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1.2:
Relavant identified used of the substance/mixture and uses advised against
1.3:
Details of the supplier of safety data sheet
1.4:
Emergency telephone number
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1. Identification of substance/mixture and of the Company/Undertaking
1.1: Product identifier
Product name:
Product number: 901116
Identified uses: Alkaline detergent for professional instrument washers
Manufacturer/Supplier: SMEG s.p.a.
Via Leonardo da Vinci 4,
Telephone: +39-0522-8211
Fax: +39-0522-821592
E –mail address: chemicals@smeg.it
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42016 – GUASTALLA
ITALY
Emergency phone #: National Poison Centre: +39 02-66101029 (CAV Niguarda – MILAN)
2. Hazard identification
2.1: Classification of the substance or mixture
Classification according to Directive 67/548/CEE (s.m.i.):
Corrosive
C R35
Classification according to Regulation CE 1272/2008 (CLP):
Skin Corr. 1A
2.2 Label elements:
Labelling according to the European Directive 67/548/CE (smi)
Hazard symbol
R-phrases
R35 Causes severe burns
S-phrases
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37 Wear suitable protective clothing and gloves
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No. CE
No. CAS
Name
Quantit
y Labeling
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where
possible)
Labelling according to Regulation CE n.1272/2008 (CLP)
Pictogram
Signal word Danger
Hazard statements
H314: Causes severe skin burns and eye damage.
Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection
P310 Immediately call a POISON CENTER or doctor/physician
P351 Rinse cautiously with water for several minutes
2.3 Other hazards:
None
3. Compostion / Information on ingredients
Content:
-- 1344-09-8
-- 9003-01-07
215-181-3 1310-58-3
Where
R22 Harmful if swallowed
R35 Causes severe burns
R36/38 Irritating to eyes and skin.
R36/37/38 Irritating to eyes, respiratory system and skin.
4. First aid measures
4.1. Description of first aid measures
General information
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
Move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with plenty of water.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Sodium silicate
Polyacrylate
Potassium hydroxide
15-30% Xi R36/38
10-20% R36/37/38
5-15% C R35, Xn R22
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4.2. Most important symptoms and effects, both acute and delayed
Not available. To the best of our knowledge, the chemical, physical and toxicological properties are not the
object of an in-depth investigation.
4.3. Indication of any immediate medical attention and special treatment needed
No data available
5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water, foam. Spray water jet.
5.2. Special hazards arising from the substance or mixture
Combustion may release toxic fumes
5.3. Advice for firefighters
Use safety measures as described in sections 7 and 8.
5.4. Additional information
No data available
6. Accidental release measures.
6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment (gloves, goggles, protective clothing)
6.2 Environmental precautions
Do not let product spread into drains or ground water.
6.3 Methods and materials for containment and cleaning up
Collect with absorbent materials (sand, diatomaceous earth). Sweep up and shovel. Keep in suitable, closed
containers for waste disposal. Suitable material for diluting or neutralizing: Water
6.4 Reference to other sections
For disposal see section 13.
7. Handling and storage
7.1. Precautions for safe handling
Avoid contact with eyes and skin.
7.2. Conditions for safe storage, including any incompatibilities
Do not store near acids. Do not store at direct sunlight/UV light. Do not store near heat sources
7.3. Specific end uses
Detergent for professional automated washing.
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8. Exposure controls/personal protection
8.1. Control parameters
Components with exposure limits
Fonte ACGIH 2013
CAS number Chemical Agent TWA [ppm] STEL [mg/m3] Critical effects
1310-58-3 Potassium
hydroxide
8.2. Exposure controls
Appropriate engineering controls
Handle in accordance with good safety practice. Wash hands after use.
Protective and hygiene measures
Eye/face protection
Safety glasses with side-shields. Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN374 derived from it.
Protection for immersion and splash
Material: Lattice and PVC
Body Protection
Protection clothing. Remove/Take off all contaminated clothing.
Respiratory protection
If product is sprayed in high concentrations or in case of insufficient ventilation adequate masks and filters
suitable for dusts/aerosols (P2) are recommended.
This recommendation has to be considered as an advice and has to be weighed by an Industrial Hygienist,
who knows the specific situation of the use expected by our customers. It must not be interpreted as an
approval of a specific scenario of exposure.
9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
a) Appearance Physical state Liquid
b) Odour distinctive
c) pH (sol.1%) 11.0 -12.0
d) Density at 20 °C 1.17-1.19 g/cm3
e) Flammability Not applicable
f) Boiling point ca. 100 °C
g) Vapour pressure Not Available
h) Hydrosolubility soluble
i) Liposolubility Not Available
j) Explosive properties Not Available
k) Oxidizing properties Not Available
9.2. Other information
Data not available
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10. Stability e reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under normal conditions (comply with conditions in section 7).
10.3 Possibility of hazardous reactions
The product reacts violently with acids (comply with conditions in section 7).
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
No data available
10.6 Hazardous decomposition products
Upon contact with acids releases toxic gases (Cl2)
11. Toxicological information
11.1 Information on toxicological effects
Since the data related to the mixture are not available, information related to the single components are
herein reported.
Acute toxicity
[1310-58-3] Potassium hydroxide LD50 oral - rat - 333 mg/kg
[9003-01-07] Polyacrylate – not available
[7681-52-9] Sodium hypochlorite solution – not available
Skin corrosion/irritation
[1310-58-3] Potassium hydroxide Pelle - rabbit - Result: Severe skin irritation - 24 h
[9003-01-07] Polyacrylate – not available
[7681-52-9] Sodium hypochlorite solution – not available
Serious eye damage/eye irritation
[1310-58-3] Potassium hydroxide Eyes - rabbit Result: Corrosive to eyes (OECD TG 405)
[9003-01-07] Polyacrylate – not available
[7681-52-9] Sodium hypochlorite solution – not available
Respiratory or skin sensitisation
No data available.
Germ cell mutagenicity
Genotoxicity in vitro – no data available
Genotoxicity in vivo - no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable,
possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity
No data available
Aspiration hazard
No data available
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Potential consequences for health
Skin: causes burns
Eyes: causes severe eye damages
Symptoms of exposure
Not available. To the best of our knowledge, the chemical, physical and toxicological properties are not the
object of an in-depth investigation
12. Ecological information
12.1 Toxicity
Toxicity to fish LC50– 440-706 mg (96h)
[1310-58-3] Potassium hydroxide – Toxicity to fish LC50 – 80 mg/l
[7681-52-9] Sodium hypochlorite Toxicity to fish LC50 – 0.01-0.1 mg/l
[7681-52-9] Sodium hypochlorite – Toxicity to daphnia and other aquatic invertebrates EC50 - 0.01-0.1 mg/l
[9003-01-07] Polyacrylate – not available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
No data available
13. Disposal considerations
13.1 Waste treatment methods
Information concerning disposal
Can be burnt together with normal waste according upon consulting the regulations in force and the authority
in charge.
European Waste Code of the product
200115 MUNICIPAL WASTE (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND
INSTITUTIONAL WASTES) INCLUDING THE WASTE COLLECTION; separately collected fractions (except
15 01); alkaline substances - hazardous waste.
European Waste Code of contaminated packaging
150102 WASTE PACKAGING, ABSORBENT, RAGS, FILTER MATERIALS AND PROTECTIVE CLOTHING
(NOT OTHERWISE SPECIFIED); packaging (including municipal packaging waste separately collected);
plastic packaging.
Disposing of the contaminated packaging and recommended detergents
Completely emptied packing can be re-cycled. Disposal according to local authority regulations.
14. Transport information
14.1 UN number:
ADR-RID-ADN-IMDG-IATA: UN1814
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14.2 UN proper shipping name
ADR-RID-ADN-IMDG-IATA: POTASSIUM HYDROXIDE IN SOLUTION
14.3 Transport hazard classes
ADR-RID-ADN-IMDG-IATA: 8
14.4 Packaging group
ADR-RID-ADN-IMDG-IATA: II
14.5 Environmental hazards
Dangerous for the environment NO
Marine pollutant NO
14.6 Special precautions for user
Road transport must be carried by vehicles authorized to the carriage of dangerous goods according to the
requirements in the current edition of the Agreement A.D.R. and the applicable national regulations. The
goods must be transported in their original packaging and, in any case, in packaging made of materials
resistant to and not likely to cause dangerous reactions with their content. People in charge of loading and
unloading dangerous goods must be trained on all the risks deriving from these substances and on all
actions that must be taken in case of emergency situations.
ADR
Tunel code (E)
IMDG
EmS F-A, S-B
Stowage and segregation Category A. “Separated from” acids.
IATA
Pkg Inst 851
LDT QTY Y840
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and Code IBC
Non applicabile
15. Regulatory information
This safety datasheet complies with the requirements of Regulation (CE) Num. 1907/2006
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Labeling of ingredients according to Regulation CE/648/2004, Annex 7:
none
15.2. Chemical Safety Assessment
No data available
16. Other information.
Further information
The receiver of our product is solely responsible for compliance with applicable laws and regulations. The
information is based on present level of our knowledge. However, the information is not a guarantee of
product properties nor represents the completion of any legal relationship.
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