According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010]
According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)
2.1 Classification of the substance or mixture
CLP
DSD/DPD
2.2 Label Elements
CLP
Skin Irritation 2 - H315
Hazardous to the aquatic environment Chronic 2 - H411
Harmful (Xn)
Dangerous to the Environment (N)
R12, R51, R53
DANGER
H315 - Causes skin irritation
Preparation Date:15 May 2015
Revision Date: 06/21/17
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Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 2
Hazard statements
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Extremely flammable aerosol
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Risk phrases
R12 - Extremely flammable.
Storage/Disposal
P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding
Response
P391
Prevention
P210 - Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking.
Flammable Aerosols 1
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50ºC/122ºF.
P501 - Dispose of content and/or container in accordance with local, regional,
-
P211 - Do not spray on an open flame or other ignition source.
R48/20 - Harmful: danger of serious damage to health by prolonged exposure through
inhalation.
R51 - Toxic to aquatic organisms. R53 - May cause long-term adverse effects in the aquatic environment.
Safety phrases
S9 - Keep container in a well ventilated place
Collect
P251 - Pressurized container: Do not pierce or burn, even after use.
P260 -
Do not breathe gas/mist/vapours/spray.
thoroughly
Wash
P264 -
Black Ice Aerosol
Precautionary statements
H411 - Toxic to aquatic life with long lasting effects
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after handling.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
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P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P321 - Specific treatment, see supplemental first aid information.
P362 - Take off contaminated clothing and wash before reuse.
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P314 - Get medical advice/attention if you feel unwell.
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spillage.
national, and/or international regulations.
DSD/DPD
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S16 - Keep away from sources of ignition - No Smoking.
S57 - Use appropriate containment to avoid environmental contamination.
2.3 Other Hazards
CLP
DSD/DPD
According to Regulation (EC) No. 1272/2008 (CLP) this material is considered
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hazardous.
According to European Directive 1999/45/EC this material is considered dangerous.
Preparation Date:15 May 2015
Revision Date: 06/21/17
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Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 3
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In Canada,
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Prevention
Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking.
Material does not meet the criteria of a substance in accordance with Regulation (EC)
the
Flammable Aerosols - B5
Flammable Aerosols - B5
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Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe gas/mist/vapours/spray.
Wash thoroughly after handling.
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
under the
Workplace Hazardous Materials Information System (WHMIS).
Black Ice Aerosol
Storage/Disposal
Specific treatment, see supplemental first aid information.
Take off contaminated clothing and wash before reuse.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
Get medical advice/attention if you feel unwell.
Protect from sunlight. Do not expose to temperatures exceeding 50ºC/122ºF.
2.3 Other hazards
OSHA HCS 2012
Under United States Regulations (29 CFR 1910.1200 - Hazard Communication
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Standard), this product is considered hazardous.
Canada
According to: WHMIS
2.1 Classification of the substance or mixture
WHMIS
2.2 Label elements
WHMIS
Other Toxic Effects - D2A
2.3 Other hazards
WHMIS
Other Toxic Effects - D2A
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product mentioned above is considered hazardous
Section 3 - Composition/Information on Ingredients
3.1 Substances
3.2 Mixtures
No 1272/2008.
Composition
Chemical
Name
Identifiers
Preparation Date:15 May 2015
Revision Date: 06/21/17
%
LD50/LC50
Classifications According to Regulation/Directive
Page 3 of 14
Comments
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 4
Suitable Extinguishing Media
LARGE FIRE: Water spray, fog or regular foam.
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EU CLP:
Annex
CAS:
EC
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In case of contact with substance, immediately flush skin with running water for at
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
VI,
Table
Gas. 1, H220;
Press.
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Black Ice Aerosol
Graphite
Heptane
Propane
Isobutane
Quartz
7782-42-5
Number:
955-3
CAS:
142-82-5
EC
Number:
563-8
EU Index:
008-00-2
CAS:
74-98-6
EC
Number:
827-9
EU Index:
003-00-5
CAS:
75-28-5
EC
Number:
857-2
CAS:
14808-60-7
EC
Number:
878-4
231-
205-
601-
200-
601-
200-
238-
< 20%
5% TO
15%
3% TO
10%
1% TO
< 0.1%
6%
NDA
Inhalation-Rat
LC50 • 103 g/m³ 4
Hour(s)
NDA
Inhalation-Rat
LC50 • 57 pph 15
Minute(s)
NDA
See Section 16 for full text of H-statements and R-phrases.
breathing. If signs/symptoms continue, get medical attention. Administer oxygen if
breathing is difficult. Give artificial respiration if victim is not breathing.
Skin
least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.
Get medical attention immediately if symptoms occur.
Eye
Ingestion
In case of contact with substance, immediately flush eyes with running water for at
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least 20 minutes. If eye irritation persists: Get medical advice/attention.
If swallowed, DO NOT induce vomiting. Get medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Refer to Section 11 - Toxicological Information.
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4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician
All treatments should be based on observed signs and symptoms of distress in the
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patient. Consideration should be given to the possibility that overexposure to materials
other than this product may have occurred.
Section 5 - Firefighting Measures
5.1 Extinguishing media
Unsuitable Extinguishing
Preparation Date:
Revision Date:
06/21/17
SMALL FIRES: Dry chemical, CO2, water spray or regular foam.
No data available
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Clean up area with absorbent material
On burning,
Closed containers may explode from internal pressure build-up when exposed to
extreme heat and discharge contents.
Keep away from heat and ignition sources – No Smoking. Take precautionary
may release carbon dioxide
Vapors may
travel to source of ignition and flash back.
Vapors may
Black Ice Aerosol
Media
5.2 Special hazards arising from the substance or mixture
Unusual Fire and Explosion
Hazards
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form explosive mixtures with air.
Overexposure to decomposition products may cause a health hazard. Symptoms may
Hazardous Combustion
not be immediately apparent. Obtain medical attention.
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and carbon monoxide.
Products
5.3 Advice for firefighters
Structural firefighters' protective clothing provides limited protection in fire situations
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ONLY; it is not effective in spill situations where direct contact with the substance is
possible.
Wear chemical protective clothing that is specifically recommended by the
manufacturer. It may provide little or no thermal protection.
Wear positive pressure self-contained breathing apparatus (SCBA).
Water may be used to cool containers to prevent pressure build-up and explosion
when exposed to extreme heat.
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions
Emergency Procedures
6.2 Environmental precautions
Ventilate enclosed areas. Do not walk through spilled material. Wear appropriate
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personal protective equipment, avoid direct contact. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing.
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate
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area). As an immediate precautionary measure, isolate spill or leak area for at least
50 meters (150 feet) in all directions. Keep unauthorized personnel away. Stay
upwind. Ventilate closed spaces before entering. Keep out of low areas.
Prevent entry into waterways, sewers, basements or confined areas.
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6.3 Methods and material for containment and cleaning up
Containment/Clean-up
Measures
6.4 Reference to other sections
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Wash floor with soap and water.
Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal
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Considerations.
Section 7 - Handling and Storage
7.1 Precautions for safe handling
Handling
measures against static charges. All equipment used when handling the product must
be grounded. Do not puncture or incinerate (burn) cans. Do not stick a pin, nail or any
other sharp object into opening on top of can. Use only with adequate ventilation. Use
good safety and industrial hygiene practices. Wear appropriate personal protective
equipment, avoid direct contact. Do not breathe (dust, vapor or spray mist) Avoid
contact with eyes, skin and clothing. Do not use near ignition sources such as sparks
or open flames. Do not cut, drill or weld on containers. Even empty containers may
contain residue that will support a flame or explode when exposed to a spark, flame or
other source of ignition. Do not eat, drink or smoke when using this product. After
handling wash hands thoroughly.
7.2 Conditions for safe storage, including any incompatibilities
Storage
Preparation Date:
Revision Date:
06/21/17
Store in a cool, dry, well-ventilated place. Keep away from heat, sparks, and flame. Do
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and place in closed containers for disposal.
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 6
500
85 ppm TWA;
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l
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ppm
Controls should be engineered to prevent release to the environment, including
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European
Good general ventilation should be used. Ventilation rates should be matched to
TWA ;
2000
TWA
Black Ice Aerosol
not store at temperatures >120º F
7.3 Specific end use(s)
Refer to Section 1.2 - Relevant identified uses.
Section 8 - Exposure Controls/Personal Protection
8.1 Control parameters
Result
Quartz
(14808-60-7)
Isobutane
(75-28-5)
Propane
(74-98-6)
Heptane
(142-82-5)
Graphite
(7782-42-5)
Exposure Limits Supplemental
OSHA
•
Graphite (7782-42-5):
•
Quartz (14808-60-7):
+ 2) mg/m3 TWA, respirable fraction)
TWAs
STELs
TWAs
TWAs
TWAs
STELs
Ceilings Not established
TWAs
Mineral Dusts:
Mineral Dusts:
Exposure Limits/Guidelines
ACGIH
0.025 mg/m3
fraction)
1000 ppm STEL
Not established
1000 ppm TWA (listed under
15 mg/m3 TWA (synthetic, total
dust); 5 mg/m3 TWA (synthetic,
i
bl
f
ti )
8.2 Exposure controls
Engineering
Measures/Controls
conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits.
If exposure limits have not been established, maintain airborne levels to an acceptable
level.
Personal Protective Equipment
Respiratory
Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or symptoms are experienced.
Eye/Face
Skin/Body
Environmental Exposure
Controls
Wear safety goggles.
Wear protective clothing and gloves.
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procedures to prevent spills, atmospheric release and release to waterways. Follow
best practice for site management and disposal of waste.
Key to abbreviations
ACGIH = American Conference of Governmental Industrial Hygiene
NIOSH = National Institute of Occupational Safety and Health
OSHA = Occupational Safety and Health Administration
Preparation Date:
Revision Date:
06/21/17
STEL = Short Term Exposure Limits are based on 15-minute exposures
TWA = Time-Weighted Averages are based on 8h/day, 40h/week exposures
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Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 7
Color Data lacking
Odor Solvent
Decomposition Temperature
Data lacking
pH
Data lacking
Evaporation Rate
< 1 n-Butyl Acetate = 1
LEL Data lacking
Autoignition
Data lacking
Stable
Black Ice Aerosol
Section 9 - Physical and Chemical Properties
9.1 Information on Physical and Chemical Properties
Material Description
Physical Form
Odor Threshold
General Properties
Boiling Point
Specific Gravity/Relative Density
Viscosity
Oxidizing Properties:
Volatility
Vapor Pressure
Flammability
Flash Point
Flammability (solid, gas)
Environmental
Octanol/Water Partition coefficient Data lacking
Aerosol
Data lacking
Data lacking
Data lacking
Data lacking
Data lacking
Data lacking
Data lacking
Data lacking
UEL
Appearance/Description
Melting Point
Water Solubility
Explosive Properties
Vapor Density
Aerosol with a solvent odor.
Data lacking
Insoluble
Data lacking
> 1 Air=1
Data lacking
9.2 Other Information
No additional physical and chemical parameters noted.
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Section 10: Stability and Reactivity
10.1 Reactivity
10.2 Chemical stability
10.3 Possibility of hazardous reactions
10.4 Conditions to avoid
10.5 Incompatible materials
No dangerous reaction known under conditions of normal use.
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Hazardous polymerization will not occur.
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Heat, sparks, open flames. Incompatible materials.
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Strong oxidizing agents, acids, and alkalis.
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10.6 Hazardous decomposition products
On burning may release carbon dioxide and carbon monoxide.
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Section 11 - Toxicological Information
11.1 Information on toxicological effects
Preparation Date:
Revision Date:
06/21/17
Page 7 of 14
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 8
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Acute Toxicity:
Inhalation-Rat LC50 • 57 pph 15 Minute(s);
Behavioral:Tremor
;
Behavioral:Convulsions or effect on
Isobutane
75-28-
Black Ice Aerosol
Quartz (<
0.1%)
Heptane
(5% TO
15%)
(1% TO 6%)
Multi-dose Toxicity:
Respiration:Fibrosis (interstitial)
1480860-7
142-825
mg/m³ 26 Week(s)-Intermittent;
spleen
;
Tumorigen / Carcinogen:
Tumorigenic:Carcinogenic by RTECS criteria
Immunological Including Allergic:Decrease in cellular immune response;
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
U.S. - CERCLA/SARA - Section 313 - PBT Chemical Listing
Preparation Date:
Revision Date:
06/21/17
Page 12 of 14
7782-42-5
75-28-5
75-28-5
75-28-5
75-28-5
75-28-5
75-28-5
75-28-5
75-28-5
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 13
• Quartz
14808-60-7
Not Listed
• Graphite
7782-42-
Not Listed
Black Ice Aerosol
• Heptane
• Propane
United States - California
Environment
U.S. - California - Proposition 65 - Carcinogens List
• Isobutane
• Heptane
• Propane
• Quartz
• Graphite
U.S. - California - Proposition 65 - Developmental Toxicity
• Isobutane
• Heptane
• Propane
• Quartz
• Graphite
U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)
• Isobutane
• Heptane
• Propane
• Quartz
• Graphite
U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)
• Isobutane
• Heptane
• Propane
• Quartz
• Graphite
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
• Isobutane
• Heptane
• Propane
• Quartz
• Graphite
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
• Isobutane
• Heptane
• Propane
• Quartz
• Graphite
15.2 Chemical Safety Assessment
No Chemical Safety Assessment has been carried out.
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Preparation Date:
Revision Date:
06/21/17
Page 13 of 14
142-82-5
74-98-6
75-28-5
142-82-5
74-98-6
14808-60-7
7782-42-5
75-28-5
142-82-5
74-98-6
14808-60-7
7782-42-5
75-28-5
142-82-5
74-98-6
14808-60-7
7782-42-5
75-28-5
142-82-5
74-98-6
14808-60-7
7782-42-5
75-28-5
142-82-5
74-98-6
14808-60-7
7782-42-5
75-28-5
142-82-5
74-98-6
14808-60-7
7782-42-5
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
carcinogen, initial date 10/1/88
(airborne particles of
respirable size)
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Not Listed
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
Page 14
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The information contained herein is based on data available. However, no warranty is
expressed or implied regarding the accuracy of the data or the results obtained from
the
use thereof.
Black Ice Aerosol
15.3 Other Information
WARNING: This product contains a chemical known to the State of California to
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cause cancer.
Section 16 - Other Information
Relevant Phrases (code & full text)
Last Revision Date
Preparation Date
Disclaimer/Statement of
Liability
Key to abbreviations
NDA = No data available
Preparation Date:
Revision Date:
06/21/17
H220 - Extremely flammable gas
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H225 - Highly flammable liquid and vapour
H280 - Contains gas under pressure; may explode if heated
H304 - May be fatal if swallowed and enters airways
H336 - May cause drowsiness or dizziness H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects
R11 - Highly flammable.
R38 - Irritating to skin.
R50 - Very toxic to aquatic organisms.
R65 - Harmful: may cause lung damage if swallowed.
R67 - Vapours may cause drowsiness and dizziness.
06/21/17
No data available
conditions beyond our control, we assume no responsibility for its use.
Because the information contained herein may be applied under
Page 14 of 14
Format: EU CLP/REACH Language: English (US)
WHMIS, EU CLP, EU DSD/DPD, OSHA HCS 2012
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