Sakrete B650923 User Manual

Page 1
Sakrete Concrete Crack Filler
Safety Data Sheet
according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
1.1. Product identifier
Product form : Mixture Product name : Sakrete Concrete Crack Filler :
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Various
1.3. Details of the supplier of the safety data sheet
Sakrete of North America 8201 Arrowridge Blvd. 28273 Charlotte, NC - USA T 866-725-7383
1.4. Emergency telephone number
Emergency number : CHEMTREC (800) 424-9300
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture GHS-US classification
Acute toxicity 4 (Oral) Carcinogenicity 1A Specific target organ toxicity - Repeated exposure 1
2.2. Label elements GHS-US labelling
Hazard pictograms (GHS-US) :
Date of issue: 01/20/2014 Revision date: 01/20/2014 Version: 1.0
CHEMTREC International +1 (703) 527-3887 24 hr
GHS07
GHS08
Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Harmful if swallowed. May cause cancer. Causes damage to lungs through prolonged or
repeated exposure.
Precautionary statements (GHS-US) : Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. If swallowed: immediately call a poison center/doctor. Rinse mouth. If exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international
2.3. Other hazards
regulations.
No additional information available
2.4. Unknown acute toxicity (GHS-US)
8 % of the mixture consists of ingredient (s) of unknown acute toxicity.
SECTION 3: Composition/information on ingredients
3.1. Substance
Not applicable
3.2. Mixture
Name Product identifier % GHS-US classification
Limestone (CAS No) 1317-65-3 30 - 60 Not classified Quartz (CAS No) 14808-60-7 10 - 30 Acute Tox. 4 (Oral)
Distillates, petroleum, solvent-dewaxed heavy paraffinic (CAS No) 64742-65-0 0.1 - 1 Carc. 1B Vinyl acetate (CAS No) 108-05-4 0.1 - 1 Carc. 2 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.
Carc. 1A STOT RE 1
01/20/2014 EN (English) Page 1
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Sakrete Concrete Crack Filler
f
A
Safety Data Sheet
according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
SECTION 4: First aid measures
4.1. Description of first aid measures
First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
First-aid measures after skin contact : If irritation occurs, flush skin with plenty of water. Get medical attention if irritation persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water. Remove contact lenses, if worn. I
First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the
Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear
Symptoms/injuries after ingestion : Harmful if swallowed. May cause stomach distress, nausea or vomiting.
4.3. Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible).
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media : Treat for surrounding material. Unsuitable extinguishing media : None known.
5.2. Special hazards arising from the substance or mixture
Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon.
5.3. Advice for firefighters
Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
breathing. Get medical advice/attention if you feel unwell.
irritation persists, get medical attention.
anything by mouth to an unconscious person. Get medical advice/attention.
skin.
production, with possible redness and swelling.
protection (SCBA).
SECTION 6: Accidental releas e measures
6.1. Personal preca utions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
6.1.2. For emergency responders
No additional information available
6.2. Methods and material for containment and cleaning up
For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable
container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE).
Methods for cleaning up : Scoop up material and place in a disposal container.
6.3. Reference to ot her sections
See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Precautions for safe handling :
void contact with skin and eyes. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/ spray.
Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store locked up.
7.3. Specific end use(s)
Not available.
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Sakrete Concrete Crack Filler
Safety Data Sheet
according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Limestone (1317- 65-3)
USA ACGIH ACGIH TWA (mg/m³) 10 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m3) 5 mg/m³
Quartz (14808-60-7)
USA ACGIH ACGIH TWA (mg/m³) 0.025 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m3) (30)/(%SiO2 + 2) mg/m3 TWA, total dust
Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0)
USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³ (mist) USA OSHA OSHA PEL (TWA) ( m g/m³) 5 mg/m³ (mist)
Vinyl acetate (108-05-4)
USA ACGIH ACGIH TWA (ppm) 10 ppm USA OSHA OSHA PEL (TWA) (ppm) 10 ppm
8.2. Exposure controls
Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended exposure limits. Hand protection : Wear suitable gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully
before eating or smoking. Handle according to established industrial hygiene and safety
practices.
(250)/(%SiO2 + 5) mppcf TWA, respirable fraction (10)/(%SiO2 + 2) mg/m
3
TWA, respirable fraction
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Physical state : Liquid. Appearance : Viscous. Colour : No data available. Odour : No data available. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : No data available. Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Not flammable. Vapour pressure : No data available. Relative vapour den sity at 20 °C : No data available. Relative density : No data available. Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available.
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Sakrete Concrete Crack Filler
Safety Data Sheet
according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available.
9.2. Other information
No additional information available
SECTION 10: Stability and reactivity
10.1. Reactivity
No dangerous reaction known under conditions of normal use.
10.2. Chemical stability
Stable under normal storage conditions.
10.3. Possibility of hazardous reactions
No dangerous reaction known under conditions of normal use.
10.4. Conditions to avoid
Incompatible materials.
10.5. Incompatible materials
None known.
10.6. Hazardous decomposition products
May include, and are not limited to: oxides of carbon.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity : Harmful if swallowed.
Limestone (1317- 65-3)
LD50 oral rat 6450 mg/kg
Quartz (14808-60-7)
LD50 oral rat 500 mg/kg
Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0)
LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg
Vinyl acetate (108-05-4)
LD50 oral rat 2920 mg/kg LD50 dermal rabbit 2320 mg/kg LC50 inhalation rat (mg/l) 11.4 mg/l/4h
Sakrete Concrete Crack Filler
ATE (oral) 1659 mg/kg, rat ATE (dermal) > 2000 mg/kg, rabbit ATE (inhalation) > 20 mg/l/4h, rat
Skin corrosion/irritation : Based on available data, the classification criteria are not met. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : May cause cancer.
Quartz (14808-60-7)
IARC group 1 National Toxicology Program (NTP) Status 2
Vinyl acetate (108-05-4)
IARC group 2B
Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met.
Specific target organ toxicity (repeated exposure)
Aspiration hazard : Based on available data, the classification criteria are not met.
01/20/2014 EN (English) 4/6
: Causes damage to lungs through prolonged or repeated exposure.
Page 5
Sakrete Concrete Crack Filler
Safety Data Sheet
according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
Symptoms/injuries after inhalation : Ma y cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the
Symptoms/injuries after eye contact : Ma y cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear
Symptoms/injuries after ingestion : Harmful if swallowed. May cause stomach distress, nausea or vomiting.
SECTION 12: Ecological information
12.1. Toxicity
Ecology - general : May cause long-term adverse effects in the aquatic environment.
12.2. Persistence and degradability
Sakrete Concrete Crack Filler
Persistence and degradability Not established.
12.3. Bioaccumulative potential
Sakrete Concrete Crack Filler
Bioaccumulative potential Not established.
12.4. Mobility in soil
No additional information available
12.5. Other adverse effects
No additional information available
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal
skin.
production, with possible redness and swelling.
regulations.
SECTION 14: Transport information
In accordance with DOT
14.1. UN number
Not applicable
14.2. UN proper ship ping name
Not applicable
14.3. Additional information
Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood.
SECTION 15: Regulatory information
15.1. US Federal regulations
Limestone (1317- 65-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Quartz (14808-60-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Distillates, petroleum, solvent-dewaxed heavy paraffinic (64742-65-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Vinyl acetate (108-05-4)
Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 302 (Specific toxic chemical listings) Listed on SARA Section 313 (Specific toxic chemical listings)
SARA Section 302 Threshold Planning
1000
Quantity (TPQ) SARA Section 313 - Emi ssion Reporting 0.1 %
15.2. US State regulations
Sakrete Concrete Crack Filler
State or local regulations This product contains Crystalline Silica, Quartz and may also contain trace amounts of other chemicals
known to the State of California to cause cancer, birth defects or other reproductive harm.
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Sakrete Concrete Crack Filler
Safety Data Sheet
according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
SOURCE AGENCY CARCINOGEN CL ASSIFICATIONS:
IARC (I) International Agency for Research on Cancer.
1 - Carcinogenic to humans;
NTP (N) National Toxicology Program.
1 - Evidence of Carcinogenicity;
SECTION 16: Other information
Indication of chan ges : None. Other information : None.
NFPA health hazard : 1 - Exposure could cause irritation but only minor
NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure
2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans.
2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration.
residual injury even if no treatment is given.
conditions, and are not reactive with water.
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product
01/20/2014 EN (English) 6/6
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