Simple Green 18300 User Manual

Page 1
Safety Data Sheet: Simple Green® Stainless Steel One-Step Cleaner & Polish
Version No. 18300-14A
Issue Date: October 22, 2014
Supersedes Date: April 26, 2013
Section 1:
IDENTIFICATION
Product Name:
Simple Green® Stainless Steel One-Step Cleaner & Polish
Additional Names:
Manufacturer’s Part Number:
*Please refer to Section 16
Recommended Use:
Light cleaner and polish for household stainless steel appliances.
Restrictions on Use:
Do not use on floors or direct food contact surfaces.
Company:
Sunshine Makers, Inc.
Huntington Beach, CA 92649 USA
Telephone:
800-228-0709 ● 562-795-6000 Mon – Fri, 8am – 5pm PST
Fax:
562-592-3830
Email:
info@simplegreen.com
Emergency Phone:
Chem-Tel 24-Hour Emergency Service: 800-255-3924
Section 2:
HAZARDS IDENTIFICATION
This product is classified as hazardous (Eye Corrosive/Irritant - Category 2A) under 2012 OSHA Hazard Communication Standards (29 CFR 1910.1200).
OSHA HCS 2012
Label Elements
Signal Word:
Warning
Hazard Symbol(s)/Pictogram(s):
Hazard Statements:
H319 – Causes serious eye irritation.
Precautionary Statements:
P305 + P351+ P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 – If eye irritant persists: Get medical attention.
P264 – Wash hands thoroughly after handling.
P280 – Wear protective gloves and eye protection when handling concentrate.
Hazards Not Otherwise Classified (HNOC): None
Other Information: None Known
Section 3:
COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient
CAS Number
Percent Range
Water
7732-18-5
> 92%*
Alkyl, aryl derivatives
68855-24-3
< 5%*
Poly(dimethyl)siloxane
63148-62-9
< 1%*
Hexylene Glycol
107-41-5
< 1%*
Citric Acid
77-92-9
< 1%*
*specific percentages of composition are being withheld as a trade secret
Section 4:
FIRST-AID MEASURES
Inhalation:
Not expected to cause respiratory irritation. If adverse effect occurs, move to fresh air.
Skin Contact:
Not expected to cause skin irritation. If adverse effect occurs, rinse skin with water.
OSHA HCS-2012 / GHS
15922 Pacific Coast Highway
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Page 2
Safety Data Sheet: Simple Green® Stainless Steel One-Step Cleaner & Polish
Version No. 18300-14A
Issue Date: October 22, 2014
Supersedes Date: April 26, 2013
Section 4:
FIRST-AID MEASURES - continued
Eye Contact:
Causes serious eye irritation. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritant persists: Get medical attention.
Ingestion:
May cause upset stomach. Drink plenty of water to dilute. See section 11.
Most Important Symptoms/Effects, Acute and Delayed:
None known.
Indication of Immediate Medical Attention and Special Treatment Needed, if necessary:
Treat symptomatically
Section 5:
FIRE-FIGHTING MEASURES
Suitable & Unsuitable Extinguishing Media:
Use Dry chemical, CO2, water spray or “alcohol” foam. Avoid high volume jet water.
Specific Hazards Arising from Chemical:
In event of fire, fire created carbon oxides may be formed.
Special Protective Actions for Fire-Fighters:
Wear positive pressure self-contained breathing apparatus; Wear full protective clothing.
This product is non-flammable. See Section 9 for Physical Properties.
Section 6:
ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures:
For non-emergency personnel: See section 8 – personal protection.
For emergency responders: Avoid eye contact. Wear Protective Gloves and safety goggles.
Environmental Precautions: Do not allow into open waterways and ground water systems.
Methods and Materials for Containment and Clean Up: Dike or soak up with inert absorbent material. See section 13 for disposal
considerations.
Section 7:
HANDLING AND STORAGE
Precautions for Safe Handling: Ensure adequate ventilation. Keep out of reach of children. Keep away from heat, sparks, open flame
smoke while using this product.
Conditions for Safe Storage including Incompatibilities: Keep container tightly closed. Keep in cool dry area. Avoid prolonged exposure to sunlight. Do not store at temperatures above 95oF (35oC) or freezing temperatures.
Section 8:
EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Limit Values:
Hexylene Glycol 107-41-5
California, Connecticut, Michigan, Minnesota, OSHA, New York, Tennessee, Vermont, Washington,
25 ppm; 125 mg/m3 PEL
Appropriate Engineering Controls:
Showers, eyewash stations, ventilation systems
Individual Protection Measures / Personal Protective Equipment (PPE)
Eye Contact:
Use protective glasses or safety goggles if splashing or spray-back is likely.
Respiratory:
Use in well ventilated areas or local exhaust ventilation when cleaning small spaces.
Skin Contact:
Use protective gloves (any material).
General Hygiene Considerations:
Wash thoroughly after handling and before eating or drinking.
OSHA HCS-2012 / GHS
and direct sunlight. Do not pierce any part of the container. Do not mix or contaminate with any other chemical. Do not eat, drink or
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Page 3
Safety Data Sheet: Simple Green® Stainless Steel One-Step Cleaner & Polish
Version No. 18300-14A
Issue Date: October 22, 2014
Supersedes Date: April 26, 2013
Section 9:
PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Milky White Liquid
Partition Coefficient: n-octanol/water:
Not determined
Odor:
No added fragrance
Autoignition Temperature:
Non-flammable
Odor Threshold:
Not determined
Decomposition Temperature:
95oF
pH:
6.5 – 7.5
Viscosity:
Like water
Freezing Point:
0oC (32oF)
Specific Gravity:
1.00 – 1.02
Boiling Point & Range:
101oC (213.8oF)
VOCs:
**Water & fragrance exemption in calculation
Flash Point:
> 212oF
SCAQMD 304-91 / EPA 24:
Not tested
Evaporation Rate:
Not determined
CARB Method 310**:
1 g/L
0.008 lb/gal
0.1%
Flammability (solid, gas):
Not applicable
SCAQMD Method 313:
Not tested
Upper/Lower Flammability or Explosive Limits:
Not applicable
VOC Composite Partial Pressure:
Not determined
Vapor Pressure:
Not determined
Relative Density:
8.34 – 8.50
Vapor Density:
Not determined
Solubility:
100% in water
Section 10:
STABILITY AND REACTIVITY
Reactivity:
Non-reactive.
Chemical Stability:
Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg).
Possibility of Hazardous Reactions:
None known.
Conditions to Avoid:
Excessive heat or cold.
Incompatible Materials:
Do not mix with oxidizers, acids, bathroom cleaners, or disinfecting agents.
Hazardous Decomposition Products:
Normal products of combustion - CO, CO2.
Section 11:
TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:
Inhalation -
Overexposure may cause headache.
Skin Contact -
Not expected to cause irritation, repeated contact may cause dry skin.
Eye Contact -
Causes serious eye irritation.
Ingestion -
May cause upset stomach.
Symptoms related to the physical, chemical and toxicological characteristics: no symptoms expected under typical use conditions.
Delayed and immediate effects and or chronic effects from short term exposure: no symptoms expected under typical use conditions.
Delayed and immediate effects and or chronic effects from long term exposure: headache, dry skin, or skin irritation may occur.
Interactive effects: Not known.
Numerical Measures of Toxicity
Acute Toxicity:
Oral LD50 (rat)
> 5 g/kg body weight
Dermal LD50 (rabbit)
Not calculated
Calculated via OSHA HCS 2012 / Globally Harmonized System of Classification and Labelling of Chemicals
Skin Corrosion/Irritation:
Non-irritant per Dermal Irritection® assay modeling. No animal testing performed.
Eye Damage/Irritation:
Causes serious eye irritation per Ocular Irritection® assay modeling. No animal testing performed. (GHS Hazard category 2A)
Germ Cell Mutagenicity:
Mixture does not classify under this category.
Carcinogenicity:
Mixture does not classify under this category.
Reproductive Toxicity:
Mixture does not classify under this category.
STOT-Single Exposure:
Mixture does not classify under this category.
STOT-Repeated Exposure:
Mixture does not classify under this category.
Aspiration Hazard:
Mixture does not classify under this category.
OSHA HCS-2012 / GHS
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Page 4
Safety Data Sheet: Simple Green® Stainless Steel One-Step Cleaner & Polish
Version No. 18300-14A
Issue Date: October 22, 2014
Supersedes Date: April 26, 2013
Section 12:
ECOLOGICAL INFORMATION
Ecotoxicity:
Volume of ingredients used does not trigger toxicity classifications under the Globally Harmonized System of Classification and Labelling of Chemicals.
Aquatic:
Not tested on finished formulation.
Terrestrial:
Not tested on finished formulation.
Persistence and Degradability:
No data available.
Bioaccumulative Potential:
No data available.
Mobility in Soil:
No data available.
Other Adverse Effects:
No data available.
Section 13:
DISPOSAL CONSIDERATIONS
Unused or Used Liquid: May be considered hazardous in your area depending on usage and tonnage of disposal – check with local,
regional, and or national regulations for appropriate methods of disposal.
Empty Containers: May be offered for recycling.
Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains.
Section 14:
TRANSPORT INFORMATION
U.N. Number:
Not applicable
U.N. Proper Shipping Name:
Cleaning Compound, Liquid NOI
Transport Hazard Class(es):
Not applicable
NMFC Number:
48580-3
Packing Group:
Not applicable
Class:
55
Environmental Hazards:
Marine Pollutant - NO
Transport in Bulk (according to Annex II of MARPOL 73/78 and IBC Code):
Unknown.
Special precautions which user needs to be aware of/comply with, in connection with transport or conveyance either within or outside their premises:
None known.
U.S. (DOT) / Canadian TDG:
Not Regulated for shipping.
ICAO/ IATA:
Not classified as Hazardous
IMO / IDMG:
Not classified as Hazardous
ADR/RID:
Not classified as Hazardous
Section 15:
REGULATORY INFORMATION
All components are listed on:
TSCA and DSL Inventory.
SARA Title III:
Sections 311/312 Hazard Categories – Not applicable.
Sections 313 Superfunds Amendments and Reauthorizations Act of 1986 – Not applicable.
Sections 302 – Not applicable.
Clean Air Act (CAA):
Not applicable
Clean Water Act (CWA):
Not applicable
CERCLA:
Not applicable
State Right To Know Lists:
Hexylene Glycol 107-41-5
Massachusetts, New Jersey, Pennsylvania
California Proposition 65:
No ingredients listed
Texas ESL:
Hexylene Gylcol
107-41-5
25ppb; 120 µg/m3 long term
250 ppb; 1200 µg/m3 short term
5 µg/m3 (PM 10) 100 µg/m3 (vapor)
10 µg/m3 long term
50 µg/m3 (PM 10) 1000 µg/m3 (vapor)
100 µg/m3 long term
Alkyl, aryl derivatives
68855-24-3
5 µg/m3 (PM 10) 100 µg/m3 (vapor)
50 µg/m3 (PM 10) 1000 µg/m3 (vapor)
Citric Acid
77-92-9
10 µg/m3
100 µg/m3
OSHA HCS-2012 / GHS
Poly(dimethyl)siloxane 63148-62-9
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Page 5
Safety Data Sheet: Simple Green® Stainless Steel One-Step Cleaner & Polish
Version No. 18300-14A
Issue Date: October 22, 2014
Supersedes Date: April 26, 2013
Section 16:
OTHER INFORMATION
Size
Item Number
UPC
2 oz.
3500000118302
043318183027
2 oz., 48 per case
18302 & 3510004818302
043318183027
16 oz.
3500000118303
043318183034
16 oz., 12 per case
18303 & 3510001218303
043318183034
32 oz.
3500000118300
043318183003
32 oz., 12 per case
18300 & 3510001218300 & 3580101218300
043318183003
1 Gallon
3500000118304
043318183041
1 Gallon, 4 per case
18304 & 3510000418304
043318183041
5 Gallon
18305 & 3500000118305
043318183058
55 Gallon
18355 & 3500000118355
043318183553
USA items listed only. Not all items listed. USA items may not be valid for international sale.
NFPA:
Health – Eye Irritant
Stability – Stable
Flammability – Non-flammable
Special - None
Acronyms
NTP
National Toxicology Program
IARC
International Agency for Research on Cancer
OSHA
Occupational Safety and Health Administration
CPSC
Consumer Product Safety Commission
TSCA
Toxic Substances Control Act
DSL
Domestic Substances List
Prepared / Revised By:
Sunshine Makers, Inc., Regulatory Department.
This SDS has been revised in the following sections:
Revised SDS layout
DISCLAIMER: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The
materials or in any process, unless specified in the text.
OSHA HCS-2012 / GHS
information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other
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