According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010]
According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD)
2.1 Classification of the substance or mixture
CLP
Flammable Liquids 3 - H226
Specific Target Organ Toxicity Repeated Exposure 1 - H372
DSD/DPD
2.2 Label Elements
CLP
Aspiration 1 - H304
Harmful (Xn)
R10, R65
DANGER
H304 - May be fatal if swallowed and enters airways
H372 - Causes damage to organs - Central Nervous System (CNS) through prolonged
or repeated exposure
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Hazard statements
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Flammable liquid and vapour
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Risk phrases
R10 - Flammable.
Prevention
P210 - Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking.
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P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P331 - Do NOT induce vomiting.
P314 - Get medical advice/attention if you feel unwell.
Storage/Disposal
P403+P235 - Store in a well-ventilated place. Keep cool.
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P405 - Store locked up.
P501 - Dispose of content and/or container in accordance with local, regional,
national, and/or international regulations.
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Precautionary statements
Response
P233 - Keep container tightly closed.
P240 - Ground and/or bond container and receiving equipment.
P241 - Use explosion-proof electrical/ventilating/lighting/equipment.
P242 - Use only non-sparking tools.
P243 - Take precautionary measures against static discharge.
P260 - Do not breathe mist/vapours/spray.
P264 - Wash thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P370+P378 - In case of fire: Use appropriate media for extinction.
DSD/DPD
Safety phrases
2.3 Other Hazards
CLP
DSD/DPD
R65 - Harmful: may cause lung damage if swallowed.
S53 - Avoid exposure - obtain special instructions before use.
According to Regulation (EC) No. 1272/2008 (CLP) this material is considered
hazardous.
According to European Directive 1999/45/EC this material is considered dangerous.
United States (US)
According to: OSHA 29 CFR 1910.1200 HCS
2.1 Classification of the substance or mixture
OSHA HCS 2012
2.2 Label elements
OSHA HCS 2012
Flammable Liquids 3
Aspiration 1
Eye Irritation 2
Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects
Specific Target Organ Toxicity Repeated Exposure 2
DANGER
May be fatal if swallowed and enters airways
Causes serious eye irritation
May cause drowsiness or dizziness
May cause damage to organs through prolonged or repeated exposure.
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Prevention
Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking.
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Keep container tightly closed.
Ground and/or bond container and receiving equipment.
Use explosion-proof electrical/ventilating/lighting/equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
Do not breathe mist/vapours/spray.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/protective clothing/eye protection/face protection.
Response
In case of fire: Use appropriate media for extinction.
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Keep cool.
Store locked up.
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
SLIP Plate No. 1
Precautionary statements
Storage/Disposal
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
Do NOT induce vomiting.
Get medical advice/attention if you feel unwell.
Store in a well-ventilated place. Keep container tightly closed.
2.3 Other hazards
OSHA HCS 2012
Under United States Regulations (29 CFR 1910.1200 - Hazard Communication
Standard), this product is considered hazardous.
Canada
According to: WHMIS
2.1 Classification of the substance or mixture
WHMIS
2.2 Label elements
WHMIS
Combustible Liquids - B3
Other Toxic Effects - D2A
2.3 Other hazards
WHMIS
Combustible Liquids - B3
Other Toxic Effects - D2A
In Canada, the product mentioned above is considered hazardous under the
Workplace Hazardous Materials Information System (WHMIS).
Section 3 - Composition/Information on Ingredients
3.1 Substances
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Suitable Extinguishing Media
LARGE FIRES: Water spray, fog or alcohol-resistant foam.
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<
1%
<
40%
<
50%
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Get medical attention.
SMALL FIRES: Dry chemical, CO2, water spray or alcohol-resistant foam.
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3.2 Mixtures
Chemical
Name
Stoddard
solvent
Graphite
Quartz
Identifiers
CAS:
EC
Number:
489-3
EU Index:
345-00-4
CAS:
EC
Number:
955-3
CAS:
7
EC
Number:
878-4
8052-41-3
7782-42-5
14808-60-
232-
649-
231-
238-
Material does not meet the criteria of a substance in accordance with Regulation (EC)
No 1272/2008.
STOT RE 2 (Liver, Kidneys); STOT SE 3:
Narc.; Asp. Tox. 1
EU DSD/DPD:
EU CLP:
OSHA HCS 2012:
EU DSD/DPD:
Carc.Cat.1 R49
EU CLP:
(Lungs, Inhl), H372; Carc. 1A, H350
OSHA HCS 2012:
Inhl); Carc. 1A
Annex VI, Table 3.1: Carc.
Annex VI, Table 3.1: Carc. 1B,
Flam. Liq. 3; Eye Irrit. 2;
Not Classified
Not Classified
Self Classified: T R48/20
Self Classified: STOT RE 1
Comb. Dust
STOT RE 1 (Lungs,
Comments
Contains <0.1% benzene
therefore mutagen and
carcinogen classifications do not
apply
NDA
NDA
Section 4 - First Aid Measures
4.1 Description of first aid measures
Inhalation
Skin
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim
is not breathing. Get medical attention if symptoms occur.
In case of contact with substance, immediately flush skin with running water for at
least 20 minutes. Wash skin with soap and water. Remove clothing and wash
thoroughly before use.
Eye
Ingestion
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Do NOT induce vomiting.
4.2 Most important symptoms and effects, both acute and delayed
Refer to Section 11 - Toxicological Information.
4.3 Indication of any immediate medical attention and special treatment needed
Notes to Physician
Section 5 - Firefighting Measures
5.1 Extinguishing media
All treatments should be based on observed signs and symptoms of distress in the
patient. Consideration should be given to the possibility that overexposure to materials
other than this product may have occurred.
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Unusual Fire and Explosion
Containers may explode when heated.
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S
Unsuitable Extinguishing
Media
5.2 Special hazards arising from the substance or mixture
Hazards
Hazardous Combustion
Products
5.3 Advice for firefighters
No data available
Vapor explosion hazard indoors, outdoors or in sewers.
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Many liquids are lighter than water.
Most vapors are heavier than air. They will spread along ground and collect in low or
confined areas (sewers, basements, tanks).
Runoff to sewer may create fire or explosion hazard.
Vapors may form explosive mixtures with air.
Vapors may travel to source of ignition and flash back.
No data available
Structural firefighters' protective clothing will only provide limited protection.
Wear positive pressure self-contained breathing apparatus (SCBA).
Move containers from fire area if you can do it without risk.
LARGE FIRES: Cool containers with flooding quantities of water until well after fire is
out.
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Personal Precautions
Emergency Procedures
6.2 Environmental precautions
Ensure adequate ventilation to remove vapors, fumes, dust etc. Do not walk through
spilled material. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Contaminated clothing may be a fire risk when dry.
As an immediate precautionary measure, isolate spill or leak area for at least 50
meters (150 feet) in all directions. If tank, rail car or tank truck is involved in a fire,
ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for
800 meters (1/2 mile) in all directions. LARGE SPILL: Consider initial downwind
evacuation for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no
smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel
away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering.
Prevent entry into waterways, sewers, basements or confined areas.
6.3 Methods and material for containment and cleaning up
Containment/Clean-up
Measures
6.4 Reference to other sections
Section 7 - Handling and Storage
7.1 Precautions for safe handling
Handling
Stop leak if you can do it without risk.
Absorb or cover with dry earth, sand or other non-combustible material and transfer to
containers.
Use clean non-sparking tools to collect absorbed material.
A vapor suppressing foam may be used to reduce vapors.
All equipment used when handling the product must be grounded.
LARGE SPILLS: Dike far ahead of liquid spill for later disposal.
LARGE SPILLS: Water spray may reduce vapor; but may not prevent ignition in
closed spaces.
Clean up area with absorbent material and place in closed containers for disposal.
Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal
Considerations.
All equipment used when handling the product must be grounded. Keep away from fire
- No Smoking. Keep away from heat and sparks. Do not use sparking tools. Take
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Ceilings
2.5 mg/m3 TWA (natural, respirable
dust)
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precautionary measures against static charges. Use only in well ventilated areas.
Avoid contact with eyes, skin and clothing. Wear appropriate personal protective
equipment, avoid direct contact. Wash thoroughly with soap and water after handling
and before eating, drinking, or using tobacco.
7.2 Conditions for safe storage, including any incompatibilities
Storage
7.3 Specific end use(s)
Store in a well-ventilated place. Keep container tightly closed. Do not store above 120
F. Store locked up.
Refer to Section 1.2 - Relevant identified uses.
Section 8 - Exposure Controls/Personal Protection
8.1 Control parameters
Result ACGIH
TWAs
TWAs
TWAs
Quartz
(14808-60-7)
Graphite as
Particulates not
otherwise
classified (PNOC)
Stoddard solvent
(8052-41-3)
8.2 Exposure controls
Engineering
Measures/Controls
Personal Protective Equipment
Respiratory
Eye/Face
Skin/Body
Environmental Exposure
Controls
Exposure Limits/Guidelines
0.025 mg/m3 TWA (respirable
fraction)
2 mg/m3 TWA (all forms except
graphite fibers, respirable fraction)
100 ppm TWA
Not established
Good general ventilation should be used. Ventilation rates should be matched to
conditions. If applicable, use process enclosures, local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommended exposure limits.
If exposure limits have not been established, maintain airborne levels to an acceptable
level.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European
Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or symptoms are experienced.
Wear chemical splash safety goggles.
Wear protective clothing and gloves.
Controls should be engineered to prevent release to the environment, including
procedures to prevent spills, atmospheric release and release to waterways.
0.05 mg/m3 TWA (respirable dust)
350 mg/m3 TWA
1800 mg/m3 Ceiling (15 min)
NIOSH
Not established
OSHA
15 mg/m3 TWA (synthetic, total
dust); 5 mg/m3 TWA (synthetic,
respirable fraction)
500 ppm TWA; 2900 mg/m3 TWA
Not established
Key to abbreviations
ACGIH=American Conference of Governmental Industrial Hygiene
NIOSH=National Institute of Occupational Safety and Health
OSHA =Occupational Safety and Health Administration
TWA =Time-Weighted Averages are based on 8h/day, 40h/week exposures
Section 9 - Physical and Chemical Properties
9.1 Information on Physical and Chemical Properties
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1480860-7
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Octanol/Water Partition coefficient
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Material Description
Physical Form
Color
Odor Threshold
General Properties
Boiling Point
Decomposition Temperature
Specific Gravity/Relative Density
Viscosity
Oxidizing Properties:
Volatility
Vapor Pressure
Evaporation Rate
Flammability
Flash Point
LEL
Flammability (solid, gas)
Environmental
Liquid
Black-gray
Data lacking
152 to 176 C(305.6 to 348.8 F)
Data lacking
= 1.08
Data lacking
Data lacking
2 mmHg (torr) @ 20 C(68 F)
0.2 n-Butyl Acetate = 1
40.6 C(105.08 F)
0.9 %
Not relevant.
Data lacking
Appearance/Description
Odor
Melting Point
pH
Water Solubility
Explosive Properties
Vapor Density
UEL
Autoignition
Black/gray liquid with a petroleum
solvent odor.
Petroleum solvent.
Data lacking
Data lacking
Negligible
Data lacking
4.7 Air=1
7 %
Data lacking
9.2 Other Information
No additional physical and chemical parameters noted.
Section 10: Stability and Reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
Stable under normal temperatures and pressures.
10.3 Possibility of hazardous reactions
Hazardous polymerization will not occur.
10.4 Conditions to avoid
Heat, sparks, open flames. Excess heat. Incompatible materials.
10.5 Incompatible materials
Strong oxidizing agents, acids, and alkalis.
10.6 Hazardous decomposition products
On burning may release carbon dioxide and carbon monoxide.
Specific Target Organ Toxicity Repeated Exposure 1
Data lacking
Data lacking
Data lacking
Data lacking
Kidney, Ureter, and Bladder:Changes in
;
Blood:Other changes
Potential Health Effects
Inhalation
Acute (Immediate)
Chronic (Delayed)
Skin
Acute (Immediate)
Chronic (Delayed)
Eye
Acute (Immediate)
Chronic (Delayed)
Ingestion
Acute (Immediate)
Chronic (Delayed)
May affect the central nervous system. Symptoms may include dizziness,
drowsiness, lethargy, coma and death.
No data available
l
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May cause gastrointestinal disturbances including diarrhea, nausea, and vomiting.
Small amounts aspirated into the respiratory system during ingestion or from vomiting
may cause bronchopneumonia or pulmonary edema, a possibly fatal condition.
No data available
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1
Other
Chronic (Delayed)
Carcinogenic Effects
Quartz
Key to abbreviations
LC =Lethal Concentration
TC=Toxic Concentration
CAS
IARC
14808-60-7
Repeated and prolonged exposure may affect the kidneys. Symptoms may include
but are not limited to weight loss, nausea, swelling of the arms and legs, vomiting,
fatigue, headaches, decreased urine or urine that is mostly water, decreased mental
sharpness, and muscle cramps and shakes. Repeated and prolonged exposure may
affect the liver. Symptoms may include yellowing of the skin (jaundice), intense
fatigue, loss of appetite, nausea, vomiting, and confusion. Repeated and prolonged
exposure may affect the central nervous system.
This product contains crystalline silica as quartz. Crystalline Silica is classified as a
Known Carcinogen according to NTP. IARC Monographs on Evaluation of
Carcinogenic Risk of Chemicals to Humans (Monograph 68, 1997) concludes that
there is sufficient evidence for the carcinogenicity of crystalline silica to humans (IARC
Group I).
Group 1-Carcinogenic
Carcinogenic Effects
NTP
Known Human Carcinogen
Section 12 - Ecological Information
12.1 Toxicity
Material data lacking.
12.2 Persistence and degradability
Material data lacking.
12.3 Bioaccumulative potential
Material data lacking.
12.4 Mobility in Soil
Material data lacking.
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment has not been conducted for this material.
12.6 Other adverse effects
Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product waste
Packaging waste
Section 14 - Transport Information
No studies have been found.
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
Dispose of content and/or container in accordance with local, regional, national, and/or
international regulations.
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14.3 Transport
hazard class(es)
group
UN1993
UN1993
3
user
14.7 Transport in bulk
according to Annex II of
MARPOL 73/78 and the IBC
Code
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Yes
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DOT
TDG
IMO/IMDG
IATA/ICAO
14.1 UN
number
NDA
UN1993
14.2 UN proper shipping
name
NDA
FLAMMABLE LIQUID, N.O.S.
(Contains mineral spirits)
FLAMMABLE LIQUID, N.O.S.
(Contains mineral spirits)
Flammable liquid, N.O.S. (Contains
mineral spirits)
See Note*
3
3
14.4 Packing
NDA
III
III
III
14.5 Environmental
hazards
NDA
Potential Marine Pollutant
NDA
NDA
14.6 Special precautions for
None specified.
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Note*:
Non-Hazardous due to combustible liquid exception
173.150(f)
Section 15 - Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
SARA Hazard Classifications
Acute, Chronic, Fire
Component
Graphite
Quartz
Stoddard solvent
CAS
7782-42-5
14808-60-7
8052-41-3
Canada DSL
Canada
Labor
Canada - WHMIS - Classifications of Substances
• Stoddard solvent
8052-41-3 B3, D2B
• Quartz
• Graphite
Canada - WHMIS - Ingredient Disclosure List
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 1 %
7782-42-5 Not Listed
8052-41-3 1 %
Yes
Yes
Inventory
Canada NDSL
No
No
No
EU EINECS
14808-60-7
7782-42-5 D2A (natural); D2B (synthetic)
Yes
Yes
Yes
D2A (In certain cases, this
classification does not apply.
For more information, consult
the section Substance Specific
Issues - Silica, crystalline,
encapsulated on Health
Canada's WHMIS Division
website.)
EU ELNICS
No
No
No
Environment
Canada - CEPA - Priority Substances List
• Stoddard solvent
• Quartz
8052-41-3 Not Listed
14808-60-7 Not Listed
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• Graphite
Europe
Other
EU - Hazardous Substances Restricted or Prohibited in Electrical Equipment (2011/65/EU) (RoHS)
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
Japan
Environment
Inventory - Japan - Industrial Safety and Health Law Substances (ISHL)
• Stoddard solvent
• Quartz
• Graphite
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
Other
Japan - Chemical Substance Control Law (CSCL) - Monitoring Chemical Substances
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
Japan - Poisonous and Deleterious Substances - Substances Not Considered Deleterious
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 Not Listed
8052-41-3 Not Listed
Japan - Poisonous and Deleterious Substances - Substances Not Considered Poisonous
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 Not Listed
8052-41-3 Not Listed
7782-42-5 Not Listed
7782-42-5 Not Listed
7782-42-5 Not Listed
United States
Labor
U.S. - OSHA - Process Safety Management - Highly Hazardous Chemicals
• Stoddard solvent
• Quartz
• Graphite
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
U.S. - OSHA - Specifically Regulated Chemicals
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
Environment
U.S. - CAA (Clean Air Act) - 1990 Hazardous Air Pollutants
• Stoddard solvent
• Quartz
• Graphite
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
U.S. - CERCLA/SARA - Hazardous Substances and their Reportable Quantities
• Stoddard solvent
8052-41-3 Not Listed
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• Quartz
• Graphite
U.S. - CERCLA/SARA - Radionuclides and Their Reportable Quantities
U.S. - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
• Stoddard solvent
• Quartz
• Graphite
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
• Stoddard solvent
• Quartz
• Graphite
U.S. - CERCLA/SARA - Section 313 - PBT Chemical Listing
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
United States - California
Environment
U.S. - California - Proposition 65 - Carcinogens List
• Stoddard solvent
• Quartz
• Graphite
U.S. - California - Proposition 65 - Developmental Toxicity
• Stoddard solvent
• Quartz
• Graphite
U.S. - California - Proposition 65 - Maximum Allowable Dose Levels (MADL)
• Stoddard solvent
• Quartz
• Graphite
U.S. - California - Proposition 65 - No Significant Risk Levels (NSRL)
• Stoddard solvent
• Quartz
• Graphite
U.S. - California - Proposition 65 - Reproductive Toxicity - Female
• Stoddard solvent
8052-41-3 Not Listed
carcinogen, initial date 10/1/88
14808-60-7 (airborne particles of
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
respirable size)
Page 13
Page 13 of 13
WHMIS, EU CLP, EU DSD/D PD, OSHA HCS 2012
Format: EU CLP/REACH Language: English (US)
Revision Date: 06/26/2017
25/March/2015
Preparation Date:
SLIP Plate No. 1
l
l
l l
l
SLIP Plate No. 1
Preparation Date:
Revision Date:
Format: EU CLP/REACH Language: English (US)
l
SLIP Plate No. 1
Format: EU CLP/REACH Language: English (US)
• Quartz
• Graphite
7782-42-5 Not Listed
U.S. - California - Proposition 65 - Reproductive Toxicity - Male
• Stoddard solvent
• Quartz
• Graphite
14808-60-7 Not Listed
7782-42-5 Not Listed
8052-41-3 Not Listed
15.2 Chemical Safety Assessment
No Chemical Safety Assessment has been carried out.
14808-60-7 Not Listed
15.3 Other Information
WARNING: This product contains a chemical known to the State of California to
cause cancer.
Section 16 - Other Information
Relevant Phrases (code & full text)
Last Revision Date
Preparation Date
Disclaimer/Statement of
Liability
Key to abbreviations
NDA=No data available
H340 - May cause genetic defects.
H350 - May cause cancer.
H372 - Causes damage to organs through prolonged or repeated exposure.
R45 - May cause cancer.
R46 - May cause heritable genetic damage.
R49 - May cause cancer by inhalation.
25/March/2015
06/26/2017
The information contained herein is based on data available. However, no warranty is
expressed or implied regarding the accuracy of the data or the results obtained from
the use thereof. Because the information contained herein may be applied under
conditions beyond our control, we assume no responsibility for its use.
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