SONY SS-00259 User Manual

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MANAGEMENT REGULATIONS FOR THE
ENVIRONMENT-RELATED SUBSTANCES TO BE
CONTROLLED WHICH ARE INCLUDED IN
PARTS AND MATERIALS
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SS-00259 (7th Edition) for General Use
Terms of Use:
Copyright and all intellectual property rights in the content of this document are vested in Sony Corporation and reserved, unless otherwise indicated.
This document is the Sony Technical Standard, SS-00259 for General Use, Seventh Edition.
Copyright 2008 Sony Corp. ALL RIGHTS RESERVED No part of this document may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without the prior written permission of Sony Corporation.
Copyright 2008 Sony Corporation
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CONTENTS
1. PURPOSE..................................................................................................................................... 1
2. SCOPE.......................................................................................................................................... 1
2.1 Scope applicable to parts and materials................................................................................ 1
2.2 Scope applicable to products................................................................................................. 1
3. TERMS AND DEFINITIONS ......................................................................................................... 2
4.
MANAGEMENT STANDARDS FOR “ENVIRONMENT-RELATED SUBSTANCES TO BE CONTROLLED”
4.1 “Environment-related Substances to be Controlled (‘Controlled Substances’)” .................... 3
4.2 Additional rules for packaging components and materials .................................................. 15
4.3 Rules for batteries (Applicable to all batteries in commercial distribution) .......................... 18
....... 3
APPENDIXES ................................................................................................................................... 19
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1. PURPOSE
With regard to the “Environment-related Substances to be Controlled (‘Controlled Substances’)” contained in the parts and devices employed in Sony electronics products, this Standard clarifies (1) banned substances, (2) substances to be phased out, and (3) exempted substances and their uses, in order to realize the following aims and objectives:
1) To prevent the above-mentioned substances from being used for Sony electronics products;
2) To comply with related laws and regulations;
3) To reduce the influence of the above substances upon the ecosystem; and
4) To contribute to the preservation of the global environment.
2. SCOPE
2.1 Scope applicable to parts and materials
Targets are the parts, materials, and other articles that are procured by the Sony group, or by third parties to which the Sony group outsources the design and manufacture of its electronics products.
The targets need to satisfy the criteria specified in this Standard. Target parts and materials:
- Semi-finished products (e.g. modules, functional units, board assemblies, and other assembly parts)
- Parts (electrical parts, mechanical parts, semiconductor devices, PWBs, recording media, and packaging components and materials)
- Screws
- Accessories (mice, remote commanders, AC adaptors, and other accessories with which you can use products)
- Materials constituting subsidiary parts and materials (e.g. adhesives, adhesive tapes, soldering materials, etc.) used for products
- Printed materials (e.g. instruction manuals, warranty cards, additional product/parts information)
- Repair parts (The application of some repair parts for products on the market shall be followed the instructions on the separately issued notice.)
- Packaging components and materials that parts suppliers use for delivery and protection (See Section
4.2.1 “Definition of packaging components and materials” for details.)
- Batteries
2.2 Scope applicable to products
1) Sony electronics products that are designed and manufactured by the Sony group for sale, loan, or
distribution
2) Sony electronics products being sold and loaned or distributed with the Sony group’s logos on them,
whose design and/or manufacture are outsourced to third parties
3) Third parties’ electronics products whose design and/or manufacture are outsourced to the Sony group
(except when the parts and materials are specified by the third parties)
Regarding the use of substances prohibited or restricted by regional or country laws and ordinances, the laws and ordinances must be observed and followed even though the substances and their uses are not clearly regulated in this Standard.
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3. TERMS AND DEFINITIONS
In this Standard, terms are defined in the following manners.
1) Environment-related Substances to be Controlled (Controlled Substances’)” Among the substances contained in parts and devices, Environment-related Substances to be
Controlled (Controlled Substances’)” are those which, according to Sonys judgment, have significant environmental-impact on both humans and the global environment.
2) Management standards To manage the above-mentioned substances, the following Levels and Exemption are used: a) Level 1 The substances and their applications classified into this Level are those that are banned for the use
in parts and materials.
b) Level 2
On the date set in each table, the substances and their applications in the respective tables shall be
reclassified into Level 1. c) Level 3 No effective date of the ban on the delivery is currently set for the substances and their applications
classified into this Level. The ones under Level 3 shall be reclassified into Level 2 for banning the use
of them in phases, depending on the availability of alternative parts or materials that satisfy the
intended uses. d) Exemption The substances and their applications classified as Exemption are those not regulated by or
exempted from laws, or excepted from the Controlled Substances because of the unavailability of
adequate alternative parts and materials that satisfy the intended uses.
3) Contained Contained is a situation in which a substance is added to, is blended with, fills up, or adheres to:
a) The parts or devices employed in products, or b) The materials used for the parts or devices, regardless if the situation is intentionally created or not.
(When a substance is unintentionally contained in, or added to a product in a processing process,
this situation is also regarded as “Contained.”) There are substances called Dopants (Doping Agents) that are intentionally added to manufacture semiconductor devices, etc. They are not treated as “Contained” if present in the devices in a very small amount.
4) Impurity An “Impurity” is a substance that satisfies either or both of the following conditions:
a) One contained in a natural material, which cannot be completely removed in a refining process by
technical means (i.e. natural impurities); and b) One generated in a synthesis process, which cannot be completely removed by technical means. There are substances called “impurities,” the name of which is used to distinguish them from main materials. If they are used for the purpose of changing the characteristics of a material, they are treated as Contained.
Note: The ‘Controlled Substance, which mingles with or adheres to parts or devices as an “Impurity,”
must not exceed its allowable concentration specified in this Standard.
5) Effective date of the ban on the delivery This indicates the date on or after which Sony wont accept the parts and/or materials specified in the
corresponding columns of Table 4.2.
6) Plastics defined in this Technical Standard Plastics refer to materials and raw materials composed of synthetic high-molecular polymers in this
Standard.
More specifically, “plastics” mainly mean the following articles composed of synthetic high-molecular
polymers: resins, films, adhesives, adhesive tapes, molded products, products made of synthetic rubber, and plastics made from raw materials of plant origin.
When a natural resin is synthesized with any one of the above articles, the synthetic substance is a plastic.
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4. MANAGEMENT STANDARDS FOR “ENVIRONMENT-RELATED SUBSTANCES TO BE CONTROLLED”
4.1 “Environment-related Substances to be Controlled (‘Controlled Substances’)”
The table below lists the Environment-related Substances to be Controlled (Controlled Substances’),” defined in this Standard.
Table 4.1 List of “Environment-related Substances to be Controlled (‘Controlled Substances’)”
Substances
Heavy metals
Chlorinated organic compounds
Brominated organic compounds
Tributyltin compounds (TBT) Triphenyltin compounds (TPT)
Asbestos Specific azo compounds Formaldehyde Polyvinyl chloride (PVC) and PVC blends Beryllium oxide
Beryllium copper Specific phthalates (DEHP, DBP, BBP, DINP, DIDP, DNOP, DNHP) Hydrofluorocarbon (HFC), Perfluorocarbon (PFC) Perfluorooctane sulfonates (PFOS) Specific benzotriazole
Cadmium and cadmium compounds Lead and lead compounds Mercury and mercury compounds Hexavalent chromium compounds Polychlorinated biphenyls (PCB)
Polychlorinated naphthalenes (PCN) Polychlorinated terphenyls (PCT)
Short-chain chlorinated paraffins (SCCP) Other chlorinated organic compounds Polybrominated biphenyls (PBB) Polybrominated diphenylethers (PBDE) (including decabromodiphenyl ether
[DecaBDE]) Other brominated organic compounds
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Table 4.2 Main “Targets” and “Effective date of the ban on the delivery” regarding ‘Controlled
Substances
Substances: Cadmium and cadmium compounds
All metals, alloys, inorganic compounds, organic compounds, inorganic salts, organic salts, and other substances that contain cadmium
Effective date of the ban on the delivery
Banned since the establishment of this Standard
Banned since January 1, 2005
Banned since October 1, 2005
N/A
Level 1
Exemption
Targets
- Packaging components and materials (See 4.2.1.)
- The stabilizers, pigments, or dyes used for plastics (including rubber) materials (e.g. labels, cabinets, phonograph records, cable tie, the keys of remote commanders, the outer plastic resins of electrical parts, and the insulators of electrical wiring)
- Paints, inks
- Surface treatment (e.g. electroplating, electroless plating, etc.) and coating
- Photographic films
- Fluorescent lamps (small-sized ones, straight-tube ones)
All uses except those specified in Exemption Typical examples are given below:
- Switches, relays, breakers, DC motors, and other electrical contact points
- Fuse elements of temperature fuses
- Glass, and the pigments as well as dyes of glass paints (paints for glass and the pigments as well as dyes used for glass)
- Solder (whose cadmium concentration is more than 20 ppm)
- CdS-photocells and the phosphors contained in fluorescent display devices
- Resistor elements (glass frit)
- Parts composed of metals containing zinc (e.g. brass, hot dip galvanizing, etc.) whose cadmium concentration is more than 100 ppm
- Cadmium plating of electrical contacts, for which high reliability is required and which has no alternative materials
- Cadmium in optical glass, filter glass
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Test objects: plastics (including rubber), paints, and inks Allowable concentration: Less than 5 ppm
Standards for measurement
1) Sample preparation Typical sample preparation methods are as follows. (1) Incineration under the existence of sulfuric acid (2) A pressurized acid decomposition method done in a sealed container (a microwave decomposition
method [e.g. EPA 3052:1996, EN 13346:2000])
(3) An acid decomposition method under the existence of nitric acid, hydrogen-peroxide water and
hydrochloric acid (e.g. EPA3050B Rev.2:1996)
(4) A wet decomposition method under the existence of sulfuric acid, nitric acid, and hydrogen-peroxide
water (e.g. BS EN 1122:2001)
Note: In the process of sample preparation, precipitates must be completely dissolved by some technical
means (e.g. alkali fusion).
2) Measurement methods Typical measurement methods are as follows. (1) Inductively Coupled Plasma-Atomic (Optical) Emission Spectroscopy (ICP-AES [ICP-OES]) (e.g. EN ISO 11885:1998) (2) Atomic Absorption Spectroscopy (AAS) (e.g. EN ISO 5961:1995) (3) Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS)
- If a combination of a sample preparation method and a measurement method can guarantee that the limit
of quantification for cadmium is less than 5 ppm, the combination is also applicable.
- Both cadmium and lead can be simultaneously analyzed by each of the measurement methods (except for
AAS) mentioned above.
Note: The extraction methods (including EN71-3:1994, ASTM F963-96a, ASTM F963-03, ASTM D 5517, and
ISO 8124-3) must not be applied to the sample preparation methods specified in this Standard.
When performing measurements based on JIS K 0102, Testing methods for industrial wastewater,
which refers only to measurement methods in section 55, sample preparation methods that are actually applied must be specified along with that JIS standard.
Substances: Lead and lead compounds
All metals, alloys, inorganic compounds, organic compounds, inorganic salts, organic salts, and other substances that contain lead
Effective date of the ban on the delivery
Banned since the establishment of this Standard
Banned since April 1, 2004
Level 1
Targets
- Packaging components and materials (See 4.2.1.)
- The paints, and inks containing lead, which are used for PWBs
- Surface coatings (plating) for the external electrodes, lead wires, and other areas of parts (e.g. electrical parts, semiconductor devices, and heat sinks)
- The stabilizers, pigments, and dyes contained in the plastic (including rubber) materials that are used for outer and exposed areas of the following articles: mice, devices, AC adaptors, connection cords, remote commanders, and power supply cords
- The paints and inks used for outer and exposed areas of devices
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Level 1
Level 3 - Electroless plating films such as electroless nickel plating and
Exemption - High melting temperature type solder (i.e. lead based alloys
All uses except those specified in Level 3 and Exemption Typical examples are given below:
- The surface coatings for the external electrodes, lead wires, etc. of the parts contained in AC adaptors, remote commanders, semiconductor devices, etc.
- Leaded solder that meets both of the following conditions: 1) lead content is less than 85 wt%; and 2) lead content is more than 1000 ppm
- All kinds of alloys (including solder materials) whose individual lead concentrations exceed their allowable ones provided in the table at the bottom of Exemption below. (*1)
- The stabilizers, pigments, and dyes contained in the plastic (including rubber) materials that are used for areas (excluding outer and exposed ones) of the following articles: mice, devices, AC adaptors, connection cords, remote commanders, and power supply cords
- The paints and inks used for areas other than the outer and exposed ones of devices
- Electroless plating films such as electroless nickel plating and electroless gold plating whose lead content is more than 1000 ppm
electroless gold plating whose lead content is 1000 ppm or less
containing 85 wt% or more)
- Electronic ceramic parts (e.g. piezoelectric devices, dielectric ones, and magnetic ones [ferrites])
- Optical glass, filter glass
- Glass of cathode ray tubes, glass of electronic components, and glass of fluorescent tubes
The above glass materials include adhesives, resistor elements, glass
frit, conductive pastes (silver or copper ones), and sealing materials.
- Solder consisting of more than two elements for the connection between the pins and the package of microprocessors with a lead content of more than 80 wt% and less than 85 wt%
- Solder to complete a viable electrical connection between semiconductor die and carrier within integrated circuit Flip Chip packages
(*1) Allowable lead concentrations
Banned since January 1, 2005
Banned since February 1, 2006
N/A
N/A
Type of alloy Allowable lead concentration
Steel up to 0.35 wt%
Aluminum alloy up to 0.4 wt%
Copper alloys (including brass and phosphor bronze)
Solder (*2) up to 1000 ppm
(*2) Allowable concentration of lead contained in conductive materials
of solder for anisotropic conductive film (ACF) and anisotropic conductive paste (ACP) should be less than 1000 ppm.
up to 4 wt%
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Test objects: plastics (including rubber), paints, and inks Allowable concentration: Less than 100 ppm
Standards for measurement
1) Sample preparation Typical sample preparation methods are as follows. (1) Incineration under the existence of sulfuric acid (2) A pressurized acid decomposition method done in a sealed container (a microwave decomposition
method [e.g. EPA 3052:1996, EN 13346:2000])
(3) An acid decomposition method under the existence of nitric acid, hydrogen-peroxide water, and
hydrochloric acid (e.g. EPA 3050B Rev.2:1996)
(4) A wet decomposition method under the existence of nitric acid and hydrogen-peroxide water
Note: In the process of sample preparation, precipitates must be completely dissolved by some technical
means (e.g. alkali fusion).
2) Measurement methods Typical measurement methods are as follows. (1) Inductively Coupled Plasma-Atomic (Optical) Emission Spectroscopy (ICP-AES [ICP-OES]) (e.g. EN ISO 11885:1998) (2) Atomic Absorption Spectroscopy (AAS) (e.g. EN ISO 5961:1995) (3) Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS)
- If a combination of a sample preparation method and a measurement method can guarantee that the limit
of quantification for lead is less than 30 ppm, the combination is also applicable.
- Both cadmium and lead can be simultaneously analyzed by each of the measurement methods (except for
AAS) mentioned above.
Note: The extraction methods (including EN71-3:1994, ASTM F963-96a, ASTM F963-03, ASTM D 5517, and
ISO 8124-3) must not be applied to the sample preparation methods specified in this Standard. EN 1122 is not applicable to the sample preparation methods for lead.
When performing measurements based on JIS K 0102, Testing methods for industrial wastewater, which refers only to measurement methods in section 54, sample preparation methods that are actually applied must be specified along with that JIS standard.
Substances: Mercury and mercury compounds
All metals, alloys, inorganic compounds, organic compounds, inorganic salts, organic salts, and other substances that contain mercury
Targets
Level 1
Exemption - Lamps other than small-sized fluorescent ones and straight-tube
- Packaging components and materials (See 4.2.1.)
- Paints, and inks
- Hour meters
- The relays, switches, or sensors whose contacts contain mercury
- Mercury or its compounds mixed in plastics
- Small-sized fluorescent lamps whose mercury content (per lamp) is 5 mg or more
- Straight-tube fluorescent lamps whose mercury content (per lamp) is 5 mg or more
- All uses except those specified in Exemption
fluorescent ones (e.g. high-pressure mercury lamps)
- Small-sized fluorescent lamps whose mercury content (per lamp) is less than 5 mg
- Straight-tube fluorescent lamps whose mercury content (per lamp) is less than 5 mg
Effective date of the ban on the delivery
Banned since the establishment of this Standard
Banned since January 1, 2005
N/A
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Substances: Hexavalent chromium compounds
All inorganic compounds, organic compounds, inorganic salts, organic salts, and other substances that contain hexavalent chromium
Targets
Level 1
Level 1 - All uses (e.g. capacitors, lubricants, insulating oils, transformers
Short-chain chlorinated paraffins with carbon chain length;10-13
Level 1
Level 3 - The plasticizers or flame retardants contained in plastics, and the flame
- Packaging components and materials (See 4.2.1.) Banned since the
- Constituents of parts or materials (e.g. inks, paints, additives, etc.)
- Residues in the surfaces of screws, steel sheets, etc. that are processed with plating or conversion coating
Substances: Polychlorinated biphenyls (PCB), polychlorinated naphthalenes (PCN), polychlorinated
terphenyls (PCT)
Targets
containing oil, paints, and flame retardants in plastics)
Substances: Short-chain chlorinated paraffins (SCCP)
Targets
- The cabinets of products (including accessories) and PWBs Banned since the
- All uses other than the above Banned since
Substances: Other chlorinated organic compounds
Targets
retardants used for PWBs
Effective date of the ban on the delivery
establishment of this Standard
Banned since January 1, 2005
Effective date of the ban on the delivery
Banned since the establishment of this Standard
Effective date of the ban on the delivery
establishment of this Standard
February 1, 2006
Effective date of the ban on the delivery
N/A
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Substances: Polybrominated biphenyls (PBB)
Targets
Level 1 - All uses (e.g. flame retardants contained in plastics) Banned since the
Substances: Polybrominated diphenylethers (PBDE) (including decabromodiphenyl ether [DecaBDE])
Targets
Level 1
Level 3 - The flame retardants contained in plastics, or used for PWBs N/A
Level 1 - All uses (e.g. paints, inks, preservatives, and fungicides) Banned since the
Level 1 - All uses (e.g. insulators and fillers) Banned since the
- All uses (e.g. flame retardants contained in plastics) Banned since the
- The parts manufactured using the molding dies, which were made in or before December 2002 (Applicable only to the bodies of the displays and TV sets shipped to countries and regions other than European ones)
The parts whose molding dies have been made since January 2003 must not contain PBDE.
Substances: Other brominated organic compounds
Targets
Substances: Tributyltin compounds (TBT) and triphenyltin compounds (TPT)
Targets
Substances: Asbestos
Targets
Effective date of the ban on the delivery
establishment of this Standard
Effective date of the ban on the delivery
establishment of this Standard
Banned since January 1, 2005
Effective date of the ban on the delivery
Effective date of the ban on the delivery
establishment of this Standard
Effective date of the ban on the delivery
establishment of this Standard
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Substances: Specific azo compounds
Azodyes that form any of the amine compounds listed in Table 4.2a through the decomposition methods cited in the EU Directive 76/769/EEC and amine compounds in Table 4.2a
Targets
Level 1 The substances which are used in parts or articles that may come into direct
and prolonged contact with the human skin (e.g. belts, straps, ear phones, head phones, and shoulder pads for bags)
Level 3 The parts or articles that do not come into continuous contact with the
human skin (e.g. cushions, mice, remote commanders, and carrying bags)
Test methods (for reference)
The methods for decomposing azo compounds and then extracting amines are as follows.
1) EN 14362-1:2003, “Textiles-Methods for the determination of certain aromatic amines derived from azo colorants
- Part 1: Detection of the use of certain azo colorants accessible without extraction
2) CEN ISO/TS 17234:2003, Leather-Chemical tests - Determination of certain azo colorants in dyed leathers
3) EN 14362-2:2003, “Textiles-Methods for the determination of certain aromatic amines derived from azo colorants
- Part 2: Detection of the use of certain azo colorants accessible by extracting the fibres
Table 4.2a List of specific amine compounds
Effective date of the ban on the delivery
Banned since the establishment of this Standard
N/A
CAS No. Amine compounds
92-67-1 4-aminodiphenyl 92-87-5 benzidine 95-69-2 4-chloro-o-toluidine 91-59-8 2-naphthylamine 97-56-3 o-aminoazotoluene 99-55-8 2-amino-4-nitrotoluene 106-47-8 p-chloroaniline 615-05-4 2,4-diaminoanisole 101-77-9 4,4’-diaminodiphenylmethane 91-94-1 3,3’-dichlorobenzidine 119-90-4 3,3’-dimethoxybenzidine 119-93-7 3,3’-dimethylbenzidine 838-88-0 3,3’-dimethyl-4,4’-diaminodiphenylmethane 120-71-8 p-cresidine 101-14-4 4,4’-methylene-bis-(2-chloroanilene) 101-80-4 4,4’-oxideaniline 139-65-1 4,4’-thiodianiline 95-53-4 o-toluidine 95-80-7 2,4-toluylenediamine 137-17-7 2,4,5-trimethylaniline 90-04-0 o-anisidine 60-09-3 4-aminoazobenzene
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Substance: Formaldehyde
Effective date of the ban on the delivery
Banned since the establishment of this Standard
Banned since January 1, 2005
Level 1
Targets
- The wooden products made from fiberboard, particleboard, or plywood, which are employed in products for import into Europe (e.g. speakers and racks)
- The wooden products made from fiberboard, particleboard, or plywood, which are employed in products for destinations other than Europe (e.g. speakers and racks)
Reference value (emission content): Obtain the value by any one of the following methods.
1) [With a chamber method] Concentration in the air: Equal to or less than 0.1 ppm (or 0.124 mg/m
3
) in an air-tight test chamber whose
volume is 12 m³, 1 m³, or 0.0225 m³
2) [With a perforator method]
- Equal to or less than 6.5 mg in 100 g of a particleboard without a surface treatment (the average value
during six months)
- Equal to or less than 7.0 mg in 100 g of a fiberboard without a surface treatment (the average value
during six months)
- Equal to or less than 8.0 mg in 100 g of a particleboard/fiberboard without a surface treatment (the
value derived from the one-time measurement based on EN120)
3) [With a desiccator method]
- Average content: 0.5 mg/l or less
- Maximum content: 0.7 mg/l or less (Use N=2 to check the average and maximum values.)
Measurement methods:
- A chamber method specified in EN 717-1:2004 (Wood based panels; determination of formaldehyde
release; formaldehyde emission by the chamber method)
- A perforator method specified in EN 120 (Wood based panels; determination of formaldehyde content;
extraction method called perforator method; EN 120:1992)
- A desiccator method specified in JIS A 5905 (Fibreboards) and JIS A 5908 (Particleboards)
Substances: Polyvinyl chloride (PVC) and PVC blends
Effective date of the ban on the delivery
Banned since before the establishment of
Level 1
Targets
- Substrates for FeliCa contactless IC cards * For reference, the targets have never contained PVC or PVC blends.
this Standard
- Coating agents and fabrics for the carrying bags, carrying cases, and carrying pouches, which are designed for use with personal computers, digital cameras, camcorders, and portable audio products (excluding
Banned since the establishment of this Standard
those for professional use)
- Cable ties used for accessories and connecting cords Banned since July 1,
2002
- Packaging components and materials to protect, contain, or transport products or supplied accessories (e.g. bags, adhesive tapes, cartons,
Banned since January 1, 2005
and blister packs)
- Heat shrink tubes Banned since April
1, 2005
- Flexible flat cables (FFC)
- Sheets and laminates used for exterior of wooden speakers
Banned since April 1, 2007
- Insulating plates, decorative panels, labels, sheets, and laminates
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Level 3
Exemption
SS-00259 (7th Edition) for General Use
Substances: Polyvinyl chloride (PVC) and PVC blends
Targets
- Connection cords for wearable equipment (e.g. cables for ear phones, head phones, and ear microphones)
- Coating for insulation and protection used for the inside or outside of devices, insulating tubes, carrying belts, spacers, holders, covers, ducts, etc.
- Power supply cords (including ones with some or all of the following: plugs, connectors, or cord bushes) designed for use in Japan, the U.S., and Canada (2P and 3P)
- Parts consisting of wires (e.g. connectors with cords) and wires used for internal wiring (e.g. motor leads)
- Connection cords (e.g. connection cords for USB or i.LINK, and video cords, AC adaptors secondary leads, flat wires, multi core cables, speaker cords, etc.)
- Harnesses and processing wires (e.g. coaxial cables, flat wires, double insulation wires, and shielded wires)
- Coating agents and fabrics for the carrying bags, carrying cases, and carrying pouches, which are designed for exclusive use with professional-electronics products
- Developing papers
- Insulation caps for capacitors, power supply switches, and fuses
- Trays, magazine sticks, reels, embossed carrier tapes used by parts suppliers for parts packaging
- Suction cups for mounting in-vehicle products
- Wiring clip used for the inside of devices (made of polyvinyl chloride-coated metal)
Other parts except those classified into Levels 1 and Exemption
- Binder for resins
- Polyvinyl electrical wires for high voltage
- Insulating tapes
- Speaker grilles
- Power supply cords designed for use in countries and regions other than Japan, the U.S., and Canada
- Parts that are not classified into Levels 1 and 3, and are composed of vinyl chloride copolymers or blends of PVC and other polymers
- Transformer leads whose joint is fixed by varnish impregnation
- Curl cords
- Extra fine electrical wires that are AWG (American Wire Gauge) 36 or more
- Professional cables for which general-purpose ones cannot be substituted (e.g. cables for broadcast cameras and microphone cables)
Effective date of the ban on the delivery
N/A
N/A
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Substances: Beryllium oxide
Targets
Level 1 - All uses except those specified in Level 3 April 1, 2008
Level 3 - Specific uses which have no alternative materials
Substances: Beryllium copper
Targets
Level 3 - All uses N/A
Substances: Specific phthalates (DEHP, DBP, BBP, DINP, DIDP, DNOP, DNHP)
All Specific phthalates in Table 4.2b
Targets
Level 3 - Plasticizer in polyvinyl chloride resin used for cable coating, cord coating,
plugs and connecters
Table 4.2b List of specific phthalates (phthalic esters)
Effective date of the ban on the delivery
Effective date of the ban on the delivery
Effective date of the ban on the delivery
N/A
Abbreviation CAS No. Specific phthalates
DEHP 117-81-7 Di (2-ethylhexyl) phthalate
DBP 84-74-2 Di-n-butyl phthalate
BBP 85-68-7 Butyl benzyl phthalate
DINP
DIDP
DNOP 117-84-0 Di-n-octyl phthalate
DNHP 84-75-3 Di-n-hexyl phthalate
Substances: Hydrofluorocarbon (HFC), Perfluorocarbon (PFC)
Level 1 - All uses installed into product (e.g. refrigerant and insulation) Banned since April
28553-12-0 68515-48-0
26761-40-0 68515-49-1
Targets
Diisononyl phthalate (technical mixture)
Diisodecyl phthalate (technical mixture)
Effective date of the ban on the delivery
1, 2008
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Level 1
Exemption
Level 1
SS-00259 (7th Edition) for General Use
Substances: Perfluorooctane sulfonates (PFOS)
Targets
- Materials whose PFOS concentration is 0.1 wt% or more
- Textiles or other coated materials whose amount of PFOS is 1 µg/m
2
or more of the coated material
Typical examples are given below:
- Electroplating, paint, colorant, dye, materials coated with water repellant agent, oil repellant agent, antifouling agent (e.g. textile, film, paper, leather), fluoropolymer coating, adhesive, and sealant
- Photographic coatings applied to films, papers, or printing plates
- Photoresists or anti reflective coatings for photolithography processes
Substance: Specific benzotriazole
2-(3',5'-Di-tert-butyl-2'-hydroxyphenyl)benzotriazole (CAS No. 3846-71-7)
Targets
Ultraviolet protectants and ultraviolet absorbers applied to decorative laminate, developing papers, molded plastic parts
Effective date of the ban on the delivery
Banned since April 1, 2008
Effective date of the ban on the delivery
Banned since April 1, 2008
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4.2 Additional rules for packaging components and materials
4.2.1 Definition of “packaging components and materials”
Packaging components and materials are defined as products made from any materials and components of any nature to be used for the containment, protection, handling, delivery and presentation of goods, from raw materials to processed goods from the producer to the user or consumer. Note: The definition excludes the components and materials for the returnable boxes, which are reused
or recycled under the control of carriers or parts suppliers, and are not disposed of by end-users or Sony.
Table 4.3 Additional rules for packaging components and materials
Substances: Heavy metals (cadmium, lead, mercury, and hexavalent chromium)
Articles that satisfy not only the rules specified in Table 4.2, but also the following conditions determined by the regulations of relevant laws
Targets
Level 1 - All packaging components and materials
Some examples are given in PACKAGING of Table 4.3a.
Effective date of the ban on the delivery
Banned since the establishment of this Standard
Exemption - Cartons for returnable boxes owned by carriers or parts suppliers N/A
Allowable concentrations
- Less than 100 ppm is determined as the allowable total-concentration of four heavy metals (cadmium, lead, mercury, and hexavalent chromium) contained in each part, ink, or paint that constitutes a package. Regarding allowable concentrations of cadmium and lead contained in plastics (including rubber), paints, and inks, however, regulations for Cadmium and cadmium compounds and Lead and lead compounds must also be satisfied.
(Typical plastic parts: handles, cushions, films, reels, adhesive tapes, magazine sticks [including stoppers],
polyvinyl bags, bands, and trays)
For hexavalent chromium:
1) First analyze total chromium content and verify that the total concentration of cadmium, lead, mercury and total chromium is less than 100 ppm. When analyzing, the same sample preparation methods as those used for cadmium and lead are applicable.
2) If this total concentration is more than 100 ppm, verify that the sum of the cadmium, lead and mercury concentration is less than the 100 ppm limit. When the sum of the cadmium, lead and mercury concentration is less than the 100 ppm limit, analyze and confirm that no hexavalent chromium is present, using the standard methods for detecting hexavalent chromium provided in Table4.3.
Standards for four heavy metals measurement
1) Sample preparation For cadmium and lead, follow the methods respectively specified in Table 4.2 ( For total chromium, follow the methods specified in Table 4.2 (
*
3).
*
3) (*4).
For mercury, typical test methods are as follows.
(1) A pressurized acid decomposition method done in a sealed container (a microwave decomposition
method [e.g. EPA 3052:1996])
(2) A heating evaporation-cold-vapor mercury-atomic-absorption method (Full-automatic test
equipment is marketed.)
(3) A wet decomposition method (e.g. Kjeldahl method) in which a decomposition flask with a reflux
condenser is used to decompose mercury by sulfuric acid or nitric acid
Note: In the process of sample preparation, particular attention is required to avoid mercury
sublimation, and precipitates must be completely dissolved by some technical means.
2) Measurement methods Regarding the measurement of cadmium; lead; and total-chromium concentrations, follow the
methods specified in Table 4.2 (
Regarding the measurement of mercury concentrations, follow the same methods as cadmium and
lead specified in Table 4.2 (
*
3) (*4).
*
3) (*4).
When the mercury concentration is predicted to be low, you are advised to use one of the following
methods. (1) A reduction-evaporation atom-absorption method (2) ICP-AES (ICP-OES) method with a hydride-generation apparatus (3) ICP-MS method with a hydride-generation apparatus
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Standard methods for detecting hexavalent chromium: Note: Standard methods specified hereafter are applicable when total concentration of the four elements of
cadmium, lead, mercury, and total chromium in packaging components and materials is 100 ppm or more.
Detection methods:
1) Sample preparation
- Extraction methods such as boiling water extraction and alkaline extraction (e.g. EPA 3060A)
2) Measurement method
- Ultraviolet-Visible (UV/VIS) Spectroscopy (e.g. EPA 7196A)
- If a combination of a sample preparation method and a measurement method can guarantee the following limits of quantification, the combination is also available.
(1) Less than 5 ppm for mercury (2) Less than 5 ppm for cadmium (3) Less than 5 ppm for the total chromium (4) Less than 30 ppm for lead
- Cadmium, lead, and total chromium can be simultaneously analyzed by each of the measurement methods (except for AAS).
(*3) Refer to Test objects: plastics (including rubber), paints, and inks,” “Substances: Cadmium and
cadmium compounds, in Table 4.2 Main Targets and Effective date of the ban on the delivery regarding Controlled Substances.’”
*
(
4) Refer to Test objects: plastics (including rubber), paints, and inks,” “Substances: Lead and lead compounds, in Table 4.2 Main Targets and Effective date of the ban on the delivery regarding Controlled Substances.’”
Table 4.3a Illustrative examples of PACKAGING components/materials and NOT PACKAGING
components/materials
Note: The following lists provide some examples of the products, which we categorize as “packaging” as well
as not packaging, to serve as a reference. They are not intended to include all products in both categories.
For consumer- and professional-electronics products (used for transporting Sony electronics products)
PACKAGING
1. Carton Including master carton and sub-master carton made from any materials.
2. Cushion
3. Protection bag, protection sheet Such as made from foamed plastic or nonwoven fabric
4. Plastic bag
5. Envelope Such as used for warranty card
6. Blister pack
7. Film Including protection films such as used for the LCD displays
8. Clamshell
9. Separator, spacer, partition
10. Printing ink Used for packaging components
11. Adhesive tape
Such as used for closing carton or poly bag, or, fixing or protection for removable component
12. Staple
13. Label
Attached to the packaging components under control of Sony, such as bar-code label
14. Joint Carton joint
15. Band Such as PP band
16. Hanging tab
17. Carrying handle Including its related components
18. Crate Such as wooden frame
19. Shrink film
20. Bottle
21. Sleeve
22. Jewel box Such as packaging for fountain pen
23. Skid
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NOT PACKAGING
1. CD case, CD bag
2. Inlay card, inlay label
Carrying case,
3. carrying pouch
4. Label
Cases or bags such as used for video tape, MD, MO, DVD and spindle case which are defined as part of product
Such as index-card or label for CD and other recording media which are defined as part of product
®
Such as used for headphones, camera, and walkman
, which are defined as
part of product
Labels attached to products and others except those attached to packaging components and materials
5. Label Labels attached by third parties such as cargo label and/or invoice
For devices, semiconductors, and any other components
PACKAGING
1. Magazine stick Such as used for IC
2. Stopper
3. Tray
4. Reel
For physical distribution
PACKAGING
1. Pallet
Made from wood, plastic, paper, etc. which is used in one-way transportation, including slip sheet.
2. Crate Such as wooden container
3. Stretch film Wrap around palletized unit
4. Wooden container
Items used for over
5. packaging
Such as carton, cushion, adhesive tape, etc. which is used for component delivery
6. Band, string Such as PP band
NOT PACKAGING
Shipping container, air
1. container
Such as 40 ft container for boat, and air cargo container
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4.3 Rules for batteries (Applicable to all batteries in commercial distribution)
4.3.1 Definitions of “Battery,” “Battery pack,” and “Button cell” in this Technical Standard
“Battery” means any source of electrical energy generated by direct conversion of chemical energy and consisting of one or more primary battery cells (non-rechargeable) or consisting of one or more secondary battery cells (rechargeable). “Battery Pack” means any set of batteries that are connected together and/or encapsulated within an outer casing so as to form a complete unit that the end-user is not intended to split up or open. “Button Cell” means any small round portable battery whose diameter is greater than its height and which is used for special purposes such as hearing aids, watches, small portable equipment and back-up power. Battery cells used for “ Battery packs” shall be compliant with the rules specified in Table 4.4, because they are identified as “Battery.” For “Batteries” and “Battery packs” follow the standards specified in Section 4.1 and 4.2 also.
Table 4.4 Rules for batteries
Substances: Heavy metals (cadmium, lead, and mercury)
All metals, alloys, inorganic compounds, organic compounds, inorganic salts, organic salts, and other substances that contain cadmium, lead, and mercury
Effective date of the ban on the delivery
Banned since January 1, 2007
Banned since January 1, 2008
Banned since January 1, 2005
Level 1
Targets
- NiCd batteries
Cd
- “Batteries” whose cadmium content, in proportion to the total weight of each one, is 20 ppm or more
- “Battery packs” whose cadmium content, in proportion to the total weight of each one, is 20 ppm or more
- “Batteries“ whose lead content, in proportion to the total
Pb
weight of each one, is 0.4% or more
- “Battery packs” whose lead content, in proportion to the total weight of each one, is 0.4% or more
- Carbon zinc batteries and alkaline batteries whose lead content, in proportion to the total weight of each one, is 0.2% or more
- Button cell batteries whose mercury content, in proportion to
Hg
the total weight of each one, is 2% or more
- The following batteries and battery packs except button cell batteries
“Batteries” whose mercury content, in proportion to the total weight of each one, is 0.0005% or more
“Battery packs” whose mercury content, in proportion to the total weight of each one, is 0.0005% or more
- Carbon zinc batteries and alkaline batteries whose mercury content, in proportion to the total weight of each one, is
0.0001% or more
(*5) The use of those batteries in Argentina has banned since January 29, 2007 in accordance with Argentina
regulations on batteries.
(*6) The use of those batteries in China has banned since January 1, 2005 in accordance with the Chinese
regulation “1997 Regulation on Mercury Content Limitation for Batteries.”
Banned since April 1, 2008 (*5)
Banned since the establishment of this Standard
Banned since April 1, 2008 (*6)
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APPENDIXES
1. MAJOR CONTROLLED SUBSTANCES, AND EXAMPLES OF APPLICABLE LAWS AND REGULATIONS
2. DETAILS OF MAJOR CONTROLLED SUBSTANCES (TYPICAL EXAMPLES)
- Cadmium and cadmium compounds
- Lead and lead compounds
- Mercury and mercury compounds
- Hexavalent chromium compounds
- Polychlorinated biphenyls (PCB), polychlorinated naphthalenes (PCN), polychlorinated terphenyls (PCT)
- Short-chain chlorinated paraffins (SCCP)
- Polybrominated biphenyls (PBB)
- Polybrominated diphenylethers (PBDE)
- Tributyltin compounds (TBT) and triphenyltin compounds (TPT)
- Asbestos
- Formaldehyde
- Polyvinyl chloride (PVC) and PVC blends
- Beryllium oxide
- Hydrofluorocarbon (HFC), Perfluorocarbon (PFC)
- Perfluorooctane sulfonates (PFOS)
- Specific benzotriazole
Disclaimer: Applicable laws and regulations, and controlled substances in Appendixes 1 and 2 are
illustrative only, not all the substances and its alias name are listed.
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1. MAJOR CONTROLLED SUBSTANCES, AND EXAMPLES OF APPLICABLE LAWS AND REGULATIONS
Note: This information is confirmed as of March 2008. The laws and regulations cited herein are subject to
change, and it is essential to consult the latest editions of the relevant laws and regulations.
Substances Laws and regulations
Cadmium and cadmium compounds
Lead and lead compounds
Mercury and mercury compounds
compounds
Polychlorinated biphenyls (PCB) Polychlorinated naphthalenes (PCN) Polychlorinated terphenyls (PCT)
Short-chain chlorinated paraffins (SCCP)
Polybrominated biphenyls (PBB)
Polybrominated diphenylethers (PBDE)
Tributyltin compounds (TBT) Triphenyltin compounds (TPT)
Specific azo compounds European Union. EU Directive 76/769/EEC and its amendments.
European Union. EU Directive 76/769/EEC and its amendments.
European Union. EU Directive 91/338/EEC and its amendments.
European Union. RoHS Directive 2002/95/EC and its amendments.
European Union. Batteries Directive 2006/66/EC.
Switzerland. Ordinance on Risk Reduction related to Chemical Products (ORRChem).
European Union. RoHS Directive 2002/95/EC and its amendments.
European Union. Batteries Directive 2006/66/EC.
Switzerland. Ordinance on Risk Reduction related to Chemical Products (ORRChem).
Denmark: Statutory Order No. 1012 and its amendments.
Argentina. The Law No.26.184 Portable Power and Resolution 14/2007.
European Union. RoHS Directive 2002/95/EC and its amendments.
European Union. Batteries Directive 2006/66/EC.
China. 1997 Regulation on Mercury Content Limitation for Batteries.
China. Inspection and Management Methods for the Import and Export of Battery Products Containing Mercury. (English translation by EIA)
European Union. RoHS Directive 2002/95/EC and its amendments. Hexavalent chromium
Switzerland. Ordinance on Risk Reduction related to Chemical Products (ORRChem).
European Union. EU Directive 76/769/EEC and its amendments.
Japan. Law Concerning the Examination and Regulation of Manufacture, etc. of Chemical Substances, Class I.
Norway. Regulations relating to restrictions on the use, etc. of certain dangerous chemicals.
European Union. EU Directive 76/769/EEC and its amendments.
European Union. RoHS Directive 2002/95/EC and its amendments.
Switzerland. Ordinance on Risk Reduction related to Chemical Products (ORRChem).
European Union. EU Directive 76/769/EEC and its amendments.
European Union. RoHS Directive 2002/95/EC and its amendments.
Switzerland. Ordinance on Risk Reduction related to Chemical Products (ORRChem).
Japan. Law Concerning the Examination and Regulation of Manufacture, etc. of Chemical Substances, Class I and Class II.
Japan. Industrial Safety and Health Law. Asbestos
Germany. Chemicals Prohibition Ordinance. (German abbreviation: ChemVerbotsV)
Formaldehyde
Germany. Chemicals Prohibition Ordinance. (German abbreviation: ChemVerbotsV)
Denmark: Statutory Order No. 289.
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Substances Laws and regulations
Heavy metals (lead, cadmium, mercury, and hexavalent chromium)
Beryllium oxide European Union. WEEE Directive 2002/96/EC and EU Directive 1999/45/EC
Hydrofluorocarbon (HFC), Perfluorocarbon (PFC)
Perfluorooctane sulfonates (PFOS)
Specific benzotriazole Japan. Law Concerning the Examination and Regulation of Manufacture of
European Union. EU Directive 94/62/EC on packaging and packaging waste and its amendments.
New York State and other 15 states in the United States. Regulations on Heavy Metals in Packaging Materials.
European Union. REGULATION 2006/842/EC.
Denmark: Statutory Order No. 552.
Switzerland. Ordinance on Risk Reduction related to Chemical Products (ORRChem).
European Union. EU Directive 76/769/EEC and its amendments.
Chemical Substances, Class I.
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2. DETAILS OF MAJOR CONTROLLED SUBSTANCES (TYPICAL EXAMPLES)
•••• Cadmium and cadmium compounds
1. Examples
Name CAS No. Chemical formula Applications
Cadmium 7440-43-9 Cd Connection materials, surface treatment
NiCd batteries
Cadmium alloys Low melting point solder, fuses, etc.
Cadmium oxide 1306-19-0 CdO Pigments, alkaline batteries, and materials
for chemical synthesis
Cadmium chloride
Cadmium sulfide 1306-23-6;
Cadmium nitrate 10325-94-7 Cd(NO3)2 Coloring agents, batteries, and
Cadmium nitrate tetrahydrate
Cadmium sulfate 10124-36-4 CdSO4 Cadmium standard cells, reagent
Cadmium stearate
Other cadmium compounds
10108-64-2 CdCl2 Plating bath, polyvinyl chloride stabilizers
CdS Pigments, paints, inks, and light receiving
8048-07-5
10022-68-1 Cd(NO3)2 · 4H2O
2223-93-0 Cd(C18H35O2)2 Polyvinyl chloride stabilizers
elements for semiconductors
photographs
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•••• Lead and lead compounds
1. Examples
Name CAS No. Chemical formula Applications
Lead; metal 7439-92-1 Pb
Lead -tin alloy Pb-Sn Solder, brazing materials, and electric
contact
Lead (II) oxide 1317-36-8 PbO Pigments, rubber vulcanization
accelerators, and solid lubricants
Lead (IV) oxide 1309-60-0 PbO2 Lead-acid batteries, rubber curing agents,
and materials for pigments
Dilead trioxide 1314-27-8 Pb2O3
Lead (II, IV) oxide 1314-41-6 Pb3O4 Pigments, lead-acid batteries, glass, and
paints
Lead azide 13424-46-9 PbN6
Lead (II) fluoride 7783-46-2 PbF2 Special optical glass, pigments
Lead (II) chloride 7758-95-4 PbCl2
Lead (IV) chloride 13463-30-4 PbCl4
Lead (II) iodide 10101-63-0 PbI2 Bronze, printing, and photographs
Lead (II) sulfide 1314-87-0 PbS Infrared ray detectors in which
semiconductor elements are utilized
Lead (II) cyanide 592-05-2 Pb(CN)2 Antirust pigments
Lead tetrafluoro borate
Lead hexa fluorosilicate
Lead nitrate 10099-74-8 Pb(NO3)2 Optical glass
Lead carbonate 598-63-0 PbCO3
Lead hydroxycarbonate
Lead perchlorate 13637-76-8 Pb(CIO4)2
Lead (II) sulfate 7446-14-2;
Lead oxide sulfate
Lead (II) phosphate
Lead thiocyanate 592-87-0 Pb(SCN)2 Stain, matches
Lead (II) acetate, trihydrate
Lead (II) acetate 301-04-2 Pb(CH3COO)2
Lead (IV) acetate 546-67-8 Pb(CH3COO)4
13814-96-5 Pb(BF4)2 Plating bath, anticorrosive surface
treatment
25808-74-6 PbSiF6 Plating bath, lead refinement
1344-36-1 (PbCO3)2Pb(OH)2 Pigments, polyvinyl chloride stabilizers
PbSO4 Pigments, rubber compounding
15739-80-7
12202-17-4 Pb4SO7 Pigments
7446-27-7 Pb3(PO4)2 Stabilizers for plastics
6080-56-4 Pb(CH3COO)2 · 3H2O
ingredients, polyvinyl chloride stabilizers, and batteries
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Name CAS No. Chemical formula Applications
Lead oleate 1120-46-3 Pb[CH3(CH2)7CH=
CH(CH
COO]2
2)7
Lubricants, curing agents, etc.
Lead stearate 7428-48-0 Pb(C17H35COO)2 Lubricants, polyvinyl chloride stabilizers
Lead (II)
10214-39-8 Pb(BO2)2 · H2O Desiccants for paints
metaborate
Lead metasilicate 11120-22-2;
PbSiO3 Ceramics
10099-76-0
Lead antimonite 13510-89-9 Pb3(SbO4)2 Pigments, coloring agents for glass
Lead arsenate
7784-40-9 PbHAsO4
(1:1)
Lead (II) arsenite 10031-13-7 Pb(AsO2)2 Pesticides
Lead chromate;
1344-37-2 PbCrO4 Pigments, paints, and inks
chrome yellow
Lead molybdate 10190-55-3 PbMoO4 Pigments
Calcium plumbate 12013-69-3 Ca2PbO4 Oxidizers
Tetramethyl lead 75-74-1 Pb(CH3)4
Tetraethyl lead 78-00-2 Pb(C2H5)4
Other lead compounds and alloys
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•••• Mercury and mercury compounds
1. Examples
Name CAS No. Chemical formula Applications
Mercury 7439-97-6 Hg Electrodes, mercury lamps
Mercury alloys; amalgam
Mercury (I) oxide 15829-53-5 Hg2O
Mercury (II) oxide 21908-53-2 HgO Mercury cells, preservatives
Mercury (I) chloride
Mercury (II) chloride
Mercury (II) nitrate
Mercury (I) sulfate 7783-36-0 Hg2SO4 Batteries
Mercury (II) fulminate
Mercury (II) acetate
Methylmercury salts
Ethymercury salts C2H5HgX;
Propylmercury salts
Phenylmercury salts
Methoxyethyl­mercury salts
Dialkylmercury R2Hg;
Diphenylmercury 587-85-9 (C6H5)2Hg
Other mercury compounds
10112-91-1 Hg2Cl2 Electrodes, pigments
7487-94-7 HgCl2 Metal etching, batteries, and preservatives
10045-94-0 Hg(NO3)2 Felt, catalysts
628-86-4 Hg(ONC)2
1600-27-7 Hg(CH3COO)2
e.g. 22967-92-6
CH3HgX; X=Cl, Br, I, OH, etc.
Fungicides
Preservatives, disinfectants
X=Cl, Br, I, OH, etc.
C
3H7
HgX;
X=Cl, Br, I, OH, etc.
C
6H5
HgX;
Preservatives, disinfectants
X=Cl, Br, I, OH, etc.
CH3OC2H4HgX;
Disinfectants, fungicides
X=Cl, Br, I, OH, etc.
R=alkyl group
nH2n+1
)
(C
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•••• Hexavalent chromium compounds
Note: Only substances containing hexavalent chromium compounds belong to this category.
1. Examples
Name CAS No. Chemical formula Applications
Chromium (VI) oxide; Chromium trioxide
Lithium chromate 14307-35-8 Li2CrO4 Antirust
Sodium chromate 7775-11-3 Na2CrO4 Antirust, tanning
Potassium chromate 7789-00-6 K2CrO4 Pigments, inks, and tanning
Patassium chlorochromate
Ammonium chromate 7788-98-9 (NH4)2CrO4 Photographs, catalysts
Copper chromate 13548-42-0 CuCrO4 Mordants
Magnesium chromate 13423-61-5 MgCrO4 Antirust, surface treatment
Calcium chromate 13765-19-0 CaCrO4 Pigments, inks, and tanning
Strontium chromate 7789-06-2 SrCrO4 Pigments, antirust
Barium chromate 10294-40-3 BaCrO4 Pigments, antirust, and coloring agents for
Lead chromate; Chrome yellow
Zinc chromate 12018-19-8;
Sodium dichromate; Sodium bichromate
Potassium dichromate; Potassium bichromate
Ammonium dichromate; Ammonium bichromate
Calcium dichromate; Calcium bichromate
Zinc dichromate; Zinc bichromate
Other hexavalent chromium compounds
1333-82-0 CrO3 Pigments, catalysts, plating, and tanning
16037-50-6 K[CrO3Cl]
ceramics
1344-37-2 PbCrO4 Pigments, paints, and inks
ZnCrO4 Pigments, anticorrosives 13530-65-9; 14018-95-2
10588-01-9 Na2Cr2O7 Pigments, photographs, tanning, and
antirust
7778-50-9 K2Cr2O7 Pigments, photographs, batteries, plating,
and tanning
7789-09-5 (NH4)2Cr2O7 Pigments, photographs, and catalysts
14307-33-6 CaCr2O7 Catalysts, antirust
ZnCr2O7 Pigments
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•••• Polychlorinated biphenyls (PCB), polychlorinated naphthalenes (PCN), polychlorinated
terphenyls (PCT)
1. Examples
Name CAS No. Chemical formula Applications
PCB; Polychlorinated biphenyls
PCN; Polycholorinated
1336-36-3 C12H
10-xCIx
(x = 1 – 10)
C
10H8-xCIx
(x
3)
Lubricants, heating mediums, and oils for capacitors
Lubricants, preservatives, and paints
naphthalenes
Trichloronaphthalenes 1321-65-9 C10H5Cl3
Tetrachloronaphthalenes 1335-88-2 C10H4Cl4
Pentachloronaphthalenes 1321-64-8 C10H3Cl5
Octachloronaphthalenes 2234-13-1 C10Cl8
PCT; Polychlorinated terphenyls
61788-33-8 C18H14-xClx
(x = 1 – 14)
Lubricants, preservatives, and paints
•••• Short-chain chlorinated paraffins (SCCP)
1. Examples
Name CAS No. Chemical formula Applications
Short-chain Chlorinated
e.g. 85535-84-8 Plasticizers, flame retardants
paraffins C10-13
•••• Polybrominated biphenyls (PBB)
1. Examples
Name CAS No. Chemical formula Applications
Polybrominated biphenyls; PBB
e.g. 67774-32-7 C12H
(x = 1 – 10)
10-xBrx
Flame retardants
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•••• Polybrominated diphenylethers (PBDE)
1. Examples
Name CAS No. Chemical formula Applications
Polybromodiphenyl ether; Polybromodiphenyloxide; Polybrominated biphenyl ethers; PBDE; PBDO; PBBE
Decabromodiphenyl ether; Decabromodiphenyloxide; DBDE; DecaBDE; DBDPE; DBDPO
Octabromodiphenyl ether; Octabromodiphenyloxide; OBDE; OctaBDE
Hexabromodiphenyl ether; Hexabromodiphenyloxide
Pentabromodiphenyl ether; Pentabromodiphenyloxide; PentaBDE
C
1163-19-5 C12Br10O Flame retardants (for PE, ABS, and
32536-52-0 C
36483-60-0 C12H4Br6O Flame retardants
32534-81-9 C
12H10-xBrx
O
(x = 1 – 10)
O Flame retardants (for ABS, HIPS,
12H2Br8
O Flame retardants
12H5Br5
SS-00259 (7th Edition) for General Use
Flame retardants
polyester)
and LDPE)
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•••• Tributyltin compounds (TBT) and triphenyltin compounds (TPT)
Note: Only tributyltin compounds and triphenyltin compounds belong to this category. Dibutyltin compounds (DBT), diphenyltin compounds (DPT), metal tin, tin alloys, tin plating, and tin
inorganic compounds do not fall under this category.
1. Examples
Name CAS No. Chemical formula Applications
Tributyltin bromide 1461-23-0 (C4H9)3SnBr Disinfectants
Tributyltin oxide; Bis (tributyltin) oxide;
Distannoxane, hexabutyl-
Triphenyl tin 668-34-8 (C6H5)3Sn Disinfectants
Triphenyltin chloride; Fentin chloride; Stannane, chlorotriphenyl-
Triphenyltin hydroxide; Fentin hydroxide; Stannane, hydroxytriphenyl-
Triphenyltin N, N –dimethyldithiocarbamate;
Stannane, [[(dimethylamino) thiomethyl] thio] triphenyl-
Triphenyltin fluorid; Fentin fluoride
Triphenyltin acetate; Fentin acetate; Stannane, (acetyloxy) triphenyl-
Triphenyltin fatty acid salts Note: The triphenyltin fatty acid
salts specified here are limited to those with a 9-, 10-, or 11-carbon chain.
56-35-9 C24H54OSn2 Disinfectants
639-58-7 (C6H5)3SnCl Disinfectants
76-87-9 (C6H5)3SnOH Disinfectants
1803-12-9 (C6H5)3Sn(CH3)2NCS2
379-52-2 (C6H5)3SnF
900-95-8 (C6H5)3SnOCOCH3
18380-71-7; 18380-72-8; 47672-31-1; 94850-90-5
Copyright 2008 Sony Corporation
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SS-00259 (7th Edition) for General Use
Name CAS No. Chemical formula Applications
Triphenyltin chloroacetate;
7094-94-2 (C
SnOCOCH2Cl
6H5)3
(chloroacetoxy) triphenylstannane
Tributyltin methacrylate;
2155-70-6 (C4H9)3SnC4H5O2
Tributyl (methacryloyloxy) stannane;
Stannane, tributyl [(2-methyl-1-oxo-2-propenyl) oxy]-
Bis (tributyltin) fumarate 6454-35-9;
24291-45-0
Tributyltin fluoride 1983-10-4;
C2H2(COO)
2
([C4H9]3Sn)2
(C4H9)3SnF
7304-48-5
Bis (tributyltin) 2, 3-dibromosuccinate
31732-71-5; 56323-17-2
([C4H9]3Sn)2C2H (BR)2(COO)2
2
Tributyltin acetate 56-36-0 (C4H9)3SnOCOCH3
Tributyltin laurate;
3090-36-6 (C4H9)3SnC12H23O2
Tributyl (lauroyloxy) stannane
Bis (tributyltin) phthalate; [(Phthaloylbis (oxy)] bis
4782-29-0 (C6H4)(COO)
([C4H9]3Sn)2
2
(tributylstannane)
Tributyltin sulfamate;
6517-25-5 (C4H9)3SnSO3NH2
Stannane, [(aminosulfonyl) oxy] tributyl-
Bis (tributyltin) maleate 14275-57-1;
C28H56O4Sn2
24291-45-0
Tributyltin chloride; Tributylchlorostannane;
1461-22-9; 7342-38-3
(C4H9)3SnCl
Stannane, tributylchloro-
Copyright 2008 Sony Corporation
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Page 34
Name CAS No. Chemical formula Applications
Mixture of tributyltin 1,2,3,4,4a,4b,5,6,10,10a-decahydro-7-i sopropyl-1,4a-dimethyl-1-phenanthlene carboxylate and its analogs; Tributyltin rosin salt
[1R-(1alpha,4a.beta.,4b.alpha.,10a.alp ha.)]-tributyl [[[1,2,3,4,4a,4b,5,6,10,10a-decahydro­7-isopropyl-1,4a-dimethyl-1-phenanthry l]carbonyl] oxy] stannane
Octyl acrylate-methyl methacrylate-tributyltin methacrylate copolymer (alkyl; C = 8)
SS-00259 (7th Edition) for General Use
85409-17-2
26239-64-5 C32H56O2Sn
67772-01-4
Copyright 2008 Sony Corporation
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Page 35
SS-00259 (7th Edition) for General Use
•••• Asbestos
1. Examples
Name CAS No. Chemical formula Applications
Asbestos 1332-21-4;
132207-32-0; 132207-33-1
Crocidolite 12001-28-4 Na2Fe5(Si8O22)(OH)2 Insulators, fillers
Chrysotile 12001-29-5 Mg3Si2O5(OH)4 Insulators, fillers
Amosite 12172-73-5 (Mg, Fe)7Si8O22(OH)2 Insulators, fillers
Anthophyllite 77536-67-5 (Mg, Fe)7Si8O22(OH)2 Insulators, fillers
Tremolite 77536-68-6 Ca2Mg5Si8O22(OH)2 Insulators, fillers
Actinolite 77536-66-4 Ca2(Mg, Fe)5Si8O22(OH)2 Insulators, fillers
Insulators, fillers
•••• Formaldehyde
1. Examples
Name CAS No. Chemical formula Applications
Formaldehyde; formalin; formic aldehyde; formol
50-00-0 CH2O Preservatives, monomer (e.g.
phenol resin and melamine resin)
•••• PVC and PVC blends
1. Examples
Name CAS No. Chemical formula Applications
PVC and PVC blends; Polyvinyl chloride and polyvinyl chloride blends
e.g. 9002-86-2 Polyvinyl chloride resin
•••• Beryllium oxide
1. Examples
Name CAS No. Chemical formula Applications
Beryllium oxide e.g. 1304-56-9 BeO Heat sink
Copyright 2008 Sony Corporation
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Page 36
SS-00259 (7th Edition) for General Use
•••• Hydrofluorocarbon (HFC), Perfluorocarbon (PFC)
1. Examples
Name CAS No. Chemical
formula
HFC-23;
75-46-7 CHF3 Refrigerant
Trifluoromethane
HFC-32;
75-10-5 CH2F2 Refrigerant
Difluoromethane
HFC-41;
593-53-3 CH3F Refrigerant
Fluoromethane
HFC-125; Pentafluoroethane 354-33-6 C2HF5 Refrigerant
HFC-134;
359-35-3 CHF2CHF2 Refrigerant
1,1,2,2-tetrafluoroethane
HFC-134a;
811-97-2 CH2FCF3 Refrigerant
1,1,1,2-tetrafluoroethane
HFC-143; 1,1,2-trifluoroethane 430-66-0 CHF2CH2F Refrigerant
HFC-143a; 1,1,1-trifluoroethane 420-46-2 CH3CF3 Refrigerant
HFC-152a; 1,1-difluoroethane 75-37-6 CH3CHF2 Refrigerant
HFC-227ea;
431-89-0 C3HF7 Extinguishing agent
1,1,1,2,3,3,3-heptafluoropropane
HFC-236fa;
690-39-1 C3H2F6 Extinguishing agent
1,1,1,3,3,3-hexafluoropropane
HFC-245ca;
679-86-7 C3H3F5 Refrigerant
1,1,2,2,3-pentafluoropropane
HFC-43-10mee;
138495-42-8 C
Solvent
5H2F10
1,1,1,2,3,4,4,5,5,5-decafluoropent ane
PFC-14; Perfluoromethane 75-73-0 CF4 Dry etching
PFC-116; Perfluoroethane 76-16-4 C2F6 Refrigerant
PFC-218; Perfluoropropane 76-19-7 C3F8 Refrigerant
PFC-31-10; Perfluorobutane 355-25-9 C4F10 Extinguishing agent
PFC-c318; Perfluorocyclobutane 115-25-3 c-C4F8 Dry etching
PFC-41-12; Perfluoropentane 678-26-2 C5F12 Solvent
PFC-51-14; Perfluorohexane 355-42-0 C6F14 Refrigerant
Applications
Copyright 2008 Sony Corporation
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•••• Perfluorooctane sulfonates (PFOS)
1. Examples
Name CAS No. Chemical formula Applications
PFOS; Perfluorooctane sulfonates
e.g. 2795-39-3
•••• Specific benzotriazole
1. Examples
Name CAS No. Chemical
2-(3',5'-Di-tert-butyl-2'-hydroxyphenyl)benzotriazole; 2-(2'-Hydroxy-3',5'-di-tert-butylphenyl)benzotriazole
SS-00259 (7th Edition) for General Use
C8F17SO2X
(X=hydroxyl, metallic salt, halide, amide, and other derivatives, including polymers)
3846-71-7 C20H25N3O Ultraviolet protectants,
Water repellant agent, oil repellant agent
Applications
formula
ultraviolet absorbers
Copyright 2008 Sony Corporation
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Page 38
SS-00259 (7th Edition) for General Use
(Note) This document is subject to change without prior notice, as a result of a revision or modifications on the SS-00259, the Sony Technical Standard titled “Management Regulations for the Environment-related Substances to be Controlled which are included in Parts and Materials.”
Management Regulations for the Environment-related Substances to be Controlled which are included in Parts and Materials
SS-00259 for General Use, Seventh Edition
Enforced 2008.04.01 Issued by Secretariat of the Sony Technical Standards, Sony Corporation
Copyright 2008 Sony Corporation
Page 39
零部件和材料中的环境管理物质 管理规定
(SS-00259 第 7 版 一般公开版)
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SS-00259 第 7 版 一般公开版
(注意)
本书的著作权等相关权利,完全归索尼株式会社所有。
本书是索尼技术标准 SS-00259 第 7 版的一般公开版。
Copyright 2008 Sony Corporation ALL RIGHTS RESERVED No part of this document may be reproduced or transmitted in any form or by any means, electronic or mechanical, including photocopying, recording or by any information storage and retrieval system, without the prior written permission of Sony Corporation.
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SS-00259 第 7 版 一般公开版
目 录
1. 目的…………………………………………………………………………………………………1
2. 适用范围……………………………………………………………………………………………1
2.1 零部件和材料的适用范围……………………………………………………………………1
2.2 产品的适用范围………………………………………………………………………………1
3. 术语的定义…………………………………………………………………………………………2
4. 环境管理物质的管理标准…………………………………………………………………………3
4.1 环境管理物质…………………………………………………………………………………3
4.2 有关包装零部件和材料的追加事项……………………………………………………… 15
4.3 有关电池的事项(适用于: 与产品同时包装或另外出售等所有商品的流通形式)…… 18
附属资料………………………………………………………………………………………………19
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SS-00259 第 7 版 一般公开版
1. 目 的
本技术标准是: 通过明确构成索尼电子产品的零部件和组件等中含有的环境管理物质之(1)禁止使用物质、(2) 计划全废物质、(3)适用对象外项目,以防止这些物质混入索尼电子产品中,同时实现遵守法令、保护地球环 境以及减轻对生态系统的影响等的目的。
2. 适用范围
2.1 零部件和材料的适用范围
本技术标准适用于: 索尼集团以及由索尼集团委托设计、制造的产品所包含的零部件、材料及其他物品。这 些对象均必须符合本技术标准的规定。
所适用的零部件和材料等为:
半成品(功能单元、模组、板组件(board assemblies)等的组装零部件等) 零部件(电气零部件、机械零部件、半导体器件、印刷线路板、记录媒体、包装零部件和材料) 螺丝 附件(配合机器使用的附属品,例如,遥控指挥器、鼠标、AC 适配器等) 产品采用的辅助材料(胶带(adhesive tape)、焊接材料、粘结剂等)之组成材料等 印刷品(操作说明书、保证书、产品和零部件相关的补充信息 等) 修理用零部件(对于已出货产品的修理用部分零部件,应依照另行规定的通知书执行) 零部件交货厂商为了发送或保护货物使用「4.2.1 包装零部件和材料的定义」的包装零部件和材料 电池
2.2 产品的适用范围
(1) 由索尼集团设计和制造、销售、借阅以及发布的索尼电子产品 (2) 索尼集团委托第三者设计和制造,且贴有索尼集团的商标进行销售、借阅或发布的索尼电子产品 (3) 第三者委托索尼集团进行设计和制造的电子产品
(但是,由该第三者指定的零部件和材料除外)
此外,对本技术标准中未明确规定的物质或是其用途,如果各国或当地法令规定禁止使用或限制使用该物质 或用途时,则必须遵照相关法令执行。
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SS-00259 第 7 版 一般公开版
3. 术语的定义
本技术标准中所使用的术语定义如下: (1) 环境管理物质
包含在零部件和组件等的物质中,由索尼判断对地球环境和人体存在着显著影响的物质。
(2) 管理级别
按照以下 3 种管理级别和适用对象外的分类进行管理。 (a) 1 级
相应对象物质及其用途禁止用于零部件和材料中。
(b) 2 级
表中规定的该日期开始(即: 禁止供货时期栏中所指定的日期)指定提升为「1 级」。
(c) 3 级
目前虽然没有规定全废的目标日期,但是指定了希望朝向完全废除使用的零部件和材料中所含有的物 质以及其用途。当判断可以引进代替的零部件、开发新材料和代替技术时,即可由 3 级提升至 2 级, 同时逐步实现全废的目标。
(d) 适用对象外
不在法令的规定范围中,或者现阶段没有代替技术方案的物质和用途部位。
(3) 含有
含有是指: 无论是否有意,在所有产品的零部件和组件或使用的材料中添加、填充、混入或粘附的物质(包
括在加工过程中无意混入或粘附于产品中的物质)。 但是,制造半导体器件等使用的掺杂剂(Dopant)虽然是有意添加,但实质上在半导体器件中其残存量极少时, 则不定义为「含有」,而定义为「杂质」。
(4) 杂质
杂质是指: 包含在天然材料中,作为工业材料的精制过程中技术上不能完全去除的物质(natural impurity),或者在合成反应的过程中产生但技术上不能完全去除的物质。 此外,为了与主原料加以区別而称为「杂质」的物质,如果其使用目的是为了改变材料的特性时,则作为「含 有」处理。
(注) 本技术标准中指定了相关的允许浓度,如果在零部件和组件中混入或者粘附了作为杂质的相应环境管
理物质时,其浓度不能大于本技术标准所规定的允许浓度。
(5) 禁止供货时期
禁止向索尼供应零部件和材料的时期。
(6) 本技术标准中定义的塑料 -由合成高分子物质形成的材料或素材- 包括由合成高分子制成的纤维、薄膜、胶带(adhesive tape)、成型产品、合成橡胶产品、植物原料塑料、
粘结剂等。
另外,天然树脂与上述的合成高分子物质合成的材料,也定义为塑料。
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4. 环境管理物质的管理标准
4.1 环境管理物质
本技术标准中作为对象的环境管理物质名称如表 4.1 所示
表 4.1 环境管理物质名称一览表
镉以及镉化合物
重金属
有机氯化合物
有机溴化合物
三丁基锡化合物(TBT) 三苯基锡化合物(TPT)
石棉 特定偶氮化合物 甲醛 聚氯乙烯(PVC)以及聚氯乙烯混合物 氧化铍
铍青铜 特定邻苯二甲酸盐(DEHP、DBP、BBP、DINP、DIDP、DNOP、DNHP) 氢氟碳化合物(HFC)、全氟化碳(PFC) 全氟辛烷磺酸(及其盐)(PFOS)
铅以及铅化合物 汞以及汞化合物 六价铬化合物 多氯联苯(PCB) 多氯化萘(PCN) 多氯三联苯(PCT)
短链型氯代烷烃(SCCP) 其他有机氯化合物 多溴联苯(PBB) 包含十溴联苯醚(DecaBDE)的多溴联苯醚(PBDE) 其他有机溴化合物
SS-00259 第 7 版 一般公开版
物质名称
特定苯并三氮唑
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SS-00259 第 7 版 一般公开版
表 4.2 环境管理物质的主要对象和禁止供货时期
物质名称: 镉以及镉化合物
对象范围: 金属、合金、无机化合物、有机化合物、无机盐、有机盐等含有镉元素的所有物质
对象 禁止供货时期
1级
包装零部件和材料(参照 4.2.1 的内容)
塑料(包括橡胶)材料中含有的稳定剂、颜料、染料(电器配线的绝缘体、
遥控指挥器・键、扎线带(cable tie)、电子元器件的外装树脂、外框(机 壳)、标签、唱片等) 涂料、油墨
表面处理(电镀、无电解电镀等)、涂层
照片胶卷
日光灯(小型日光灯、直管日光灯)
适用对象外以外之所有用途。 例如,
直流电动机、开关、继电器、断路器等电气接点
温度保险丝的可熔体
玻璃以及玻璃涂料的颜料、染料(用于玻璃的颜料、染料以及玻璃用涂
料) 焊料(镉含量大于 20 ppm(Cd > 20 ppm)的焊料)
荧光显示装置中含有的荧光体、CdS(硫化镉)光敏传感器
电阻(玻璃料)
含锌金属(黄铜、熔融镀锌等)构成的零部件及相应部位中的镉含量大于
100 ppm 的零部件及相应部位(Cd > 100 ppm)
立即执行
立即执行 (从 2005 年 1 月 1 日开始)
立即执行 (从 2005 年 10
月 1 日开始)
适用对象外
要求使用可靠性高的电气接点电镀,但是没有替代材料的电镀
光学玻璃、滤光玻璃
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SS-00259 第 7 版 一般公开版
测定对象: 塑料(包括橡胶)、涂料、油墨 含镉允许浓度应小于 5 ppm( Cd 5 ppm)
测定标准: (1)预处理
有关预处理方法主要有下列 4 种:
1. 存在硫酸状态下进行的灰化法(硫酸灰化法)
2. 在密闭容器内进行的加压酸分解法[包括微波分解法(例如,EN 13346: 2000 或 EPA 3052: 1996)]
3. 采用硝酸、过氧化氢溶液、盐酸进行的酸分解法(例如,EPA 3050B Rev.2: 1996)
4. 采用硫酸、硝酸、过氧化氢溶液进行的湿式分解法(例如,BS EN 1122: 2001)
等。
(注) 如果在上述所有的预处理过程中,产生沉淀物(不溶解物质)时,必须采取某种方法(碱溶法等)完全
溶解该沉淀物。
(2)测定法
有关测定方法主要有下列 3 种:
1. 电感耦合等离子体发射光谱法[ICP-AES(ICP-OES)];(例如,EN ISO 11885: 1998)
2. 原子吸收分光光度法(AAS);(例如,EN ISO 5961: 1995)
3. 电感耦合等离子体质谱法(ICP-MS)
除上述方法以外,通过组合预处理和测定方法的结果可以保证镉的定量下限值小于 5 ppm 时,则规定该组
合方法所得到的测定结果合格。 此外,镉和铅也可以同时采用上述(2)中的测定法进行分析,但是,「2.原子吸收分光光度法(AAS)」的方 法除外。
(注) 在 EN 71-3: 1994、ASTM F963-96a、ASTM F963-03、ASTM D 5517、ISO 8124-3 中具代表性的萃取法
不适合作为预处理的方法。
因 JIS K0102「工业废水的试验法」第 55 项仅记载了测定法,所以必须同时记述预处理的方法。
物质名称: 铅以及铅化合物
对象范围: 金属、合金、无机化合物、有机化合物、无机盐、有机盐等含有铅元素的所有物质
对象 禁止供货时期
1级
包装零部件和材料(参照 4.2.1 的内容)
用于印刷线路板中的含铅涂料与油墨
零部件的外部电极、引线端子等的表面处理(例如,电气零部件、半导
体器件、散热片等)
AC 适配器、电源线、连接电缆、遥控指挥器、鼠标、机器的外露部位所
使用的塑料(包括橡胶)材料中含有的稳定剂、颜料、染料 用于机器的外露部位的涂料、油墨
立即执行
立即执行 (从 2004 年 4
月 1 日开始)
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SS-00259 第 7 版 一般公开版
1级
3级
适用对象外
3级」和适用对象外以外的所有用途 例如,
内藏在 AC 适配器、遥控指挥器、半导体器件等中的零部件之外部电极、
引线端子等的表面处理
铅的重量百分比小于 85 wt%的有铅焊锡中,其铅含量大于 1000 ppm 的
焊料(Pb > 1000 ppm)
大于如下允许浓度(*1)的各种合金(包括焊锡材料)
AC 适配器、电源线、连接电缆、遥控指挥器、鼠标、机器的外露部位以
外使用的塑料(包括橡胶)材料中含有的稳定剂、颜料、染料 用于机器的外露部位以外的涂料、油墨
在无电解镀镍、无电解镀金等的无电解电镀皮膜中的铅含量大于 1000 ppm
的皮膜(Pb > 1000 ppm)
在无电解镀镍、无电解镀金等的无电解电镀皮膜中的铅含量小于或等于
1000 ppm 的皮膜(Pb ≤ 1000 ppm) 连接零部件和组件用的高熔点焊料(即,铅的重量百分比大于或等于
85 wt%的有铅焊锡) 电子陶瓷零部件(例如,压电材料、介质材料、磁性材料[铁素体系])
光学玻璃、滤光玻璃
用于显像管、电子元器件、荧光管的玻璃材料
用于电子元器件的玻璃材料包括电阻、导电浆(银浆、铜浆)、粘结剂、 玻璃料、密封材料(密封胶(sealant))等 用于焊接微处理器端子和器件封装的焊料中,由 2 种以上的元素组成之
含铅量大于 80 wt%但小于 85 wt%的焊料(80 wt% < Pb < 85 wt%) 连接集成电路板叩焊晶片内部的半导体芯片和连接电路板的焊料(包括
IC 内部焊接用突块(bump)下面使用的焊锡膏)。
*
(
1)各种合金的含铅允许浓度
合金的种类 含铅允许浓度 钢材 ≤ 0.35 wt% 铝合金 ≤ 0.4 wt% 铜合金(也包括铸铜、磷青铜) ≤ 4 wt% 焊料(*2) ≤ 1000 ppm
各向异性的导电胶片(ACF)及各向异性的导电糊剂(ACP)中如果使用焊料 时,该导电物质应采用的焊料为: 各种合金的含铅允许浓度中规定的焊
*
2),即小于或等于 1000 ppm 的焊料。
料(
立即执行 (从 2005 年 1
月 1 日开始)
立即执行 (从 2006 年 2
月 1 日开始)
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SS-00259 第 7 版 一般公开版
测定对象: 塑料(包括橡胶)、涂料、油墨 含铅允许浓度应小于 100 ppm( Pb 100 ppm)
测定标准: (1)预处理
有关预处理方法主要有下列 4 种:
1. 存在硫酸状态下进行的灰化法(硫酸灰化法)
2. 在密闭容器内进行的加压酸分解法[包括微波分解法(例如,EN 13346: 2000 或 EPA 3052: 1996)]
3. 采用硝酸、过氧化氢溶液、盐酸进行的酸分解法(例如,EPA 3050B Rev.2: 1996)
4. 采用硝酸、过氧化氢溶液
进行的湿式分解法
等。
(注) 如果在上述所有的预处理过程中,产生沉淀物(不溶解物质)时,必须采取某种方法(碱溶法等)完全
溶解该沉淀物。
(2)测定法
有关测定方法主要有下列 3 种:
1. 电感耦合等离子体发射光谱法[ICP-AES(ICP-OES)];(例如,EN ISO 11885: 1998)
2. 原子吸收分光光度法(AAS);(例如,EN ISO 5961: 1995)
3. 电感耦合等离子体质谱法(ICP-MS)
除上述方法以外,通过组合预处理和测定方法的结果可以保证铅的定量下限值小于 30 ppm 时,则规定该
组合方法所得到的测定结果合格。 此外,镉和铅也可以同时采用上述(2)中的测定法进行分析,但是,「2.原子吸收分光光度法(AAS)」的方 法除外。
(注) 在 EN 71-3: 1994、ASTM F963-96a、ASTM F963-03、ASTM D 5517、ISO 8124-3 中具代表性的萃取法
不适合作为预处理的方法。另外,EN 1122 也不适合作为铅的预处理法。
因 JIS K0102「工业废水的试验法」第 54 项仅记载了测定法,所以必须同时记述预处理的方法。
物质名称: 汞以及汞化合物
对象范围: 金属、合金、无机化合物、有机化合物、无机盐、
对象 禁止供货时期
包装零部件和材料(参照 4.2.1 的内容)
涂料、油墨
计时器
接点中使用汞的继电器、开关、传感器
1级
适用对象外
塑料中的添加剂
小型日光灯(用于液晶背光等): 每一支的含量大于或等于 5 mg 的产品
直管日光灯: 每一支的含量大于或等于 5 mg 的产品
「适用对象外」以外的所有用途
小型日光灯、直管日光灯以外的灯(高压汞灯等)
小型日光灯: 每一支的含量小于 5 mg 的产品
直管日光灯: 每一支的含量小于 5 mg 的产品
根据著作权法,严禁擅自复制、转载。
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立即执行
立即执行 (从 2005 年 1
月 1 日开始)
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SS-00259 第 7 版 一般公开版
物质名称: 六价铬化合物
对象范围: 无机化合物、有机化合物、无机盐、有机盐等含有六价的铬元素的所有物质
对象 禁止供货时期
包装零部件和材料(参照 4.2.1 的内容) 立即执行
1级
包含在零部件和材料成分中的涂料、油墨以及其他添加剂等
在电镀、化学转化处理等的表面处理(螺丝、钢板等)过程中,残留在被处
理部位的物质
物质名称: 多氯联苯(PCB)、多氯化萘(PCN)、多氯三联苯(PCT)
对象 禁止供货时期
油浸变压器、电容器、绝缘油、润滑油、塑料用的阻燃剂等的所有用途 立即执行
1级
物质名称: 短链型氯代烷烃(SCCP)
立即执行 (从 2005 年 1
月 1 日开始)
对象为「碳链长为 10-13 的短链型氯代烷烃」
用于包括附件在内的产品外框(机壳)、印刷线路板的用途时。 立即执行
1级
上述以外的所有用途。 立即执行
物质名称: 其他有机氯化合物
3级
用于塑料的阻燃剂和增塑剂,以及印刷线路板等的阻燃剂用途时
对象 禁止供货时期
(从 2006 年 2 月 1日开始)
对象 禁止供货时期
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SS-00259 第 7 版 一般公开版
物质名称: 多溴联苯(PBB)
对象 禁止供货时期
用于塑料的阻燃剂等的所有用途 立即执行
1级
物质名称: 包含十溴联苯醚(DecaBDE)的多溴联苯醚(PBDE)
对象 禁止供货时期
用于塑料的阻燃剂等的所有用途
立即执行
1级
使用 2002 年 12 月以前既有的模具制造的零部件(限定为: 出口欧洲以外国
家的电视、显示器的框体) 但是,2003 年 1 月以后制造的新型模具零部件中禁止使用本项物质
立即执行 (从 2005 年 1
月 1 日开始)
物质名称: 其他有机溴化合物
对象 禁止供货时期
3级
用于塑料的阻燃剂和印刷线路板等的阻燃剂之用途
物质名称: 三丁基锡化合物(TBT)、三苯基锡化合物(TPT)
对象 禁止供货时期
1级
用于涂料、油墨、防腐剂、杀霉剂等的所有用途 立即执行
物质名称: 石棉
对象 禁止供货时期
1级
用于绝缘材、填料等的所有用途 立即执行
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SS-00259 第 7 版 一般公开版
物质名称: 特定偶氮化合物
对象为: 按照欧盟欧盟化学品限制指令 76/769/EEC 中引用的试验法进行分解,生成表 4.2a 的特定胺化 合物之特定偶氮化合物,以及 4.2a 的特定胺化合物
对象 禁止供货时期
1级
3级
与人体持续接触的产品,其接触人体部位(入耳式耳机、头戴式耳机、肩包
的肩垫、皮带、绳索等)所使用的颜料。
不与人体持续接触的产品或零部件(遥控指挥器、胶垫、携带笔记本电脑专
用包、鼠标等)
立即执行
试验法(参考)
分解偶氮化合物提取胺的方法如下所述:
(1) EN 14362-1: 2003“ Textiles-Methods for the determination of certain aromatic amines
derived from azo colorants
-Part 1: Detection of the use of certain azo colorants accessible without extraction” (2) CEN ISO/TS 17234: 2003“Leather-Chemical tests-Determination of certain azo colorants in
dyed leathers”
(3) EN 14362-2: 2003“ Textiles-Methods for the determination of certain aromatic amines
derived from azo colorants
-Part 2: Detection of the use of certain azo colorants accessible by extracting the fibres”
表 4.2a 特定胺化合物一览表
CAS No. 名称
92-67-1 4-氨基联苯 92-87-5 联苯胺 95-69-2 4-氯邻甲苯胺 91-59-8 2-萘胺 97-56-3 邻氨基偶氮甲苯 99-55-8 2-氨基-4-硝基甲苯 106-47-8 4-氯苯胺 615-05-4 2,4-二氨基苯甲醚 101-77-9 4,4'-二氨基二苯甲烷 91-94-1 3,3'-二氯联苯胺 119-90-4 3,3'-二甲氧基联苯胺 119-93-7 3,3'-二甲基联苯胺 838-88-0 3,3'-二甲基-4,4'-二氨基二苯甲烷 120-71-8
5-甲基邻茴香甲胺 101-14-4 4,4'-二氨基-3,3'-二氯二苯甲烷 101-80-4 4,4'-二氨基联苯醚 139-65-1 4,4'-二氨基二苯硫醚 95-53-4 邻甲苯胺 95-80-7 2,4-二氨基甲苯 137-17-7 2,4,5-三甲基苯胺 90-04-0 邻甲氧基苯胺 60-09-3 4-氨基偶氮苯
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SS-00259 第 7 版 一般公开版
物质名称: 甲醛
对象 禁止供货时期
1级
出口欧州的产品中使用的纤维板(Fibreboard)、刨花板(particleboard),
以及使用胶合板的木工产品(扬声器、机架等)
非出口欧州的产品中使用的纤维板(Fibreboard)、刨花板(particleboard),
以及使用胶合板的木工产品(扬声器、机架等)
立即执行
立即执行 (从 2005 年 1
月 1 日开始)
标准値(排放浓度): 采用如下方法中的其中一种方法 (1)测试室法 在空气中浓度 12 m
于或等于 0.124 mg/m
3
、1 m3或 0.0225 m3的气密试验槽中的标准値应为小于或等于 0.1 ppm(小
3
)
(2)穿孔法 ·未经表面处理的 100g 刨花板中的标准値应为小于或等于 6.5 mg(6 个月的平均值)
·未经表面处理的 100g 纤维板中的标准値应为小于或等于 7.0 mg(6 个月的平均值) 或
·未经表面处理的 100g 刨花板及纤维板中的标准値应为小于或等于 8.0 mg(这里是指遵照 如下(2)中的 EN 120 规定之 1 次的测定值)
(3)干燥器法 平均标准値应为小于或等于 0.5 mg/l、最大的标准値应为小于或等于 0.7 mg/l(用 N =2
来确认平均值、最大值)
测定法:(1)测试室法依照 EN 717-1:2004 (Wood based panels; determination of formaldehyde release;
formaldehyde emission by the chamber method)规定
(2)穿孔法依照 EN 120 (Wood based panels; determination of formaldehyde content; extraction
method called perforator method; EN 120:1992)规定
(3)干燥器法依照 JIS A 5905 (Fibreboards)、JIS A 5908(Particleboards)规定
物质名称: 聚氯乙烯(PVC)以及聚氯乙烯混合物
对象
非接触 IC 卡(FeliCa)用基材 立即执行
禁止供货时期
(一开始生产 时就未使用本 对象物质)
1级
电脑、数码相机、摄像机、便携式多媒体播放器等所使用的配件背包、
专用携带配件盒、配件腰包的材料和涂装剂(但是,业务用除外)
捆绑附件、连接电源线的扎线带(cable tie) 立即执行
立即执行
(从 2002 年 7 月 1 日开始)
产品以及与产品一同包装的附件等使用的包装零部件和材料(袋、胶带
(adhesive tape)、纸箱、泡罩包装等)
立即执行 (从 2005 年 1
月 1 日开始)
热收缩软管 立即执行
(从 2005 年 4 月 1 日开始)
扁型软电线(FFC)
木制扬声器外装部分采用的片材(Sheet)、层压板
绝缘板、装饰板、标签、片材(例如,绝缘 Sheet、保护膜等)、层压板
立即执行 (从 2007 年 4
月 1 日开始)
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物质名称: 聚氯乙烯(PVC)以及聚氯乙烯混合物
对象
连接电缆(1): 便携型机器用电缆(例如,入耳式耳机、头戴式耳机、耳
禁止供货时期
戴式麦克风用的电缆等)
机器内外部使用的绝缘和保护用的涂层、绝缘软管、携带用挂带
(carrying belt)、垫片(spacer)、 holder(是指固定用的零部件)、套 管保护盖(cover)、配线槽(duct)等
出口日本、美国、加拿大的电源线(包括插头、连接器、电线套筒): [2P
与 3P] 使用线材(带电缆的连接器等)的零部件以及机体内布线用线材(马达引
线等) 连接电缆(2): USB 用电缆、i.LINK 用电缆、录像机电缆、AC 适配器次
级引线、扁平线、多芯绞合型电缆、扬声器电缆等
3级
束线、加工线材(同轴电缆、扁平线、双重屏蔽电线、屏蔽线等)
业务用电子产品用配件背包、专用携带配件盒、配件腰包的材料及涂装
剂 印相纸(照相纸)
作为电容器、电源开关、保险丝用途的绝缘盖
零部件交货厂商用于包装零部件的托盘、料条(装运管)、带盘、压纹承
载带等 安装车用机器(In-vehicle product)的吸盘
用于机器内部的配线用夹(用聚氯乙烯涂装过的金属物品)
除此之外,还包括本项中未列举的零部件(但是「1 级」及「适用对象外」 中所列举的除外)
适用对象外
树脂用粘料(粘接料)
高压塑料电线
绝缘带
扬声器的格栅(Speaker grille)
电源线(上述 3 级中所述,出口日本、美国、加拿大以外地区的电源线)
含有氯乙烯共聚物,以及聚氯乙烯与其他聚合物的混合物之零部件。但
是上述 1 级与 3 级所指定的零部件除外 变压器的引线部分(清漆浸渍的部分)
卷线
AWG36 以上的极细电线
不能使用通用电缆的业务用机器所采用的电缆(例如,广播电视台用摄
像机电缆、麦克风电缆等)
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SS-00259 第 7 版 一般公开版
物质名称: 氧化铍
对象 禁止供货时期
1级
3级
3级
对象为表 4.2b 的物质
3级
管理级别 3 级以外的所有用途
无替代物之特殊用途的产品或零部件
物质名称: 铍青铜
对象 禁止供货时期
所有用途
物质名称: 特定邻苯二甲酸盐(DEHP、DBP、BBP、DINP、DIDP、DNOP、DNHP)
对象 禁止供货时期
用于电缆绝缘、电源线绝缘,及其对应的插头或连接器部位的聚氯乙烯树
脂含有增塑剂用途的特定邻苯二甲酸盐时
表 4.2b 特定邻苯二甲酸盐(邻苯二甲酸盐)一览表
从2008年4月 1 日开始
简称 CAS 号码 名称 DEHP 117-81-7 邻苯二甲酸(2-乙基己基酯)
DBP 84-74-2 邻苯二甲酸二丁酯 BBP 85-68-7 邻苯二甲酸丁苄酯
DINP 28553-12-0
68515-48-0
DIDP 26761-40-0
68515-49-1
邻苯二甲酸二异壬酯
邻苯二甲酸二异癸酯
DNOP 117-84-0 邻苯二甲酸二正辛酯 DNHP 84-75-3 邻苯二甲酸二己酯
物质名称: 氢氟碳化合物(HFC)、全氟化碳(PFC)
对象 禁止供货时期
安装于产品中的冷媒、隔热材料等的所有用途
1级
立即执行 (从 2008 年 4
月 1 日开始)
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物质名称: 全氟辛烷磺酸(及其盐)(PFOS)
对象 禁止供货时期
零部件采用的材料中的 PFOS 浓度大于或等于 0.1 wt%时
每个涂布材料(包括纤维或是其他的涂布材料)中的 PFOS 含量大于或等于
1级
1μg/m
例如,
2
电镀、涂料、颜料、燃料、用拒水剂/拒油剂/防污剂等涂布的材料(纤 维、薄膜、纸、皮革等)、氟聚合物树脂涂层、粘结剂、密封胶(sealant) 等
用于薄膜、纸、印刷版材中的照片用涂布剂
适用对象外
光刻工艺采用的光刻胶或是防止反射用的涂布剂
物质名称: 特定苯并三氮唑
对象为2-(3',5'-二叔丁基-2'-羟基苯基)苯并三唑(CAS No. 3846-71-7)
对象 禁止供货时期
用于如下产品中做为紫外线防护剂、紫外线吸收剂用途的特定苯并三氮唑
装饰性层压板
1级
印相纸(照相纸)
成型塑料产品
SS-00259 第 7 版 一般公开版
立即执行 (从 2008 年 4
月 1 日开始)
立即执行 (从 2008 年 4
月 1 日开始)
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4.2 有关包装零部件和材料的追加事项
4.2.1 包装零部件和材料的定义
包装零部件和材料是指: 生产者为了将产品(包括原材料到加工品)以「装入」、「保护」、「掌握处理」、「运送」、 「交付」等方式送到使用者或消费者手中,使用各类材料及零部件制成的产品。 (注) 但是,在运输公司或零部件交货厂商的管理下回收且再次使用的物流箱等的包装除外。在此所指的物
流箱等不包含在由索尼集团内部或终端用户废弃的包装材料中。
表 4.3 有关包装零部件和材料的追加事项
物质名称: 重金属
(镉、铅、六价铬、汞)
除 4.1 项(表 4.2)的规定外,还需遵守法律规定,同时符合以下条件
对象 禁止供货时期
对象为表 4.3a 中记载的包装零部件和材料
1级
适用对象外
允许浓度:
汞、镉、六价铬、铅的重金属允许浓度,依照组成包装时的各零部件材料、油墨、涂料的类别,规定为
重金属的合计应小于 100 ppm。但是,在塑料(包括橡胶)、涂料、油墨各相应部位中的含镉或铅的允许 浓度,应符合「镉和镉化合物」及「铅和铅化合物」的规定。
【主要的塑料部位: 提手、塑料袋、缓冲材料、薄膜、托盘、带盘、胶带(adhesive tape)、料条(裝運 管(包括止动器))、打包带等】
(1)首先,必须先分析六价铬的总铬量,确认 4 种元素合计小于 100 ppm。此时,可以与镉和铅同时进行预
处理。
(2)如果 4 种元素合计大于或等于 100 ppm 时,必需确认镉、铅、汞 3 种元素的合计含量小于 100 ppm。
当镉、铅、汞的合计含量小于 100 ppm 时,再进行六价铬的检测判定。最后应确认没有检测到六价铬。
测定标准: (1)预处理
在此规定镉和铅的预处理方法,应依照塑料中的镉( 另外,总铬的预处理方法也是依照塑料中的镉(
汞的预处理方法主要有下列 3 种:
1. 在密闭容器内进行的加压酸分解法[包括微波分解法(例如,EPA 3052: 1996)]
2. 加热气化-冷原子吸光法
3. 将硫酸、硝酸放入附带回流冷凝器的分解烧瓶(基耶达尔法)中进行的湿式分解法 等
(注) 必须注意无论采用何种方法都不能让汞挥发。另外,产生沉淀物时,必须采取某种方法完全溶解该沉
淀物。
(2)测定法
在此规定镉、铅、总铬的测定法,应依照塑料中的镉( 另外,汞的测定方法也是依照塑料中的镉( 能混入低浓度的汞时,如下分析方法较为适合: 还原气化原子吸光法、附带氢气发生器的 ICP-AES (ICP-OES)与附带氢气发生器的 ICP-MS。
运输公司或零部件交货厂商所使用的物流箱除外
*
3)和铅(*4)的规定处理。
*
3)的规定处理。
*
*
3)和铅(*4)的规定进行。但是,预估包装零部件和材料中可
3)和铅(*4)的规定进行。
立即执行
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六价铬的检测判定 这是为了确认包装零部件和材料中的镉、铅、汞、总铬 4 种元素合计是否大于或等于 100 ppm 的方法。
检测方法: (1)预处理
萃取法[沸水萃取法、碱萃取法(例如,EPA 3060A)]
(2)测定法
紫外-可见光分光光度法(例如,EPA 7196A)
如果本测定标准是组合了预处理和测定法,其结果可以保证个别的定量下限值为: 汞小于 5 ppm、镉小于 5 ppm、总铬小于 5 ppm、铅小于 30 ppm 时,则规定该组合所得到的测定结果合格。 此外,镉、铅、总铬量可以同时采用第 5 页(
*
3)或第 7 页(*4) (2)中的测定法进行分析,但是「2.原子吸
收分光光度法(AAS)」的方法除外。
(*3) 参照「表 4.2 关于环境管理物质的主要对象和禁止供货时期」中的物质名称: 镉以及镉化合物、测定对
象:塑料(包括橡胶)、涂料、油墨。
*
(
4) 参照「表 4.2 关于环境管理物质的主要对象和禁止供货时期」中的物质名称: 铅以及铅化合物、测定对 象:塑料(包括橡胶)、涂料、油墨。
表 4.3a 识别包装零部件和材料的具体例子
(注) 本表并不是网罗所有的包装零部件和材料。
用于包装消费者用产品以及业务用产品的包装零部件和材料(用于运输索尼电子产品的包装零部件和材料)
PACKAGING
1. 纸箱(箱子) 由各种材料制成的个装箱、辅助纸箱、主纸箱
2. 缓冲材料
3. 防护带(片材(sheet)) 泡沫塑料或不织布等
4. 塑料袋
5. 信封 装保证书的信封等
6. 泡罩包装
7. 薄膜 包含粘贴液晶显示器表面等的防护膜
8. 对折泡壳
9. 隔离板/间隔物(spacer)
10. 印刷 用于印刷包装零部件的
11. 胶带(adhesive tape) 用于封缄纸箱、塑料袋,以及保护和固定可动部分的胶带
12. U 形钉
13. 标签 在索尼的监督管理下粘贴于包装零部件上的标签,例如条形码标签
14. 接头(joint) 粘接纸箱等
15. 打包带 PP 打包带等
16. 挂钩(hang tab)
17. 提手 提手及其构成零部件
18. 外框 木框等
19. 热收缩薄膜
20. 瓶
21. 套筒
22. 装饰箱 例如装钢笔或化妆品的装饰箱
23. 防滑垫
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NOT PACKAGING
1. CD 盒子/袋
2. 检索卡片/标签 属于产品的一部分,附属于 CD 或其他记录媒体的检索卡片或标签等
3. 专用携带配件盒/配件腰包 属于产品的一部分,耳机、照相机、WALKMAN®随身听等的附属品
4. 标签 粘贴在产品上等的标签,但是,包装零部件和材料上的标签除外
5. 标签 由第 3 者粘贴的货物标签或发票等
器件、半导体以及其他零部件使用的包装零部件和材料
1. 料条(装运管) 用于运输 IC 等的包装零部件
2. 止动器
3. 托盘
4. 带盘
物流采用的包装零部件和材料
属于产品的一部分,用于录像带、CD、MO、MD、DVD 等的盒子、袋、芯 轴等
PACKAGING
PACKAGING
1. 板条托盘 包括滑托板之木制、塑料制、纸制等 One-Way 规格的托盘
2. 板条箱
3. 缠绕膜(拉伸膜) 防止货物变形等用
4. 木制集装箱
5. 辅助包装采用的包装材料
6. 打包带/绳 PP 打包带等
1. 轮船和空运集装箱 轮船输送用 40 英尺集装箱、空运集装箱等
运输零部件时的辅助包装所采用的纸箱、缓冲材料、胶带(adhesive tape)等
NOT PACKAGING
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4.3 有关电池的事项(适用于: 与产品同时包装或另外出售等所有商品的流通形式)
4.3.1 关于本技术标准中的「电池」、「电池组」以及「钮扣电池」的定义
「电池」是指: 通过直接变换化学能源,使其产生电气能源。它是由单一或复数个一次电池(即原电池 primary battery: 不能再充电),或是单一或复数个二次电池(即蓄电池 secondary battery: 可再充电)所组成的。
「电池组」是指: 由复数的电池相互连接,且终端用户(end-user)无企图分解,即以全套装置(complete unit)
的形式安装于外壳(outer casing)中的电池套组。
「钮扣电池」是指: 其直径比高度长,外形小并且为圆形的携带型「电池」。因特别的目的用于助听器、腕表、
小型可携带式机器产品、备用电源等中的电池。 因「电池组」采用的电池也是归纳为「电池」,所以适用表 4.4 记载的规定。 此外,「电池」及「电池组」相关的内容,应依照本技术标准的 4.1 及 4.2 项的规定进行。
表 4.4 有关电池的事项
物质名称: 重金属(镉、铅、汞)
对象范围为金属、合金、无机化合物、有机化合物、无机盐、有机盐等含有镉、铅、汞元素的所有物质。
对象 禁止供货时期
镉(Cd)
镍/镉电池。
立即执行 (从 2007 年 1 月
1日开始)
「电池」: 镉含量大于或等于电池总重量 20 ppm 的电池。
「电池组」: 镉含量大于或等于电池总重量 20 ppm 的电池组。
立即执行 (从 2008 年 1 月 1日开始)
「电池」: 铅含量大于或等于电池总重量 0.4%的电池。
1 级
铅(Pb)
「电池组」: 铅含量大于或等于电池总重量 0.4%的电池组。
锰电池和碱锰电池: 铅含量大于或等于电池总重量 0.2%的电池。
立即执行 (从 2005 年 1 月
1日开始)
立即执行 (从 2008 年 4 月
1 日开始) (
汞(Hg)
「钮扣电池」: 汞含量大于或等于电池总重量 2%的钮扣电池。
「钮扣电池」以外的
立即执行
「电池」: 汞含量大于或等于电池总重量 0.0005%的电池。 「电池组」: 汞含量大于或等于电池总重量 0.0005%的电池组。 锰电池和碱锰电池: 汞含量大于或等于电池总重量 0.0001%的电池。
立即执行 (从 2008 年 4 月
1 日开始) (
(*5) 出口阿根廷的电池产品必须遵守阿根廷的电池法规,于 2007 年 1 月 29 日的禁止供货时期开始执行相关规
定。
*
(
6) 出口中国的电池产品必须遵守「关于限制电池产品汞含量的规定」,于 2005 年 1 月 1 日的禁止供货时期开 始执行相关规定。
*
5)
*
6)
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附属资料
1. 世界各国和地区就物质使用所实施的法律法规(主要示例)
2. 所属物质的详细信息(主要示例)
镉以及镉化合物 铅以及铅化合物 汞以及汞化合物 六价铬化合物 多氯联苯(PCB)、多氯化萘(PCN)、多氯三联苯(PCT) 短链型氯化萘(SCCP) 多溴联苯(PBB) 多溴联苯醚(PBDE) 三丁基锡化合物(TBT)、三苯基锡化合物(TPT) 石棉 特定偶氮化合物 甲醛 聚氯乙烯(PVC)以及聚氯乙烯混合物 氧化铍 氢氟碳化合物(HFC)、全氟化碳(PFC) 全氟辛烷磺酸(及其盐) (PFOS) 特定苯并三氮唑
注意事项: 本附属资料 1 和 2 中所列举的法令及化学物质仅为示例,并不是汇总全部的内容。也就是说,某些 化学物质可能有本表以外的其他名称。
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1. 世界各国和地区就物质的使用所实施的法律法规(主要示例)
(注) 以下登载的是截至 2008 年 3 月底已确认的内容。由于法律法规的内容会有变动,因此请参照各国的法律
法规以确认最新版的详细内容。
物质名称 法律法规
镉以及镉化合物
铅以及铅化合物
汞以及汞化合物
六价铬化合物
多氯化萘(PCN)、 多氯三联苯(PCT)
欧盟欧盟化学品限制指令(76/769/EEC)及其修订版 欧盟欧盟镉指令(91/338/EEC)及其修订版 欧盟RoHS 指令(2002/95/EC)及其修订版 欧盟电池指令(2006/66/EC) 瑞士减少化学品风险条令(
简称 ORRChem) 等
欧盟RoHS 指令(2002/95/EC)及其修订版 欧盟电池指令(2006/66/EC)
瑞士减少化学品风险条令(※简称 ORRChem)
丹麦 指令 No.1012 及其修订版
阿根廷便携式电气能源法律 26,184 号及决议 14/2007 等 欧盟RoHS 指令(2002/95/EC)及其修订版 欧盟电池指令(2006/66/EC) 中国关于限制电池产品汞含量的规定 中国进出口电池产品汞含量检验监管办法 等
欧盟RoHS 指令(2002/95/EC)及其修订版 瑞士减少化学品风险条令(
简称 ORRChem) 等
欧盟欧盟化学品限制指令(76/769/EEC)及其修订版 多氯联苯(PCB)、
日本化学物质审查规制法(
简称化审法) 第 1 种特定化学物质 等
短链型氯代烷烃(SCCP) 挪威对特定有害化学物质使用等相关限制 等
多溴联苯(PBB)
欧盟欧盟化学品限制指令(76/769/EEC)及其修订版
欧盟RoHS 指令(2002/95/EC)及其修订版
简称 ORRChem) 等
多溴联苯醚(PBDE)
瑞士减少化学品风险条令(
欧盟欧盟化学品限制指令(76/769/EEC)及其修订版
欧盟RoHS 指令(2002/95/EC)及其修订版
简称 ORRChem) 等
三丁基锡化合物(TBT)、 三苯基锡化合物(TPT)
瑞士减少化学品风险条令(
日本・化学物质审查规制法(简称化审法) 第1 种、第 2 种特定化学物质 等
日本劳动安全卫生法 石棉
德国化学品禁止规则(简称 ChemVerbotsV) 等
特定偶氮化合物 欧盟欧盟化学品限制指令(76/769/EEC)以其修订版 等
德国化学品禁止规则(简称 ChemVerbotsV) 甲醛
丹麦 指令 No.289 等
欧盟有关包装以及包装废弃物指令(94/62/EC)及其修订版 重金属(镉、汞、六价铬)
美国纽约州等 16 个州的包装材料重金属规定 等
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物质名称 法律法规
氧化铍 欧盟WEEE 指令(2002/96/EC)及欧盟欧盟指令(1999/45/EC) 等
氢氟碳化合物(HFC)、全氟化碳 (PFC)
欧盟欧盟法规(2006/842/EC)
丹麦指令 No. 552
瑞士减少化学品风险条令(
简称 ORRChem) 等
全氟辛烷磺酸(及其盐) (PFOS) 欧盟欧盟化学品限制指令(76/769/EEC)及其修订版 等
特定苯并三氮唑 日本化学物质审查规制法(简称化审法) 第 1 种特定化学物质
※瑞士的「减少化学品风险条令」的英文名称为: Ordinance on Risk Reduction related to Chemical Products( 简称 O R RChem).
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所属物质的详细信息(典型实例)
●镉以及镉化合物
1.所属物质的例子
中文名称
英文名称 CAS号码 化学分子式 主要用途
(通称、简称、化学名称等)
SS-00259 第 7 版 一般公开版
镉合金
氧化镉
氯化镉
硫化镉镉黄
硝酸镉
四水合硝酸镉
硫酸镉
硬脂酸镉
其他镉化合物
Cadmium 7440-43-9 Cd
Cadmium alloys
Cadmium oxide 1306-19-0 CdO
CdS
2
Cadmium chloride 10108-64-2 CdCl
Cadmium sulfide 1306-23-6;
8048-07-5
Cadmium nitrate 10325-94-7 Cd(NO
Cadmium nitrate
10022-68-1 Cd(NO
3)2
4H2O
3)2
tetrahydrate
Cadmium sulfate 10124-36-4 CdSO
Cadmium stearate 2223-93-0 Cd(C
4
18H35O2)2
Other cadmium compounds
接点材料、表面处理、镍镉
电池
低熔点焊锡、保险丝等
颜料、碱性电池、化学合成
材料
电镀浴(液)、聚氯乙烯的稳
定剂
颜料、半导体受光元件、油
漆、油墨
着色剂、电池、相片
镉电池、电镀光泽剂、试剂
聚氯乙烯的稳定剂
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●铅以及铅化合物
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
铅;金属铅
铅-锡合金
氧化铅;一氧化铅;氧化亚铅; 氧化铅(II);密陀僧(黄铅);黄丹 二氧化铅;氧化高铅;过氧化铅
三氧化二铅;
四氧化三铅;铅丹;红丹
叠氮化铅;铅叠氮化物
二氟化铅;氟化亚铅;氟化铅(II)
二氯化铅;氯化铅(II);氯化铅
四氯化铅;氯化铅(IV)
碘化亚铅;碘化铅(II)
硫化铅(II)
氰化铅(II)
氟硼酸铅
六氟硅酸铅
硝酸铅
碳酸铅
碱式碳酸铅;盐基碳酸铅;铅白
过氯酸铅
硫酸亚铅;硫酸铅(II)
三盐基硫酸铅
磷酸铅
硫氰酸铅
三水合乙酸铅;三水醋酸铅(II)
乙酸铅;醋酸铅(II);铅糖
乙酸高铅盐;四乙酸铅
SS-00259 第 7 版 一般公开版
英文名称 CAS号码 化学分子式 主要用途
Lead metal 7439-92-1 Pb
Lead-tin alloy Pb-Sn
焊锡、硬焊材料(brazing material)、电气接点
Lead (II) oxide 1317-36-8 PbO
颜料、橡胶硫化促进 剂、固体润滑剂
Lead (IV) oxide 1309-60-0 PbO
2
铅蓄电池、橡胶固化 剂、颜料的原料
Dilead trioxide 1314-27-8 Pb
Lead (II,IV) oxide 1314-41-6 Pb
2O3
颜料、铅蓄电池、玻
3O4
璃、涂料
Lead azide 13424-46-9 PbN
Lead (II) fluoride 7783-46-2 PbF
Lead (II) chloride 7758-95-4 PbCl
Lead (IV) chloride 13463-30-4 PbCl
Lead (II) iodide 10101-63-0 PbI
Lead (II) sulfide 1314-87-0 PbS
Lead (II) cyanide 592-05-2 Pb(CN)
Lead
13814-96-5 Pb(BF
tetrafluoroborate
Lead
25808-74-6 PbSiF
6
特殊光学玻璃、颜料
2
2
4
2
青铜、印刷、相片
半导体红外线检测器
防锈颜料
2
电镀浴(液)、耐腐蚀
4)2
表面处理
电镀浴(液)、铅精炼
6
hexafluorosilicate
Lead nitrate 10099-74-8 Pb(NO
Lead carbonate 598-63-0 PbCO
Lead hydroxycarbonate
1344-36-1 (PbCO
Pb(OH)
Lead perchlorate 13637-76-8 Pb(ClO
Lead (II) sulfate 7446-14-2;
15739-80-7
3)2
3
3)2
2
4)2
PbSO
4
颜料、聚氯乙烯的稳 定剂
颜料、橡胶配合剂、 聚氯乙烯的稳定剂、
光学玻璃
电池
Lead oxide sulfate 12202-17-4 Pb
Lead (II)
7446-27-7 Pb
4SO7
(PO4)2
3
塑料稳定剂
颜料
phosphate
染色、火柴
COO)
3
COO)2
3
COO)4
3
2
2
Lead thiocyanate 592-87-0 Pb(SCN)
Lead(II) acetate, trihydrate
6080-56-4 Pb(CH
3H2O
Lead(II) acetate 301-04-2 Pb(CH
Lead(IV) acetate 546-67-8 Pb(CH
根据著作权法,严禁擅自复制、转载。
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SS-00259 第 7 版 一般公开版
中文名称
(通称、简称、化学名称等) 油酸铅
硬脂酸铅
硼酸铅
硅酸铅
锑酸铅
砷酸铅;砷酸氢铅;酸性砷 酸铅 亚砷酸铅
铬酸铅;铬黄
钼酸铅
铅酸钙
四甲基铅;四甲铅;TML
英文名称 CAS号码 化学分子式 主要用途
Lead oleate 1120-46-3
Pb[CH
(CH
Lead stearate 7428-48-0 Pb(C
(CH2)7CH=CH
3
COO]2
2)7
COO)2
17H35
润滑剂、硬化剂等
聚氯乙烯的稳定剂、润 滑剂
Lead(II) metaborate 10214-39-8 Pb(BO
Lead metasilicate
11120-22-2;
PbSiO
2)2
H2O
3
油漆的干燥剂
陶瓷
10099-76-0
Lead antimonate 13510-89-9 Pb
(SbO4)2
3
Lead arsenate(1:1) 7784-40-9 PbHAsO
Lead(II)arsenite 10031-13-7 Pb(AsO
Lead chromate;
1344-37-2 PbCrO
2)2
4
4
颜料、玻璃着色
殺虫剂
颜料、涂料、油墨
chrome yellow
Lead molybdate 10190-55-3 PbMoO
Calcium plumbate 12013-69-3 Ca
PbO4
2
Tetramethyllead 75-74-1 Pb(CH
4
3)4
颜料
氧化剂
四乙基铅;四乙铅;TEL
其他铅化合物以及合金
Tetraethyllead 78-00-2 Pb(C
Other lead compounds and alloys
2H5)4
根据著作权法,严禁擅自复制、转载。
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Page 66
●汞以及汞化合物
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
汞;金属汞
汞合金;汞齐
氧化亚汞;氧化汞(I)
一氧化汞;氧化汞(II)
氯化亚汞;氯化汞(I);甘汞
二氯化汞;氯化汞(II);升汞
SS-00259 第 7 版 一般公开版
英文名称 CAS号码 化学分子式 主要用途
Mercury 7439-97-6 Hg
Mercury alloys ; amalgam
Mercury(I)oxide 15829-53-5 Hg
O
2
Mercury(II)oxide 21908-53-2 HgO
Mercury(I)chloride 10112-91-1 Hg
Mercury(II)chloride 7487-94-7 HgCl
2Cl2
2
电极、汞灯
汞电池、防腐剂
电极、颜料
金属蚀刻、干电 池、防腐剂
硝酸汞;硝酸汞(II)
硫酸亚汞;硫酸汞(I)
雷汞;雷酸汞(II)
乙酸汞;醋酸汞(II)
甲基汞盐
乙基汞盐
丙基汞盐
苯基汞盐
甲氧基乙基汞盐
二烃基汞
二苯汞
其他汞化合物
Mercury(II)nitrate 10045-94-0 Hg(NO
Mercury(I)sulfate 7783-36-0 Hg
Mercury(II)
628-86-4 Hg(ONC)
2SO4
fulminate
Mercury(II)acetate 1600-27-7 Hg(CH
Methylmercury salts
e.g.
22967-92-6
X=Cl,Br,I,OH, etc.
Ethylmercury salts
C
CH
3
2H5
3
HgX ;
HgX ;
X=Cl,Br,I,OH, etc.
HgX ;
Propylmercury salts
C
3H7
X=Cl,Br,I,OH, etc.
HgX ;
Phenylmercury salts
C
6H5
X=Cl,Br,I,OH, etc.
Methoxyethylmercury salts
Dialkylmercury
CH
3OC2H4
X=Cl,Br,I,OH, etc.
Hg ;
R
2
R=alkyl group
(C
nH2n+1
Diphenylmercury 587-85-9 (C
Other mercury
6H5)2
compounds
3)2
2
COO)2
HgX ;
)
Hg
毛毡、催化剂
电池
防霉剂
防腐剂、杀菌剂
防腐剂、杀菌剂
杀菌剂、防霉剂
根据著作权法,严禁擅自复制、转载。
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Page 67
●六价铬化合物
1.所属物质的例子 仅含有六价的铬元素的物质才属于此类。
中文名称
(通称、简称、化学名称等)
三氧化铬;氧化铬(VI);无水 铬酸;铬酸
铬酸锂
铬酸钠
铬酸钾
氯铬酸钾
铬酸铵
铬酸铜
铬酸镁
铬酸钙;钙铬黄
铬酸锶
铬酸钡
铬酸铅;铬黄
铬酸锌;黄锌;锌黄
重铬酸钠
重铬酸钾
重铬酸铵
重铬酸钙
重铬酸锌
其他六价铬化合物
Chromium(VI) oxide; chromium trioxide
Lithium chromate 14307-35-8 Li
Sodium chromate 7775-11-3 Na
Potassium chromate 7789-00-6 K
Potassium chlorochromate
Ammonium chromate 7788-98-9 (NH
Copper chromate 13548-42-0 CuCrO
Magnesium chromate 13423-61-5 MgCrO
Calcium chromate 13765-19-0 CaCrO
Strontium chromate 7789-06-2 SrCrO
Barium chromate 10294-40-3 BaCrO
Lead chromate; chrome yellow
Zinc chromate
Sodium dichromate; sodium bichromate
Potassium dichromate; potassium bichromate
Ammonium dichromate; ammonium bichromate
Calcium dichromate; calcium bichromate
Zinc dichromate; zinc bichromate
Other hexavalent chromium compounds
英文名称 CAS号码 化学分子式 主要用途
SS-00259 第 7 版 一般公开版
1333-82-0 CrO
3
颜料、催化剂、电镀、 鞣革(Tanning)
CrO4
2
CrO4
2
CrO4
2
防锈
防锈、鞣革(Tanning)
颜料、油墨、鞣革 (Tanning)
16037-50-6 K[CrO
4)2
Cl]
3
CrO4
相片、催化剂
媒染剂
4
防锈、表面处理
4
颜料、油墨、鞣革
4
(Tanning) 颜料、防锈
4
防锈、颜料、陶瓷用
4
着色剂 颜料、涂料、油墨
ZnCrO
4
4
颜料、防锈
1344-37-2 PbCrO
12018-19-8; 13530-65-9;
14018-95-2
10588-01-9 Na
2Cr2O7
颜料、防锈、相片、 鞣革(Tanning)
7778-50-9 K
2Cr2O7
颜料、相片、电镀、 电池、鞣革(Tanning)
颜料、相片、催化剂
7789-09-5 (NH
4)2Cr2O7
14307-33-6 CaCr
ZnCr
2O7
2O7
颜料
防锈、催化剂
根据著作权法,严禁擅自复制、转载。
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Page 68
●多氯联苯(PCB)、多氯化萘(PCN)、多氯三联苯(PCT)
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
英文名称 CAS号码
SS-00259 第 7 版 一般公开版
化学分子
主要用途
PCB;多氯联苯;氯化联苯 PCB; polychlorinated biphenyls 1336-36-3
PCN;多氯化萘;氯化萘 PCN; polychlorinated naphthalenes
C
12H10-xClx
(x=1-10)
C
10H8-xClx
(x≧3)
热载体、润滑剂 和电容器油
润滑剂、防腐剂、 涂料
三氯化萘 Trichloronaphthalene 1321-65-9 C10H5Cl3 四氯化萘
五氯化萘
八氯化萘
Tetrachloronaphthalene 1335-88-2 C
Pentachloronaphthalene 1321-64-8 C
Octachloronaphthalene 2234-13-1 C
PCT;多氯三联苯 PCT; polychlorinated terphenyls 61788-33-8
C
(x=1-14)
10H4Cl4
10H3Cl5
10Cl8
18H14-xClx
润滑剂、防腐剂、 涂料
●短链型氯代烷烃 (SCCP)
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
氯化烷烃;短链氯化石蜡; 碳原子数 C10-13 氯代烃
Short-chain Chlorinated paraffins C10-13
英文名称 CAS号码 化学分子式 主要用途
e.g.
增塑剂、阻燃剂
85535-84-8
●多溴联苯 (PBB)
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
英文名称 CAS号码 化学分子式 主要用途
PBB;多溴联苯 PBB; Polybrominated biphenyls
根据著作权法,严禁擅自复制、转载。
- 27 –
e.g.
67774-32-7
C
12H10-xBrx
(x=1-10)
阻燃剂
Page 69
●多溴联苯醚(PBDE)
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
SS-00259 第 7 版 一般公开版
英文名称 CAS号码 化学分子式 主要用途
多溴二苯醚;聚溴二苯醚;PBDE;PBDO; PBBE
十溴二苯醚;DBDE;DecaBDE;DBDPE; DBDPO
八溴二苯醚;OBDE;OctaBDE
六溴二苯醚
五溴二苯醚;PentaBDE
Polybromodiphenyl ethers; polybromodiphenyloxides; polybrominated biphenyl ethers; PBDE; PBDO; PBBE
Decabromodiphenyl ether; decabromodiphenyloxide; DBDE;DecaBDE;DBDPE; DBDPO
Octabromodiphenyl ether; octabromodiphenyloxide; OBDE;OctaBDE
Hexabromodiphenyl ether; hexabromodiphenyloxide
Pentabromodiphenyl ether; pentabromodiphenyloxide; PentaBDE
C
12H10-xBrx
(x=1-10)
1163-19-5 C
12Br10
O
32536-52-0 C12H2Br8O
36483-60-0 C12H4Br6O
32534-81-9 C12H5Br5O
阻燃剂
O
阻燃剂(PE、 ABS 、 聚 酯 用)
阻燃剂 (ABS、HIPS、 LDPE用)
阻燃剂
阻燃剂
根据著作权法,严禁擅自复制、转载。
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SS-00259 第 7 版 一般公开版
●三丁基锡化合物(TBT)、三苯基锡化合物(TPT)
1.所属物质的例子 仅三丁基锡化合物和三苯基锡化合物属于此类,而二丁基锡化合物(DBT)和二苯基锡化合物(DPT)等则不属于此
类。 另外,金属锡、锡合金、电镀锡、锡的无机化合物也不属于此类。 所属物质的例子如下所示。
中文名称
(通称、简称、化学名称等)
三正丁基溴化锡 Tributyltin bromide 1461-23-0 (C4H9)3SnBr
三丁基氧化锡(TBTO); 双三丁基氧化锡
Tributyltin oxide; Bis(tributyltin)oxide; Distannoxane,hexabutyl-
三苯基锡 Triphenyltin 668-34-8 (C6H5)3Sn
三苯基氯化锡;氯化三苯基锡 Triphenyltin chloride;
Fentin chloride; Stannane,chlorotriphenyl-
三苯基羟基锡;三苯基氢氧化锡 Triphenyltin Hydroxide;
Fentin hydroxide; Stannane,Bydroxytriphenyl-
三苯基锡=N,N’-二甲基二硫代 氨基甲酸酯;二甲基二硫代氨基 甲酸三苯基锡
Triphenyltin N,N’
-dimethyldithiocarbamate; Stannane,[[(dimethylamino)thi
omethy1]thio]triphenyl-
三苯基氟化锡
Triphenyltin fluoride; Fentin fluoride
英文名称 CAS号码 化学分子式 主要用途
杀菌剂
56-35-9 C24H54OSn2
杀菌剂
杀菌剂
639-58-7 (C6H5)3SnCl
76-87-9 (C6H5)3SnOH
1803-12-9 (C6H5)3Sn(CH3)2
NCS
2
379-52-2 (C
6H5)3
SnF
杀菌剂
杀菌剂
三苯基锡醋酸盐;醋酸三苯基锡;
三苯基乙酸锡
三苯基锡脂肪酸盐(仅限于脂肪 酸的碳原子数为 9、10 或 11 之 物)
Triphenyltin acetate;
900-95-8 (C
Fentin acetate; Stannane,(acetyloxy)triphenyl-
Triphenyltin fatty acid salts 18380 -71-7 ;
18380-72-8; 47672-31-1;
94850-90-5
根据著作权法,严禁擅自复制、转载。
SnOCOCH3
6H5)3
- 29 –
Page 71
SS-00259 第 7 版 一般公开版
中文名称
(通称、简称、化学名称等)
三苯基锡氯代乙酸盐;三苯基锡 氯代醋酸盐
三丁基甲基丙烯酸锡(TBTM) Tributyltin methacrylate;
英文名称 CAS 号码 化学分子式 主要用途
Triphenyltin chloroacetate; (chloroacetoxy)triphenylstann
7094-94-2
(C6H5)3SnOCOCH2C
l
ane
2155-70-6 (C4H9)3SnC4H5O2
Tributyl(methacryloyloxy) stannane;
Stannane,Tributyl[(2-methyl­l-oxo-2-propeny)oxy]-
C
双(三丁基锡)富马酸盐 Bis(tributyltin) fumarate 6454-35-9;
24291-45-0
三丁基氟化锡 Tributyltin fluoride 1983-10-4;
(COO)2
2H2
([C
4H9]3
Sn)2
(C4H9)3SnF
7304-48-5
双(三丁基锡)2,3-二溴丁二酸 盐
Bis(tributyltin)2,3­dibromosuccinate
31732-71-5;
56323-17-2
([C4H9]3Sn)2C2H2
(BR)
(COO)2
2
乙酸三丁基锡;醋酸三丁基锡 Tributyltin acetate 56-36-0 (C4H9)3SnOCOCH3
月桂酸三丁基锡;三丁基((1­氧代十二烷基)氧)锡
Tributyltin laurate; Tributyl(lauroyloxy)stannane
3090-36-6 (C
SnC12H23O2
4H9)3
双(三丁基锡)苯二甲酸盐; 三丁基锡苯二甲酸盐
三丁基锡磺酸盐
双(三丁基锡)马来酸盐
三丁基氯化锡
Bis(tributyltin)phthalate;
4782-29-0
[(Phthaloylbis(oxy)]bis(tr ibutylstannane)
Tributyltin sulfamate;
6517-25-5 (C4H9)3SnSO3NH2
Stannane,[(aminosulfonyl)oxy ]tributyl-
Bis(tributyltin) maleate 14275-57-1;
24291-45-0
Tributyltin chloride; Tributylchlorostannane;
1461-22-9;
7342-38-3
Stannane, tributylchloro-
(C
)(COO)2
6H4
([C
4H9]3
Sn)2
C28H56O4Sn2
(C4H9)3SnCl
根据著作权法,严禁擅自复制、转载。
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中文名称
(通称、简称、化学名称等)
三丁基锡环烷酸锡和其异构
体的混合物;萘酸三丁基锡;
三丁基环烷酸锡(TBTN)
英文名称 CAS号码 化学分子式 主要用途
Mixture of tributyltin cyclopentanecarboxylate and its analogs;
Stannane,tributyl-, mono (naphthenoyloxy)Derives.; Tributyltin naphthenate
SS-00259 第 7 版 一般公开版
85409-17-2
1,2,3,4,4a,4b,5,6,10,10a-
十氢-7-异丙基-1,4a-二甲基
-1-菲甲酸甲酯三丁基锡和其
异构体的混合物 ;三丁基锡
松香盐
丙烯酸辛酯,甲基丙烯酸甲酯 和甲基丙烯酸三丁基锡酯的 共聚物(烷基=丙烯酸盐的碳 原子数限定为 8 个);
Mixture of tributyltin 1,2,3,4,4a,4b,5,6,10,10a­decahydro-7-isopropyl-1,4 a-dimethyl-1-phenanthlene carboxylate and its analogs;
Tributyltin rosin salt
Octyl acrylate-Methyl methacrylate-Tributyltin methacrylate copolymer
(alkyl; C=8)
26239-64-5 C
32H56O2
Sn
67772-01-4
根据著作权法,严禁擅自复制、转载。
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●石棉
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
SS-00259 第 7 版 一般公开版
英文名称 CAS号码 化学分子式 主要用途
石棉 (总称)
蓝石棉
温石棉
铁石棉
直闪石
透闪石
阳起石
Asbestos
Crocidolite 12001-28-4 Na
Chrysotile 12001-29-5 Mg
Amosite 12172-73-5 (Mg,Fe)
Anthophyllite 77536-67-5 (Mg,Fe)
Tremolite 77536-68-6 Ca
Actinolite 77536-66-4 Ca
●甲醛
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
甲醛(单体);福尔马林
Formaldehyde; formalin; formic aldehyde; formol
●聚氯乙烯 (PVC) 以及 PVC 混合物
1.所属物质的例子
中文名称
(通称、简称、化学名称等)
1332-21-4;
绝缘体、填料
132207-32-0;
132207-33-1
(Si8O22)(OH)2
2Fe5
(OH)4
3Si2O5
(OH)2
7Si8O22
(OH)2
7Si8O22
2Mg5Si8O22
(Mg,Fe)5Si8O22(OH)2
2
(OH)2
绝缘体、填料
绝缘体、填料
绝缘体、填料
绝缘体、填料
绝缘体、填料
绝缘体、填料
英文名称 CAS号码 化学分子式 主要用途
50-00-0 CH2O
防腐剂、单体(如, 酚醛树脂和三聚 氰胺树脂)
英文名称 CAS号码 化学分子式 主要用途
PVC 和 PVC 混合物 ;聚氯乙 烯和聚氯乙烯混合物
氧化铍
1. 所属物质的例子
中文名称
(通称、简称、化学名称等)
氧化铍
PVC and PVC blends; polyvinyl chloride and
9002-86-2
polyvinyl chloride blends
英文名称 CAS 号码 化学分子式 主要用途
Beryllium oxide
1304-56-9
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- 32 –
e.g.
e.g.
聚氯乙烯树脂
BeO 散热片
Page 74
氢氟碳化合物(HFC)、全氟化碳(PFC)
1. 所属物质的例子
中文名称
(通称、简称、化学名称等)
SS-00259 第 7 版 一般公开版
英文名称 CAS 号码 化学分子式 主要用途
HFC-23;三氟甲烷 HFC-23;
75-46-7 CHF3 冷媒
Trifluoromethane
HFC-32; 二氟甲烷 HFC-32;
75-10-5 CH2F2 冷媒
Difluoromethane
HFC-41;氟代甲烷 HFC-41;
593-53-3 CH3F 冷媒
Fluoromethane
HFC-125;五氟乙烷 HFC-125; Pentafluoroethane 354-33-6 C2HF5 冷媒
HFC-134;1,1,2,2-四氟乙烷
HFC-134;
359-35-3 CHF2CHF2 冷媒
1,1,2,2-tetrafluoroethane
HFC-134a;1,1,1,2-四氟乙烷
HFC-134a;
811-97-2 CH2FCF3 冷媒
1,1,1,2-tetrafluoroethane
HFC-143;1,1,2-三氟乙烷
HFC-143;
430-66-0 CHF2CH2F 冷媒
1,1,2-trifluoroethane
HFC-143a;1,1,1-三氟乙烷
HFC-143a;
420-46-2 CH3CF3 冷媒
1,1,1-trifluoroethane
HFC-152a;1,1-二氟乙烷
HFC-152a;
75-37-6 CH3CHF2 冷媒
1,1-difluoroethane
HFC-227ea ;1,1,1,2,3,3,3- 七 氟丙烷
HFC-227ea; 1,1,1,2,3,3,3-heptafluorop
431-89-0 C
灭火剂
3HF7
ropane
HFC-236fa ; 1,1,1,3,3,3-六氟 丙烷
HFC-245ca;1,1,2,2,3- 五 氟 丙 烷
HFC-236fa; 1,1,1,3,3,3-hexafluoroprop ane
HFC-245ca; 1,1,2,2,3-pentafluoropropa ne
690-39-1 C
679-86-7 C
灭火剂
3H2F6
冷媒
3H3F5
HFC-43-10mee; 1,1,1,2,3,4,4,5,5,5-十氟戊 烷
PFC-14;四氟甲烷;全氟甲烷
PFC-116;六氟乙烷;全氟乙烷
PFC-218;八氟丙烷;全氟丙烷
PFC-31-10;十氟丁烷;全氟丁烷
PFC-c318;八氟环丁烷
PFC-41-12;十二氟戊烷;全氟戊烷
PFC-51-14;十四氟己烷;全氟己烷
HFC-43-10mee;
138495-42-8 C 1,1,1,2,3,4,4,5,5,5-decafl uoropentane
PFC-14; Perfluoromethane
PFC-116; Perfluoroethane
PFC-218; Perfluoropropane
PFC-31-10; Perfluorobutane
PFC-c318; Perfluorocyclobutane
PFC-41-12; Perfluoropentane
PFC-51-14; Perfluorohexane
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溶剂
5H2F10
75-73-0 CF4 干腐蚀
76-16-4 C2F6 冷媒
76-19-7 C3F8 冷媒
355-25-9 C4F10 灭火剂
115-25-3 c-C4F8 干腐蚀
678-26-2 C5F12 溶剂
355-42-0 C6F14 冷媒
Page 75
●全氟辛烷磺酸(及其盐)(PFOS)
1. 所属物质的例子
中文名称
(通称、简称、化学名称等)
SS-00259 第 7 版 一般公开版
英文名称 CAS 号码 化学分子式 主要用途
PFOS; 全氟辛烷磺酸;全氟辛基 磺酸钾
●特定苯并三氮唑
1. 所属物质的例子
中文名称
(通称、简称、化学名称等)
2-(3',5'-二叔丁基-2'-羟基苯 基)苯并三唑;
2-(2'-羟基-3',5'-二叔丁基苯 基)-苯并三唑
PFOS; Perfluorooctane sulfonates
英文名称 CAS 号码 化学分子式 主要用途
2-(3',5'-Di-tert-butyl-2'-hy droxyphenyl)benzotriazole;
2-(2'-Hydroxy-3',5'-di-tert­butylphenyl)benzotriazole
e.g.
2795-39-3
C
8F17SO2
(X=羟基,金 属盐, 卤化 物, 氨基,及 包括聚合物 在内的其他 衍生物)
3846-71-7 C
X
20H25N3
拒水剂、拒油 剂
紫外线防护
O
剂、紫外线吸 收剂
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- 34 –
Page 76
SS-00259 第 7 版 一般公开版
(注意事项) 有时可能在未公告的情况下,对索尼技术标准 SS-00259 零部件和材料中的环 境管理物质 管理规定进行内容的修订或修改。
零部件和材料中的环境管理物质 管理规定 (SS-00259 第 7 版一般公开版)
发行日: 2008年4月1日 发行 : 索尼株式会社
技术标准事务局
根据著作权法,严禁擅自复制、转载。
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