Conforms to OSHA HazCom 2012 Standard
SAFETY DATA SHEET
Section 1: IDENTIFICATION
1.1 PRODUCT IDENTIFIER
Product Name:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
Sakrete Blacktop Repair
Sealant.
Sakrete of North America
8201 Arrowridge Blvd.
Charlotte, NC
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone
Number:
28273
866-725-7383
CHEMTREC 800-424-9300
INTERNATIONAL + 01-703-527-3887
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL
Skin irritation 2
Serious eye damage 1
Carcinogenicity 2
Reproductive toxicity 1B
Specific target organ toxicity - Single exposure 3
2.2 LABEL ELEMENTS
Hazard Pictogram:
Hazard class
Signal Word:
Hazard Statement:
Danger
Causes skin irritation. Causes serious eye damage. Suspected of
causing cancer. May damage fertility or the unborn child. May cause
Prevention:
respiratory irritation.
Wash hands thoroughly after handling. Obtain special instructions
before use. Do not handle until all safety precautions have been read
and understood. Wear protective glove s/protect ive clothing/ey e
protection/face protection. Avoid breathing dust/fume/gas/mist/vapors/
Response:
spray. Use only outdoors or in a well-ventilated area.
If on skin: Wash with plenty of water. If skin irritation or rash occurs:
Get medical advice/attention. Take off contaminated clothing and
wash it before reuse. If in eyes: Rinse cautiously with water for
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SAFETY DATA SHEET
several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a poison center/doctor. If inhaled:
Remove person to fresh air and keep comfortable for breathing. If
Storage:
Disposal:
2.3 ADDITIONAL INFORMATION
exposed or concerned: Get medical advice/attention.
Store locked up. Store in a well-ventilated place.
Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Hazards not otherwise
specified:
13.9 % of the mixture consists of ingredient(s) of unknown acute toxicity.
Not applicable.
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 MIXTURES
Ingredient CAS No Wt. %
Calcium carbonate 1317-65-3 40 - 70
Butyl benzyl phthalate 85-68-7 7 - 13
Titanium dioxide 13463-67-7 3 - 7
Stoddard solvent 8052-41-3 1 - 5
Ethylene glycol 107-21-1 1 - 5
The exact percentage (concentration) of composition has been withheld as a trade secret in accordance
with paragraph (i) of §1910.1200.
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. If easy to do, remove contact lenses, if worn. Get
Skin:
medical attention immediately.
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Wash clot hing before
Inhalation:
reuse. Call a physician if irritation develops and persists.
If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical advice/attention if
Ingestion:
you feel unwell.
If swallowed, do NOT induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
person. Get medical advice/attention.
Causes serious eye damage. Symptoms may include discomfort or
pain, excess blinking and tear production, with possible redness and
Skin:
Inhalation:
swelling.
Causes skin i rritation. Symptoms may include redness, drying,
defatting and cracking of the skin.
May cause respiratory irritation.
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
Ingestion:
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians:
Specific Treatments:
May be harmful if swallowed. May cause stomach distress, nausea or
vomiting.
Symptoms may not appear immediately.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Section 5: FIRE-FIGHTING MEASURES
5.1 EXTINGUISHING MEDIA
Suitable Extinguishing Media:
Unsuitable Extinguishing Media:
5.2 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion:
5.3 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Powder, water spray, foam, carbon dioxide.
Not available.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection
(SCBA). Provide ventilation. Use water spray to keep fire-exposed containers cool.
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel. Avoid contact with the skin and eyes.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to
sewer or allow to enter waterways. Use appropriate Personal
Methods for Cleaning-Up:
Protective Equipment (PPE).
Scoop up material and place in a di sposal contain er. Provide ve ntilation.
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Avoid breathing
vapour or mist. Handle and open container with care. When using do
not eat or drink. Wash hands before eating, drinking, or smoking.
General Hygiene Advice:
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
(See section 8)
Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
Keep out of the reach of children. Keep container tightly closed and
in a well-ventilated place. (See section 10)
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SAFETY DATA SHEET
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
Calcium carbonate 15 mg/m³ (total); 5 mg/m³ (resp) 10 mg/m³
Butyl benzyl phthalate Not available. Not available.
Titanium dioxide 15 mg/m3 (total dust) 10 mg/m³
Stoddard solvent 100 ppm 100 ppm
Ethylene glycol 50 ppm 50 ppm
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection:
Body Protection:
Respiratory Protection:
Use ventilation adequate to keep exposures (airborne levels of dust,
fume, vapor, etc.) below recommended exposure limits.
Wear approved eye (properly fitted dust- or splash-proof chemical safety
goggles) / face (face shield) protection.
Wear suitable waterproof gloves.
Wear suitable waterproof protective clothing.
A NIOSH approved dust mask or filtering facepiece is recommended in
poorly ventilated areas or when permissible exposure limits may be
exceeded. Respirators should be selected by and used under the
direction of a trained health and safety professional following
requirements found in OSHA’s respirator standard (29 CFR 1910.134)
General Health and Safety
Measures:
and ANSI’s standard for respiratory protection (Z88.2).
Handle according to established industrial hygiene and safety
practices. Do not eat, smoke or drink where material is handled,
processed or stored. Wash hands carefully before eating or smoking.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Color:
Odor:
Odor Threshold:
Physical State:
pH:
Melting Point/Freezing Point:
Initial Boiling Point and Boiling Range:
Paste-like compound.
Various.
Sweet acrylic, with a mild ammonia odor.
Not available.
Paste.
7.5 - 9
< 0 °C (< 32 °F)
> 100 °C (> 212 °F)
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
Flash Point:
Evaporation Rate:
Flammability:
Lower Flammability/Explosive Limit:
Upper Flammability/Explosive Limit:
Vapor Pressure:
Vapor Density:
Relative Density/Specific Gravity:
Solubility:
Partition coefficient: n-octanol/water:
Auto-ignition Temperature:
Decomposition Temperature:
Viscosity:
Percent Volatile, wt. %:
VOC content, wt. %:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
10.2 CHEMICAL STABILITY
Stable under normal storage conditions.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Incompatible materials.
10.5 INCOMPATIBLE MATERIALS
Strong oxidizing agents.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon.
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure:
Symptoms related to physical/chemical/toxicological characteristics:
Eye:
Skin:
Skin contact, eye contact, inhalation, and ingestion.
Causes serious eye damage. Symptoms may include discomfort or pain,
excess blinking and tear production, with possible redness a nd swelling.
Causes skin irritation. Symptoms may include redness, drying, defatting
and cracking of the skin.
Not available.
<1 (butyl acetate = 1)
Not Flammable.
Not available.
Not available.
25 mmHg @ 20 °C (68 °F)
Not available.
Not available.
Dispersible.
Not available.
Not available.
Not available.
Not available.
20 – 40 %
39 g/L
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SAFETY DATA SHEET
Acute Toxicity:
Ingestion:
Inhalation:
May be harmful if swallowed. May cause stomach distress, nausea or vomiting.
May cause respiratory irritation.
Ingredient LC50 LD50
Calcium carbonate Not available. Oral 6450 mg/kg, rat
Butyl benzyl phthalate Inhalation >6.7 mg/L 4 h, rat
Titanium dioxide Not available.
Stoddard solvent Inhalation > 5500 mg/m³ 4 h, rat
Ethylene glycol Inhalation > 2.5 mg/L 6hr, rat
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
7.4 mg/L 4 h, rat 3869.5 mg/kg, rat 7759.5 mg/kg, rabbit
Ingredient
Calcium carbonate Not listed.
Butyl benzyl phthalate CP65, I-3
Titanium dioxide G-A4, I-2B, O, CP65
Stoddard solvent Not listed.
Ethylene glycol G-A4
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation:
Serious Eye Damage/Irritation:
Respiratory Sensitization:
Skin Sensitization:
STOT-Single Exposure:
Chronic Health Effects:
Causes skin irritation.
Causes serious eye damage.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Respirable crystalline silica in the form of quartz or cristobalite
from occupational sources is listed by the International Agency
for Research on Cancer (IARC) and National Toxicology
Program (NTP) as a lung carcinogen. Prolonged exposure to
respirable crystalline silica has been known to cause silicosis, a
lung disease, which may be disabling. While there may be a
factor of individual susceptibility to a given exposure to
respirable silica dust, the risk of contracting silicosis and the
severity of the disease is clearly related to the amount of dust
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
exposure and the length of time (usually years) of exposure.
Suspected of causing cancer.
This product is not classified as a mutagen.
May damage the unborn child.
Oral 2330 mg/kg, rat
Dermal 6700 mg/kg, rat
Oral >10000 mg/kg, rat
Dermal >10000mg/kg, rabbit
Oral >5000 mg/kg, rat
Dermal >3000 mg/kg, rabbit
Oral 4000 mg/kg, rat
Dermal 9530 µL/kg, rabbit
Chemical Listed as Carcinogen or
Potential Carcinogen
(NTP, IARC, OSHA, ACGIH, CP65)*
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
STOT-Repeated Exposure:
Aspiration Hazard:
Toxicologically Synergistic
Materials:
Other Information:
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
13.1 WASTE TREATMENT METHODS
Disposal Method:
Other disposal recommendations:
14.1 UN NUMBER
Not regulated.
14.2 UN PROPER SHIPPING NAME
Not applicable.
14.3 TRANSPORT HAZARD CLASS(ES)
Not applicable.
14.4 PACKING GROUP
Not applicable.
14.5 ENVIRONMENTAL HAZARDS
Not available.
Fertility:
May damage fertility.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Not available.
Not available.
Section 12: ECOLOGICAL INFORMATION
No ecological consideration when used according to directions.
Normal dilution of this product to drains, sewers, septic system s
and treatment plants is not considered environmentally harmful.
Not available.
Section 13: DISPOSAL CONSIDERATIONS
Section 14: TRANSPORT INFORMATION
This material must be disposed of in accordance with all
local, state, provincial, and federal regulations.
Not available.
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICAL
MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012
SARA Title III
Ingredient Section 302 (EHS)
TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA
RQ (lbs.) Section 313
Calcium carbonate Not listed. Not listed. Not listed. Not listed.
Butyl benzyl phthalate Not listed. Not listed. 100 Not listed.
Titanium dioxide Not listed. Not listed. Not listed. Not listed.
Stoddard solvent Not listed. Not listed. Not listed. Not listed.
Ethylene glycol Not listed. Not listed. 5,000 313
California Proposition 65:
State Regulations
This product contains chemicals known to the State of California to cause cancer, birth defects or other
reproductive harm.
Global Inventories:
Ingredient USA
TSCA
Calcium carbonate Yes.
Butyl benzyl phthalate Yes.
Titanium dioxide Yes.
Stoddard solvent Yes.
Ethylene glycol Yes.
Health:
Fire:
Reactivity:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
OSHA (O) Occupational Safety and Health Administration.
NFPA-National Fire Protection Association:
3
1
0
ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen.
A2 - Suspected human carcinogen.
A3 - Animal carcinogen.
A4 - Not classifiable as a human carcinogen.
A5 - Not suspected as a human carcinogen.
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SAFETY DATA SHEET
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans.
2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in
humans and sufficient evidence of carcinogenicity in experimental animals.
2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in
humans in the absence of sufficient evidence of carcinogenicity in experimental animals.
3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens.
2 - Reasonably anticipated to be carcinogens.
Section 16: OTHER INFORMATION
Date of Preparation:
Version:
Revision Date:
March 15, 2013
1.0
July 17, 2014
Disclaimer: We believe the statements, technical information and recommendations contained herein
are reliable, but they are given without warranty or guarantee of any kind. The information contained in
this document applies to this specific material as supplied. It may not be valid for this material if it is used
in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability
and completeness of this information for the user’s own particular use.
Prepared by:
Nexreg Compliance Inc.
Phone: (519) 488-5126
Prepared for:
www.nexreg.com
Sakrete of North America
.
End of Safety Data Sheet
Trade Name: Sakrete Blacktop Repair Print date: 2013-03-15
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