number
6659-3
EPA Statement
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required
for safety data sheets, and for workplace labels of non-pesticide chemicals.
Developmental
NFPA
HMIS
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
Health hazards 1
Health hazards 1
22-Apr-2015
Flammability 1 Instability 0
Flammability 1 Physical hazards 0 Personal protection B
-
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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