Sakrete B650912, B650959, B650955 User Manual

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White)

; Sakrete Non-Shrink Construction Grout; Sakrete Fast Setting Concrete

Mix;

Safety Data Sheet

according to Date of issue

Product form

:

Mixture

Product name

:

Sakrete Mortar/Stucco Mix Type S Sakrete Surface Bonding Cement Sakrete Non Sak Sakrete Stone Veneer Mortar Sakrete Mortar Mix Type N Sakrete Masonry Coating

Use of the substance/mixture

:

Various.

Emergency number

:

CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527

Acute toxicity 4 (Oral)

Skin Irritation 2

Serious Eye Damage 1

Skin Sensitization 1

Carcinogenicity 1A

Specific Target Organ Toxicity After Single Exposure 3

Specific Target Organ Toxicity After Repeated Exposure 1

Hazard pictograms (GHS-US)

:

Signal word (GHS-US)

:

Danger

Hazard statements (GHS-US)

:

Harmful if swallowed. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. May cause cancer. May cause respiratory irritation. Causes damage to through prolonged or repeated exposure.

Precautionary statements (GHS-US)

:

Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/pro outdoors or in a well advice/attention. Was irritation or rash occurs: Get medical advice/attention. several minutes. Remove contact lenses, if present and easy to do. Immediately call a poison center/doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Store locked up. Store in a well accordance with all local, regional, national and international regulations.

Other hazards not contributing to the

:

Not applicable.

Sakrete Stone Veneer Mortar; Sakrete Mortar Mix Type N; Sakrete Masonry Coating

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.3. Details of the supplier of the safety data sheet

Sakrete of North America 8201 Arrowridge Blvd. 28273 Charlotte, NC - USA T 866-725-7383

1.4. Emergency telephone number

the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.

: 01/20/2014 Revision date: 01/20/2014 Version: 1.0

-Shrink Construction Grout

rete Fast Setting Concrete Mix

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture GHS-US classification

2.2. Label elements GHS-US labelling

-3887 24 hr

lungs

tective clothing/eye protection/face protection. Use only

-ventilated area. Do not breathe dust. If exposed or concerned: Get medical

If swallowed: Immediately call a poison center/doctor. Rinse mouth. If on skin:

h with plenty of water. Take off contaminated clothing and wash it before reuse. If skin

If in eyes: Rinse cautiously with water for

Continue rinsing.

2.3. Other hazards

classification

01/20/2014 EN (English)

-ventilated place. Keep container tightly closed. Dispose of contents and container in

Page 1

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakret

e Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix; Sakrete Stone Veneer

Mortar; Sakrete Mortar Mix Type N;

Safety Data Sheet

according to

Sakrete Masonry Coating: 34% of the mixture consists of ingredient(s) of unknown acute toxicity.

Sakrete Mortar Mix Type N: 13% of the mixture consists of ingredient(s) of unknown acute toxicity.

Name

Product identifier

%

GHS-US classification

Quartz

(CAS No) 14808-60-7

30 - 85

Acute Tox. 4 (Oral), H302 STOT RE 1, H372

Cement, portland, chemicals

65997-15-1

5 - 55

Skin Irrit. 2, H315

STOT SE 3, H335

Limestone

(CAS No) 1317-65-3

0.5 - 17

Not classified

Calcium magnesium hydroxide (CaMg(OH)4)

39445-23-3

1 - 51

Skin Irrit. 2, H315 STOT SE 3, H335

Calcium magnesium hydroxide oxide (CaMg(OH)2O)

58398-71-3

1 - 51

Not classified

Gypsum (Ca(SO4).2H2O)

(CAS No) 13397-24-5

0.5 - 5

Not classified

Calcium hydroxide

1305-62-0

0.5 - 51

Skin Corr. 1B, H314 Eye Dam. 1, H318

Calcium sulfate

(CAS No) 7778-18-9

0.5 - 5

Not classified

Calcium oxide

1305-78-8

0.5 - 2

Acute Tox. 4 (Oral), H302

STOT SE 3, H335

Cement, alumina, chemicals

(CAS No) 65997-16-2

1 - 52

Skin Irrit. 2, H315 Eye Dam. 1, H318

1

Sakrete Mortar/Stu c co Mix Type S (White); Sakrete Masonry Coating

The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.

First-aid measures after inhalation

:

If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

First-aid measures after skin contact

:

In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation d

First-aid measures after eye contact

:

In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately.

First-aid measures after ingestion

:

If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Immediately call a POISON CENTER or doctor/physician.

Symptoms/injuries after inhalation

:

May cause respiratory tract irritation.

Symptoms/injuries after skin contact

:

Causes skin irritation. May cause burns in the presence of moisture. Skin contact during hydration may slowly develop su permanent injury. prolonged contact with skin. contact.

Symptoms/injuries after eye contact

:

Causes serious eye damage. May cause burns in the presence of moisture. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling.

Symptoms/injuries after ingestion

:

Harmful if swallowed. May cause stomach distress, nausea or vomiting.

Sakrete Masonry Coating

2.4. Unknown acute toxicity (GHS US)

Sakrete Surface Bonding Cement (Gray/White): 25% of the mixture consists of ingredient(s) of unknown acute toxicity. Sakrete Non-Shrink Construction Grout: 24% of the mixture consists of ingredient(s) of unknown acute toxicity. Sakrete Stone Veneer Mortar: 18% of the mixture consists of ingredient(s) of unknown acute toxicity. Sakrete Mortar-Stucco Mix Type S (Gray): 14% of the mixture consists of ingredient(s) of unknown acute toxicity. Sakrete Mortar-Stucco Mix Type S (White): 12% of the mixture consists of ingredient(s) of unknown acute toxicity.

SECTION 3: Composition/information on ingredients

3.1. Substances

Not applicable.

3.2. Mixture

the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.

Carc. 1A, H350

(CAS No)

2

Sakrete Fast Setting Concrete Mix; Sakrete Non-Shrink Construction Grout

SECTION 4: First aid measures

4.1. Description of first aid measures

Eye Dam. 1, H318 Skin Sens. 1, H317

Eye Dam. 1, H318

Skin Irrit. 2, H315 Eye Dam. 1, H318

Get medical advice/attention if you feel unwell.

evelops and persists.

4.2. Most important symptoms and effects, both acute and delayed

fficient heat that may cause severe burns possibly resulting in

Do not allow product to harden around any body part or allow continuous,

Handling can cause dry skin. May cause sensitization by skin

4.3. Indication of any immediate medical attention and special treatment needed

Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible).

01/20/2014 EN (English)

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Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakret

e Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix; Sakrete Stone Veneer

Mortar; Sakrete Mortar Mix Type N;

Safety Data Sheet

according to

Suitable extinguishing media

:

Treat for surrounding material.

Unsuitable extinguishing media

:

Not available.

Fire hazard

:

Products of combustion may include, and are not limited to: oxides of carbon.

Firefighting instructions

:

Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).

General measures

:

Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.

For containment

:

Contain spill, then place in a suitable container. Do not flush to sewer or allow to enter waterways.

Methods for cleaning up

:

Vacuum or sweep material and place in a disposal container.

Precautions for safe handling

:

Avoid contact with skin and eyes. Avoid generating and breathing dust. Do not swallow. Good housekeeping is important to prevent accumulation of dust. The use of compressed air for cleaning clothing, equipment, etc, is not recommend When using do not eat, drink or smoke.

Hygiene measures

:

Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.

Storage conditions

:

Keep out of the reach of children. Store in dust-tight, dry, labelled containers. Keep container tightly closed when not in use. Avoid any dust buildup by frequent cleaning and suitable construction of the storage area. Do not stor sprinklers.

Quartz (14808-60-7)

USA ACGIH

ACGIH TWA (mg/m³)

0.025 mg/m³

USA OSHA

OSHA PEL (TWA) (mg/m3)

(30)/(%SiO2 + 2) mg/m3 TWA, total du st (10)/(%SiO2 + 2) mg/m3 TWA, respirable fraction

Cement, portland, chemicals (65997-15-1)

USA ACGIH

ACGIH TWA (mg/m³)

1 mg/m³

USA OSHA

OSHA PEL (TWA) (mg/m3)

5 mg/m³

Calcium sulfate (7778-18-9)

USA ACGIH

ACGIH TWA (mg/m³)

10 mg/m³

USA OSHA

OSHA PEL (TWA) (mg/m³)

5 mg/m³

Gypsum (Ca(SO4).2H2O) (13397-24-5)

USA ACGIH

ACGIH TWA (mg/m³)

10 mg/m³

USA OSHA

OSHA PEL (TWA) (mg/m³)

5 mg/m³

Limestone (1317-65-3)

USA ACGIH

ACGIH TWA (mg/m³)

10 mg/m³

Sakrete Masonry Coating

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.

6.2. Methods and material for containment and cleaning up

Use appropriate Personal Protective E quipment (PPE ).

6.3. Reference to other sections

No additional information available.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

No additional information available.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

ed. Handle and open container with care.

e in an area equipped with emergency water

(250)/(%SiO2 + 5) mppcf TWA, respirable fraction

01/20/2014 EN (English)

3/7

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakret

e Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix; Sakrete Stone Veneer

Mortar; Sakrete Mortar Mix Type N;

Safety Data Sheet

according to

Limestone (1317-65-3)

USA OSHA

OSHA PEL (TWA) (mg/m3)

5 mg/m³

Calcium oxide (1305-78-8)

USA ACGIH

ACGIH TWA (mg/m³)

2 mg/m³

USA OSHA

OSHA PEL (TWA) (mg/m3)

5 mg/m³

Calcium hydroxide (1305-62-0)

USA ACGIH

ACGIH TWA (mg/m³)

5 mg/m³

USA OSHA

OSHA PEL (TWA) (mg/m³)

5 mg/m³

Appropriate engineering controls

:

Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits.

Hand protection

:

Wear suitable waterproof gloves.

Eye protection

:

Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and face protection (face shield).

Skin and body protection

:

Wear suitable waterproof protective clothing.

Respiratory protection

:

A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a t OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection (Z88.2).

Other information

:

Handle according to established industrial hygiene and safety practices. Do not eat, smoke or drink where material is handled, processed or stored. smoking.

Physical state

:

Solid

Appearance

:

Powder.

Colour

:

Various.

Odour

:

Characteristic.

Odour threshold

:

No data available.

pH : 10 - 12

Relative evaporation rate (butylacetate=1)

:

No data available.

Melting point

:

No data available.

Freezing point

:

No data available.

Boiling point

:

No data available.

Flash point

:

No data available.

Self ignition temperature

:

No data available.

Decomposition temperature

:

No data available.

Flammability (solid, gas)

:

Not Flammable.

Vapour pressure

:

No data available.

Relative vapour density at 20 °C

:

No data available.

Relative density

:

No data available.

Solubility

:

No data available.

Log Pow

:

No data available.

Log Kow

:

No data available.

Viscosity, kinematic

:

No data available.

Viscosity, dynamic

:

No data available.

Explosive properties

:

No data available.

Oxidising properties

:

No data available.

Explosive limits

:

No data available.

VOC content

:

0%, Not applicable; 0 wt, Not applicable.

Sakrete Masonry Coating

8.2. Exposure controls

the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.

rained health and safety professional following requirements found in

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Wash hands carefully before eating or

9.2. Other information

01/20/2014 EN (English)

4/7

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakret

e Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix; Sakrete Stone Veneer

Mortar; Sakrete Mortar Mix Type N;

Safety Data Sheet

according to

Acute toxicity

:

Harmful if swallowed.

Quartz (14808-60-7)

LD50 oral rat

500 mg/kg

Calcium sulfate (7778-18-9)

LD50 oral rat

> 3000 mg/kg

Calcium oxide (1305-78-8)

LD50 oral rat

500 mg/kg

Calcium hydroxide (1305-62-0)

LD50 oral rat

7340 mg/kg

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakrete Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix ; Sakrete Stone Veneer Mortar; Sakrete Mortar Mix Type N; Sakrete Masonry Coating

ATE (oral)

520 - 880 mg/kg, rat

ATE (dermal)

No data available.

ATE (inhalation)

No data available.

Skin corrosion/irritation

:

Causes skin irritation.

Serious eye damage/irritation

:

Causes serious eye damage.

Respiratory or skin sensitisation

:

May cause an allergic skin reaction.

Germ cell mutagenicity

:

Based on available data, the classification criteria are not met.

Carcinogenicity

:

May cause cancer.

Quartz (14808-60-7)

IARC group

1

National Toxicity Program (NTP) Status

2

Reproductive toxicity

:

Based on available data, the classification criteria are not met.

Specific target organ toxicity (single exposure)

:

May cause respiratory irritation.

Specific target organ toxicity (repeated

:

Causes damage to lungs through prolonged or repeated exposure. (Respirable crystalline silic a in the form of quartz or cristobalite from oc Agency for Research on Cancer (IARC) and National Toxicology Program (NTP) as a lung carcinogen. Prolonged exposure to respirable crystalline silica has been known to cause silicosis, a lung disease, which susceptibility to a given exposure to respirable silica dust, the risk of contracting silicosis and the severity of the disease is clearly related to the amount of dust exposure and the length of (usually years) of exposure.)

Aspiration hazard

:

Based on available data, the classification criteria are not met.

Symptoms/injuries after inhalation

:

May cause respiratory tract irritation.

Symptoms/injuries after skin contact

:

Causes skin irritation. May cause burns in the presence of moisture. Skin contact during hydration may slowly develop sufficient heat that may cause severe burns possibly resulting in permanent injury. Do not allow product to harden around any body part or allow con prolonged contact with skin. Handling can cause dry skin. May cause sensiti contact.

Sakrete Masonry Coating

SECTION 10: Stability and reactivity

10.1. Reactivity

No dangerous reaction known under conditions of normal use.

10.2. Chemical stability

Stable under normal storage conditions. Keep dry in storage.

10.3. Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use.

10.4. Conditions to avoid

Incompatible materials. Moisture.

10.5. Incompatible ma terials

Wet cement is alkaline and incompatible with acid, ammonium salts and aluminum metal.

10.6. Hazardous decomposition products

May include, and are not limited to: oxides of carbon.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.

exposure)

cupational sources is listed by the International

may be disabling. While there may be a factor of individual

01/20/2014 EN (English)

zation by skin

time

tinuous,

5/7

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakret

e Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix; Sakrete Stone Veneer

Mortar; Sakrete Mortar Mix Type N;

Safety Data Sheet

according to

Symptoms/injuries after eye contact

:

Causes serious eye damage. May cause burns in the presence of moisture. Symptoms may include discomfort or pa swelling.

Symptoms/injuries after ingestion

:

Harmful if swallowed. May cause stomach distress, nausea or vomiting.

Other information

:

Likely routes of exposure: ingestion, inhalation, skin and eye.

Ecology - general

:

No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic systems and treatment plants is not considered en

Calcium sulfate (7778-18-9)

LC50 fishes 1

2980 mg/l (96 h: Lepomis macrochirus [static])

LC50 fish 2

> 1970 mg/l (96 h: Pimephales promelas [static])

Calcium oxide (1305-78-8)

LC50 fishes 1

1070 mg/l (96 h: Cyprinus carpio [static])

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakrete Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix ; Sakrete Stone Veneer Mortar; Sakrete Mortar Mix Type N; Sakrete Masonry Coating

Persistence and degradability

No data available.

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakrete Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix ; Sakrete Stone Veneer Mortar; Sakrete Mortar Mix Type N; Sakrete Masonry Coating

Bioaccumulative potential

No data available.

Calcium oxide (1305-78-8)

BCF fish 1

(no bioaccumulation)

Calcium hydroxide (1305-62-0)

BCF fish 1

(no bioaccumulation)

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakrete Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix ; Sakrete Stone Veneer Mortar; Sakrete Mortar Mix Type N; Sakrete Masonry Coating

Ecology - soil

No data available.

Other adverse effects

:

No data available.

Waste disposal recommendations

:

This material must be disposed of in accordance with all local, state, provincial, and federal regulations.

Other information

:

No supplementary information available.

Sakrete Masonry Coating

the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.

SECTION 12: Ecological information

12.1. Toxicity

12.2. Persistence and degradability

12.3. Bioaccumulative potential

in, excess blinking and tear production, with possible redness and

vironmentally harmful.

12.4. Mobility in soil

12.5. Other adverse effects

SECTION 13: Disposal considerations

13.1. Waste treatment methods

SECTION 14: Transport information

In accordance with DOT.

14.1. UN number

Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Additional information

01/20/2014 EN (English)

6/7

Sakrete Mortar/Stucco Mix Type S (Gray/White); Sakrete Surface Bonding Cement (Gray/White); Sakret

e Non-Shrink Construction Grout; Sakrete Fast Setting Concrete Mix; Sakrete Stone Veneer

Mortar; Sakrete Mortar Mix Type N;

Safety Data Sheet

according to

Quartz (14808-60-7)