Sakrete B650980 User Manual

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SAFETY DATA SHEET
1.1 PRODUCT IDENTIFIER
Product Name:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
Sakrete NOMIX Post Set 40lb
Various.
Sakrete of North America 8201 Arrowridge Blvd. Charlotte, NC
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone Number:
Date of Preparation:
28273 866-725-7383
CHEMTREC 800-424-9300 INTERNATIONAL + 01-703-527-3887
December 21, 2012 Version #: 1.0
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL
Acute toxicity 4 (Oral) Skin irritation 2 Serious eye damage 1 Skin sensitization 1 Carcinogenicity 1A Specific target organ toxicity - Single exposure 3 Specific target organ toxicity - Repeated exposure 1
2.2 LABEL ELEMENTS
Hazard Pictogram:
Hazard class
Signal Word: Hazard Statement:
Danger Harmful if swallowed. Causes skin irritation. Causes serious eye
damage. May cause an allergic skin reaction. May ca use cancer. May cause respiratory irritation. Causes damage t o organs through
Prevention:
prolonged or repeated exposure. Do not eat, drink or smoke when using this product. Wash skin
thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and
Trade Name: Sakrete NOMIX Post Set 40lb Print date: 2014-07-17
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SAFETY DATA SHEET
understood. Wear protective gloves/protective clothing/eye protection/face protection. Use only outdoors or in a well-ventilated
Response:
area. Do not breathe dust. If swallowed: Immediately call a poison center/doctor. Rinse mouth.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. If exposed or concerned: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing.
Storage:
Disposal:
2.3 ADDITIONAL INFORMATION
Call a poison center/doctor if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container
tightly closed. Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Hazards not otherwise classified:
26 % of the mixture consists of ingredient(s) of unknown acute toxicity.
This product is a hazardous chemical as defined by NOM-018-STPS-2000.
Not applicable.
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 MIXTURES
Silica, crystalline, quartz Portland cement
Ingredient
Not available. Not available. Not available. 1/0/0
Calcium oxide UN1910 Aluminum sulfate Aluminum oxide
Not available. Not available. Not available. Not available.
The exact percentage (concentration) of chemicals has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.
* Per NOM-018-STPS-2000
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get
Skin:
medical attention immediately. In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Wash clot hing before
Inhalation:
reuse. Call a physician if irritation develops and persists. If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical advice/attention if you feel unwell.
UN # H / F/ R / *
3/0/1
CAS No Wt. %
14808-60-7 40 - 70 65997-15-1 10 - 30
1305-78-8 3 - 7
10043-01-3 1 - 5
1344-28-1 1 - 5
Trade Name: Sakrete NOMIX Post Set 40lb Print date: 2014-07-17
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SAFETY DATA SHEET
Ingestion:
If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
person. Get medical advice/attention.
Causes serious eye damage. May cause burns in the presence of moisture. Symptoms may include discomfort or pain, excess blinking
Skin:
and tear production, with possible redness and swelling. Causes skin irritation. May cause burns in the presence of moisture.
Skin contact during hydration may slowly develop sufficient heat that may cause severe burns possibly resulting in permanent injury. Do not allow product to harden around any body part or allow continuous, prolonged contact with skin. Handling can cause dry skin. May cause
Inhalation: Ingestion:
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians: Specific Treatments:
sensitization by skin contact. May cause respiratory tract irritation. Harmful if swallowed. May cause stomach distress, nausea or
vomiting.
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Section 5: FIRE-FIGHTING MEASURES
5.1 FLAMMABILITY
Flammability:
5.2 EXTINGUISHING MEDIA
Suitable Extinguishing Media: Unsuitable Extinguishing Media:
5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion:
5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Not flammable by OSHA criteria.
Treat for surrounding material. Not available.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Methods for Cleaning-Up:
Protective Equipment (PPE). Vacuum or sweep material and place in a disposal container.
Trade Name: Sakrete NOMIX Post Set 40lb Print date: 2014-07-17
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SAFETY DATA SHEET
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Good housekeeping is important to prevent accumulation of dust. Avoid generating and breathing dust. The use of compressed air for cleaning clothing, equipment, etc, is not recommended. Handle and open container with care. When using do not eat or drink. Wash
General Hygiene Advice:
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
hands before eating, drinking, or smoking. (See section 8) Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
Keep out of the reach of children. Store in dust-tight, dry, labeled containers. Keep containers closed when not in use. Avoid any dust buildup by frequent cleaning and suitable construction of the storage area. Do not store in an area equipped with emergency water sprinklers. (See section 10)
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
)/(%SiO2+2) TWA (resp))
3
)/(%SiO2+2) TWA (total))
+5) m p p c f T W A ( r e s p ) ) 0.025 mg/m³
2
Silica, crystalline, quartz
((10 mg/m ((30 mg/m
((250)/(%SiO
Portland cement 15 mg/m³ (total); 5 mg/m³ (resp) Calcium oxide 5 mg/m³ 2 mg/m3 Aluminum sulfate Not available. Not available. Aluminum oxide 15 mg/m
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASSURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection: Body Protection:
(total) TWA 5 mg/m3 (resp) 10 mg/m3
Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits.
Wear approved eye (properly fitted dust- or splash-proof chemical safety goggles) / face (face shield) protection.
Wear suitable waterproof gloves. Wear suitable waterproof protective clothing.
1 mg/m³ (no asbestos and <1%
crystalline silica, respirable fraction)
Trade Name: Sakrete NOMIX Post Set 40lb Print date: 2014-07-17
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SAFETY DATA SHEET
Respiratory Protection:
A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA’s respirator standard (29 CFR 1910.134)
General Health and Safety Measures:
and ANSI’s standard for respiratory protection (Z88.2).
Handle according to established industrial hygiene and safety practices. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Color: Odor: Odor Threshold: Physical State: pH: Melting Point/Freezing Point: Initial Boiling Point and Boiling Range: Flash Point: Evaporation Rate: Flammability: Lower Flammability/Explosive Limit: Upper Flammability/Explosive Limit: Vapor Pressure: Vapor Density: Relative Density/Specific Gravity: Solubility: Partition coefficient: n-octanol/water: Auto-ignition Temperature: Decomposition Temperature: Viscosity:
Percent Volatile, wt. %: VOC content, wt. %:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
Powder. Not available. Not available. Not available. Powder. 12 - 13 Not available. Not available. Not available. Not available. Not Flammable. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. 0%, Not applicable; 0 wt, Not applicable.
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10.2 CHEMICAL STABILITY
Stable under normal storage conditions. Keep dry in storage.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Incompatible materials. Moisture.
10.5 INCOMPATIBLE MATERIALS
None known.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon.
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure: Symptoms related to physical/chemical/toxicological characteristics:
Eye:
Skin contact, skin absorption, eye contact, inhalation, and ingestion.
Causes serious eye damage. May cause burns in the presence of moisture. Symptoms may include discomfort or pain, excess blinking and
Skin:
tear production, with possible redness and swelling. Causes skin irritation. May cause burns in the presence of moisture. Skin
contact during hydration may slowly develop sufficient heat that may cause severe burns possibly resulting in permanent injury. Do not allow product to harden around any body part or allow continuous, prolonged contact with
Ingestion:
Inhalation:
skin. Handling can cause dry skin. May cause sensitization by skin contact. Harmful if swallowed. May cause stomach distress, nausea or vomiting. May cause respiratory tract irritation.
Acute Toxicity:
Ingredient IDLH LC50 LD50
Silica, crystalline, quartz Portland cement 5000 mg/m
Ca [25 mg/m3 (cristobalite,
tridymite); 50 mg/m
3
(quartz, tripoli)]
Not available. Not available.
Calcium oxide 25 mg/m3 Not available. Oral 500 mg/kg, rat Aluminum sulfate Not available. Not available. Oral 1930 mg/kg, rat Aluminum oxide Not available. Not available. Oral >5000 mg/kg, rat
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
Not available.
621 mg/kg, rat
Ingredient
Silica, crystalline, quartz G-A2, I-1, N-1, O, CP65 Portland cement G-A4 Calcium oxide Not listed.
Not available. Oral 500 mg/kg, rat
Not available.
Chemical Listed as Carcinogen or
Potential Carcinogen
(NTP, IARC, OSHA, ACGIH, CP65)*
Trade Name: Sakrete NOMIX Post Set 40lb Print date: 2014-07-17
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SAFETY DATA SHEET
Aluminum sulfate Not listed. Aluminum oxide Not listed.
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory Sensitization: Skin Sensitization: STOT-Single Exposure: Chronic Health Effects:
Causes skin irritation. May cause burns in the presence of moisture.
Causes serious eye damage. May cause burns in the presence of moisture.
Based on available data, the classification criteria are not met. May cause an allergic skin reaction. May cause respiratory irritation. Respirable crystalline silica in the form of quartz or cristobalite
from occupational sources is listed by the International Agency for Research on Cancer (IARC) and National Toxicology Program (NTP) as a lung carcinogen. Prolonged exposure to respirable crystalline silica has been known to cause silicosis, a lung disease, which may be disabling. While there may be a factor of individual susceptibility to a given exposure to respirable silica dust, the risk of contracting silicosis and the severity of the disease is clearly related to the amount of dust
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
Fertility:
STOT-Repeated Exposure:
Aspiration Hazard:
exposure and the length of time (usually years) of exposure. May cause cancer. This product is not classified as a mutagen.
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Causes damage to organs through prolonged or repeated
exposure. Based on available data, the classification criteria are not met.
Toxicologically Synergistic Materials:
Other Information:
Not available. Not available.
Section 12: ECOLOGICAL INFORMATION
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic system s
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
and treatment plants is not considered environmentally harmful.
Not available.
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SAFETY DATA SHEET
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12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
Section 13: DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Disposal Method:
Other disposal recommendations:
Section 14: TRANSPORT INFORMATION
14.1 UN NUMBER
14.2 UN PROPER SHIPPING NAME
14.3 TRANSPORT HAZARD CLASS (ES)
14.4 PACKING GROUP
14.5 ENVIRONMENTAL HAZARDS
Not available.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
DOT NOM-004-SCT2-1994
Not regulated. Not regulated.
DOT NOM-004-SCT2-1994
Not applicable. Not applicable.
DOT NOM-004-SCT2-1994
Not applicable. Not applicable.
DOT NOM-004-SCT2-1994
Not applicable. Not applicable.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICLA
US: MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom
2012
Mexico: MSDS prepared pursuant to NOM-018-STPS-2000.
This material must be disposed of in accordance with all local, state, provincial, and federal regulations.
Not available.
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SAFETY DATA SHEET
SARA Title III
Ingredient Section 302
(EHS) TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA RQ (lbs.) Section 313
Silica, crystalline, quartz Not listed. Not listed. Not listed. Not listed. Portland cement Not listed. Not listed. Not listed. Not listed. Calcium oxide Not listed. Not listed. Not listed. Not listed. Aluminum sulfate Not listed. Not listed. 5,000 Not listed. Aluminum oxide Not listed. Not listed. Not listed. 313
California Proposition 65:
State Regulations
This product contains Crystalline Silica, Quartz and may also contain trace amounts of other chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.
Global Inventories Ingredient USA
TSCA
Silica, crystalline, quartz Yes. Portland cement Yes. Calcium oxide Yes. Aluminum sulfate Yes. Aluminum oxide Yes.
Health: Fire: Reactivity:
Health: Fire: Reactivity:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
Mexico Classification:
NFPA - National Fire Protection Association:
3 1 0
HMIS - Hazardous Materials Identification System
3*
1 0
Blue = Health Red = Flammability Yellow = Reactivity White = Special Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
CP65 California Proposition 65 OSHA (O) Occupational Safety and Health Administration.
Trade Name: Sakrete NOMIX Post Set 40lb Print date: 2014-07-17
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SAFETY DATA SHEET
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ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen.
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens.
Section 16: OTHER INFORMATION
Date of Preparation: Version: Revision Date:
December 21, 2012
1.0
July 17, 2014
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.
1
Prepared by:
Nexreg Compliance Inc. Phone: (519) 488-5126
Prepared for:
www.nexreg.com
Sakrete of North America
.
End of Safety Data Sheet
Trade Name: Sakrete NOMIX Post Set 40lb Print date: 2014-07-17
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