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SAFETY DATA SHEET
Revision Date 03-Apr-2015
1. IDENTIFICATION
Product identifier
Product Name
Other means of identification
Product Code
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Manufacturer Address
ITW Permatex
10 Columbus Blvd.
Hartford, CT 06106 USA
Company Phone Number
24 Hour Emergency Phone Number
Spray Nine Glass & Stainless Steel Cleaner 19 oz.
23319
None
Glass cleaner - Aerosol
No information available
Distributor
ITW Permatex Canada
35 Brownridge Road, Unit 1
Halton Hills, ON Canada L7G 0C6
Telephone: (800) 924-6994
1-87-Permatex
(877) 376-2839
Chem-Tel: 800-255-3924
International Emergency:
00+1+ 813-248-0585
Contract Number: MIS0003453
Version 3
E-mail address
2. HAZARDS IDENTIFICATION
Classification
OSHA Regulatory Status
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Gases under pressure
Label elements
Emergency Overview
Warning
Contains gas under pressure; may explode if heated
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Liquefied gas
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Odor CitrusAppearance White Physical state Liquid
Precautionary Statements - Prevention
Pressurized container: Do not pierce or burn, even after use
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
Precautionary Statements - Storage
Protect from sunlight. Store in a well-ventilated place
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
Not applicable
Other Information
The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w
1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases
(2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3
3. COMPOSITION/INFORMATION ON INGREDIENTS
substance(s)
Chemical Name CAS No Weight-% Trade Secret
PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 1 - 5 *
2-BUTOXYETHANOL 111-76-2 1 - 5 *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
Description of first aid measures
General advice
Eye contact
Skin contact
Get medical advice/attention if you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician.
Wash contaminated clothing before reuse.
Inhalation
Ingestion
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. If symptoms persist, call a physician.
IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an
unconscious person. Call a physician.
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Self-protection of the first aider
Most important symptoms and effects, both acute and delayed
Symptoms
Indication of any immediate medical attention and special treatment needed
Note to physicians
Use personal protective equipment as required.
See section 2 for more information.
Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Carbon dioxide (CO2), Dry chemical, Foam
Unsuitable extinguishing media
Do not use a solid water stream as it may scatter and spread fire.
Specific hazards arising from the chemical
Heating causes rise in pressure with risk of bursting. Keep product and empty container away from heat and sources of ignition.
Explosion data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
None.
None.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions
Environmental precautions
Environmental precautions
Methods and material for containment and cleaning up
Methods for containment
Methods for cleaning up
Prevention of secondary hazards
Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin.
Use personal protective equipment as required. Do not puncture or incinerate cans.
Do not flush into surface water or sanitary sewer system. See Section 12 for additional
ecological information.
Prevent further leakage or spillage if safe to do so.
Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel
into suitable containers for disposal.
Clean contaminated objects and areas thoroughly observing environmental regulations.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid breathing
vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling.
Wash contaminated clothing before reuse. Use personal protective equipment as required.
Contents under pressure. Do not puncture or incinerate cans.
Conditions for safe storage, including any incompatibilities
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Storage Conditions
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Keep from
freezing.
Incompatible materials
Strong oxidizing agents, Acids
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
2-BUTOXYETHANOL
111-76-2
NIOSH IDLH Immediately Dangerous to Life or Health
Other Information
Appropriate engineering controls
Engineering Controls
Individual protection measures, such as personal protective equipment
.
TWA: 20 ppm TWA: 50 ppm
TWA: 240 mg/m
(vacated) TWA: 25 ppm
(vacated) TWA: 120 mg/m
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992).
Showers
Eyewash stations
Ventilation systems
(vacated) S*
S*
3
3
IDLH: 700 ppm
TWA: 5 ppm
TWA: 24 mg/m
3
Eye/face protection
Skin and body protection
Respiratory protection
Wear safety glasses with side shields (or goggles).
Wear protective gloves and protective clothing.
None under normal use conditions. In case of insufficient ventilation, wear suitable
respiratory equipment.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of
equipment, work area and clothing is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical state
Appearance
Odor
Odor threshold
Property
pH
Melting point / freezing point
Boiling point / boiling range
Flash point
Evaporation rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit:
Lower flammability limit:
Vapor pressure
Liquid
White
Citrus
No information available
Values
10.47-11.0
No information available
> 100 °C / 212 °F
> 93 °C / > 200 °F
< 1 Butyl acetate = 1
No information available
No information available
No information available
No information available
Remarks • Method
Aerosol Contents under pressure
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Vapor density
Relative density
Water solubility
Solubility in other solvents
Partition coefficient
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing properties
Other Information
Softening point
Molecular weight
VOC Content (%)
Density
Bulk density
>1
0.993-0.998
Soluble in water
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
No information available
7.8%
No information available
No information available
10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Air = 1
Possibility of Hazardous Reactions
None under normal processing.
Conditions to avoid
Heat, flames and sparks. Keep from freezing.
Incompatible materials
Strong oxidizing agents, Acids
Hazardous Decomposition Products
Carbon oxides
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Inhalation
Eye contact
Skin contact
Ingestion
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
2-BUTOXYETHANOL
111-76-2
May cause irritation of respiratory tract.
Contact with eyes may cause irritation. May cause redness and tearing of the eyes.
May cause skin irritation and/or dermatitis.
Ingestion may cause irritation to mucous membranes.
= 470 mg/kg ( Rat ) = 99 mg/kg ( Rabbit ) = 450 ppm ( Rat ) 4 h
Information on toxicological effects
Symptoms
Delayed and immediate effects as well as chronic effects from short and long-term exposure
No information available.
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Sensitization
Germ cell mutagenicity
Carcinogenicity
Chemical Name ACGIH IARC NTP OSHA
2-BUTOXYETHANOL
111-76-2
ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Not classifiable as a human carcinogen
Chronic toxicity
No information available.
No information available.
The table below indicates whether each agency has listed any ingredient as a carcinogen.
A3 Group 3 - -
May cause adverse effects on the bone marrow and blood-forming system. May cause
adverse liver effects.
Target Organ Effects
Blood, Central nervous system, Eyes, Hematopoietic System, kidney, Liver, Respiratory
system, Skin.
The following values are calculated based on chapter 3.1 of the GHS document .
ATEmix (oral)
ATEmix (dermal)
ATEmix (inhalation-dust/mist)
ATEmix (inhalation-vapor)
15667 mg/kg
36667 mg/kg
50 mg/l
15000 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
4% of the mixture consists of components(s) of unknown hazards to the aquatic environment
Chemical Name Algae/aquatic plants Fish Crustacea
2-BUTOXYETHANOL
111-76-2
- 1490: 96 h Lepomis macrochirus
mg/L LC50 static 2950: 96 h
Lepomis macrochirus mg/L LC50
1000: 48 h Daphnia magna mg/L
EC50 1698 - 1940: 24 h Daphnia
magna mg/L EC50
Persistence and degradability
No information available.
Bioaccumulation
No information available.
Mobility
No information available.
Chemical Name Partition coefficient
PETROLEUM GASES, LIQUEFIED, SWEETENED
68476-86-8
2-BUTOXYETHANOL
111-76-2
Other adverse effects
No information available
Waste treatment methods
Disposal of wastes
Contaminated packaging
US EPA Waste Number
<=2.8
0.81
13. DISPOSAL CONSIDERATIONS
Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Do not reuse container.
Not applicable
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14. TRANSPORT INFORMATION
DOT
UN/ID no
Proper shipping name:
Hazard Class
Emergency Response Guide
Number
IATA
UN/ID no
Proper shipping name:
Hazard Class
ERG Code
IMDG
UN/ID no
Proper shipping name:
Hazard Class
EmS-No
1950
Aerosols, Limited Quantity (LQ)
2.2
126
ID 8000
Consumer commodity
9
9L
1950
Aerosols, Limited Quantity (LQ)
2.2
F-D, S-U
15. REGULATORY INFORMATION
International Inventories
TSCA
DSL/NDSL
EINECS/ELINCS
ENCS
IECSC
KECL
PICCS
AICS
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical
or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
Chemical Name SARA 313 - Threshold Values %
2-BUTOXYETHANOL - 111-76-2 1.0
SARA 311/312 Hazard Categories
Acute health hazard
Chronic Health Hazard
Fire hazard
Sudden release of pressure hazard
Reactive Hazard
Complies
Complies
Complies
Not Listed
Complies
Complies
Complies
Complies
Yes
No
No
No
No
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CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
WATER
7732-18-5
2-BUTOXYETHANOL
111-76-2
AMMONIA SOLUTION
1336-21-6
U.S. EPA Label Information
EPA Pesticide Registration Number
Not applicable
- - X
X X X
X X X
NFPA
HMIS
NFPA (National Fire Protection Association)
HMIS (Hazardous Material Information System)
Revision Date
Health hazards 1
Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B
03-Apr-2015
Flammability 1 Instability 0
-
Disclaimer
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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