CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin and respiratory conditions.
LISTED CARCINOGENS: OSHA - Not listed IARC - Not listed NTP - Not listed
SIMONIZSIMONIZ
SDS
Simoniz Citrus Clean S3376012
GHS Signal Word:
WARNING
GHS Hazard Pictograms:
GHS Classifications:
Health, Acute toxicity, 5 Oral
Health, Skin corrosion/irritation, 2
Health, Respiratory or skin sensitization, 1 Skin
Health, Serious Eye Damage/Eye Irritation, 2 B
Health, Specific target organ toxicity - Single exposure, 3
Environmental, Hazards to the aquatic environment - Chronic, 4
Physical, Flammable Aerosols, 3
Safety Data Sheet
Revision Date: 3/27/2015SDS Number: 4280-AP4280
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GHS Phrases:
H303 - May be harmful if swallowed
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H320 - Causes eye irritation
H335 - May cause respiratory irritation
H413 - May cause long lasting harmful effects to aquatic life
H229 - Pressurized container: may burst if heated
GHS Precautionary Statements:
P102 - Keep out of reach of children.
P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking
P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352 - IF ON SKIN: Wash with soap and water.
P304+341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P332+313 - If skin irritation occurs: Get medical advice/attention.
P337 - If eye irritation persists: _
P337+313 - Get medical advice/attention.
P338 - Remove contact lenses if present and easy to do. Continue rinsing.
P363 - Wash contaminated clothing before reuse.
P374 - Fight fire with normal precautions from a reasonable distance.
Move to fresh air and keep at rest. Call a physician if symptoms develop and persist.
Wash with soap and water. If skin irritation persists, call a physician immediately. Remove contaminated clothing and
wash before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical
attention if irritation develops and persists.
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low to
avoid getting into the lungs. Call a poison control center if large amounts are ingested. Never give anything by mouth
to an unconscious person.
Means of Extinction:
Suitable Extinguishing Media: Powder, water spray, foam, carbon dioxide.
Unsuitable Extinguishing Media: Not available.
Products of Combustion: May include, and are not limited to: oxides of carbon.
Explosion Data:
Sensitivity to Mechanical Impact: Not available.
Sensitivity to Static Discharge: Not available.
Protection of Firefighters: Containers may explode when heated. Keep upwind of fire. Wear
full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).
Use personal protection recommended in Section 8. Isolate the hazard
area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition.
Ruptured cylinders may rocket.
Many gases are heavier than air and will spread along ground
and collect in low or confined areas (sewers, basements, tanks). This material is a water
pollutant. Keep out of drains, sewers, ditches, and waterways. Minimize use of water to prevent
environmental contamination.
Contain and/or absorb spill with inert material (e.g. sand,
vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter
waterways. Use appropriate Personal Protective Equipment (PPE).
Vacuum or sweep material and place in a disposal container. Allow
gas to dissipate harmlessly into the atmosphere.
EXPOSURE LIMITS
25ppm(140mg/m3) WEEL-TWA
3ppm(15mg/m3) NIOSH (REL)
30ppm AIHA STD (TWA-8h)
1000 ppm
SIMONIZSIMONIZ
ACCIDENTAL RELEASE MEASURES6
Personal Precautions:
Environmental Precautions:
Methods for Containment:
Methods for Clean-Up:
SDS
Simoniz Citrus Clean S3376012
Safety Data Sheet
Revision Date: 3/27/2015SDS Number: 4280-AP4280
48
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HANDLING AND STORAGE7
Handling Precautions:
Storage Requirements:
EYE, SKIN AND RESPIRATORY IRRITANT. Contents under pressure. Keep out of reach of children.
Read label cautions carefully. Follow label directions to avoid injury. Use with adequate ventilation. Do
not use in confined areas. Keep away from heat, sparks or open flames. Wash hands thoroughly after
each use. Do not smoke while using. Avoid contact with skin and eyes. Avoid breathing vapor or mist.
Do not puncture container.
Keep out of reach of children. Do not store near heat, sparks, or open flames. Do not expose to
temperatures above 120°F as container may vent, rupture or burst. Do not puncture or incinerate
container.
Store in accordance with NFPA30B for LEVEL 1 AEROSOLS
EXPOSURE CONTROLS/PERSONAL PROTECTION8
Engineering Controls:
Personal Protective Equip:
IngredientsOSHA-PELACGIH-TLVOTHER
Diethylene Glycol Ethyl EtherNot EstablishedNot Established
Amides, CocoNot Established1mg/m3 TWA
Orange TerpenesNot EstablishedNot Established
Ethanolamine3ppm (6mg/m3)3ppm (6ppm STEL)
Ethanol1000 ppm
Benzenesulfonic AcidNot EstablishedNot Established
Nonylphenol PolyethoxylateNot EstablishedNot Established
Liquified Petroleum Gas1000 ppm(1800mg/m3)Not Established
Use ventilation adequate to keep exposures below recomended exposure limits.
Eyes Protection: Wear eye/face protection.
Hand Protection: Wear suitable gloves.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment.
Mixture packaged in pressurized aerosol spray can.
0.985-0.995 g/ml
< 10 cSt
> 200F
Non-flammable
Not established
Not established
10.5 - 11.5
< 1.00 (BuAc=1)
Not established
May cause long-term adverse effects in the aquatic environment
citrus
Soluble in water
< 95%
Not established
> 200F
Not established
8.0%
Not established
Not established
Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Product is stable under normal conditions.
heat, sparks, open flames and temperatures above 120°F
Strong Oxidizing Agents.
CO, CO2, and hydrocarbons.
Will not occur.
Do not allow into drains or water sourses. Waste and empty containers should be disposed of in accordance with regulations made under
the Control of Pollution Act and the Enviromental Protection Act. Using information provided in this data sheet advice should be obtained
from the Waste Regulation Authority, weather special waste regulations apply.
DOT
UN Number UN1950
UN proper shipping name Aerosols, non-flammable
Transport Hazard Class(es)
Class 2.2
Subsidiary risk ---
Label(s) 2.2
Packing group Not applicable
IATA
UN Number UN1950
UN proper shipping name Aerosols, non-flammable
Transport Hazard Class(es)
Class 2.2
Subsidiary risk ---
Label(s) 2.2
Packing group Not applicable
Environmental hazards No
Other information
Passenger and cargo aircraft Allowed
Cargo aircraft only Allowed
IMDG
UN Number UN1950
UN proper shipping name Aerosols, non-flammable
Transport Hazard Class(es)
Class 2.2
Subsidiary risk ---
Label(s) 2.2
Packing group Not applicable
Environmental hazards No
SIMONIZSIMONIZ
SDS
Simoniz Citrus Clean S3376012
TRANSPORT INFORMATION14
DOT Class: Non-Flammable Gas (2.2) #2.2
UN #: UN 1950, Class: 2, Proper Shipping Name: Aerosols, Packing Group II