Health, Acute toxicity, 5 Inhalation
SIMONIZSIMONIZ
SDS
Simoniz Graffiti & Stain Remover S3346012
PRODUCT AND COMPANY IDENTIFICATION1
Manufacturer
Simoniz, USA
201 Boston Turnpike
Bolton, CT 06043
Tel: 800-227-5536
Emergency Phone: CHEM-TEL: (800) 255-3924
Safety Data Sheet
Revision Date: 3/31/2015SDS Number: 2750-AP2750
1 7
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Product Name:
Revision Date:
Version:
SDS Number:
Common Name:
Product Use:
NFPA:
HMIS III:
4
1 0
Simoniz Graffiti & Stain Remover S3346012
3/31/2015
1
2750-AP2750
Aerosol Graffiti Remover
Graffiti Remover
HAZARDS IDENTIFICATION2
Eyes - Yes Ingestion - Unlikely Inhalation - Yes Skin - YesRoute of Entry:
Health = 1, Fire = 4, Reactivity = 0
H1/F4/PH0
1
4
0
GHS Signal Word:
DANGER
GHS Hazard Pictograms:
GHS Classifications:
Physical, Flammable Aerosols, 1
Health, Acute toxicity, 5 Oral
Health, Skin corrosion/irritation, 2
Health, Serious Eye Damage/Eye Irritation, 2 A
Health, Specific target organ toxicity - Single exposure, 3
Cas # | Percentage | Chemical Name
-------------------------------------------------------------------------------------------------------
67-64-1 | 40-70% | 2-Propanone
108-88-3 | 20-40% | Toluene
78-93-3 | 5-10% | 2-Butanone
124-38-9 | 5-10% | Carbon dioxide
Safety Data Sheet
SIMONIZSIMONIZ
GHS Phrases:
H222 - Extremely flammable aerosol
H229 - Pressurized container: may burst if heated
H303 - May be harmful if swallowed
H315 - Causes skin irritation
H319 - Causes serious eye irritation
H333 - May be harmful if inhaled
H336 - May cause drowsiness or dizziness
GHS Precautionary Statements:
P102 - Keep out of reach of children.
P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking
P251 - Pressurized container: Do not pierce or burn, even after use.
P270 - Do not eat, drink or smoke when using this product.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P301+312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+352 - IF ON SKIN: Wash with soap and water.
P304+341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338 - IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do.
Continue rinsing.
P333+313 - If skin irritation or a rash occurs: Get medical advice/attention.
P363 - Wash contaminated clothing before reuse.
P410+412 - Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F
SDS
Simoniz Graffiti & Stain Remover S3346012
Revision Date: 3/31/2015SDS Number: 2750-AP2750
2 7
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COMPOSITION/INFORMATION ON INGREDIENTS3
Ingredients:
4
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
FIRST AID MEASURES
Move to fresh air and keep at rest. Call a physician if symptoms develop and persist.
Wash with soap and water. If skin irritation persists, call a physician immediately. Remove contaminated clothing and
wash before reuse.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical
attention if irritation develops and persists.
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low to
avoid getting into the lungs. Call a poison control center if large amounts are ingested. Never give anything by mouth
to an unconscious person.
Use personal protection recommended in Section 8. Isolate the hazard
area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition.
Ruptured cylinders may rocket.
Many gases are heavier than air and will spread along ground
and collect in low or confined areas (sewers, basements, tanks). This material is a water
pollutant. Keep out of drains, sewers, ditches, and waterways. Minimize use of water to prevent
environmental contamination.
Contain and/or absorb spill with inert material (e.g. sand,
vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter
waterways. Use appropriate Personal Protective Equipment (PPE).
Vacuum or sweep material and place in a disposal container. Allow
gas to dissipate harmlessly into the atmosphere.
SIMONIZSIMONIZ
SDS
Simoniz Graffiti & Stain Remover S3346012
FIRE FIGHTING MEASURES5
Flammability: Flammable
Flash Point: Not established
Autoignition Temp: Not established
LEL: Not established
UEL: Not established
Means of Extinction:
Suitable Extinguishing Media: Powder, foam, carbon dioxide.
Unsuitable Extinguishing Media: Not available.
Products of Combustion: May include, and are not limited to: oxides of carbon.
Explosion Data:
Sensitivity to Mechanical Impact: Not available.
Sensitivity to Static Discharge: Not available.
Protection of Firefighters: Containers may explode when heated. Keep upwind of fire. Wear
full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).
Safety Data Sheet
Revision Date: 3/31/2015SDS Number: 2750-AP2750
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ACCIDENTAL RELEASE MEASURES6
Personal Precautions:
Environmental Precautions:
Methods for Containment:
Methods for Clean-Up:
HANDLING AND STORAGE7
Handling Precautions:
Storage Requirements:
HARMFUL IF INHALED OR SWALLOWED. VAPOR HARMFUL. EYE, SKIN AND RESPIRATORY
IRRITANT. Contents under pressure. Keep out of reach of children. Read label cautions carefully.
Follow label directions to avoid injury. Use with adequate ventilation. Do not use in confined areas.
Keep away from heat, sparks or open flames. Wash hands thoroughly after each use. Do not smoke
while using. Avoid contact with skin and eyes. Avoid breathing vapor or mist. Do not puncture
container.
Keep out of reach of children. Do not store near heat, sparks, or open flames. Do not expose to
temperatures above 120°F as container may vent, rupture or burst. Do not puncture or incinerate
container.
Store in accordance with NFPA 30B for LEVEL 3 AEROSOLS.
EXPOSURE LIMITS
2-Propanone 1000 ppm 500 ppm (750 ppm STEL)
Toluene 200 ppm 20 ppm
2-Butanone 200 ppm 200 ppm
Mixture packaged in pressurized aerosol spray can.
0.82 - 0.84 g/ml
< 5 cSt
Not established
Flammable
Not established
Not applicable
>1.00 (BuAc=1)
Not established
Not established
SIMONIZSIMONIZ
EXPOSURE CONTROLS/PERSONAL PROTECTION8
Safety Data Sheet
SDS
Simoniz Graffiti & Stain Remover S3346012
Revision Date: 3/31/2015SDS Number: 2750-AP2750
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Engineering Controls:
Personal Protective Equip:
INGREDIENTS OSHA-PEL ACGIH-TLV OTHER
Carbon dioxide 5000 ppm 5000 ppm (30,000 ppm STEL)
Use ventilation adequate to keep exposures below recomended exposure limits.
Eyes Protection: Wear eye/face protection.
Hand Protection: Wear suitable gloves.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment.
PHYSICAL AND CHEMICAL PROPERTIES9
Appearance: clear colorless liquid
Physical State:
Spec Grav./Density:
Viscosity:
Boiling Point:
Flammability:
Vapor Pressure:
pH:
Evap. Rate:
Decomp Temp:
Odor:
Solubility:
Percent Volatile:
Heat Value:
Flash Point:
VOC:
Auto-Ignition Temp:
UFL/LFL:
ketone
Partially soluble in water
100%
Not established
Not established
38.5%
Not established
Not established
STABILITY AND REACTIVITY10
Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition:
Hazardous Polymerization:
Product is stable under normal conditions.
heat, sparks, open flames and temperatures above 120°F
Strong Acids; Strong Bases; Strong Oxidizing Agents. Reducing Agents
CO, CO2, and hydrocarbons.
Will not occur.
TOXICOLOGICAL INFORMATION11
May cause long-term adverse effects in the aquatic environment
Not available.
Not available.
Not available.
DOT
UN Number UN1950
UN proper shipping name Aerosols, flammable
Transport Hazard Class(es)
Class 2.1
Subsidiary risk ---
Label(s) 2.1
Packing group Not applicable
IATA
UN Number UN1950
UN proper shipping name Aerosols, flammable
Transport Hazard Class(es)
Class 2.1
Subsidiary risk ---
Label(s) 2.1
Packing group Not applicable
Environmental hazards No
Other information
Passenger and cargo aircraft Allowed
Cargo aircraft only Allowed
IMDG
UN Number UN1950
UN proper shipping name Aerosols, flammable
Transport Hazard Class(es)
Class 2.1
Subsidiary risk ---
Label(s) 2.1
Packing group Not applicable
Safety Data Sheet
SIMONIZSIMONIZ
ECOLOGICAL INFORMATION12
Ecotoxicity:
Persistence / Degradability:
Bioaccumulation / Accumulation:
Mobility in Environment:
DISPOSAL CONSIDERATIONS13
Do not allow into drains or water sourses. Waste and empty containers should be disposed of in accordance with regulations made under
the Control of Pollution Act and the Enviromental Protection Act. Using information provided in this data sheet advice should be obtained
from the Waste Regulation Authority, weather special waste regulations apply.
SDS
Simoniz Graffiti & Stain Remover S3346012
Revision Date: 3/31/2015SDS Number: 2750-AP2750
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TRANSPORT INFORMATION14
DOT Class: Flammable Gas (2.1) #2.1
UN #: UN 1950, Class: 2, Proper Shipping Name: Aerosols, flammable
Environmental hazards No
COMPONENT / (CAS/PERC) / CODES
----------------------------------------------------------------
TXHWL
SARA313, TOXICPOL, TOXICRCRA, TSCA, TXAIR, TXHWL
TXAIR, TXHWL
*Carbon dioxide (124389 5-10%) MASS, OSHAWAC, PA, TSCA, TXAIR
REGULATORY KEY DESCRIPTIONS
----------------------------------------------------------------
CERCLA = Superfund clean up substance
HAP = Hazardous Air Pollutants
MASS = MA Massachusetts Hazardous Substances List
NJHS = NJ Right-to-Know Hazardous Substances
OSHAWAC = OSHA Workplace Air Contaminants
PA = PA Right-To-Know List of Hazardous Substances
SARA313 = SARA 313 Title III Toxic Chemicals
TOXICRCRA = RCRA Toxic Hazardous Wastes (U-List)
TSCA = Toxic Substances Control Act
TXAIR = TX Air Contaminants with Health Eects Screening Level
TXHWL = TX Hazardous Waste List
CSWHS = Clean Water Act Hazardous substances
EPCRAWPC = EPCRA Water Priority Chemicals
PRIPOL = Clean Water Act Priority Pollutants
PROP65 = CA Prop 65
TOXICPOL = Clean Water Act Toxic Pollutants
HWRCRA = RCRA Hazardous Wastes
- California Safe Drinking Water and Toxic Enforcement Act of 1986
Proposition 65.
Safety Data Sheet
SIMONIZSIMONIZ
REGULATORY INFORMATION15
*2-Propanone (67641 40-70%) CERCLA, HAP, MASS, NJHS, OSHAWAC, PA, SARA313, TOXICRCRA, TSCA, TXAIR,
*Toluene (108883 20-40%) CERCLA, CSWHS, EPCRAWPC, HAP, MASS, NJHS, OSHAWAC, PA, PRIPOL, PROP65,
*2-Butanone (78933 5-10%) CERCLA, HAP, HWRCRA, MASS, NJHS, OSHAWAC, PA, SARA313, TOXICRCRA, TSCA,
SDS
Simoniz Graffiti & Stain Remover S3346012
Revision Date: 3/31/2015SDS Number: 2750-AP2750
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Proposition 65
This product is known to contain chemical(s) currently listed as carcinogens or reproductive toxins under California
Safety Data Sheet
SIMONIZSIMONIZ
OTHER INFORMATION16
The information provided herein was believed to be accurate at the time of preparation and prepared from a compilation of sources believed
to be reliable, but it is the responsibility of the user to investigate and understand other pertinent sources of information, to comply with all
laws and procedures applicable to the safe handling and use of this product, and to determine the suitability of the product for its intended
use.
Publication Date: 3/31/15
Revision No.: 1
SDS
Simoniz Graffiti & Stain Remover S3346012
Revision Date: 3/31/2015SDS Number: 2750-AP2750
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