Simple Green SMP 50128 User Manual

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Page 1

Safety Data Sheet: Simple Green® Lime Scale Remover

Version No. 50128-14A

Issue Date: October 7, 2014

Supersedes Date: April 25, 2014

Section 1:

IDENTIFICATION

Product Name:

Simple Green® Lime Scale Remover

Additional Names:

Manufacturer’s Part Number:

*Please refer to Section 16

Recommended Use:

Acid based cleaner for the removal of lime, scale, and mineral buildup

Restrictions on Use:

Do not use in conjunction with other chemicals OR with on surfaces not resistant to acids.

Company:

Sunshine Makers, Inc.

Huntington Beach, CA 92649 USA

Telephone:

800-228-0709 ● 562-795-6000

Fax:

562-592-3830

Email:

info@simplegreen.com

Emergency Phone:

Chem-Tel 24-Hour Emergency Service: 800-255-3924

Section 2:

HAZARDS IDENTIFICATION

This product is classified as hazardous (Skin Corrosive – 1C) under 2012 OSHA Hazard Communication Standards (29 CFR

1910.1200).

OSHA HCS 2012

Label Elements

Signal Word:

DANGER

Hazard Symbol(s)/Pictogram(s):

Hazard Statements:

H314 – Causes severe skin burns and eye damage

Precautionary Statements:

P501 – Dispose of contents/container in accordance with local/regional/national regulations.

Hazards Not Otherwise Classified (HNOC): None

Other Information: None Known

Section 3:

COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient

CAS Number

Percent Range

Water

7732-18-5

> 81%*

Urea Hydrochloride

506-89-8

≤ 6%*

Sodium Citrate

6132-04-3

< 5%*

Ethoxylated Alcohol

68439-46-3

< 5%*

Potassium Iodide

7681-11-0

< 1%*

Fragrance

Proprietary Mixture

< 1%*

Colorant

Proprietary Mixture

< 1%*

*specific percentages of composition are being withheld as a trade secret

OSHA HCS-2012 / GHS

Mon – Fri, 8am – 5pm PST

15922 Pacific Coast Highway

P260 – Do not breathe dusts or mists. P264 – Wash hands thoroughly after handling. P280 – Wear protective gloves/eye protection. P301 + P330 + P331 – IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 – IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P363 – Wash contaminated clothing before reuse. P304 + P340 – IF INHALED: Remove person to fresh air and keep comfortable for breathing. P310 – Immediately call a POISON CENTER. P321 – Specific treatment (see first aid on this label). P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 – Store locked up.

Page 1 of 5

Page 2

Safety Data Sheet: Simple Green® Lime Scale Remover

Version No. 50128-14A

Issue Date: October 7, 2014

Supersedes Date: April 25, 2014

Section 4:

FIRST-AID MEASURES

Inhalation:

IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER.

Skin Contact:

IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER.

Eye Contact:

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER.

Ingestion:

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER.

Most Important Symptoms/Effects, Acute and Delayed:

None known.

Indication of Immediate Medical Attention and Special Treatment Needed, if necessary:

Treat symptomatically

Section 5:

FIRE-FIGHTING MEASURES

Suitable & Unsuitable Extinguishing Media:

Use Dry chemical, CO2, water spray or “alcohol” foam. Avoid high volume jet water.

Specific Hazards Arising from Chemical:

In event of fire, fire created carbon oxides may be formed.

Special Protective Actions for Fire-Fighters:

Wear positive pressure self-contained breathing apparatus; Wear full protective clothing.

This product is non-flammable. See Section 9 for Physical Properties.

Section 6:

ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures: For non-emergency and emergency personnel: See section

8 – personal protection. Avoid eye contact. Safety goggles required.

Environmental Precautions: Do not allow into open waterways and ground water systems.

Methods and Materials for Containment and Clean Up: Dike or soak up with inert absorbent material. See section 13 for disposal

considerations.

Section 7:

HANDLING AND STORAGE

Precautions for Safe Handling: Ensure adequate ventilation. Keep out of reach of children. Keep away from heat, sparks, open flame

smoke while using this product.

Conditions for Safe Storage including Incompatibilities: Keep container tightly closed. Keep in cool dry area. Avoid prolonged exposure to sunlight. Do not store at temperatures above 109oF (42.7oC). If separation occurs, mix the product for reconstitution.

Section 8:

EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limit Values:

No components listed with TWA or STEL values under OSHA or ACGIH.

Appropriate Engineering Controls:

Showers, eyewash stations, ventilation systems

Individual Protection Measures / Personal Protective Equipment (PPE)

Eye Contact:

Use protective glasses or safety goggles if splashing or spray-back is likely.

Respiratory:

Use in well ventilated areas or local exhaust ventilations when cleaning small spaces.

Skin Contact:

Use protective gloves (any material) when used for prolonged periods or dermally sensitive.

General Hygiene Considerations:

Wash thoroughly after handling and before eating or drinking.

Section 9:

PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Turquoise Liquid

Partition Coefficient: n-octanol/water:

Not determined

Odor:

Added wintergreen odor

Autoignition Temperature:

Non-flammable

Odor Threshold:

Not determined

Decomposition Temperature:

109oF

pH:

1.0 – 1.5

Viscosity:

Like water

Freezing Point:

0-3.33oC (32-38oF)

Specific Gravity:

1.00 – 1.03

OSHA HCS-2012 / GHS

and direct sunlight. Do not pierce any part of the container. Do not mix or contaminate with any other chemical. Do not eat, drink or

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Page 3

Safety Data Sheet: Simple Green® Lime Scale Remover

Version No. 50128-14A

Issue Date: October 7, 2014

Supersedes Date: April 25, 2014

Section 9:

PHYSICAL AND CHEMICAL PROPERTIES - continued

Boiling Point & Range:

101oC (213.8oF)

VOCs:

**Water & fragrance exemption in calculation

Flash Point:

> 212oF

SCAQMD 304-91 / EPA 24:

Not tested

Evaporation Rate:

Not determined

CARB Method 310**:

0.001 g/L

0.000 lb/gal

0.01%

Flammability (solid, gas):

Not applicable

SCAQMD Method 313:

Not tested

Upper/Lower Flammability or Explosive Limits:

Not applicable

VOC Composite Partial Pressure:

Not determined

Vapor Pressure:

Not determined

Relative Density ASTM D-4017:

8.34 – 8.59 lb/gal

Vapor Density:

Not determined

Solubility:

100% in water

Reactivity:

Non-reactive.

Section 10:

STABILITY AND REACTIVITY

Chemical Stability:

Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg).

Possibility of Hazardous Reactions:

None known.

Conditions to Avoid:

Excessive heat or cold.

Incompatible Materials:

Do not mix with oxidizers, acids, bathroom cleaners, disinfecting agents or ammonia.

Hazardous Decomposition Products:

Normal products of combustion - CO, CO2.

Section 11:

TOXICOLOGICAL INFORMATION

Likely Routes of Exposure:

Inhalation -

Overexposure may cause headache.

Skin Contact -

Up to four hours of contact with no rinsing may lead to corrosion.

Eye Contact -

Up to four hours of contact with no rinsing may lead to corrosion.

Ingestion -

May cause upset stomach.

Symptoms related to the physical, chemical and toxicological characteristics: no symptoms expected under typical use conditions.

Delayed and immediate effects and or chronic effects from short term exposure: no symptoms expected under typical use conditions.

Delayed and immediate effects and or chronic effects from long term exposure: headache, dry skin, or skin irritation may occur.

Interactive effects: Not known.

Numerical Measures of Toxicity

Acute Toxicity:

Oral LD50 (rat)

> 5 g/kg body weight

Dermal LD50 (rabbit)

> 5 g/kg body weight

Calculated via OSHA HCS 2012 / Globally Harmonized System of Classification and Labelling of Chemicals

Skin Corrosion/Irritation:

Mild Corrosive per Corrositex-In Vitro Dermal Corrosivity testing.

Eye Damage/Irritation:

Mild Corrosive per Corrositex-In Vitro Dermal Corrosivity testing.

Germ Cell Mutagenicity: