Senseo HD6566/60 Technical data

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SAFETY DATA SHEET

According to EC 1907/2006 (REACH)

Date last verification : 2018-03-23 Revision date : 2017-05-29 Publication date : 2001-07-02

Last modifications in sections : 2 - 3

Version number : 3.0

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

SDS : 13923 Product code : 8827 012 00020 Supplier : DE RIDDER B.V.

Oosterwerf 4 1911 JB Uitgeest The Netherlands TEL:+31 (0) 251  315920

Tradename : HD7012/00 WEU SENSEO DESCALER Chemical name : CITRIC ACID MONOHYDRATE CAS number : 5949-29-1 EC-number : 201-069-1 REACH registration number : 01-2119457026-42 Formula : C6H8O7.H2O

Molecular weight : 210.15

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use : Various Uses advised against : Data not available.

1.3. Details of the supplier of the safety data sheet

Supplier safety data sheet : Philips Electronics Nederland B.V., Philips Environment & Safety, High Tech Campus 37, 5656 AE

Responsible department : [email protected]

Eindhoven, Tel. +31 (0)40 27 41 645

1.4. Emergency telephone number

Emergency telephone number : +31 (0)497-598315

* SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

(EC) No 1272/2008

Serious eye irritation Category 2 H319

2.2. Label elements

(EC) No 1272/2008

Hazard pictogram(s)

Signal word : Warning

Hazard statements

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H319 Causes serious eye irritation.

Precautionary statements

P264 Wash hands/skin thoroughly after handling. P280.3 Wear eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

P337+P313 If eye irritation persists: Get medical advice/attention.

Hazardous component(s) CITRIC ACID MONOHYDRATE

Remarks on labelling none

Continue rinsing.

2.3. Other hazards

If applicable: see section 6.1 and section 7.1.

* SECTION 3: Composition/information on ingredients

Component

CAS-no. EC-no.

Index No. Registration no.

Percentage(%) Label

CITRIC ACID MONOHYDRATE

For the full text of the H-sentences mentioned in this section, see section 16.

5949-29-1 201-069-1 01-2119457026-42

100.0 GHS07 H319 Eye irrit. 2

SECTION 4: First aid measures

4.1. Description of first aid measures

Skin : Remove contaminated clothes as soon as possible. Remove residue substance as soon as possible (e.g. rinse with plenty

Ingestion : If victim is conscious let him rinse the mouth with water. Do NOT let him drink. In case of general disorders bring victim into

Inhalation : Bring victim into the fresh air as soon as possible and let rest. In case of severe exposure call for a doctor. In case of

Eyes : Rinse for a long time with plenty of water. In case of eye-sight disturbances bring victim immediately into the hospital, in

4.2. Most important symptoms and effects, both acute and delayed

Skin local : The substance is prickling: redness.

Ingestion local : The substance is prickling: sore throat.

Inhalation local : The substance is with atomising prickling: sore throat.

Eyes local : The substance is irritating: redness, pain.

Remarks symptoms : The substance has an effect on: the blood.

of water). In case of a serious exposure call for a doctor.

the hospital, otherwise call for a doctor.

breathing problems, loose squeezing clothes and if victim is conscious bring victim in high sitting position. In case of stagnation of breathing give IMMEDIATELY oxygen and transport to hospital as soon as possible.

other cases call for a doctor

general : Probably no absorbtion worth mentioning.

general : The substance may be absorbed after ingestion.

general : Probably no absorbtion worth mentioning.

4.3. Indication of any immediate medical attention and special treatment needed

For advice on further treatment contact a (national) poison center.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable fire-extinguisher

water, special extinguishing powder, water spray

Unsuitable fire-extinguisher

not traceable

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition products in fire : carbon monoxide

5.3. Advice for firefighters

In the event of fire, wear protective clothing and use breathing apparatus that is independent of the ambient air.

SECTION 6: Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures

Precautions

Use protective equipment. See section 8. Read label before use. Take precautionary measures against static discharge.

Emergency procedure

Possibility of dust explosion! Acute risk to health! IMMEDIATELY evacuate and close off the danger zone. Notify expert!

6.2. Environmental precautions

Remainder material or uncleaned empty packagings have to be incinerated in a proper installation or dumped on an approved landfill, in accordance with local and national legislation.

6.3. Methods and material for containment and cleaning up

Spillage procedure

Where necessary, cover the spilt material with dry sand or dry earth in order to prevent displacement by wind or draught, sweep or shovel into plastic bags and remove to the central depot for hazardous waste.

6.4. Reference to other sections

See section 8 for appropriate personal protection. See section 13 for additional information on waste treatment.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Observe label precautions. Do not eat, drink or smoke in work areas. Remove contaminated clothing and protective equipment. Wash hands after leaving the work area. Take precautionary measures against static discharge. Take precautionary measures against dust formation.

Local exhausting : Depends on processing circumstances, but at least good room ventilation.

Storage code (on behalf of PGS

15)

: none

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : See also any precautionary statements in section 2.2.

Storage temperature :

Store product in a closed packaging, cool, dry, in a well ventilated area, NOT in a metal packaging.

≥15 ºC - ≤25 ºC

7.3. Specific end use(s)

Data not available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits :

applicable to: The Netherlands

No TWA has been laid down.

C=Ceiling; S=Skin

Remarks exposure limits :

Avoid breathing dust. Observe the TWA-value for irritant inhalable dust (10 mg/m3) and respirable dust (5 mg/m3) if the values for components are not available.

DNEL (Derived No Effect Level)

Data not available.

PNEC (Predicted No Effect Concentration)

Fresh water: 0.44 mg/l Fresh water sediment: 34.6 mg/kg Marine water sediment: 3.46 mg/kg Soil: 33.1 mg/kg Sewage Treatment Plant (STP): 1000 mg/l Marine water: 0.044 mg/l

CITRIC ACID MONOHYDRATE

CITRIC ACID MONOHYDRATE Source : ECHA

8.2. Exposure controls

Advised personal protection :

Hands : butyl rubber gloves

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Breakthrough time : For information: consult the supplier of the gloves. Eyes : dust goggles Inhalation : dust mask P2 Skin : protective clothing (such as: apron, coverall, boots)

polyvinyl chloride gloves

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : solid Colour : white Odour : odourless Odour threshold (20ºC; 1013 mbar) : not traceable pH : Melting point/range : Apparent melting point : 100 ºC Boiling point/range : The product decomposes before it boils. Flash point/range : not applicable Vapor rate/range : not applicable Flammability (solid, gas) : data not available Explosive limits : Vapour pressure : not applicable Relative density : Solubility in water : 1630 g/l (20 ºC) Log Po/w : -1.7 Source : Chemicalcards Autoignition temperature : Decomposition temperature : >170 ºC Viscosity : not applicable Dust explosions possible in air : yes Oxidising properties : no

≥1.80 - ≤1.85 (50 g/l) ≥135 ºC - ≤153 ºC

LEL:≥100 g/m3

≥1.500 - ≤1.660 (water=1) (20 ºC)

≥540 ºC - ≤1010 ºC

9.2. Other information

Solubility in fat : 419 g/l (25 ºC) (ETHANOL) Electrostatic chargement : yes Critical temperature : not applicable General : Product is hydroscopic.

SECTION 10: Stability and reactivity

10.1. Reactivity

See section 10.2 - 10.6.

10.2. Chemical stability

The substance or mixture is stable under normal conditions. See also section 10.4.

10.3. Possibility of hazardous reactions

Reactions with water : no

Other hazardous conditions : Data not available.

10.4. Conditions to avoid

Avoid discharge of static electricity. Avoid dust formation.

10.5. Incompatible materials

Hazardous reactions with : oxidizing substances, metals, reducing substances, metal nitrates, alkaline solutions,

alkaline substances

10.6. Hazardous decomposition products

Hazardous decomposition products at heating : methylmaleic anhydride

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute oral toxicity

There are no data available.

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Acute dermal toxicity

There are no data available.

Acute inhalation toxicity

There are no data available.

Ames test

negative

Skin corrosion/irritation

The substance or mixture is not classified for skin corrosion/-irritation.

Serious eye damage/irritation

Causes serious eye irritation.

Respiratory or skin sensitisation

The substance or mixture is not classified for respiratory or skin sensitisation.

Germ cell mutagenicity

The substance or mixture is not classified for germ cell mutagenicity.

Carcinogenicity

The substance or mixture is not classified for carcinogenicity.

Additional information regarding carcinogenicity (NTP, IARC, OSHA)

NTP: no IARC: no OSHA: no CITRIC ACID MONOHYDRATE

Reproductive toxicity

The substance or mixture is not classified for reproductive toxicity.

Specific target organ toxicity-single exposure

The substance or mixture is not classified for specific target organ toxicity-single exposure.

Specific target organ toxicity-repeated exposure

The substance or mixture is not classified for specific target organ toxicity-repeated exposure.

Aspiration hazard

The substance or mixture is not classified for aspiration hazard.

Symptoms

Skin local : The substance is prickling: redness.

general : Probably no absorbtion worth mentioning.

Ingestion local : The substance is prickling: sore throat.

general : The substance may be absorbed after ingestion.

Inhalation local : The substance is with atomising prickling: sore throat.

general : Probably no absorbtion worth mentioning.

Eyes local : The substance is irritating: redness, pain.

Remarks symptoms : The substance has an effect on: the blood.

CITRIC ACID MONOHYDRATE

Source : Merck

SECTION 12: Ecological information

12.1. Toxicity

Ecotoxicity

LC-50: 440 mg/l/96H (Fish) EC-50: 120 mg/l/48H (Daphnia)

12.2. Persistence and degradability

Biological oxygen demand (5) : 0.481 g/g Chemical oxygen demand : 0.686 g/g Biological(5)/chemical oxygen demand ratio Degradability : readily

: 0.701

12.3. Bioaccumulative potential

Bioconcentration factor (BCF) Log Po/w : -1.7

: not traceable

12.4. Mobility in soil

Henry Constant : not traceable

12.5. Results of PBT and vPvB assessment

Data not available.

12.6. Other adverse effects

CITRIC ACID MONOHYDRATE

Source : ACROS Source : ACROS

Source : Merck Source : Merck

Method : OECD 302B Source : Merck

Source : Chemicalcards

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Remarks on ecotoxicity : none

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Remainder material or uncleaned empty packagings have to be incinerated in a proper installation or dumped on an approved landfill, in accordance with local and national legislation.

SECTION 14: Transport information

14.1. UN number