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45545
User Manual
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Slip Plate 45545 User Manual

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Page 1
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WHMIS, EU CLP, EU DSD/D PD, OSHA HCS 2012
Revision Date: 06/23/17
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Hazard statements
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H350 - May cause cancer.
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Safety Data Sheet
Section 1: Identification of the Substance/Mixture and of the Company/Undertaking
1.1 Product identifier Product Name
Seed SLIK - SG Blend
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified use(s)
1.3 Details of the supplier of the safety data sheet
Dry Lubricant
Manufacturer
1.4 Emergency telephone number
Manufacturer Manufacturer
Superior Graphite 10 S. Riverside Plaza
Chicago, IL 60606 United States
1-800-424-9300 - For Hazardous Materials [or Dangerous Goods] Incident Spill, Leak, Fire, Exposure, or Accident Call CHEMTREC Day or Night
+1 703-527-3887 - Outside USA and Canada (collect calls accepted)
Section 2: Hazards Identification
EU/EEC
According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)
2.1 Classification of the substance or mixture
CLP
Carcinogenicity 1A - H350 Specific Target Organ Toxicity Repeated Exposure 1 - H372
DSD/DPD
2.2 Label Elements
CLP
Toxic (T) Carcinogenic Substances - Category 1
R48/23, R49
DANGER
H372 - Causes damage to organs - Lungs through prolonged or repeated exposure
Precautionary statements
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Prevention
Obtain special instructions before use.
Hazard statements
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May cause cancer.
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Risk phrases
R48/23 - Toxic: danger of serious damage to health by prolonged exposure through
Prevention
P201 - Obtain special instructions before use.
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P314 - Get medical advice/attention if you feel unwell.
Storage/Disposal
P405 - Store locked up.
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P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53 - Avoid exposure - obtain special instructions before use.
Get medical advice/attention if you feel unwell.
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Response
P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe . P264 - Wash thoroughly after handling. P270 - Do not eat, drink or smoke when using this product.
P281 - Use personal protective equipment as required.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
DSD/DPD
Safety phrases
inhalation. R49 - May cause cancer by inhalation.
S37 - Wear suitable gloves.
2.3 Other Hazards
CLP
May form combustible dust concentrations in air. According to Regulation (EC) No. 1272/2008 (CLP) this material is considered
DSD/DPD
hazardous. May form combustible dust concentrations in air.
According to European Directive 1999/45/EC this material is considered dangerous.
United States (US)
According to: OSHA 29 CFR 1910.1200 HCS
2.1 Classification of the substance or mixture
OSHA HCS 2012
2.2 Label elements
OSHA HCS 2012
Precautionary statements
Response
Carcinogenicity 1A Specific Target Organ Toxicity Repeated Exposure 1
Combustible Dust
DANGER
Causes damage to organs - Lungs through prolonged or repeated exposure via Inhalation
May form combustible dust concentrations in air.
Do not handle until all safety precautions have been read and understood. Do not breathe dust. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing/eye protection/face protection.
IF exposed or concerned: Get medical advice/attention.
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<
1%
80%
20%
LD50/LC50
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Storage/Disposal
Store locked up.
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2.3 Other hazards
OSHA HCS 2012
Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous.
Canada
According to: WHMIS
2.1 Classification of the substance or mixture
WHMIS
2.2 Label elements
WHMIS
Other Toxic Effects - D2A
2.3 Other hazards
WHMIS
Other Toxic Effects - D2A
May form combustible dust concentrations in air. In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS).
Section 3 - Composition/Information on Ingredients
3.1 Substances
Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008.
3.2 Mixtures
Chemical Name
Graphite
Talc
Quartz
Identifiers
CAS:
7782-42-5
EC Number:
955-3
CAS:
14807-96-6
EC Number:
877-9
CAS:
14808-60-7
EC Number:
878-4
231-
238-
238-
%
NDA
NDA
NDA
See Section 16 for full text of H-statements and R-phrases.
Composition
Classifications According to Regulation/Directive
EU DSD/DPD: EU CLP: OSHA HCS 2012:
EU DSD/DPD: EU CLP:
OSHA HCS 2012: EU DSD/DPD:
EU CLP:
1A, H350
OSHA HCS 2012:
Not Classified
Not Classified
Comb. Dust
Self Classified: T R48/23
Self Classified: STOT RE 1 (Lungs, Inhl), H372
STOT RE 1 (Lungs, Inhl)
Self Classified: T R48/20; Carc. 1 R49
Self Classified: STOT RE 1 (Lungs, Inhl), H372; Carc.
STOT RE 1 (Lungs, Inhl); Carc. 1A
Comments
NDA
NDA
NDA
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Unusual Fire and Explosion
Dust dispersed in air in sufficient concentrations and in the presence if an ignition
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Suitable Extinguishing Media
LARGE FIRE: Water spray, fog or regular foam.
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SMALL FIRES: Dry chemical, CO2, water spray or regular foam.
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Section 4 - First Aid Measures
4.1 Description of first aid measures
Inhalation
Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. If breathing is difficult get medical attention.
Skin Eye Ingestion
IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. If irritation develops and persists, get medical attention.
In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. Get medical attention.
Do NOT induce vomiting. Rinse mouth. Do not give anything by mouth to an unconscious person. Get medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Refer to Section 11 - Toxicological Information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician
4.4 Other information
Section 5 - Firefighting Measures
5.1 Extinguishing media
Unsuitable Extinguishing Media
5.2 Special hazards arising from the substance or mixture
Hazards Hazardous Combustion Products
5.3 Advice for firefighters
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions Emergency Procedures
All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred.
Call 911 or emergency medical service. Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination.
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No data available.
source is an explosion hazard. On burning, may release carbon dioxide and carbon monoxide.
Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. LARGE FIRES: Move containers from fire area if you can do it without risk. LARGE FIRES: Do not scatter spilled material with high pressure water streams. LARGE FIRES: Dike fire-control water for later disposal.
Avoid contact with material that generates respirable dust unless proper PPE is used. Do not walk through spilled material.
Use normal clean up procedures. Ventilate closed spaces before entering.
6.2 Environmental precautions
Avoid run off to waterways and sewers.
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TWAs
TWAs
TWAs
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2 mg/m3 TWA (containing no Asbestos and <1% Quartz, respirable dust)
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6.3 Methods and material for containment and cleaning up
Containment/Clean-up Measures
6.4 Reference to other sections
Carefully shovel or sweep up spilled material and place in suitable container. Avoid generating dust.
Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations.
Section 7 - Handling and Storage
7.1 Precautions for safe handling
Handling
Use only with adequate ventilation. Use appropriate Personal Protective Equipment (PPE) Do not breathe dust. Avoid accumulation of dust. Good housekeeping practices should be in place to prevent accumulation of dusts on surfaces. If dusts are generated during processing eliminate ignition sources. Take precautionary measures against static charges. Graphite is conductive and can cause short circuits and other electrical malfunctions. Graphite causes slippery conditions. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco.
7.2 Conditions for safe storage, including any incompatibilities
Storage
7.3 Specific end use(s)
Ventilate enclosed areas. Keep container closed.
Refer to Section 1.2 - Relevant identified uses.
Section 8 - Exposure Controls/Personal Protection
8.1 Control parameters
Result ACGIH
Quartz (14808-60-7)
Graphite as Particulates not
otherwise classified (PNOC)
Talc (14807-96-6)
Exposure Limits Supplemental
OSHA
•
Graphite (7782-42-5): Mineral Dusts:
•
Talc (14807-96-6): Mineral Dusts:
•
Quartz (14808-60-7): Mineral Dusts:
+ 2) mg/m3 TWA, respirable fraction)
8.2 Exposure controls
Engineering Measures/Controls
Personal Protective Equipment
Respiratory
Exposure Limits/Guidelines
0.025 mg/m3 TWA (respirable fraction)
2 mg/m3 TWA (all forms except graphite fibers, respirable fraction)
2 mg/m3 TWA (particulate matter containing no asbestos and <1% crystalline silica, respirable fraction)
(15 mppcf TWA (natural))
(20 mppcf TWA (if 1% Quartz or more, use Quartz limit))
((30)/(%SiO2 + 2) mg/m3 TWA, total dust; (250)/(%SiO2 + 5) mppcf TWA, respirable fraction; (10)/(%SiO2
0.05 mg/m3 TWA (respirable dust)
2.5 mg/m3 TWA (natural, respirable dust)
Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. All dust control equipment should contain explosion relief vents or an explosion supression system or an oxygen­deficient environment. Make sure that dust handling systems are designed to prevent escape of dust into the work area and that they do not leak.
For limited exposure use an N95 dust mask. For prolonged exposure use an air-
NIOSH
OSHA
Not established
15 mg/m3 TWA (synthetic, total dust); 5 mg/m3 TWA (synthetic, respirable fraction)
Not established
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Wear long sleeves and/or protective coveralls.
Follow best practice for site management and disposal of waste. Controls should be engineered to prevent release to the environment, including procedures to prevent spills, atmospheric release and release to waterways.
= 2.69
Data lacking
No additional physical and chemical parameters noted.
No dangerous reaction known under conditions of normal use.
Stable under normal temperatures and pressures.
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Eye/Face Hands
Skin/Body
Environmental Exposure Controls
purifying respirator with high efficiency particulate air (HEPA) filters. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or symptoms are experienced.
Wear protective eyewear (goggles, face shield, or safety glasses). Eye wash station should be available.
Wear protective gloves .
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Key to abbreviations
ACGIH=American Conference of Governmental Industrial Hygiene NIOSH=National Institute of Occupational Safety and Health OSHA =Occupational Safety and Health Administration TWA =Time-Weighted Averages are based on 8h/day, 40h/week exposures
Section 9 - Physical and Chemical Properties
9.1 Information on Physical and Chemical Properties
Material Description
Physical Form Color Odor Threshold
General Properties
Boiling Point Decomposition Temperature Specific Gravity/Relative Density Viscosity Oxidizing Properties:
Volatility
Vapor Pressure Evaporation Rate
Flammability
Flash Point LEL Flammability (solid, gas)
Environmental
Octanol/Water Partition coefficient
Solid Gray Data lacking
Data lacking Data lacking
Data lacking Data lacking
Data lacking Data lacking
Data lacking Data lacking Data lacking
Appearance/Description Odor
Melting Point pH Water Solubility Explosive Properties
Vapor Density
UEL Autoignition
Gray powder with no odor. None
Data lacking
Data lacking Insoluble Data lacking
Data lacking
Data lacking Data lacking
9.2 Other Information
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10.1 Reactivity
10.2 Chemical stability
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Will not occur.
Accumulation of dusts - mixtures of graphite dust and air are explosive when ignited.
Strong oxidizing agents, acids, and alkalis.
On burning may release carbon dioxide and carbon monoxide.
•
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•
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10.3 Possibility of hazardous reactions
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10.4 Conditions to avoid
10.5 Incompatible materials
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10.6 Hazardous decomposition products
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Section 11 - Toxicological Information
11.1 Information on toxicological effects
Talc (80%)
Quartz (< 1%)
GHS Properties
Acute toxicity
Aspiration Hazard
Carcinogenicity
Germ Cell Mutagenicity
Skin corrosion/Irritation
Skin sensitization
STOT-RE
STOT-SE
Toxicity for Reproduction
Respiratory sensitization
14807­96-6
14808­60-7
Irritation: Tumorigen / Carcinogen:
RTECS criteria Multi-dose Toxicity:
Respiration:Fibrosis (interstitial) mg/m³ 26 Week(s)Intermittent; Lungs, Thorax, or Respiration:Fibrosis, focal (pneumoconiosis)
spleen Tumorigen / Carcinogen:
by RTECS criteria
Skin-Human • 300 µg 3 Day(s)-Intermittent • Mild irritation;
;
Immunological Including Allergic:Decrease in cellular immune response
Inhalation-Rat TCLo • 18 mg/m³ 6 Hour(s) 2 Year(s)Intermittent;
;
Lungs, Thorax, or Respiration:Bronchiogenic carcinoma
Inhalation-Hamster TCLo • 3 mg/m³ 6 Hour(s) 78 Week(s)Intermittent;
;
Lungs, Thorax, or Respiration:Changes in lung weight
Inhalation-Rat TCLo • 50 mg/m³ 6 Hour(s) 71 Week(s)Intermittent;
;
Liver:Tumors
Classification
EU/CLP OSHA HCS 2012•Data lacking
EU/CLP OSHA HCS 2012•Data lacking
EU/CLP OSHA HCS 2012•Carcinogenicity 1A EU/CLP OSHA HCS 2012•Data lacking EU/CLP OSHA HCS 2012•Data lacking EU/CLP OSHA HCS 2012•Data lacking EU/CLP OSHA HCS 2012•Specific Target Organ Toxicity Repeated Exposure 1 EU/CLP OSHA HCS 2012•Data lacking EU/CLP OSHA HCS 2012•Data lacking EU/CLP OSHA HCS 2012•Data lacking
Components
Data lacking
Data lacking
Carcinogenicity 1A
Data lacking
Data lacking
Data lacking
Specific Target Organ Toxicity Repeated Exposure 1
Data lacking
Data lacking
Data lacking
;
Endocrine:Tumors
;
Tumorigenic:Carcinogenic by
Lungs, Thorax, or
; Inhalation-Rat TCLo • 80
;
Blood:Changes in
Tumorigenic:Carcinogenic
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Route(s) of entry/exposure
Inhalation, Skin, Eye, Ingestion
EU/CLP
Data lacking
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Serious eye damage/Irritation
Medical Conditions Aggravated by Exposure
Potential Health Effects Inhalation
Acute (Immediate) Chronic (Delayed)
Skin
Acute (Immediate) Chronic (Delayed)
Eye
Acute (Immediate)
Chronic (Delayed)
Ingestion
Acute (Immediate) Chronic (Delayed)
Carcinogenic Effects
Quartz
Key to abbreviations
TC=Toxic Concentration
CAS
14808-60-7
OSHA HCS 2012•Data lacking
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Disorders of the lungs.
Exposure to dust may cause irritation. Repeated and prolonged exposure to dust may cause lung effects including
pneumoconiosis.
Exposure to dust may cause mechanical irritation. No data available.
Exposure to dust may cause mechanical irritation. Excessive concentrations of nuisance dust in the workplace may reduce visibility and may cause unpleasant
deposits in eyes. No data available.
Excessive concentrations of nuisance dust in the workplace may cause mechanical irritation to mucous membranes.
No data available. This product contains crystalline silica as quartz. Crystalline Silica is classified as a
Known Carcinogen according to NTP. Repeated and prolonged exposure may cause cancer.
IARC
Group 1-Carcinogenic
Carcinogenic Effects
•
Known Human Carcinogen
NTP
Section 12 - Ecological Information
12.1 Toxicity
Data lacking.
12.2 Persistence and degradability
Data lacking.
12.3 Bioaccumulative potential
Data lacking.
12.4 Mobility in Soil
Data lacking.
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment has not been conducted for this material.
12.6 Other adverse effects
No studies have been found.
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Chronic
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None specified.
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Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product waste Packaging waste
Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Dispose of content and/or container in accordance with local, regional, national, and/or international regulations.
Section 14 - Transport Information
DOT
NDA
TDG
NDA
IMO/IMDG IATA/ICAO
NDA
NDA
14.1 UN
number
user
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
14.2 UN proper
shipping name
Not Regulated Not Regulated Not Regulated Not Regulated
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14.3 Transport hazard
NDA NDA NDA NDA NDA NDA NDA NDA NDA NDA NDA NDA
class(es)
14.4 Packing group
14.5 Environmental hazards
Section 15 - Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
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Component
Graphite Quartz Talc
CAS
7782-42-5 14808-60-7 14807-96-6
Canada
Labor
Canada - WHMIS - Classifications of Substances
• Talc
• Quartz
• Graphite
Canada DSL
Yes Yes Yes
Inventory
Canada NDSL
No No No
EU EINECS
14807-96-6 D2A
14808-60-7
7782-42-5 D2A (natural); D2B (synthetic)
Yes Yes Yes
D2A (In certain cases, this classification does not apply. For more information, consult the section Substance Specific Issues - Silica, crystalline,
encapsulated on Health Canada's WHMIS Division website.)
EU ELNICS
No No No
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Canada - WHMIS - Ingredient Disclosure List
• Talc
• Quartz
• Graphite
14807-96-6 Not Listed 14808-60-7 1 % 7782-42-5 Not Listed
Environment
Canada - CEPA - Priority Substances List
• Talc
• Quartz
• Graphite
Europe
Other
EU - Hazardous Substances Restricted or Prohibited in Electrical Equipment (2011/65/EU) (RoHS)
• Talc
• Quartz
• Graphite
Japan
Environment
Inventory - Japan - Industrial Safety and Health Law Substances (ISHL)
• Talc
• Quartz
• Graphite
Other
Japan - Chemical Substance Control Law (CSCL) - Monitoring Chemical Substances
• Talc
• Quartz
• Graphite
Japan - Poisonous and Deleterious Substances - Substances Not Considered Deleterious
• Talc
• Quartz
• Graphite
Japan - Poisonous and Deleterious Substances - Substances Not Considered Poisonous
• Talc
• Quartz
• Graphite
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
United States
Labor
U.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals
• Talc
• Quartz
• Graphite
U.S. - OSHA - Specifically Regulated Chemicals
• Talc
• Quartz
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed
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7782-42-5 Not Listed
Environment
U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants
• Talc
• Quartz
• Graphite
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
• Talc
• Quartz
• Graphite
U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities
• Talc
• Quartz
• Graphite
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs
• Talc
• Quartz
• Graphite
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
• Talc
• Quartz
• Graphite
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
• Talc
• Quartz
• Graphite
U.S. - CERCLA/SARA - Section 313 - PBT Chemical Listing
• Talc
• Quartz
• Graphite
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
United States - California
Environment
U.S. - California - Proposition 65 - Carcinogens List
• Talc
• Quartz
• Graphite
U.S. - California - Proposition 65 - Developmental Toxicity
• Talc
• Quartz
• Graphite
U.S. - California - Pr oposition 65 - Maximum Allowable Dose Levels (MADL)
• Talc
14807-96-6 Not Listed
carcinogen, initial date 10/1/88
14808-60-7 (airborne particles of
respirable size)
7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed
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Page 12 of 12
WHMIS, EU CLP, EU DSD/D PD, OSHA HCS 2012
Revision Date: 06/23/17
27/March/2015
Preparation Date:
Seed SLIK -
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R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation.
6/23/17
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Page 12 of 12
WHMIS, EU CLP, EU DSD/D PD, OSHA HCS 2012
Revision Date:
27/March/2015
Preparation Date:
SG Blend
WHMIS, EU CLP, EU DSD/D PD, OSHA HCS 2012
Revision Date:
Preparation Date:
Seed SLIK -
SG Blend
Seed SLIK -
SG Blend
-
• Quartz
• Graphite
U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)
• Talc
• Quartz
• Graphite
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
• Talc
• Quartz
• Graphite
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
• Talc
• Quartz
• Graphite
15.2 Chemical Safety Assessment
No Chemical Safety Assessment has been carried out.
14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
14807-96-6 Not Listed 14808-60-7 Not Listed 7782-42-5 Not Listed
15.3 Other Information
WARNING: This product contains a chemical known to the State of California to cause cancer.
Section 16 - Other Information
Relevant Phrases (code & full text)
H373 - May cause damage to organs through prolonged or repeated exposure.
Last Revision Date Preparation Date Disclaimer/Statement of
Liability
Key to abbreviations
NDA=No data available
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27/March/2015 The information contained herein is based on data available. However, no warranty is
expressed or implied regarding the accuracy of the data or the results obtained from the use thereof. Because the information contained herein may be applied under conditions beyond our control, we assume no responsibility for its use.
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