SAFETY DATA SHEET
(according to Annex II of EU Regulation 2015/830)
EcoSept
SECTION 1. Identification of the substance/mixture and of the company/undertaking
1.1: Product identified
Product name: EcoSept
Product number: 903626
1.2: Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Disinfectant for washing machine for thermolabile tools and non-invasive
medical devices
1.3: Details of the Supplier of the safety data sheet
Manufacturer/Supplier: SMEG s.p.a.
Via Leonardo da Vinci 4,
Telephone number: +39-0522-8211
Fax: +39-0522-821592
e-mail address: chemicals@smeg.it
1.4: Emergency telephone number
Emergency phone number: CENTRE OF POISON CONTROL CAV Niguarda – MILANO Tel. +39 02-66101029
SECTION 2. Hazard identification
2.1. Classification of the substance or mixture
The product is classified as dangerous according to the Regulation (EC) n. 1272/2008 (CLP) and subsequent modifications
and integrations. The product requires a Safety Data Sheet (SDS) in accordance with Regulation (EC) n. 1907/2006 and
subsequent modifications and integratios. Further information concerning health and/or environmental risks is reported in
SECTIONS 11 and 12 of this document.
Classification and hazard statements:
Acute toxicity, cat 4 H302 Harmful if swallowed
Eye Irritation, cat 2 H319 Causes serious eye irritation
2.2. Label elements
Labelling according to Regulation (EC) 1272/2008 (CLP) and subsequent amendments.
Hazard pictograms:
42016 – GUASTALLA
ITALIA
Signal word: Warning
Hazard Statements:
H302 Harmful if swallowed.
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H319 Causes serious eye irritation.
Precautionary Statements:
P264 Wash exposed areas thoroughly after handling.
P280 Wear protective gloves, eye protection, face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician if feel unwell.
P305+P351+P338 IF IN EYES: rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P330 Rinse mouth.
P337+P313 If eye irritation persists, get medical advice/attention.
It contains: 2-PHENOXYETHANOL
2.3. Other hazards.
Based on data available, the product does not contain PBT or vPvB substances in a percentage > 0.1%.
SECTION 3. Composition/information on ingredients
3.1. Substances
No relevant information.
3.2. Mixtures
Content:
Identification Conc. %.
2-PHENOXYETHANOL
CAS. 122-99-6 50 – 90 Acute Tox. 4 H302, Eye
Irrit. 2 H319
CE. 204-589-7
INDEX. 603-098-00-9
Note: upper value of the range excluded.
For full text of H-statements (H): see SECTION 16.
SECTION 4. First aid measures
4.1. Description of first aid measures
EYE CONTACT: Remove contact lenses, if present and easy to do. Rinse thoroughly with plenty of water for at least 15
minutes. Obtain medical attention if the problem persists.
SKIN CONTACT: Take off the contaminated clothing. Rinse with plenty of water. If irritation persists, get medical advice and
attention. Wash all contaminated clothes before the reuse.
INHALATION: Move the person into fresh air. If breathing is difficult, call doctor/physician.
INGESTION: Call doctor/physician. Induce vomiting only under doctor/physician indication. Never give anything by mouth
to an unconscious person and if not indicated by the doctor/physician.
4.2. Most important symptoms and effects, both acute and delayed
For symptoms and effects from the contained substances, see SECTION 11.
4.3. Indication of any immediate medical attention and special treatment needed
No data available.
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SECTION 5. Firefighting measures
5.1. Extinguishing media
SUITABLE EXTINGUISHING MEDIA:
Use common extinguishing media: carbon dioxide, foam, dry powder and water spray.
UNSUITABLE EXTINGUISHING MEDIA:
None in particular.
5.2. Special hazards arising from the substance or mixture
HAZARD ARISING FROM EXPOSITION IN CASE OF FIRE
Avoid breathing the combustion products.
5.3. Advices for firefighters
GENERAL INFORMATION
Use water spray for cooling exposed containers to avoid the product decomposition and the release of harmful for the
health substances. Do not enter fire area without proper protective equipment. Prevent run-off from firefighting into storm
drains, water bodies of other environmentally sensitive areas.
EQUIPMENT
Full firefighting protective equipment like Self-Contained Breathing Apparatus (EN 137), flame-resistant clothing (EN 469),
flame-resistant gloves (EN 659) and firefighters boots (HO A29 or A30).
SECTION 6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures.
Contain the spill if safe to do so.
Use adequate personal protective equipment (PPE), including the personal protective equipment described in SECTION 8,
to avoid contact skin, eyes and clothing contaminations. These statements are valid both for non-emergency and
emergency personnel.
6.2. Environmental precautions
Prevent entry into drains, sewers, and other waterways.
6.3. Methods and material for containment and cleaning up
Collect the spill in a suitable container. Assess the compatibility of the container with the product according to info in
SECTION 10. Absorb and/or contain the remaining with inert absorbing material. Ventilate the area. Verify the
incompatibility of the material with the container according to SECTION 7. Dispose of contaminated material in accordance
with SECTION 13.
6.4. Reference to other sections.
For any information regarding personal protection and the disposal, refer to SECTIONS 8 and 13
.
SECTION 7. Handling and storage
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7.1. Precaution for safe handling
Handle after reading all the other sections of this safety data sheet. Avoid releasing of the product in the environment. Not
eating, drinking, and smoking while handling. Remove contaminated clothing and personal protection equipment before
eating.
7.2. Conditions for safe storage, including any incompatibilities
Store in the original container. Keep container tightly closed and store in a dry, cool and well-ventilated place. Keep/Store
away from direct sunlight and not close to incompatible materials (see SECTION 10).
SECTION 8. Exposure controls/personal protection
8.1. Control parameters
Reference legislation:
AUS Österreich Grenzwerteverordnung 2011 - GKV 2011
DEU Deutschland MAK-und BAT-Werte-Liste 2012
2-PHENOXYETHANOL
Threshold limits
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
MAK AUS 110 20 110 20
AGW DEU 110 20 220 40 SKIN.
MAK DEU 110 20 220 40 SKIN.
8.2. Exposure controls
Handle always in accordance with good safety practice before to use personal protection equipment, ensure good
ventilation of the workplace by means of an effective local intake system.
Ask eventually to the chemicals supplier for specific personal protection equipment.
The selected personal protective equipment has to satisfy CE marking requirements according to the legislation in force.
Ensure eyewash/safety shower stations are available in the immediate vicinity of any potential exposure.
HAND PROTECTION
Wear protective gloves category III (standard EN 374).
When selecting the material of work gloves consider: compatibility, degradation, breaking time, and permeability. In case
of mixture, before to use verify if the gloves are resistant from chemicals. Gloves must be inspected prior to use and their
lifetime depends on the duration and modality of use.
SKIN PROTECTION
Wear protection clothing with long sleeves and professional safety footwear category I (Directive 89/686/CEE and standard
EN ISO 20344). Wash with soap water and dry hands after removing/taking off all protective clothing.
EYE PROTECTION
Wear safety glasses (standard EN 166).
If there is the risk of splash hazard, consider adequate protection of mucous (mouth, nose, eyes) to avoid accidental
absorptions.
RESPIRATORY PROTECTION
In case of exceeding the threshold values (e.g. TLV-TWA) of the substances or one of the substances in the product, wear a
mask with type A filter which class (1, 2 or 3) should be selected according to the limit concentrations in use (standard EN
14387). In case of presence of other gases or vapours and/or gases or vapours with particles (aerosol, smoke, fog, etc.)
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consider a combined filter.
The use of respiratory protection media is necessary in case of the technical measures taken are not sufficient to limit the
exposure of workers at the threshold values considered. Consider that the mask protection is in any case limited.
In case the substance is odourless or the olfactory threshold is higher of the relative TLV-TWA, and in case of emergency,
wear an open-circuit SCBA - Self Contained compressed air Breathing Apparatus (standard EN 137) or a fresh air hose
breathing apparatus (standard EN 138). For respiratory protection specific equipment, refer to standard EN 529.
ENVIRONMENTAL EXPOSURE CONTROL
Emissions from production processes, including ventilation systems, should be checked according to the national (or local)
environmental protection legislation.
SECTION 9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state Liquid
Appearance Colourless
Odour Odourless
Odour threshold Not available
pH (sol.1%) 8,45
Melting point/freezing point Not available
Initial boiling point Not available
Boiling range Not available
Flash point Not available
Evaporation rate Not available
Flammability (solid, gas) Not available
Lower flammable limit Not available
Upper flammable limit Not available
Upper explosive limit. Not available
Lower explosive limit. Not available
Vapour pressure Not available
Vapour Density Not available
Relative Density 1,087 kg/L
Solubility Not available
Partition coefficient: n-octanol/water Not available
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity Not available
Explosive properties Not available
Oxidising properties Not available
9.2. Other information.
VOC (Directive 2010/75/EC): 100,00 % - 1.086,71 g/L.
VOC (Volatile Carbon): 62,83 % - 682,78 g/L.
SECTION 10. Stability and Reactivity
10.1. Reactivity
Hazardous reactions will not occur under normal conditions.
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2-PHENOXYETHANOL: 1 % in water reacts, slightly acid (pH=6).
10.2. Chemical stability
Stable at standard handling and storage conditions.
10.3. Possibility of hazardous reactions
Under normal use and storage conditions, hazardous reactions are not predictable.
10.4. Conditions to avoid
None in particular. Follow the good practice when using chemical products.
10.5. Incompatible materials
2-PHENOXYETHANOL: strong oxidant.
10.6. Hazardous decomposition products
No data available.
SECTION 11. Toxicological information
11.1. Information on toxicological effects
Since experimental toxicological data are not available for this product, information related to the single components cited
on SECTION 3 are herein reported.
Acute effects: the product is toxic if swallowed and even small quantities swallowed could create health disorders
(abdominal pain, stomach ache, nausea, diarrhoea, vomiting). Eye contact could cause eyes irritation, symptoms could be:
redness, swollen eye, lachrymation, and pain.
.
SECTION 12. Ecological information
Use according the good working practice, avoiding the release in the surrounding environment. Report spills and releases
in sewers, water bodies or on soil/vegetation.
12.1. Toxicity
No data available.
12.2. Persistence and degradability
2-PHENOXYETHANOL
Water solubility. 28600 mg/L
Readily Biodegradable.
12.3. Bioaccumulative potential
2-PHENOXYETHANOL
n-octanol/water partition
coefficient
BCF 0,3493
12.4. Mobility in soil
2-PHENOXYETHANOL
Soil/water partition
coefficient.
1,2
1,6
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12.5. Results of PBT and vPvB assessment
Based on available data, the product does not contain PBT or vPvB substances in a percentage upper than 0,1%.
12.6. Other adverse effects
No data available.
SECTION 13. Disposal Considerations
13.1. Waste treatment methods
INFORMATION CONCERNING DISPOSAL
Reuse, if possible. The product residues must be considered as special hazardous waste. The dangerousness of waste, which
contains in part this product, must be assessed according to the regulations in force. A licensed disposal company has to be
commissioned for the waste disposal in agreement with the national, and in case local, regulations in force.
CONTAMINATED PACKAGING
Contaminated packaging has to be recovered or disposed of at an approved site according to the national regulations for
waste management.
SECTION 14. Transport information
14.1. UN Number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Not applicable.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II di MARPOL 73/78 end IBC code
Not relevant information.
SECTION 15. Regulatory information
15.1. Safety, health and environmental regulations/legislations specific for the substance or mixture
Seveso Category: None
Restrictions on the use according to Annex XVII of Regulation (EC) 1907/2006 (REACH):
Product:
Point. 3
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Substances in the Candidate List (Art. 59 REACH):
None
Substances subject to authorisation (Annex XIV REACH):
None
Substances subject to notification in case of export Regulation (EU) 649/2012:
None
Substances subject of Rotterdam Convention:
None
Substances subject of Rotterdam Convention:
None
Sanitary Controls:
Workers exposed to this chemical product should be subject of health surveillance according to the specific national law.
15.2. Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
SEZIONE 16. Other information
Hazard Statements (H) cited in SECTIONS 2 and 3 of the SDS:
Acute Tox. 4 Acute Toxicity, category 4
Eye Irrit. 2 Eye Irritation, category 2
H302 Harmful if swallowed
H319 Causes serious eye irritation
LEGEND:
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- CAS NUMBER: Chemical Abstract Service number
- EC50: Maximal effective concentration to 50 % of a test population
- EC-Number: EINECS ad ELINCS number (European database of existing substances)
- CLP: Classification Labelling Packaging Regulation; Regulation (EC) 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labelling of Chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilisation Concentration for the 50% of the test population
- IMDG: International Maritime Dangerous Goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier Number of Annex VI of CLP Regulation
- LC50: Lethal Concentration to 50 % of a test population
- LD50: Lethal Dose to 50 % of a test population
- OEL: Occupational Exposure Limit
- PBT: Persistent, Bioaccumulative and Toxic substance according to REACH Regulation
- PEC: Predicted Effect Concentration
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- PEL: Predicted Effect Level
- PNEC: Predicted No Effect Concentration
- REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals, Regulation (EC) n. 1907/2006
- RID: Regulations concerning the International Carriage of Dangerous Goods by Rail
- TLV: Threshold Limit Value
- TLV-C: Threshold Limit Value – Ceiling limit (absolute exposure limit that should not be exceeded at any time)
- TLV-STEL: Threshold Limit Value short-term exposure limit
- TLW-TWA: Threshold Limit Value Time-weighted average
- VOC: Volatile Organic Compound
- vPvB: very Persistent and very Bioaccumulative substance according to REACH Regulation
- WGK: Aquatic Hazard Class (Germany).
REFERENCES:
1. Regulation (UE) 1907/2006 of the European Parliament (REACH)
2. Regulation (UE) 1272/2008 of the European Parliament (CLP)
3. Regulation (UE) 790/2009 of the European Parliament (I amendment CLP)
4. Regulation (UE) 453/2010 of the European Parliament
5. Regulation (UE) 286/2011 of the European Parliament (II amendment CLP)
6. Regulation (UE) 618/2012 of the European Parliament (III amendment CLP)
7. Regulation (UE) 487/2013 of the European Parliament (IV amendment CLP)
8. Regulation (UE) 944/2013 of the European Parliament (V amendment CLP)
9. Regulation (UE) 605/2014 of the European Parliament (VI amendment CLP)
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
- N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition
- ECHA website
Notes for the uses:
To the best of our knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy,
suitability or completeness is not guaranteed and no warranties of any type wither express of implied are provided. The
information contained herein relates only to this specific product.
Assure appropriate training to the personnel on the use of good hygiene practice and good safety practice when using
chemicals.
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