Simple Green 01001 User Manual

Safety Data Sheet:

Simple Green® d Pro 3 Plus

Version No. 01128-18A

Issue Date: January 25, 2018

Supersedes Date: none

Section 1:

IDENTIFICATION

Product Name:

Simple Green® d Pro 3 Plus
Antibacterial • Cleaner • Disinfectant • Sanitizer • Deodorizer • Fungicide • Mildewstat • Virucide*

Additional Names:

Simple Green d Pro 3 Plus™

Product Part Number(s):

*Please refer to Section 16

Recommended Use:

Disinfecting, sanitizing, cleaning and deodorizing on hard, non-porous surfaces.

Restrictions on Use:

It is a violation of Federal law to use this product in a manner inconsistent with its labeling.

Manufactured for:

Sunshine Makers, Inc.

Huntington Beach, CA 92649 USA

Telephone:

800-228-0709 ● 562-795-6000 Mon – Fri, 8am – 5pm PST

Fax:

562-592-3830

Email:

[e-mail]

Emergency Phone:

Chem-Tel 24-Hour Emergency Service: 800-255-3924

Section 2:

HAZARDS IDENTIFICATION

This product is classified as hazardous (Eye Damage/Irritant – Category 1; Skin Corrosive/Irritant – Category 2; Acute Toxicity – Oral
4; Acute Toxicity – Dermal 5) under 2012 OSHA Hazard Communication Standards (29 CFR 1910.1200).

OSHA HCS 2012

Label Elements

Signal Word:

Danger

Hazard Symbol(s)/Pictogram(s):

Hazard Statements:

H302 – Harmful if swallowed.

H313 – May be harmful in contact with skin.

H315 – Causes skin irritation

H318 – Causes serious eye damage

Precautionary Statements:

P264 – Wash hands thoroughly after handling.

P270 – Do not eat, drink or smoke when using this product.

P301 + P312 – IF SWALLOWED: Call a poison Center/doctor.

P330 – Rinse mouth.

P280 – Wear protective gloves.

P302 + P352 – IF ON SKIN: Wash with plenty of water.

P321 – Specific treatment (see first aid on this label).

P332 + P313 – If skin irritation occurs: Get medical advice/attention.

P362 + P364 – Take off contaminated clothing and wash it before reuse.

P312 – Call a Poison Center if you feel unwell.

P280 – Wear eye protection.

P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.

P310 – Immediately call a Poison Center/Doctor.

P501 – Dispose of contents/container in accordance with local, regional and national regulations.

Hazards Not Otherwise Classified (HNOC): None

Other Information: Product label is regulated by the U.S. Environmental Protection Agency and may not agree with the Occupational

Safety and Health Administration-regulated statements found on this Safety Data Sheet.

OSHA HCS-2012 / GHS

15922 Pacific Coast Highway

Page 1 of 6

Safety Data Sheet:

Simple Green® d Pro 3 Plus

Version No. 01128-18A

Issue Date: January 25, 2018

Supersedes Date: none

Section 3:

COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient

CAS Number

Percent Range

Water

7732-18-5

≥ 90%*

Didecyl dimethyl ammonium chloride

7173-51-5

2.22%

Alkyl (50% C14, 40% C12, 10% C16) dimethyl benzyl ammonium chloride

68424-85-1

1.51%

Tetrasodium EDTA

64-02-8

≤ 1%*

Ethanol

64-17-5

≤ 1%*

Citric Acid

77-92-9

≤ 1%*

Fragrance

Proprietary

≤ 1%*

Colorant

Proprietary

≤ 1%*

*specific percentages of composition are being withheld as a trade secret

Section 4:

FIRST-AID MEASURES

Inhalation:

Remove from area to fresh air. Get immediate medical attention. If not breathing, clear airway and start artificial
respiration. If victim is having trouble breathing, give supplemental oxygen if available.

Skin Contact:

Causes skin irritation. IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice/attention.

Eye Contact:

Causes serious eye damage. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a Poison Center/Doctor.

Ingestion:

If swallowed, immediately give 3-4 glasses of milk (in unavailable, give water.) Do not induce vomiting. If vomiting

may be needed.

Most Important Symptoms/Effects, Acute and Delayed:

None known.

Indication of Immediate Medical Attention and Special Treatment Needed, if necessary:

Treat symptomatically

Section 5:

FIRE-FIGHTING MEASURES

Suitable & Unsuitable Extinguishing Media:

Use Dry chemical, CO2, water spray or “alcohol” foam. Avoid high volume jet water.

Specific Hazards Arising from Chemical:

In event of fire, fire created carbon oxides, ammonia, nitrogen chloride, nitrogen
oxides may be formed.

Special Protective Actions for Fire-Fighters:

Must wear NIOSH/MSHA approved self-containing breathing apparatus and
protective clothing. Cool fire-exposed containers with water spray.

This product is non-flammable. See Section 9 for Physical Properties.

Section 6:

ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment and Emergency Procedures: For non-emergency and emergency personnel: See section

8 – personal protection. Avoid eye contact. Safety goggles required.

Environmental Precautions: Do not allow into open waterways and ground water systems.

Methods and Materials for Containment and Clean Up: Dike or soak up with inert absorbent material. See section 13 for disposal

considerations.

Section 7:

HANDLING AND STORAGE

Precautions for Safe Handling: Ensure adequate ventilation. Keep out of reach of children. Keep away from heat, sparks, open flame

smoke while using this product.

OSHA HCS-2012 / GHS

does occur, give fluids again. Get immediate medical attention. Have physician determine if patient’s condition
allows for induction of vomiting or evacuation of the stomach. Do not give anything by mouth to an unconscious or
convulsing person. Note to Physician: Possible mucosal damage may contraindicate the use of gastric lavage.
Measures against circulatory shock, as well as oxygen and measures to support breathing manually or mechanically

and direct sunlight. Do not pierce any part of the container. Do not mix or contaminate with any other chemical. Do not eat, drink or

Page 2 of 6

Safety Data Sheet:

Simple Green® d Pro 3 Plus

Version No. 01128-18A

Issue Date: January 25, 2018

Supersedes Date: none

Section 7:

HANDLING AND STORAGE - continued

Conditions for Safe Storage including Incompatibilities: Store only in original container. Keep this product under locked storage

packaging only.

Section 8:

EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limit Values:

Value Type (Form of Exposure)

Control parameters / Permissible Concentration

Basis

Ethanol 64-17-5

STEL

1,000 ppm

ACGIH

REL

1,000 ppm; 1,900 mg/m3

NIOSH/GUIDE

PEL

1,000 ppm; 1,900 mg/m3

OSHA_TRANS

TWA

1,000 ppm; 1,900 mg/m3

Z1A

STEL

1,000 ppm

CAD ON OEL

Appropriate Engineering Controls:

Showers & eyewash stations. In processes where mists or vapors may be generated, proper
ventilation must be provided in accordance with good ventilation practices.

Individual Protection Measures / Personal Protective Equipment (PPE)

Eye Contact:

Wear chemical splash goggles where there is potential for eye contact. Use safety glasses with side shields when
there is no potential for eye contact.

Respiratory:

When necessary, NIOSH/MSHA jointly approved respirator is advised in the absence of proper environmental
controls.

Skin Contact:

Rubber or neoprene, to prevent skin contact with concentrate.

General Hygiene Considerations:

Wash thoroughly after handling and before eating or drinking.

See section 16 for NFPA rating.

Section 9:

PHYSICAL AND CHEMICAL PROPERTIES

Appearance:

Clear Green Liquid

Partition Coefficient: n-octanol/water:

Not determined

Odor:

Sweet lavender-pine fragrance

Autoignition Temperature:

Non-flammable

Odor Threshold:

Not determined

Decomposition Temperature:

unknown

pH:

7.0 – 9.0

Viscosity:

Cps @ 25

o

C <100

Freezing Point:

0oC (32oF)

Specific Gravity:

0.995 – 1.01

Boiling Point & Range:

101o C (213.8oF)

VOCs:

**Water & fragrance exemption in calculation

Flash Point:

>94

o

C (> 201oF)

SCAQMD 304-91 / EPA 24:

Not tested

Evaporation Rate:

Not determined

CARB Method 310**:

6.39 g/L

0.053 lbs./gal

0.63%

Flammability (solid, gas):

Not determined

SCAQMD Method 313:

Not tested

Upper/Lower Flammability or Explosive Limits:

Not applicable

VOC Composite Partial Pressure:

Not determined

Vapor Pressure:

Not determined

Relative Density:

8.3 – 8.42 lbs./gal

Vapor Density:

Not determined

Solubility:

100% in water

Percent Active:

4.22% - 4.44%

Section 10:

STABILITY AND REACTIVITY

Reactivity:

Non-reactive.

Chemical Stability:

Stable under normal conditions 70oF (21oC) and 14.7 psig (760 mmHg).

Possibility of Hazardous Reactions:

Reactive with oxidizers

Conditions to Avoid:

Excessive heat or cold.

OSHA HCS-2012 / GHS

sufficient to make it inaccessible to children or persons unfamiliar with its proper use. Keep container tightly closed. Keep in cool dry
area. Avoid prolonged exposure to sunlight. Do not store at temperatures above 109
or impacting of side walls. Non-refillable container. Do not reuse or refill this container. Store concentrate and dilutions in HDPE

o

F (42.7oC). Do not store on side. Avoid creasing

Page 3 of 6

Safety Data Sheet:

Simple Green® d Pro 3 Plus

Version No. 01128-18A

Issue Date: January 25, 2018

Supersedes Date: none

Section 10:

STABILITY AND REACTIVITY - continued

Incompatible Materials:

Strong oxidizing or reducing agents. Do not mix with oxidizers (Hydrogen Peroxide, “bleach”,

DO NOT MIX WITH ANYTHING BUT CLEAN WATER.

Hazardous Decomposition Products:

Thermal decomposition may produce toxic vapors/fumes of hydrogen chloride, amines, and
other materials, and oxides of carbon and nitrogen.

Section 11:

TOXICOLOGICAL INFORMATION

Likely Routes of Exposure:

Inhalation -

May cause irritation of mucous membranes

Skin Contact -

Skin Irritant.

Eye Contact -

Serious Eye damage.

Ingestion -

May cause stomach upset.

Symptoms related to the physical, chemical and toxicological characteristics: no symptoms expected under typical use conditions.

Delayed and immediate effects and or chronic effects from short term exposure: No health effects information available for human

concentrate may possibly produce severe eye or skin irritation.

Delayed and immediate effects and or chronic effects from long term exposure: No health effects information available for human

circulatory shock and/or convulsions. Mists or vapors of this concentrate may cause irritation of mucous membranes

Interactive effects: Not known.

Numerical Measures of Toxicity

Acute Toxicity:

Oral LD50 (rat)

300 – 2000 mg/kg

Dermal LD50 (rabbit)

2000 – 5000 mg/kg

No toxicity information is available for this specific material. This toxicity information provided is for similar formulations.

Skin Corrosion/Irritation:

Irritant per calculation. No animal testing performed.

Eye Damage/Irritation:

Serious eye damage per calculation. No animal testing performed.

Germ Cell Mutagenicity:

Mixture does not classify under this category.

Carcinogenicity:

Mixture does not classify under this category.

Reproductive Toxicity:

Mixture does not classify under this category.

STOT-Single Exposure:

Mixture does not classify under this category.

STOT-Repeated Exposure:

Mixture does not classify under this category.

Aspiration Hazard:

Mixture does not classify under this category.

Section 12:

ECOLOGICAL INFORMATION

Ecotoxicity:

Volume of ingredients used does not trigger toxicity classifications under the Globally Harmonized System of
Classification and Labelling of Chemicals.

Aquatic:

Not tested on finished formulation.

Terrestrial:

Not tested on finished formulation.

Persistence and Degradability:

No data available.

Bioaccumulative Potential:

No data available.

Mobility in Soil:

No data available.

Other Adverse Effects:

No data available.

OSHA HCS-2012 / GHS

Sodium Hypochlorite), acids, strong alkalines, disinfectants, antibacterials, antimicrobials,
bathroom cleaners or any type of stain remover.

exposure. Based on the available animal toxicity information for similar materials, it is anticipated that direct contact with this

exposure. Based on the available animal toxicity information for similar materials, Prolonged exposures may cause chemical burns
with possible irreversible damage. Ingestion may cause burning pain in the mouth, throat and abdomen; swelling of the larynx;

Page 4 of 6

Safety Data Sheet:

Simple Green® d Pro 3 Plus

Version No. 01128-18A

Issue Date: January 25, 2018

Supersedes Date: none

Section 13:

DISPOSAL CONSIDERATIONS

Unused or Used Liquid

PESTICIDE DISPOSAL: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture or rinsates is a

Environmental Control Agency, or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance.

Empty Containers:

CONTAINER DISPOSAL: Non-Refillable Container. Do not reuse or refill this container. Triple rinse container promptly after emptying.

available or puncture and dispose of in a sanitary landfill, or by incineration.

Never dispose of used degreasing rinsates into lakes, streams, and open bodies of water or storm drains.

Section 14:

TRANSPORT INFORMATION

U.N. Number:

Not applicable

U.N. Proper Shipping Name:

Cleaning Compound, Liquid NOI

Transport Hazard Class(es):

Not applicable

Packing Group:

Not applicable

Environmental Hazards:

Marine Pollutant - NO

Transport in Bulk (according to Annex II of MARPOL 73/78 and IBC Code):

Unknown.

Special precautions which user needs to be aware of/comply with, in connection
with transport or conveyance either within or outside their premises:

None known.

U.S. (DOT) / Canadian TDG:

Not Regulated for shipping.

ICAO/ IATA:

Not classified as Hazardous

IMO / IDMG:

Not classified as Hazardous

ADR/RID:

Not classified as Hazardous

Section 15:

REGULATORY INFORMATION

Federal Insecticide, Fungicide and Rodenticide Act (FIFRA)

This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling

pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use.

HAZARDS TO HUMANS AND DOMESTIC ANIMALS

contaminated clothing and wash clothing before reuse.

FIRST AID: In case of emergency, call a poison control center or doctor for treatment advice. Have the product container or label with

NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage.

OSHA HCS-2012 / GHS

violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or

Triple rinse as follows: Fill the container ¼ full with water and recap. Shake for 10 seconds. Drain for 10 seconds after the flow begins
to drip. Follow Pesticide Disposal instructions for rinsate disposal. Repeat this procedure two more times. Then offer for recycling if

requirements under federal pesticide law. These requirements may differ from the classification criteria and hazard information
required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the

DANGER: Corrosive. Causes irreversible eye damage and skin burns. Harmful if swallowed or absorbed through the skin. Do not get in
eyes, on skin, or on clothing. Wear goggles or face shield and rubber gloves and protective clothing when handling. Wash thoroughly
with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove

you when calling a poison control center or doctor, or going for treatment.
IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first
5 minutes, then continue rinsing eye.

IF ON SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes.
IF SWALLOWED: Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control

center or doctor. Do not give anything by mouth to an unconscious person. Call a poison control center or doctor immediately for
treatment advice.
IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably
mouth-to-mouth, if possible.

Page 5 of 6

Safety Data Sheet:

Simple Green® d Pro 3 Plus

Version No. 01128-18A

Issue Date: January 25, 2018

Supersedes Date: none

Section 15:

REGULATORY INFORMATION - continued

EPA REGISTRATION NUMBER:

10324-154-56782

All components are listed on:

TSCA and DSL Inventory.

SARA Title III:

Sections 311/312 Hazard Categories – Not applicable.

CAS

Hazard Category

Typical Max Concentrations.

Ethanol

64-17-5

F

0.64%

Sections 313 Superfunds Amendments and Reauthorizations Act of 1986 – Not applicable.

Sections 302 – Not applicable.

Clean Air Act (CAA):

Not applicable

Clean Water Act (CWA):

Not applicable

State Right To Know Lists:

Ethanol, 64-17-5, Massachusetts, New Jersey, Pennsylvania

California Proposition 65:

No chemicals within this product are required to be notified under California Proposition 65

Texas ESL:

Didecyldimethylammonium chloride

7173-51-5

10 µg/m3 long term

100 µg/m3 short term

Quaternary ammonium compounds, benzyl-C12-16-alkyldimethyl

chlorides

68424-85-1

10 µg/m3 long term

100 µg/m3 short term

Tetrasodium EDTA

64-02-8

5 µg/m3 (PM10); 100 µg/m3

(Vapor) long term

50 µg/m3 (PM10); 1000 µg/m3

(Vapor) short term

Ethanol

64-17-5

term

term

Section 16:

OTHER INFORMATION

Size

UPC

1 gallon Retail Label

043318004575

1 gallon Industrial Label

043318004568

5 gallon Industrial Pail

043318004544

55 gallon Industrial Drum

043318004551

USA items listed only. Not all items listed. USA items may not be valid for international sale.

NFPA:

Health – Eye Corrosive

Stability – Stable

Flammability – Slight

Special - None

Acronyms

NTP

National Toxicology Program

IARC

International Agency for Research on Cancer

OSHA

Occupational Safety and Health Administration

CPSC

Consumer Product Safety Commission

TSCA

Toxic Substances Control Act

DSL

Domestic Substances List

Prepared / Revised By:

Sunshine Makers, Inc., Regulatory Department.

This SDS has been revised in the following sections:

DISCLAIMER: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The

materials or in any process, unless specified in the text.

OSHA HCS-2012 / GHS

1000 ppb; 1880 μg/m3 long

10000 ppb; 18800 μg/m3 short

information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty
or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other

Page 6 of 6