SAFETY DATA SHEET
Issue date
This Safety Data Sheet (SDS) is intended to provide product information for workplaces, emergency personnel and other situations where there is potential for
longer exposure or exposure to larger quantities of product. For consumer use, applicable precautionary information is provided on the product label. This SDS is
designed to cover both U.S. and Canadian requirements. Differences between U.S. and Canadian requirements are noted where applicable.
18 May 2015
FM000002‐00,01.1
Section 1: Identification of Product and Company
Product Name
Synonyms
Product Use
Restrictions on Use Follow directions on the product label
Manufacturer Name
Address
Emergency Telephone Number U.S. Canada
Monday -Friday 8 am - 5 pm ET (except holidays)
Outside these hours
Automatic Dishwasher Detergent Gel
Natural Automatic Dishwasher Detergent Gel
Automatic Dishwashing
Seventh Generation, Inc.
60 Lake Street, Burlington, VT 05401, USA
1‐800‐211‐4279
1‐800‐255‐3924 (ChemTel)
Section 2: Hazards Identification
Hazardous Materials Identification System (HMIS) Rating
Legend: 4‐Severe, 3‐Serious, 2‐Moderate, 1‐Slight, 0‐Minimal
HEALTH
FLAMMABILITY
PHYSICAL HAZARDS
PERSONAL PROTECTION
0
0
0
A
National Fire Protection Association (NFPA) Rating
Classification
U.S.
Canada
Emergency Overview No known health hazards.
Precautionary Statements
Eyes Minimal Irritant
Skin Non‐Irritant
Ingestion Non‐Toxic
Inhalation No health effects are expected.
Hazards not otherwise identified None known
Percent ingredients with unknown acute toxicity 0% of the product consists of ingredients of unknown acute oral toxicity. Refer to Section 3.
This product is not considered hazardous under the 2012 OSHA Hazard Communication Standard (29 CFR
1910.1200).
This product is not considered hazardous under the WHMIS 2015.
Not determined
Section 3: Composition, Information on Ingredients
Regardless of hazard classification, Seventh Generation discloses all intentionally added ingredients and, if applicable incidental ingredients ≥1% on the consumer
product label.
Ingredient Function CAS Number
aqua (water) diluent 7732‐18‐5 30% ‐ 100% Not applicable
sodium citrate water softener 68‐04‐23% ‐ 10% >8000 mg/kg
ppg‐10‐laureth‐7 cleaning agent 68439‐51‐03% ‐ 10% >2000 mg/kg
Concentration
1
LD50
2
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SAFETY DATA SHEET
glycerin enzyme stabilizer 56‐81‐51% ‐ 3% >12600 mg/kg
sodium silicate alkalinity builder 1344‐09‐81% ‐ 3% 1960 mg/kg
citric acid pH adjuster 77‐92‐91% ‐ 3% 3000 mg/kg
xanthan gum thickener 11138‐66‐2 ≤1% >5000 mg/kg
sodium borate enzyme stabilizer 1303‐96‐4 ≤1% 2660 mg/kg
calcium chloride enzyme stabilizer 10043‐52‐4 ≤1% 1000 mg/kg
sodium hydroxide pH adjuster 1310‐73‐2 ≤1% 140 mg/kg
protease enzyme soil remover 9014‐01‐1 ≤1% 1800 mg/kg
amylase enzyme soil remover 9000‐90‐2 ≤1% >2000 mg/kg
essential oils & botanical extracts* mixture ≤1% >5000 mg/kgfragrance
benzisothiazolinone (and)
methylisothiazolinone
*Free & Clear: not applicable.
*Lemon: citrus grandis (grapefruit) peel oil, citrus limon (lemon) peel oil, cymbopogon schoenanthus (lemongrass) oil. d‐Limonene is a component of these essential
oils.
1
Where ranges are shown, the exact concentration has been withheld as a trade secret.
2
LD50 Acute oral toxicity (rat) – This is a value provided by the raw material supplier or scientific literature. It is not a value generated by Seventh Generation by
testing using rats. Seventh Generation uses alternative, non‐animal based methods and scientific literature to determine the safety classification of our products
and their ingredients.
preservatives
2634‐33‐5 &
2682‐20‐4
≤1% >2500 mg/kg
Section 4: First Aid Measures
Eye Contact Flush eyes with water immediately after contact. Call a physician if irritation develops or persists.
Skin Contact Rinse thoroughly with water if skin contact occurs. Call a physician if irritation develops or persists.
Ingestion Drink 4‐8 ounces of water or milk immediately. If prolonged nausea or pain occurs call a doctor.
Inhalation No need for first aid is expected.
Notes to Physician Treat symptomatically.
Most important symptoms and effects Acute exposure may result in eye irritation.
Section 5: Fire Fighting Measures
Suitable Extinguishing Media As appropriate for surrounding fire. Use water, dry chemical, carbon dioxide or foam.
Unsuitable Extinguishing Media Not available.
Specific Hazards arising from the chemical mixture Not available.
Hazardous Combustion Products Not available.
Protective Equipment and Precautions for Firefighters
Fire fighters should wear full protective clothing and self contained breathing apparatus as for
surrounding fire.
Section 6: Accidental Release Measures
Personal Precautions
Industrial Setting Wear appropriate personal protective equipment (refer to Section 8).
Environmental Precautions Avoid entry into lakes, streams, ponds or public waterways.
Methods for Containment and Cleaning Up
Household Setting
Small spills and leaks may be cleaned up and disposed of in normal household trash or diluted and
disposed of via sewer.
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