Sakrete B650937 User Manual

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Conforms to OSHA HazCom 2012 Standard
SAFETY DATA SHEET
1.1 PRODUCT IDENTIFIER
Product Name:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
Sakrete Blacktop Crack Filler
Various.
Sakrete of North America
8201 Arrowridge Blvd. Charlotte, NC 28273
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone Number:
866-725-7383
CHEMTREC 800-424-9300 INTERNATIONAL + 01-703-527-3887
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL
Skin sensitization 1 Carcinogenicity 1A Specific target organ toxicity - Repeated exposure 1
2.2 LABEL ELEMENTS
Hazard Pictogram:
Hazard class
Signal Word: Hazard Statement:
Prevention:
Danger May cause an allergic skin reaction. May cause cancer. Causes
damage to organs through prolonged or repeated exposure. Contaminated work clothing must not be allowed out of the
workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink
Response:
or smoke when using this product.
If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention.
Storage:
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
reuse. If exposed or concerned: Get medical advice/attention.
Store locked up.
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Wash contaminated clothing before
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Conforms to OSHA HazCom 2012 Standard
SAFETY DATA SHEET
Disposal:
2.3 ADDITIONAL INFORMATION
Dispose of contents and container in accordance with all local, regional, national and international regulations.
Hazards not otherwise specified:
14.8 % of the mixture consists of ingredient(s) of unknown acute toxicity.
Not applicable.
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 MIXTURES
Ingredient CAS No Wt. %
Asphalt 8052-42-4 30 - 60 Kaolin 1332-58-7 7 - 13 Silica, crystalline, quartz 14808-60-7 3 - 7 Mica 12001-26-2 1 - 5 Aluminatesilicate 1327-36-2 1 - 5 Feldspar-group minerals 68476-25-5 1 - 5
Titanium dioxide 13463-67-7 0.1 - 1 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance
with paragraph (i) of §1910.1200.
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get
Skin:
medical attention immediately. In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Wash clot hing before
Inhalation:
reuse. Call a physician if irritation develops and persists. If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical advice/attention if
Ingestion:
you feel unwell. If swallowed, do NOT induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
Skin:
Inhalation: Ingestion:
person. Get medical advice/attention.
May cause eye irritation. Symptoms may include di scomfort or pain, excess blinking and tear production, with possible redness and swelling.
May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin.
May cause respiratory tract irritation. May be harmful if swallowed. May cause stomach distress, nausea
or vomiting.
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians: Specific Treatments:
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Section 5: FIRE-FIGHTING MEASURES
5.1 EXTINGUISHING MEDIA
Suitable Extinguishing Media: Unsuitable Extinguishing Media:
5.2 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion:
5.3 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Treat for surrounding material. Not available.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain and/or absorb spill with inert materia l (e.g. sand, vermiculit e), then place in a suitable container. Do not flush to sewer or allow to enter
Methods for Cleaning-Up:
waterways. Use appropriate Personal Protective Equipment (PPE). Scoop up material and place in a disposal container.
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Avoid breathing vapour or mist. Handle and open container with care. When using do not eat or drink. Wash hands before eating, drinking, or smoking.
General Hygiene Advice:
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
(See section 8) Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
Keep out of the reach of children. Store in dust-tight, dry, labeled containers. Keep containers closed when not in use. Do not store in an area equipped with emergency water sprinklers. (See section 10)
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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SAFETY DATA SHEET
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
Asphalt 5 mg/m³ 0.5 mg/m³ (fume) Kaolin 15 mg/m3 2 mg/m3
)/(%SiO2+2) TWA (resp))
3
)/(%SiO2+2) TWA (total))
+5) mppcf TWA (resp)) 0.025 mg/m³
2
Silica, crystalline, quartz
((10 mg/m ((30 mg/m
((250)/(%SiO Mica 20 mppcf 10 mg/m³ (total); 3 mg/m³ (resp) Aluminatesilicate Not available. Not available. Feldspar-group minerals Not available. Not available.
Titanium dioxide 15 mg/m3 (total dust) 10 mg/m³
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection: Body Protection:
Respiratory Protection:
Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits.
Safety glasses or goggles are recommended when using product.
Wear suitable waterproof gloves. Wear suitable waterproof protective clothing.
A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA’s respirator standard (29 CFR 1910.134)
General Health and Safety Measures:
and ANSI’s standard for respiratory protection (Z88.2).
Handle according to established industrial hygiene and safety practices. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Color: Odor: Odor Threshold: Physical State: pH:
Not available. Not available. Not available. Not available. Liquid. Not available.
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
Melting Point/Freezing Point: Initial Boiling Point and Boiling Range: Flash Point: Evaporation Rate: Flammability: Lower Flammability/Explosive Limit: Upper Flammability/Explosive Limit: Vapor Pressure: Vapor Density: Relative Density/Specific Gravity: Solubility: Partition coefficient: n-octanol/water: Auto-ignition Temperature: Decomposition Temperature: Viscosity:
Percent Volatile, wt. %: VOC content, wt. %:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
10.2 CHEMICAL STABILITY
Stable under normal storage conditions.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Incompatible materials.
10.5 INCOMPATIBLE MATERIALS
None known.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon.
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure:
Skin contact, skin absorption, eye contact, inhalation, and ingestion.
Not available. Not available. Not available. Not available. Not Flammable. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available.
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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SAFETY DATA SHEET
Symptoms related to physical/chemical/toxicological characteristics:
Acute Toxicity:
Eye:
Skin:
Ingestion:
Inhalation:
Ingredient LC50 LD50
May cause eye irritation. Symptoms may include di scomfort or pain, excess blinking and tear production, with possible redness and swelling.
May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin.
May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
May cause respiratory tract irritation.
Asphalt Not available. Kaolin Not available. Not available. Silica, crystalline, quartz Not available. Oral 500 mg/kg, rat Mica Not available. Not available. Aluminatesilicate Not available. Not available. Feldspar-group minerals Not available. Not available.
Titanium dioxide
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
> 20 mg/L 4 h, rat > 2000 mg/kg, rat > 2000 mg/kg, rabbit
Ingredient
Asphalt G-A4, I-2B, N-1, O, CP65 Kaolin G-A4 Silica, crystalline, quartz G-A2, I-1, N-1, O, CP65 Mica Not listed. Aluminatesilicate Not listed. Feldspar-group minerals Not listed.
Titanium dioxide
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation: Serious Eye Damage/Irritation:
Respiratory Sensitization: Skin Sensitization: STOT-Single Exposure: Chronic Health Effects:
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. May cause an allergic skin reaction. Based on available data, the classification criteria are not met. Respirable crystalline silica in the form of quartz or cristobalite
from occupational sources is listed by the International Agency for Research on Cancer (IARC) and National Toxicology Program (NTP) as a lung carcinogen. Prolonged exposure to respirable crystalline silica has been known to cause silicosis, a lung disease, which may be disabling. While there may be a factor of individual susceptibility to a given exposure to
Not available.
Oral >5000 mg/kg, rat
Dermal >2000 mg/kg, rabbit
Oral >10000 mg/kg, rat
Dermal >10000mg/kg, rabbit
Chemical Listed as Carcinogen or
Potential Carcinogen
(NTP, IARC, OSHA, ACGIH, CP65)*
G-A4, I-2B, O, CP65
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
Fertility:
STOT-Repeated Exposure:
Aspiration Hazard:
Toxicologically Synergistic Materials:
Other Information:
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
13.1 WASTE TREATMENT METHODS
Disposal Method:
Other disposal recommendations:
14.1 UN NUMBER
Not regulated.
14.2 UN PROPER SHIPPING NAME
Not applicable.
respirable silica dust, the risk of contracting silicosis and the severity of the disease is clearly related to the amount of dust exposure and the length of time (usually years) of exposure.
May cause cancer. This product is not classified as a mutagen.
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Causes damage to organs through prolonged or repeated
exposure. Based on available data, the classification criteria are not met.
Not available. Not available.
Section 12: ECOLOGICAL INFORMATION
No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic system s and treatment plants is not considered environmentally harmful.
Not available.
Section 13: DISPOSAL CONSIDERATIONS
Section 14: TRANSPORT INFORMATION
This material must be disposed of in accordance with all local, state, provincial, and federal regulations.
Not available.
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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SAFETY DATA SHEET
14.3 TRANSPORT HAZARD CLASS(ES)
Not applicable.
14.4 PACKING GROUP
Not applicable.
14.5 ENVIRONMENTAL HAZARDS
Not available.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICAL
MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012
SARA Title III
Ingredient Section 302 (EHS)
TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA RQ (lbs.) Section 313
Asphalt Not listed. Not listed. Not listed. Not listed. Kaolin Not listed. Not listed. Not listed. Not listed. Silica, crystalline, quartz Not listed. Not listed. Not listed. Not listed. Mica Not listed. Not listed. Not listed. Not listed. Aluminatesilicate Not listed. Not listed. Not listed. Not listed. Feldspar-group minerals Not listed. Not listed. Not listed. Not listed.
Titanium dioxide
California Proposition 65:
Not listed. Not listed. Not listed. Not listed.
State Regulations
This product contains Crystalline Silica, Quartz and may also contain trace amounts of other chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.
Global Inventories: Ingredient USA
TSCA
Asphalt Yes. Kaolin Yes. Silica, crystalline, quartz Yes. Mica No. Aluminatesilicate Yes. Feldspar-group minerals Yes.
Titanium dioxide
Yes.
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
NFPA-National Fire Protection Association:
Health: Fire: Reactivity:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
OSHA (O) Occupational Safety and Health Administration. ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen.
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens.
Section 16: OTHER INFORMATION
Date of Preparation: Version: Revision Date:
March 15, 2013
1.0 July 17, 2014
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.
Prepared by:
Nexreg Compliance Inc. Phone: (519) 488-5126
Prepared for:
www.nexreg.com
Sakrete of North America
2 1 0
.
End of Safety Data Sheet
Trade Name: Sakrete Blacktop Crack Filler Print date: 2013-03-15
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