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SAFETY DATA SHEET
Issue date
This Safety Data Sheet (SDS) is intended to provide product information for workplaces, emergency personnel and other situations where there is potential for
longer exposure or exposure to larger quantities of product. For consumer use, applicable precautionary information is provided on the product label. This SDS is
designed to cover both U.S. and Canadian requirements. Differences between U.S. and Canadian requirements are noted where applicable.
17 May 2015
FM000004-00.1
Section 1: Identification of Product and Company
Product Name
Synonyms
Product Use
Restrictions on Use Follow directions on the product label
Manufacturer Name
Address
Emergency Telephone Number U.S. Canada
Monday -Friday 8 am - 5 pm ET (except holidays)
Outside these hours
Automatic Dishwasher Detergent (powder)
Natural Dishwasher Detergent
Automatic Dishwashing
Seventh Generation, Inc.
60 Lake Street, Burlington, VT 05401, USA
1-800-211-4279
1-800-255-3924 (ChemTel)
Section 2: Hazards Identification
Hazardous Materials Identification System (HMIS) Rating
Legend: 4-Severe, 3-Serious, 2-Moderate, 1-Slight, 0-Minimal
HEALTH
FLAMMABILITY
PHYSICAL HAZARDS
PERSONAL PROTECTION
2
0
0
A
National Fire Protection Association (NFPA) Rating
Classification
U.S.
Canada
Category
Eyes Irritant Category 2A
Emergency Overview
Signal Word CAUTION
Hazard(s) EYE IRRITANT
Pictogram(s)
Precautionary Statements
Eyes May cause irritation and discomfort.
Skin No irritation expected when used according to directions. Possible irritation from prolonged contact.
Ingestion May cause gastrointestinal irritation with nausea, vomiting, and delayed diarrhea.
Inhalation
Hazards not otherwise identified None known
Percent ingredients with unknown acute toxicity 0% of the product consists of ingredients of unknown acute oral toxicity. Refer to Section 3.
This product is considered hazardous under the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200).
This product is considered hazardous under the WHMIS 2015.
May be harmful if swallowed. Contact with eyes may cause irritation. May cause irritation of respiratory
tract.
While inhalation of a product dust is unlikely, sudden inhalation of large quantity of dust may cause
upper respiratory irritation.
Not determined
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Section 3: Composition, Information on Ingredients
Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients ≥1% on the consumer
product label.
Ingredient Function CAS Number
sodium chloride processing aid 7647-14-5 30% - 100% 3000 mg/kg
sodium sulfate processing aid 7757-82-6 10% - 30% 5989 mg/kg
sodium carbonate cleaning agent 497-19-8 10% - 30% 4090 mg/kg
citric acid water softener 77-92-9 10% - 30% 3000 mg/kg
sodium percarbonate oxygen stain removal agent 15630-89-4 1% - 3% 2400 mg/kg
ppg-10-laureth-7 cleaning agent 68439-51-0 1% - 3% >2000 mg/kg
sodium polyaspartate anti-filming agent 34345-47-6 1% - 3% >5000 mg/kg
sodium silicate cleaning enhancer 1344-09-8 ≤1% 1960 mg/kg
protease enzyme soil remover 9014-01-1 ≤1% 1800 mg/kg
amylase enzyme soil remover 9000-90-2 ≤1% >2000 mg/kg
1
Where ranges are shown, the exact concentration has been withheld as a trade secret.
2
LD50 Acute oral toxicity (rat) – This is a value provided by the raw material supplier or scientific literature. It is not a value generated by Seventh Generation by
testing using rats. Seventh Generation uses alternative, non-animal based methods and scientific literature to determine the safety classification of our products
and their ingredients.
Concentration
1
LD50
2
Section 4: First Aid Measures
Eye Contact
Skin Contact Rinse with water. Remove contaminated clothing and shoes.
Ingestion
Inhalation While inhalation of product dust is unlikely, move to fresh air away from dust.
Notes to Physician Treat symptomatically.
Most important symptoms and effects Acute exposure may result in eye irritation.
Promptly flush with large amounts of water for at least 15 minutes. Contact a physician if redness or
irritation persists.
Do not induce vomiting. Drink 4-8 ounces of water or milk immediately. Contact a poison control center
or physician.
Section 5: Fire Fighting Measures
Suitable Extinguishing Media As appropriate for surrounding fire. Use water, dry chemical, carbon dioxide or foam.
Unsuitable Extinguishing Media Not available.
Specific Hazards arising from the chemical mixture Not available.
Hazardous Combustion Products Not available.
Protective Equipment and Precautions for Firefighters
Fire fighters should wear full protective clothing and self contained breathing apparatus as for
surrounding fire.
Section 6: Accidental Release Measures
Personal Precautions
Industrial Setting Wear appropriate personal protective equipment (refer to Section 8).
Environmental Precautions Avoid entry into lakes, streams, ponds or public waterways.
Methods for Containment and Cleaning Up
Household Setting Small spills and leaks may be cleaned up and disposed of in normal household trash.
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Before attempting clean up, refer to hazard data given. Material may be slippery if spilled and wet.
Industrial Setting
Section 7: Handling and Storage
Safe Handling
Household Setting Use as directed on product label.
Industrial Setting Wear appropriate personal protective equipment (refer to section 8).
Prevent spill from entering a waterway. Stop spill at source and contain material. Transfer powder to
container for recovery or disposal. Dispose liquid in accordance with all applicable local, state, and
federal regulations. Small amounts may be flushed to sewer.
Safe Storage
Storage Incompatibilities None known.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Store in original container in a cool, dry place and keep container closed when not in use.
Section 8: Exposure Controls, Personal Protection
Exposure Limits None known.
Engineering Controls Not applicable.
Personal Protective Equipment (PPE)
Household Setting No special precautions necessary as long as product is used as directed.
Industrial Setting
Respiratory Protection None required under normal conditions. General ventilation required.
Eye Protection Goggles or other protective eye wear may be worn for protection.
Skin Protection Gloves may be worn for protection.
Hygiene Measures Handle in accordance with good industrial hygiene and safety practice.
Section 9: Physical and Chemical Properties
Physical State Solid (powder).
Color White to light yellow
Clarity Solid
Odor Unscented. Characteristic of the ingredients
Odor Threshold Not available.
pH (1% aqueous dilution) 9.4 - 10.0
Melting Point Not available.
Flammability Not flammable.
Upper Explosive Limit (UEL) Not applicable.
Lower Explosive Limit (LEL) Not applicable.
Vapor Pressure (mmHg) Not available.
Vapor Density (Air = 1) Not available.
Solubility in Water Soluble
Auto-Ignition Temperature Not available.
Decomposition Temperature Not available.
Bulk Density Not available.
VOC (weight %) Not available.
Section 10: Stability and Reactivity
Reactivity Not available.
Chemical Stability Stable.
Possibility of Hazardous Reactions None known.
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Conditions to Avoid None known.
Incompatible Materials
Household Setting
Industrial Setting Strong oxidizers or reducing agents, strong acids or strong bases.
Hazardous Decomposition Products None known.
Section 11: Toxicological Information
Potential Route(s) of Exposure Eyes. Skin. Ingestion. Inhalation.
Effects of Acute Exposure
Oral Toxicity LD50 >3000 mg/kg, calculated based on ingredients.
Dermal Toxicity Not available.
Inhalation Toxicity Not available.
Eye Contact
Skin Contact Non-Irritant, based on Human Repeat Insult Patch Test (HRIPT).
Component Information Refer to section 3 for ingredient LD50 (acute oral).
Effects of Chronic Exposure
Sensitization
Carcinogenicity Not expected to have chronic health effects.
NTP No Ingredients Listed
IARC No Ingredients Listed
OSHA No Ingredients Listed
Teratogenicity Not expected to have chronic health effects.
Mutagenicity Not expected to have chronic health effects.
Target Organ Effects Not expected to have chronic health effects.
In general, cleaning products should not be mixed with other household chemicals, unless specifically
provided for in the use directions.
Moderate Irritant, based on ingredients.
Not expected to have chronic health effects.
Does not indicate a potential for allergic contact sensitization, based on Human Repeat Insult Patch Test
(HRIPT).
Not expected to have chronic health effects.Reproductive Effects
Section 12: Ecological Information
Ecotoxicity Not available.
Persistence and Degradability Non inorganic components are biodegradable.
Bioaccumulative Potential Not applicable.
Mobility in Soil Not available.
Environmental Fate No adverse effects expected.
Section 13: Disposal Considerations
Product Waste
Household Setting Product residues in the container may be discarded in trash.
Industrial Setting
California Hazardous Waste Code 561
Connecticut Hazardous Waste Code CT05
Washington Hazardous Waste Code WT02
Any disposal must be in compliance with applicable local, state, provincial and federal laws and
regulations.
When used as directed, the product is septic-safe.
When disposed as waste in its original form, this product is not considered hazardous waste under
Federal regulations, however regulations may vary by state or province and may designate it as
hazardous waste. Check with your local waste and waste water authorities. We are aware of the
following state waste classifications:
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Empty Packaging
Offer empty container for recycling. If recycling
is not available, discard in trash.
Section 14: Transport Information
U.S. DOT (Surface Transport) Not regulated.
Not regulated as finished product.
U.S. States (Surface Transport)
Canadian TDG (Surface Transport) Not regulated.
IATA (Air Transport) Not regulated.
IMDG (Marine Transport) Not regulated.
Regulated in some states if the product is disposed of in its original form as waste by commercial
users/handlers. Refer to Section 13. for applicable state waste codes.
Section 15: Regulatory Information
U.S.
Toxic Substances Control Act (TSCA) This product complies with the inventory requirements of the U.S. Toxic Substances Control Act (TSCA).
California Prop 65 This product is not subject to the labeling requirements of California’s Proposition 65.
California Air Resources Board (CARB) Not applicable.
Canada
Domestic Substances List (DSL) This product complies with the inventory requirements under Canada’s Domestic Substances List (DSL).
Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and,
Right to Know
if applicable incidental ingredients ≥1% on the product label. Please refer to Section 3. of this SDS for
ingredient listing.
Section 16: Other Information
Prepared by Seventh Generation Inc.
Issuing Date 17 May 2015
Revision Date 17 May 2015
Revision Note Revised format as per OSHA 2012 and WHMIS 2015.
Please note: This product is manufactured and marketed for consumer use and should be used as directed on the product label for the intended purpose. Seventh
Generation warrants that this product conforms to our standard specification when released to the market and when used according to directions. To the best of
our knowledge, the information contained herein is accurate. However, we do not assume any liability whatsoever for the accuracy or completeness of the
information contained herein. Final determination of the suitability of any product is the sole responsibility of the user. All products may present unknown hazards
and should be used with requisite caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Other abbreviations used in this document:
DOT – (U.S.) Department of Transportation
EPA – (U.S.) Environmental Protection Agency
IARC – International Agency for Research on Cancer
NTP – (U.S. Department of Health and Human Services) National Toxicology Program
OSHA – (U.S.) Occupational Safety and Health Administration
TDG – (Canadian) Transport of Dangerous Goods
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WHMIS – (Canadian) Workplace Hazardous Materials Information System
End of Safety Data Sheet
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