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Section 1: PRODUCT AND COMPANY IDENTIFICATI ON
1.1
Product Name:
Product Form:
1.2
Product Use:
1.3
Supplier:
Phone Number:
1..4
Emergency Number:
Sakrete Cement Colors
Mixture
I
norganic pigment
Sakrete of North America
8201 Arrowridge Blvd.
Charlotte, NC 28273
866-725-7383
CHEMTREC (800) 424-9300
Section 2: HAZARDS IDENTIFICATION
2.1 Classification of the Chemical: Not classified
2.2 Label Elements:
Hazard Pictogram:
Signal Word: Hazard
Statement:
Prevention:
Response :
Storage:
Disposal:
N/A
N/A
No known significant effects or critical hazards.
N /A
N /A
Store in original container protected from direct sunlight in a dry, cool, and
well-ventilated area, away from incompatible materials and food and drink
N /A
2.3 Additional Information:
Hazards not otherwise classified :
Section 3: COMPOSITION / INFORMATION ON INGREDIENTS
N/ A
3.1
Mixture:
Ingredient
Calcium Carbonate
Iron (III) Oxide
CAS #
1317-65-3
1309-37-1
Wt. %
5-10
>90 %
%
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentration applicable, are classified as hazardous to health and hence require reporting in this section.
Occupational exposure limits, if available, arc listed i n Section 8.
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Section 4: FIRST AID MEASURES
4.1 Description of First Aid Measures:
Eye
:
Skin
:
Inhalation:
Ingestion:
4.2 Most Important Symptoms and Effects, both Acute and Delayed:
Eye
:
Skin:
Inhalation:
Ingestion:
I
n case of contact, immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses. Get medical
attention if irritation occurs.
In case of contact, immediately flush skin with plenty of water. Remove contaminated
clothing and shoes. Get medical attention if symptoms occur.
Remove victim to fresh ai r and keep at rest i n a position comfortable for breathing.
Get medical attention if symptoms occur.
Wash out mouth with water. Remove victim to fresh air and keep a t rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting uncles
directed to do so by medical personnel. Get medical attention if symptoms occur.
May cause mechanical irritation (abrasion).
May cause mechanical irritation (abrasion).
No known significant effects or critical hazards.
No known significant effects or critical hazards.
4.3
Indication of Any Immediate Medical Attention and Special Treatments Needed:
Note to Physicians: Treat symptomatically. No specific treatment.
Specific Treatments: No special measures required
Section 5: FIRE FIGHTING MEASURES
5.1 Extinguishing Media :
Suitable Extinguishing Media :
Use an extinguishing agent suitable for the surrounding fire.
In case of fire use water spray (fog), foam or dry chemical.
Unsuitable Extinguishing Media:
5.2 Special Hazards Arising From the Chemical
Products of Decomposition:
5.3 Special Protective Equip ment and Precautions for Fire Fighters
removing all persons from the vicinity of the incident
None known.
: No specific fire or explosion hazard.
Decomposition products may include the following
materials: carbon dioxide, carbon monoxide, metal
oxide/oxides
if
there is a fi re.
: Promptly isolate the scene by
No
action shall be taken involving any
personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and selfcontained breathing apparatus
(SCBA)
with a full face-piece operated i n positive pressure mode.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal Precauti o ns, Protective Equipment and Emergency Procedures
taken involving any personal risk or without suitable train
i
ng. Evacuate surrounding areas. Keep
unnecessary and unprotected personnel from entering. Do not touch or wal k through spilled material.
Avoid breathing dust. Put on appropriate person protective equipment.
: No action shall be
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Ingredient
OSHA PEL – TWA (respirable fraction)
OSHA PEL – TWA (total dust)
Calcium Carbonate
5mg/m3 8 hours
15 mg/m3 8 hours
6.2 Environmental Precautions
waterways, drains and sewers. Inform the relevant authorities if the product has caused
soil,
environmental pollution (sewers, waterways, soil or air).
: Avoid dispersal of spilled material and runoff and contact with
6.3 Methods and Materials for Containment/Cleanup
release
Avoid
from upwind. Vacuum or sweep up material and place i n designated, labeled waste container.
creating dusty conditions and prevent wind dispersal. Dispose of via a licensed waste disposal
: Move containers from spill area. Approach
contractor. Note: see section 1for emergency contact information and section 13 for waste disposal.
Prevent entry into sewers, water courses, basements or confined areas.
Section 7: HANDLING AND STORAGE
7.1 Precautions for Safe Handling
equipment before entering eating areas. Workers should wash hands and face before eating, drinking
and smoking. Put on appropriate personal protective equipment. Eating, drinking, and smoking should
be prohibited in areas where this material is handled, stored and processed.
7.2 Conditions for Safe Storage, Including Any Incompatibilities
regulations.
area, away
closed and
kept
avoid
Store in original container protected from direct sunlight i n a dry, cool and well-ventilated
from incompatible materials (see section 10) and food and drink. Keep container tightly
sealed until ready for use. Containers that have been opened must be carefully resealed and
upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to
environmental contamination. Empty containers or liners may retain some product residues.
Section 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION
8.1 Control Parameters:
Exposure Guidelines
this product contains ingredient with exposure limits, personal, workplace, atmosphere or biological
If
monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or
the necessity to use respiratory protective equipment.
: Avoid breathing dust. Remove contaminated clothing and protective
: Store in accordance with local
:
8.2 Exposure Controls:
Engineering Controls
8.3 Individual Protective Measures:
Personal Protective
Equipment
Eye/Face Protection
shields.
Skin Protection
Respiratory Protection
: Use only with adequate ventilation. If user operations generate dust, fumes,
gas, vapor or mist, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminate
below any recommended or statutory limits.
:
: If contact with product is possible, wear safety glasses with side
: Wear sui table protective clothing and gloves. Suitable protective footwear.
: Dust- protection mask.
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General Hygiene Considerations
handling
chemical products, before eating, smoking and using the lavatory and at the end of
: Wash hands, forearms and face thoroughly after
the working period. Appropriate techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before reuse. Ensure that eyewash
stations and safety showers are close to the workstation location.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.
1Information on Basic Physical and Chemical Properties:
Appearance
: Powder
Color: Various
Odor: Odorless
Odor Threshold: N/A
Physical State
pH
: 4 to 8
Viscosity : N/ A
: Solid
Freezing Point: N /A
Boiling Point: N /A
Melting Point
Flash Point
: > 1000 °C (1832 °F)
: N/A
Evaporation Rate: N /A
Lower Flammability Limit: N /A
Vapor Pressure
Vapor Density
Relative Density
Bulk Density
Lower Explosion Limit
: N/A
: N/A
: 4 to 5
: 300 to 1000 kg/m
: N/A
3
Upper Explosion Limit
Solubility in Water: I
Coefficient of Water/Oil Distribution
Auto-ignition Temperature: N /A
Decomposition Temperature
Section 10: STABILITY AND REACTIVITY
10.1 Reactivity:
10.2 Chemical Stability:
10.3 Possibility of Hazardous
Reactions
:
: N/A
nsoluble
i n
cold water
: N/A
: N/ A
No specific test data related to reactivity available for this
product or its i ngredients.
This product is stable.
No hazardous reactions known under conditions of normal
storage and use.
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10.4
Conditions to Avoid:
No specific data.
10.5 Incompatible Materials:
10.6
Hazardous Decomposition Products:
No specific data.
Under normal conditions of storage and use, hazardous
decomposition products should not be produced.
Section 11: TOXICOLOGICAL INFORMATION
11.1 Information on Toxicological Effects
Likely routes of exposure: Skin contact, eye contact, i n halation, and ingestion.
Eye:
Skin:
Inhalation :
Ingestion:
Acute Toxicity
Ingredient
Calcium Carbonate
May cause mechanical irritation (abrasion).
May cause mechanical irritation (abrasion).
No known significant effects or cri tical hazards.
No known significant effects or critical hazards.
:
LD50 - Oral
6450 mg/kg, rat
11.2 Delayed, Immediate and Chronic Effects of Short- and Long- Term Exposure:
Short Term Exposure: N /A
Long Term Exposure:
Potential Delayed Effects - N /A
General - Long term exposure to high concentrations of dust containing iron oxide can cause
a benign condition termed "pulmonary siderosis". This condition is not associated with any
physical impairment of lung function.
Carcinogenicity -
Mutagenicity -
Teratogenicity -
Developmental Effects -
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Fertility Effects - No known significant effects or critical hazards.
STOT - Single Exposure -
irritation.
Skin Irritation/Corrosion
Eye Irritation/Corrosion
Calcium Carbonate = Category 3, may cause respiratory tract
- Moderate irritant
- Moderate irritant
Section 12: ECOLOGICAL INFORMATION
12.1
Toxicity:
Ingredient Name
Calcium Carbonate Acute EC50 >200 mg/I
12 .2
Persistence and Degradability: N /A
12 .3
Bioaccumulative Potential
Result
Acute EC50 >1000 mg/I
Acute LC50 >10000 mg/I
Acute LC50 56000 mg/I
: N /A
Species
Algae
Daphnia
Fish
Fish - Gambusia affinis
Exposure
72 hours
48 hours
96 hours
48 hours
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Iron (111) Oxide
1309-37-1
MA- S, N J - HS, PA- RTK HS
23-29
%
Calcium Carbonate
1317-65-3
MA- S, NJ- HS, PA- RTK HS
5-10
%
C.I. Pigment Yellow 42
51274-00-1
62-68
%
12.4
Mobility in Soil
12.5
Other Adverse Eff
: N /A
13.1
Waste Treatment Methods:
ects: No known sign ificant effects or critical hazards.
Section 13: DIPOSAL CONSIDERATIONS
Disposal Method
: The generation of waste should be avoided or minimized wherever possible.
This material and its container must be disposed of in a safe way. Empty
containers or liners may retain some product residues. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, d rains and
sewers. Waste disposal should be in accordance with existing federal state,
RCRA Classification
provincial and or local environmental control laws.
: If discarded in its purchased form, this product would not be a hazardous
waste either by listing or by characteristic. However, under RCRA, it is the
responsibility of the product user to determine at the time of disposal,
whether a material containing the product or derived from the product
should be classified as a hazardous waste. (
40
CFR
261.20-24).
Section 14: TRANSPORTATI ON INFORMATION
14.1
DOT (US)
14.2
IM DG
14.3 IATA: Not regulated
15.1
Safety, Health and Environmental Regulations/Legislations Specific for the Ch emical:
: Not regulated
: Not regulated
Section 15: REGULATORY INFORMATION
SARA Title
III:
Ingredient Section 302 Section 311/312 CERCLA Section 313
Sakrete Cement Colors
US Toxic Substance Control Act
None None
: Listed on the TSCA Inventory
None
None
STATE REGU LATIO NS:
The following chemicals are specifically listed by individual states; other product specific health and safety data
in other sections on the SDS may also be applicable for state requirements. For details on your regulatory
requi rements you should contact the appropriate agency in your state.
Ingredient
CAS#
State Code
Concentration (%)
Massachusetts Substances: M A- S
Massachusetts Extraordinary Hazardous Substances: MA- Extra IIS
New Jersey Hazardous Substances: NJ - HS
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Ingredient Name
CAS#
Concentration (%)
Cancer
Crystalline Quartz Silica
14808-60-7
0.1-1 %
Y ES
Health:
1 Flammability:
0
Physical :
0
Health: 1
Fire: 0
Reactivity:
0
Pennsylvania RTK Hazardous Substances: PA- RTK HS
Pennsylvania Special Hazardous Substances: PA- Special HS
California Prop. 65: WAR
N I
NG: this product contains a chemical known to the State of California to
cause cancer. Potential exposure to some or all of the Cal ifornia Proposition
product have been determined to be below the No Significant Risk Level (NSRL).
HMIS- Hazardous Material Information System:
65
chemicals in this
NFPA- Nation al Fire Protection Association:
Hazard Rating:
0 = minimal 1= slight
Date of Preparation: July
Version
: 1.0
Revision Date
:
Disclaimer
: We believe the statements, technical information and recommendations contained
Prepared for
: Sakrete of North America
2 = moderate 3 = severe 4 = extreme
Section 16: OTHER INFORMATION
1, 2015
January 5, 2016
herein are reliable, but they are given without warranty or guarantee of any kind. The
information contained in this document applies to this specific material as supplied. It
may not be valid for this material if it is used in combination with any other materials.
t is the user's responsibility to satisfy oneself as to the suitability and completeness
I
of this information for the user's own particular use.
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