Scrubbing Bubbles 696208 User Manual

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

1/13

1. PRODUCT AND COMPANY IDENTIFICATION

Product information

Product name

:

SCRUBBING BUBBLES® TOILET BOWL CLEANER­RAINSHOWER

Recommended use

:

Toilet Cleaner

Restrictions on use

:

Use only as directed on label

Manufacturer, importer,
supplier

:

S.C. Johnson & Son, Inc.
1525 Howe Street
Racine WI 53403-2236

Telephone

:

[phone]

Emergency telephone
number

:

24 Hour Medical Emergency Phone: [phone]
24 Hour International Emergency Phone: [phone]
24 Hour Transport Emergency Phone: [phone]

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

Globally Harmonized System (GHS) Classification

Hazard classification

Hazard category

Hazards identification

Skin corrosion

Category 1B

Causes severe skin burns and
eye damage.

Serious eye damage

Category 1

Causes serious eye damage.

Labelling
Hazard symbols

Corrosion

Signal word
Danger

Hazard statements

Causes serious eye damage.

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

2/13

Precautionary statements

If medical advice is needed, have product container or label at hand.
Keep out of reach of children.
Read label before use.
Immediately call a POISON CENTER/doctor.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Wash hands thoroughly after handling.

Other hazards

:

None identified

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical name

CAS-No.

Weight percent

Hydrochloric acid

7647-01-0

5.00 - 10.00

2,2'-(octadec-9-enylimino)bisethanol

25307-17-9

1.00 - 5.00

Alcohols, C13-15-branched and linear,
ethoxylated EO=8

157627-86-6

1.00 - 5.00

The specific chemical identity and/or exact percentage (concentration) of this composition has been
withheld as a trade secret.

For additional information on product ingredients, see www.whatsinsidescjohnson.com.

4. FIRST AID MEASURES

Description of first aid measures

Eye contact

:

IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing. Immediately call a POISON CENTER/doctor. Get
medical attention immediately.

Skin contact

:

IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower. Wash contaminated
clothing before reuse. Immediately call a POISON
CENTER/doctor.

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

3/13

Inhalation

:

IF INHALED: If breathing is difficult, remove victim to fresh air
and keep at rest in a position comfortable for breathing.

Ingestion

:

IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Rinse mouth.

Most important symptoms and effects, both acute and delayed

Eyes

:

Causes serious eye damage.

Skin effect

:

Causes severe skin burns.
No adverse effects expected when used as directed.

Inhalation

:

May cause respiratory tract irritation.

Ingestion

:

Causes digestive tract burns.
No adverse effects expected when used as directed.

Indication of any immediate medical attention and special treatment needed

See Description of first aid measures unless otherwise stated.

5. FIREFIGHTING MEASURES

Suitable extinguishing
media

:

Use water spray, alcohol-resistant foam, dry chemical or
carbon dioxide.

Specific hazards during
firefighting

:

Container may melt and leak in heat of fire.

Further information

:

Wear full protective clothing and positive pressure self­contained breathing apparatus. In case of fire and/or explosion
do not breathe fumes.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

:

Wear personal protective equipment.
Wash thoroughly after handling.

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

4/13

Environmental
precautions

:

Outside of normal use, avoid release to the environment.

Methods and materials
for containment and
cleaning up

:

Dike large spills.
Clean residue from spill site.
Absorb spillage to prevent material damage.

7. HANDLING AND STORAGE

Handling

Precautions for safe
handling

:

Avoid contact with skin, eyes and clothing.
For personal protection see section 8.
Use only as directed.
KEEP OUT OF REACH OF CHILDREN AND PETS.
Avoid breathing vapours, mist or gas.
Wash thoroughly after handling.

Advice on protection
against fire and explosion

:

Normal measures for preventive fire protection.

Storage

Requirements for storage
areas and containers

:

Keep container closed when not in use.
Store locked up.
Store in original container.
Store in corrosive resistant aluminium container with a resistant
inner liner.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients
unless noted in the table above.

Personal protective equipment

Respiratory protection

:

Use only with adequate ventilation.
Substantial amounts of mist/vapors can be controlled with
local exhaust ventilation or respiratory protection.

Hand protection

:

Rubber gloves

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

5/13

Eye protection

:

Wear splash-resistant Chemical goggles.

Skin and body protection

:

Protective footwear.

Hygiene measures

:

Handle in accordance with good industrial hygiene and safety
practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form

:

liquid

Color

:

green

Odour

:

Marine/Ozone

Odour Threshold

:

Test not applicable for this product type

pH

:

< 1

Melting point/freezing point

:

0 °C

Initial boiling point and
boiling range

:

100 °C

Flash point

:

> 100 °C
> 212 °F

Evaporation rate

:

Test not applicable for this product type

Flammability (solid, gas)

:

Does not sustain combustion.

Upper/lower flammability or
explosive limits

:

Test not applicable for this product type

Vapour pressure

:

Test not applicable for this product type

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

6/13

Vapour density

:

Test not applicable for this product type

Relative density

:

1.01 - 1.05 g/cm3

Solubility(ies)

:

soluble

Partition coefficient: n­octanol/water

:

Test not applicable for this product type

Auto-ignition temperature

:

Test not applicable for this product type

Decomposition temperature

:

Test not applicable for this product type

Viscosity, dynamic

:

400 - 700 mPa.s
at 20 °C

Viscosity, kinematic

:

Test not applicable for this product type

Oxidizing properties

:

Test not applicable for this product type

Volatile Organic
Compounds
Total VOC (wt. %)*

:

0.1 % - additional exemptions may apply
*as defined by US Federal and State Consumer Product
Regulations

Other information

:

None identified

:

10. STABILITY AND REACTIVITY

Reactivity

:

Do not mix with bleach or any other household cleaners.

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

7/13

Chemical stability

:

Stable under recommended storage conditions.

Possibility of hazardous
reactions

:

Stable under recommended storage conditions.

Conditions to avoid

:

Direct sources of heat.

Incompatible materials

:

Do not mix with bleach or any other household cleaners.

Hazardous decomposition
products

:

Thermal decomposition can lead to release of irritating gases
and vapours.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity

:

LD50 3715 mg/kg

Acute inhalation toxicity

:

LC50 > 10 mg/L

Acute dermal toxicity

:

LD50 > 5000 mg/kg

GHS Properties

Classification

Routes of entry

Acute toxicity

No classification proposed

Oral

Acute toxicity

No classification proposed

Dermal

Acute toxicity

No classification proposed

Inhalation - Dust and Mist

Acute toxicity

No classification proposed

Inhalation - Vapour

Acute toxicity

No classification proposed

Inhalation - Gas

Skin corrosion

Category 1B -

Serious eye damage

Category 1 -

Skin sensitisation

No classification proposed

-

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

8/13

Respiratory
sensitisation

No classification proposed

-

Germ cell mutagenicity

No classification proposed

-

Carcinogenicity

No classification proposed

-

Reproductive toxicity

No classification proposed

-

Specific target organ
toxicity - single
exposure

No classification proposed

-

Specific target organ
toxicity - repeated
exposure

No classification proposed

-

Aspiration hazard

No classification proposed

-

Aggravated Medical
Condition

:

Individuals with chronic respiratory disorders such as asthma,
chronic bronchitis, emphysema, etc. may be more susceptible
to irritating effects

12. ECOLOGICAL INFORMATION

Product : The product itself has not been tested.
Toxicity

The ingredients in this formula have been reviewed and no adverse impact to the environment is
expected when used according to label directions.

Toxicity to fish

Hydrochloric acid

semi­static test
LC50

Lepomis macrochirus
(Bluegill sunfish)

3.25 - 3.5
mg/l

96 h

2,2'-(octadec-9­enylimino)bisethanol

LC50
Read­across
(Analogy)

Danio rerio (zebra fish)

0.1 mg/l

96 h

Components

End point

Species

Value

Exposure
time

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

9/13

Alcohols, C13-15-branched
and linear, ethoxylated EO=8

LC50

Oncorhynchus mykiss
(rainbow trout)

> 1 - < 10
mg/l

48 h

Toxicity to aquatic invertebrates

Hydrochloric acid

static test
EC50

Daphnia magna (Water
flea)

4.92 mg/l

48 h

2,2'-(octadec-9­enylimino)bisethanol

EC50
Measured

Daphnia magna (Water
flea)

0.043 mg/l

48 h

EC10

Daphnia magna (Water
flea)

0.0107
mg/l

21 d

Alcohols, C13-15-branched
and linear, ethoxylated EO=8

EC50

Daphnia magna (Water
flea)

> 1 - < 10
mg/l

48 h

Toxicity to aquatic plants

Hydrochloric acid

static test
EC50

Chlorella vulgaris (Fresh
water algae)

4.7 mg/l

72 h

2,2'-(octadec-9­enylimino)bisethanol

Growth
inhibition
EC50

Pseudokirchneriella
subcapitata (green algae)

0.0867
mg/l

72 h
Alcohols, C13-15-branched

and linear, ethoxylated EO=8

EC50

Desmodesmus
subspicatus (green algae)

> 1 - < 10
mg/l

72 h

Components

End point

Species

Value

Exposure
time

Components

End point

Species

Value

Exposure
time

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

10/13

Persistence and degradability

Component

Biodegradation

Exposure
time

Summary

Hydrochloric acid

No data available

2,2'-(octadec-9­enylimino)bisethanol

44 %

28 d

Not readily
biodegradable.

Alcohols, C13-15-branched
and linear, ethoxylated EO=8

60 %

28 d

Readily biodegradable.

Bioaccumulative potential

Component

Bioconcentration
factor (BCF)

Partition Coefficient n­Octanol/water (log)

Hydrochloric acid

No data available

0.25

2,2'-(octadec-9­enylimino)bisethanol

No data available

3.4 Calculated

Alcohols, C13-15-branched
and linear, ethoxylated EO=8

No data available

No data available

Mobility

Component

End point

Value

Hydrochloric acid

No data available

2,2'-(octadec-9­enylimino)bisethanol

No data available

Alcohols, C13-15-branched
and linear, ethoxylated EO=8

No data available

PBT and vPvB assessment

Component

Results

Hydrochloric acid

Not fulfilling PBT and vPvB criteria

2,2'-(octadec-9­enylimino)bisethanol

Not fulfilling PBT and vPvB criteria

Alcohols, C13-15-branched
and linear, ethoxylated EO=8

Not fulfilling PBT and vPvB criteria

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

11/13

Other adverse effects

:

None known.

13. DISPOSAL CONSIDERATIONS

Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION

Please refer to the Bill of Lading/receiving documents for up-to-date shipping information.

Land transport

Sea transport

Air transport

UN number

1760

1760

1760

UN proper
shipping name

Corrosive Liquid,
N.O.S. (Hydrochloric
acid, 2,2'-(Octadec­9­enylimino)bisethanol)

Corrosive Liquid,
N.O.S. (Hydrochloric
acid, 2,2'-(Octadec-9­enylimino)bisethanol)

Corrosive Liquid, N.O.S.
(Hydrochloric acid, 2,2'­(Octadec-9­enylimino)bisethanol)

Transport hazard
class(es)

8 8 8

Packing group

II

II

II

Environmental
hazards

-

- -

Special
precautions for
user

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

Limited quantities
derogation may be
applicable to this
product, please
check transport
documents.

Limited quantities
derogation may be
applicable to this
product, please check
transport documents.

Transport in
bulk according
to Annex II of
MARPOL 73/78
and the IBC
Code

Product not
transported as bulk.

Product not
transported as bulk.

Product not transported
as bulk.

15. REGULATORY INFORMATION

Notification status

:

All ingredients of this product are listed or are excluded from
listing on the U.S. Toxic Substances Control Act (TSCA)

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

12/13

Chemical Substance Inventory.

Notification status

:

All ingredients of this product comply with the New Substances
Notification requirements under the Canadian Environmental
Protection Act (CEPA).

California Prop. 65

:

This product is not subject to the reporting requirements under
California's Proposition 65.

16. OTHER INFORMATION

HMIS Ratings

Health

3

Flammability

0

Reactivity

0

NFPA Ratings

Health

3

Fire

0

Reactivity

0

Special

-

This information is being provided in accordance with the Occupational Safety and Health
Administration (OSHA) regulation (29 CFR 1910.1200). The information supplied is designed for
workplaces where product use and frequency of exposure exceeds that established for the labeled
consumer use.

Further information

Safety Data Sheet

according to Hazard Communication Standard; 29 CFR 1910.1200

SCRUBBING BUBBLES® TOILET BOWL CLEANER- RAINSHOWER

Version 1.2

Print Date 01/02/2018

Revision Date 09/12/2017

SDS Number 350000032523
GEN_SOF Number 59840

13/13

This document has been prepared using data from sources considered to be technically reliable. It
does not constitute a warranty, expressed or implied, as to the accuracy of the information contained
herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all
available information when using product for any particular use and to comply with all Federal, State,
Provincial and Local laws and regulations.

Prepared by

SC Johnson Global Safety Assessment &
Regulatory Affairs (GSARA)