Page 1
Sakrete Paver Set Polymeric Sand; Sakrete
PermaSand PolymerJointing Sand
Safety Data Sheet
according to
Date of issue
Product form
:
Mixture
Product name
:
Sakrete Paver Set Polymeric Sand
Sakrete PermaSand Polymer Jointing Sand
Use of the substance/mixture
:
Various.
Emergency number
:
CHEMTREC (800) 424-9300
CHEMTREC International +1 (703) 527
Acute toxicity 4 (Oral)
Serious Eye Irritation 2A
Skin Sensitization 1
Carcinogenicity 1A
Specific Target Organ Toxicity After Repeated Exposure 1
Hazard pictograms (GHS-US)
:
Signal word (GHS-US)
:
Danger
Hazard statements (GHS-US)
:
Harmful if swallowed. Causes serious eye irritation. May caus e an allergic skin reacti on . May
cause cancer
Precautionary statements (GHS-US)
:
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood
Do not eat, drink or
smoke when using this product
workplace
swallowed: I
water
advice/attent
lenses, if present and easy to do. Continue rinsing
advice/attention
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Other hazards not contributing to the
:
Not applicable.
Sakrete Paver Set Polymeric Sand: 4% of the mixture consists of ingredient(s) of unknown acute toxicity.
Sakrete PermaSand Polymer Jointing Sand: 2% of the mixture consists of ingredient(s) of unknown acute toxicity.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Sakrete of North America
8201 Arrowridge Blvd.
28273 Charlotte, NC - USA
T 866-725-7383
1.4. Emergency telephone number
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
: 02/14/2014 Revision date: 02/14/2014 Version: 1.0
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture GHS-US classification
2.2. Label elements GHS-US labelling
-3887 24 hr
. Causes damage to lungs through prolonged or repeated exposure.
. Do not breathe dust. Wash hands thoroughly after handling.
. Contaminated work clothing must not be allowed out of the
. Wear protective gloves/protective clothing/eye protection/fac e protecti on. If
mmediately call a poison center/doctor. Rinse mouth. If on sk in: Wash with plenty
. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical
ion. If in eyes: Rinse cautiously with water for several minutes. Remove contact
. If eye irritation persists: Get medical
. If exposed or concerned: Get medical advice/attention. Store locked up.
2.3. Other hazards
classification
2.4. Unknown acute toxicity (GHS-US)
02/14/2014 EN (English)
Page 1
Page 2
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand
PolymerJointing Sand
Safety
according to
Name
Product identifier
%
GHS-US classification
Quartz
(CAS No) 14808-60-7
60 - 100
Acute Tox. 4 (Oral)
STOT RE 1
Cement, portland, chemicals
(CAS No) 65997-15-1
0.5 - 2
Skin Irrit. 2
STOT SE 3
The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.
First-aid measures aft er inhalat i on
:
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact
:
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing
and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists.
First-aid measures after eye contact
:
In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. If
irritation persists, get medical attention.
First-aid measures after ingestion
:
If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious per
doctor/physician.
Symptoms/injuries after inhalation
:
May cause respiratory tract irritation.
Symptoms/injuries after skin contact
:
May cause skin irritation. May cause burns in the presence of moisture. Skin contact during
hydration may slowly develop sufficient heat that may cause severe burns possibly
permanent injury.
prolonged contact with skin. Handling can cause dry skin. May cause sensitisation by skin
contact.
Symptoms/injuries after eye contact
:
Causes serious eye irritation. May cause burns in the presence of moisture. Symptoms may
include discomfort o
swelling.
Symptoms/injuries after ingestion
:
Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Suitable extinguishing media
:
Treat for surrounding material.
Unsuitable extinguishing media
:
Not available.
Fire hazard
:
Products of combustion may include, and are not limited to: oxides of carbon.
Firefighting instructions
:
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
General measures
:
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For containment
:
Contain spill, then place in a suitable container. Do not flush to sewer or allow to enter
waterways.
Methods for cleaning up
:
Vacuum or sweep material and place in a disposal container.
Data Sheet
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
SECTION 4: First aid measures
4.1. Description of first aid measures
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
Carc. 1A
Eye Dam. 1
Skin Sens. 1
4.2. Most important symptoms and effects, both acute and delayed
resulting in
Do not allow product to harden around any body part or allow continuous,
r pain, excess blinking and tear production, with possible redness and
son. Immediately call a POISON CENTER or
4.3. Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Methods and material for containment and cleaning up
Use appropriate Personal Protective Equipment (PPE).
6.3. Reference to other sections
No additional information available.
02/14/2014 EN (English)
2/6
Page 3
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand
PolymerJointing Sand
Safety
according to
Precautions for safe handling
:
Do not swallow. Avoid contact with skin and eyes. Good housekeeping is important to prevent
accumulation of dust. Avoi
cleaning clothing, equipment, etc, is not recommended. Handle and open container with care.
When using do not eat, drink or smoke.
Hygiene measures
:
Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Storage conditions
:
Keep out of the reach of children. Store in dust-tight, dry, labelled containers. Keep container
tightly closed when
construction of the storage area. Do not store in an area equipped with emergency water
sprinklers.
Quartz (14808-60-7)
USA ACGIH
ACGIH TWA (mg/m³)
0.025 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m3)
(30)/(%SiO2 + 2) mg/m3 TWA, total du st
(10)/(%SiO2 + 2) mg/m3 TWA, respirable fraction
Cement, portland, chemicals (65997-15-1)
USA ACGIH
ACGIH TWA (mg/m³)
1 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m³)
5 mg/m³
Appropriate engineering controls
:
Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits.
Hand protection
:
Wear suitable waterproof gloves.
Eye protection
:
Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and
face protecti
Skin and body protection
:
Wear suitable waterproof protective clothing.
Respiratory protection
:
A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areas or
when permissible exposure limits may be exceeded. Respirators should be selected by and used
under the direction of a trained health and safety professional following requirements found in
OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection
(Z88.2).
Other information
:
Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully
before eating or smoking. Handle according to established industrial hygiene and safety
practices.
Physical state
:
Solid.
Appearance
:
Powder.
Colour
:
Various.
Odour
:
Characteristic.
Odour threshold
:
No data available.
pH : 12 – 13
Relative evaporation rate (butylacetate=1)
:
No data available.
Melting point
:
No data available.
Freezing point
:
No data available.
Boiling point
:
No data available.
Flash point
:
No data available.
Self ignition temperature
:
No data available.
Decomposition temperature
:
No data available.
Flammability (solid, gas)
:
Not flammable.
Vapour pressure
:
No data available.
Data Sheet
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
d generating and breathing dust. The use of compressed air for
not in use. Avoid any dust buildup by frequent cleaning and suitable
7.3. Specific end use(s)
No additional information available.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
8.2. Exposure controls
on (face shield).
(250)/(%SiO2 + 5) mppcf TWA, respirable fraction
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
02/14/2014 EN (English)
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Page 4
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand
PolymerJointing Sand
Safety
according to
Relative vapour density at 20 °C
:
No data available.
Relative density
:
No data available.
Solubility
:
No data available.
Log Pow
:
No data available.
Log Kow
:
No data available.
Viscosity, kinematic
:
No data available.
Viscosity, dynamic
:
No data available.
Explosive properties
:
No data available.
Oxidising properties
:
No data available.
Explosive limits
:
No data available.
VOC content
:
0%, Not applicable; 0 wt, Not applicable.
Acute toxicity
:
Harmful if swallowed.
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand PolymerJointing Sand
LD50 oral rat
510 - 525 mg/kg
LD50 dermal rabbit
No data available.
LC50 inhalation rat (mg/l)
No data available.
Quartz (14808-60-7)
LD50 oral rat
500 mg/kg
Skin corrosion/irritation
:
Based on available data, the classification criteria are not met.
Serious eye damage/irritation
:
Causes serious eye irritation.
Respiratory or skin sensitisation
:
May cause an allergic skin reaction.
Germ cell mutagenicity
:
Based on available data, the classification criteria are not met.
Carcinogenicity
:
May cause cancer.
Quartz (14808-60-7)
IARC group
1
National Toxicity Program (NTP) Status
2
Reproductive toxicity
:
Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure)
:
Based on available data, the classification criteria are not met.
Specific target organ toxicity (repeated
:
Causes damage to lungs through prolonged or repeated exposure. (Respirable crystal line sil ic a
in the form of quartz or cristobalite from occupational sources is listed by the International
Agency for Research on Cancer (IARC) and National Toxicology Program (NTP) as a lung
carcinogen. Prolonged exposure to res
silicosis, a lung disease, which may be disabling. While there may be a factor of individual
susceptibility to a given exposure to respirable silica dust, the risk of contracting silicosis and the
severity
(usually years) of exposure.)
Data Sheet
9.2. Other information
SECTION 10: Stability and reactivity
10.1. Reactivity
No dangerous reaction known under conditions of normal use.
10.2. Chemical stability
Stable under normal storage conditions. Keep dry in storage.
10.3. Possibility of hazardous reactions
No dangerous reaction known under conditions of normal use.
10.4. Conditions to avoid
Incompatible materials. Moisture.
10.5. Incompatible ma terials
Wet cement is alkaline and incompatible with acid, ammonium salts and aluminum metal.
10.6. Hazardous decomposition products
May include, and are not limited to: oxides of carbon.
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
exposure)
pirable crystalline silica has been known to cause
02/14/2014 EN (English)
of the disease is clearly related to the amount of dust exposure and the length of time
4/6
Page 5
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand
PolymerJointing Sand
Safety
according to
Aspiration hazard
:
Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation
:
May cause respiratory tract irritat i on.
Symptoms/injuries after skin contact
:
May cause skin irritation. May cause burns in the presence of moisture. Skin contact during
hydration may slowly develop sufficient heat that may cause severe burns possibly
permanent injury.
prolonged contact with skin.
contact.
Symptoms/injuries after eye contact
:
Causes serious eye irritation. May cause burns in the presence of moisture. Symptoms may
include discomfort or pain, excess blinking and tear production, with possible redness and
swelling.
Symptoms/injuries after ingestion
:
Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Other information
:
Likely routes of exposure: ingestion, inhalation, skin and eye.
Ecology - general
:
No ecological consideration when used according to directions. Normal dilution of this product to
drains, sewers, septic systems and treatment plants is not considered environmentally harmful.
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand PolymerJointing Sand
Persistence and degradability
No data available.
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand PolymerJointing Sand
Bioaccumulative potential
No data available.
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand PolymerJointing Sand
Ecology - soil
No data available.
Other adverse effects
:
No data available.
Waste disposal recommendations
:
This material must be disposed of in accordance with all local, state, provincial, and federal
regulations.
Other information
:
No supplementary information available.
Special transport precautions
:
Do not handle until all safety precautions have been read and understood.
Quartz (14808-60-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Cement, portland, chemicals (65997-15-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand PolymerJointing Sand
State or local regulations
This product contains Crystalline Silica, Quartz and may also contain other chemicals
known to the State of California to cause cancer, birth defects or other reproductive harm.
Data Sheet
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Other adverse effects
Do not allow product to harden around any body part or allow continuous,
resulting in
Handling can cause dry skin. May cause sensitisation by skin
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SECTION 14: Transport information
In accordance with DOT
14.1. UN number
Not applicable
14.2. UN proper shipping name
Not applicable
14.3. Additional information
SECTION 15: Regulatory information
15.1. US Federal regulations
15.2. US State regulations
02/14/2014 EN (English)
5/6
Page 6
Sakrete Paver Set Polymeric Sand; Sakrete PermaSand
PolymerJointing Sand
Safety
according to
IARC (I)
International Agency for Research on Cancer.
1 - Carcinogenic to humans;
4 - Probably not carcinogenic to humans.
NTP (N)
National Toxicology Program.
1 - Evidence of Carcinogenicity;
5 - Twelfth Report - Items under consideration.
Indication of changes
:
None.
Other information
:
None.
NFPA health hazard
:
2 - Intense or continued exposure could cause
temporary incapacitation or possible residual injury
unless prompt medical attention is given.
NFPA fire hazard
:
0 - Materials that will not burn.
NFPA reactivity
:
0 - Normally stable, even under fire exposure
conditions, and are not reactive with water.
Data Sheet
SOURCE AGENCY CARCINOGEN CLASSIFIC ATIONS:
SECTION 16: Other information
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
2A - Probably carcinogenic to humans;
2B - Possibly carcinogenic to humans;
3 - Not classifiable;
2 - Known Human Carcinogens;
3 - Reasonably anticipated to be Human Carcinogen;
4 - Substances delisted from report on Carcinogens;
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product
02/14/2014 EN (English)
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