Page 1
Conforms to OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
SAFETY DATA SHEET
Section 1: IDENTIFICATION
1.1 PRODUCT IDENTIFIER
Product Name:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
Sakrete High Strength Concrete Mix
Various.
Sakrete of North America
8201 Arrowridge Blvd.
Charlotte, NC
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone
Number:
Date of Preparation:
28273
866-725-7383
CHEMTREC 800-424-9300
INTERNATIONAL + 01-703-527-3887
July 19, 2013 Version #: 1.0
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL ACCORDING TO OSHA HAZCOM 2012
Acute toxicity 4 (Oral)
Skin irritation 2
Serious eye damage 1
Skin sensitization 1
Carcinogenicity 1A
Specific target organ toxicity - Repeated exposure 1
2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012
Hazard Pictogram:
Hazard class
Signal Word:
Hazard Statement:
Danger
Harmful if swallowed. Causes skin irritation. Causes serious eye
damage. May cause an allergic skin reaction. May ca use cancer.
Prevention:
Causes damage to lungs through prolonged or repeated exposure.
Do not eat, drink or smoke when using this product. Wash hands
thoroughly after handling. Contaminated work clothing must not be
allowed out of the workplace. Obtain special instructions before
use. Do not handle until all safety precautions have been read and
understood. Wear protective gloves/protective clothing/eye
protection/face protection. Use only outdoors or in a well-ventilated
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
area. Do not breathe dust.
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SAFETY DATA SHEET
Response:
If swallowed: Immediately call a poison center/doctor. Rinse mouth.
If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor. If on skin: Wash with plenty
of water. Take off contaminated clothing and wash it before reuse. If
skin irritation or rash occurs: Get medical advice/attention. If
Storage:
Disposal:
2.3 ADDITIONAL INFORMATION
Hazards not otherwise classified:
8 % of the mixture consists of ingredient(s) of unknown acute toxicity.
This product is a hazardous chemical as defined by NOM-018-STPS-2000.
Mexico Classification:
exposed or concerned: Get medical advice/attention.
Store locked up.
Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Not applicable.
Blue = Health Red = Flammability Yellow = Reactivity White = Special
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
WHMIS Classification(s):
Class D2A - Carcinogenicity
Class D2A - Chronic Toxic Effect s
Class E - Corrosive Material
WHMIS Hazard Symbols:
WHMIS Signal Word:
DANGER
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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SAFETY DATA SHEET
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 MIXTURES
Ingredient
UN # H / F/ R / *
Silica, crystalline, quartz Not available. 2/0/0 14808-60-7 60 - 100
Portland cement Not available. 2/0/0 65997-15-1 7 - 13
Ashes (residues) Not available. Not available. 68131-74-8 1 - 5
Ferric oxide Not available. 1/0/0 1309-37-1 1 - 5
Calcium carbonate Not available. 1/0/0 1317-65-3 0.1 - 1
The exact percentage (concentration) of chemicals has been withheld as a trade secret in accordance
with paragraph (i) of §1910.1200.
* Per NOM-018-STPS-2000
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. If easy to do, remove contact lenses, if worn. Get
Skin:
medical attention immediately.
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Wash clot hing before
Inhalation:
reuse. Call a physician if irritation develops and persists.
If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical advice/attention if
Ingestion:
you feel unwell.
If swallowed, do NOT induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
person. Get medical advice/attention.
Causes serious eye damage. May cause burns in the presence of
moisture. Symptoms may include discomfort or pain, excess blinking
Skin:
and tear production, with possible redness and swelling.
Causes skin irritation. May cause burns in the presence of moisture.
Skin contact during hydration may slowly develop sufficient heat that
may cause severe burns possibly resulting in permanent injury. Do not
allow product to harden around any body part or allow continuous,
prolonged contact with skin. Handling can cause dry skin. May cause
Inhalation:
Ingestion:
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians:
Specific Treatments:
sensitization by skin contact.
May cause respiratory tract irritation.
Harmful if swallowed. May cause stomach distress, nausea or
vomiting.
Symptoms may not appear immediately.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
CAS No Wt. %
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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Page 4
SAFETY DATA SHEET
Conforms to OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
Section 5: FIRE-FIGHTING MEASURES
5.1 FLAMMABILITY
Flammability:
5.2 EXTINGUISHING MEDIA
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion:
Explosion Data:
Sensitivity to Mechanical Impact: Not available.
Sensitivity to Static Discharge: Not available.
5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Not flammable by WHMIS/OSHA criteria.
Treat for surrounding material.
Not available.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection
(SCBA).
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to
sewer or allow to enter waterways. Use appropriate Personal
Methods for Cleaning-Up:
Protective Equipment (PPE).
Vacuum or sweep material and place in a disposal container.
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Good
housekeeping is important to prevent accumulation of dust. Avoid
generating and breathing dust. The use of compressed air for
cleaning clothing, equipment, etc, is not recommended. Handle and
open container with care. When using do not eat or drink. Wash
General Hygiene Advice:
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
hands before eating, drinking, or smoking. (See section 8)
Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
Keep out of the reach of children. Store in dust-tight, dry, labeled
containers. Keep containers closed when not in use. Avoid any dust
buildup by frequent cleaning and suitable construction of the storage
area. Do not store in an area equipped with emergency water
sprinklers. (See section 10)
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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SAFETY DATA SHEET
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
)/(%SiO2+2) TWA (resp));
3
)/(%SiO2+2) TWA (total));
+5) mppcf TWA (resp)) 0.025 mg/m³
2
Silica, crystalline, quartz
((10 mg/m
((30 mg/m
((250)/(%SiO
Portland cement 15 mg/m³ (total); 5 mg/m³ (resp)
Ashes (residues) Not available. Not available.
Ferric oxide 10 mg/m3
Calcium carbonate 15 mg/m³ (total); 5 mg/m³ (resp) 10 mg/m³
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection:
Body Protection:
Respiratory Protection:
Use ventilation adequate to keep exposures (airborne levels of dust,
fume, vapor, etc.) below recommended exposure limits.
Wear approved eye (properly fitted dust- or splash-proof chemical safety
goggles) / face (face shield) protection.
Wear suitable waterproof gloves.
Wear suitable waterproof protective clothing.
A NIOSH approved dust mask or filtering facepiece is recommended in
poorly ventilated areas or when permissible exposure limits may be
exceeded. Respirators should be selected by and used under the
direction of a trained health and safety professional following
requirements found in OSHA’s respirator standard (29 CFR 1910.134)
General Health and Safety
Measures:
and ANSI’s standard for respiratory protection (Z88.2).
Handle according to established industrial hygiene and safety
practices. Do not eat, smoke or drink where material is handled,
processed or stored. Wash hands carefully before eating or smoking.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Color:
Odor:
Odor Threshold:
Physical State:
Powder.
Various.
Characteristic.
Not available.
Solid.
1 mg/m³ (no asbestos and
<1% crystalline silica,
respirable fraction)
5 mg/m
(iron oxide fume;
dust as Fe)
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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Page 6
SAFETY DATA SHEET
Conforms to OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
pH:
Melting Point/Freezing Point:
Initial Boiling Point and Boiling Range:
Flash Point:
Evaporation Rate:
Flammability:
Lower Flammability/Explosive Limit:
Upper Flammability/Explosive Limit:
Vapor Pressure:
Vapor Density:
Relative Density/Specific Gravity:
Solubility:
Partition coefficient: n-octanol/water:
Auto-ignition Temperature:
Decomposition Temperature:
Viscosity:
Oxidizing Properties:
Explosive Properties:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
10.2 CHEMICAL STABILITY
Stable under normal storage conditions. Keep dry in storage.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Incompatible materials. Moisture.
10.5 INCOMPATIBLE MATERIALS
Wet cement is alkaline and incompatible with acid, ammonium salts and aluminum metal.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon.
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure:
Skin contact, skin absorption, eye contact, inhalation, and ingestion.
12 - 13
Not available.
Not available.
Not available.
Not available.
Not Flammable.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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SAFETY DATA SHEET
Symptoms related to physical/chemical/toxicological characteristics:
Eye:
Causes serious eye damage. May cause burns in the presence of
moisture. Symptoms may include discomfort or pain, excess blinking and
Skin:
tear production, with possible redness and swelling.
Causes skin irritation. May cause burns in the presence of moisture. Skin
contact during hydration may slowly develop sufficient heat that may cause
severe burns possibly resulting in permanent injury. Do not allow product to
harden around any body part or allow continuous, prolonged contact with
Acute Toxicity:
Ingestion:
Inhalation:
Ingredient IDLH LC50 LD50
skin. Handling can cause dry skin. May cause sensitization by skin contact.
Harmful if swallowed. May cause stomach distress, nausea or vomiting.
May cause respiratory tract irritation.
Silica, crystalline, quartz Not available. Not available. Oral 500 mg/kg, rat
Portland cement Not available. Not available. Not available.
Ashes (residues) Not available. Not available. Oral >2000 mg/kg, rat
Ferric oxide Not available. Not available. Oral >10000 mg/kg, rat
Calcium carbonate Not available. Not available. Oral 6450 mg/kg, rat
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
Not available. 525 mg/kg, rat Not available.
Ingredient
Silica, crystalline, quartz G-A2, I-1, N-1, O, CP65
Portland cement G-A4
Ashes (residues) Not listed.
Ferric oxide G-A4, I-3
Calcium carbonate Not listed.
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory Sensitization:
Skin Sensitization:
STOT-Single Exposure:
Chronic Health Effects:
Causes skin irritation. May cause burns in the presence of
moisture.
Causes serious eye damage. May cause burns in the presence of
moisture.
Based on available data, the classification criteria are not met.
May cause an allergic skin reaction.
Based on available data, the classification criteria are not met.
Respirable crystalline silica in the form of quartz or cristobalite
from occupational sources is listed by the International Agency
for Research on Cancer (IARC) and National Toxicology
Program (NTP) as a lung carcinogen. Prolonged exposure to
respirable crystalline silica has been known to cause silicosis, a
lung disease, which may be disabling. While there may be a
factor of individual susceptibility to a given exposure to
respirable silica dust, the risk of contracting silicosis and the
Chemical Listed as Carcinogen or
Potential Carcinogen
(NTP, IARC, OSHA, ACGIH, CP65)*
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
Teratogenicity:
Embryotoxicity:
Fertility:
STOT-Repeated Exposure:
Aspiration Hazard:
Toxicologically Synergistic
Materials:
Other Information:
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
13.1 WASTE TREATMENT METHODS
Disposal Method:
Other disposal
recommendations:
severity of the disease is clearly related to the amount of dust
exposure and the length of time (usually years) of exposure.
May cause cancer.
This product is not classified as a mutagen.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Causes damage to organs through prolonged or repeated
exposure.
Based on available data, the classification criteria are not met.
Not available.
Not available.
Section 12: ECOLOGICAL INFORMATION
No ecological consideration when used according to directions.
Normal dilution of this product to drains, sewers, septic system s
and treatment plants is not considered environmentally harmful.
Not available.
Section 13: DISPOSAL CONSIDERATIONS
This material must be disposed of in accordance with all local,
state, provincial, and federal regulations.
Not available.
Not hazardous by WHMIS criteria.
Not hazardous by WHMIS criteria.
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
Section 14: TRANSPORT INFORMATION
14.1 UN NUMBER
14.2 UN PROPER SHIPPING NAME
14.3 TRANSPORT HAZARD CLASS (ES)
14.4 PACKING GROUP
14.5 ENVIRONMENTAL HAZARDS
Not available.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
DOT TDG NOM-004-SCT2-1994
Not regulated. Not regulated. Not regulated.
DOT TDG NOM-004-SCT2-1994
Not applicable. Not applicable. Not applicable.
DOT TDG NOM-004-SCT2-1994
Not applicable. Not applicable. Not applicable.
DOT TDG NOM-004-SCT2-1994
Not applicable. Not applicable. Not applicable.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICAL
Canada: This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
US: MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200)
HazCom 2012
Mexico: MSDS prepared pursuant to NOM-018-STPS-2000.
SARA Title III
Ingredient Section 302 (EHS)
TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA
RQ (lbs.) Section 313
Silica, crystalline, quartz Not listed. Not listed. Not listed. Not listed.
Portland cement Not listed. Not listed. Not listed. Not listed.
Ashes (residues) Not listed. Not listed. Not listed. Not listed.
Ferric oxide Not listed. Not listed. Not listed. Not listed.
Calcium carbonate Not listed. Not listed. Not listed. Not listed.
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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SAFETY DATA SHEET
California Proposition 65:
State Regulations
This product contains Crystalline Silica, Quartz and may also contain trace amounts of other
chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.
Global Inventories:
Ingredient
Silica, crystalline, quartz DSL Yes.
Portland cement DSL Yes.
Ashes (residues) DSL Yes.
Ferric oxide DSL Yes.
Calcium carbonate NDSL Yes.
NFPA-National Fire Protection Association:
Health:
Fire:
Reactivity:
HMIS-Hazardous Materials Identification System:
Health:
Fire:
Physical Hazard:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
CP65 California Proposition 65
OSHA (O) Occupational Safety and Health Administration.
ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen.
A2 - Suspected human carcinogen.
A3 - Animal carcinogen.
A4 - Not classifiable as a human carcinogen.
A5 - Not suspected as a human carcinogen.
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans.
2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in
humans and sufficient evidence of carcinogenicity in experimental animals.
2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in
humans in the absence of sufficient evidence of carcinogenicity in experimental animals.
3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens.
2 - Reasonably anticipated to be carcinogens.
DSL/NDSL
Canada
USA
TSCA
3
1
0
3*
1
0
.
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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SAFETY DATA SHEET
Section 16: OTHER INFORMATION
Date of Preparation:
Expiry Date:
Version:
Revision Date:
July 19, 2013
July 19, 2016
1.0
July 17, 2014
Disclaimer: We believe the statements, technical information and recommendations contained herein
are reliable, but they are given without warranty or guarantee of any kind. The information contained in
this document applies to this specific material as supplied. It may not be valid for this material if it is used
in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability
and completeness of this information for the user’s own particular use.
Prepared by:
Nexreg Compliance Inc.
Phone: (519) 488-5126
Prepared for:
www.nexreg.com
Sakrete of North America
End of Safety Data Sheet
Trade Name: Sakrete High Strength Concrete Mix Print date: 2014-07-17
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