Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Safety Data Sheet
according to
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
Date of issue
Product form
:
Mixture
Product name
:
Sakrete Fast Setting Cement Patcher
Sakrete Leak Stopper Hydraulic Cement (Gray)
Use of the substance/mixture
:
Various.
Emergency number
:
CHEMTREC (800) 424-9300
CHEMTREC International +1 (703) 527
Corrosive to Metals 1
Acute toxicity 4 (Oral)
Skin Irritation 2
Serious Eye Damage 1
Skin Sensitization 1
Carcinogenicity 1A
Specific Target Organ Toxicity After Single Exposure 3
Specific Target Organ Toxicity After Repeated Exposure 1
Hazard pictograms (GHS-US)
:
Signal word (GHS-US)
:
Danger
Hazard statements (GHS-US)
:
May be corrosive to aluminium. Harmful if swallowed. Causes skin irritation. Causes serious eye
damage. May cause an allergic skin reaction. May cause cancer. May cause respiratory irritation.
Causes damage to
Precautionary statements (GHS-US)
:
Keep only in original container. Do not eat, drink or smoke when using this product. Wash hands
thoroughly after handling. Contami
Obtain special instructions before use. Do not handle until all safety precautions have been read
and understood. Wear protective gloves/protective clothing/eye protecti on/f ace prot ect i on. Use
o
material damage.
Immediately call a poison center/doctor. Rinse mouth. If in eyes: Rinse cautiou
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor. If on skin: Wash with plenty of water. Take off
contaminated clothing and wash it before reuse. If skin irritat
advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call
a poison center/doctor if you feel unwell.
inner liner.
Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Other hazards not contributing to the
:
Not applicable.
Sakrete Leak Stopper Hydraulic Cement (Gray): 47% of the mixture consists of ingredient(s) of unknown acute toxicity.
Sakrete Fast Setting Cement Patcher: 13 % of the mixture consists of ingredient(s) of unknown acute toxicity.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Sakrete of North America
8201 Arrowridge Blvd.
28273 Charlotte, NC - USA
T 866-725-7383
1.4. Emergency telephone number
: 01/20/2014 Revision date: 01/20/2014 Version: 1.0
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture GHS-US classification
2.2. Label elements GHS-US labelling
-3887 24 hr
lungs through prolonged or repeated exposure.
nated work clothing must not be allowed out of the workplace.
nly outdoors or in a well-ventilated area. Do not breathe dust. Absorb spillage to prevent
If exposed or concerned: Get medical advice/attention. If swallowed:
ion or rash occurs: Get medical
Store in corrosive resistant container with a resistant
Store locked up. Store in a well-ventilated place. Keep container tightly closed.
2.3. Other hazards
classification
2.4. Unknown acute toxicity (GHS US)
01/20/2014 EN (English)
sly with water for
Page 1
Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Safety Data Sheet
according to
Name
Product identifier
%
GHS-US classification
Quartz
(CAS No) 14808-60-7
0.5 - 75
Acute Tox. 4 (Oral), H302
STOT RE 1, H372
Cement, alumina, chemicals
65997-16-2
10 - 30
Skin Irrit. 2, H315
Eye Dam. 1, H318
Cement, portland, chemicals
(CAS No) 65997-15-1
5 - 30
Skin Irrit. 2, H315
STOT SE 3, H335
Calcium oxide
(CAS No) 1305-78-8
1.5 - 7
Acute Tox. 4 (Oral), H302
STOT SE 3, H335
Sodium carbonate
497-19-8
1 - 5
Met. Corr. 1 H290
Eye Irr i t 2 A H319
Aluminum sulfate
(CAS No) 10043-01-3
1.5 - 31
Met. Corr. 1, H290
Eye Dam. 1, H318
Calcium hydroxide
1305-62-0
0.5 - 22
Skin Corr. 1B, H314
Eye Dam. 1, H318
Calcium magnesium hydroxide (CaMg(OH)4)
39445-23-3
1.5 - 32
Skin Irrit. 2, H315
STOT SE 3, H335
Calcium magnesium hydroxide oxide (CaMg(OH)2O)
(CAS No) 58398-71-3
1.5 - 32
Not classified
Limestone
(CAS No) 1317-65-3
0. 5 - 1.5
Not classified
Calcium sulfate
(CAS No) 7778-18-9
0. 5 - 1.5
Not classified
Gypsum (Ca(SO4).2H2O)
(CAS No) 13397-24-5
0. 5 - 1.5
Not classified
1
Sakrete Fast Setting Cement Patcher
Sakrete Leak Stopper Hydraulic Cement
The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.
First-aid measures after inhalation
:
If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for
breathing. Get medical advice/attention if you feel unwell.
First-aid measures after skin contact
:
In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing
and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists.
First-aid measures after eye contact
:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to
do, remove contact lenses, if worn. Get medical attention immediately.
First-aid measures after ingestion
:
If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give
anything by mouth to an unconscious person. Immediately call a POISON CENTER or
doctor/physician.
Symptoms/injuries after inhalation
:
May cause respiratory tract irritation.
Symptoms/injuries after skin contact
:
Causes skin irritation. May cause burns in the presence of moisture. Skin contact during
hydration may slowly develop sufficient heat that may cause severe burns possibly
permanent injury.
prolonged contact with skin.
contact.
Symptoms/injuries after eye contact
:
Causes serious eye damage. May cause burns in the presence of moisture. Symptoms may
include discomfort or pain, excess blinking and tear production, with possible redness and
swelling.
Symptoms/injuries after ingestion
:
Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Suitable extinguishing media
:
Treat for surrounding material.
Unsuitable extinguishing media
:
Not available.
Fire hazard
:
Products of combustion may include, and are not limited to: oxides of carbon.
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable.
3.2. Mixture
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
(CAS No)
(CAS No)
(CAS No)
Carc. 1A, H350
Eye Dam. 1, H318
Skin Sens. 1, H317
Skin Irrit. 2, H315
Eye Dam. 1, H318
(CAS No)
2
SECTION 4: First aid measures
4.1. Description of first aid measures
4.2. Most important symptoms and effects, both acute and delayed
Do not allow product to harden around any body part or allow continuous,
Eye Dam. 1, H318
resulting in
Handling can cause dry skin. May cause sensitization by skin
4.3. Indication of any immediate medical attention and special treatment needed
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where
possible).
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
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Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Safety Data Sheet
according to
Firefighting instructions
:
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory
protection (SCBA).
General measures
:
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
For containment
:
Contain spill, then place in a suitable container. Do not flush to sewer or allow to enter
waterways.
Methods for cleaning up
:
Vacuum or sweep material and place in a disposal container. Absorb spillage to prevent material
damage.
Precautions for safe handling
:
Avoid contact with skin and eyes. Do not swallow. Avoid generating and breathing dust. Good
housekeeping is important to prevent accumulation of dust. The use of compressed air for
cleaning clothing, equipment, etc, is not recommended. Handle and open container with care.
When using do
Hygiene measures
:
Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Storage conditions
:
Keep out of the reach of children. Store in dust-tight, dry, labelled containers. Keep container
tightly closed when not in use. Avoid any dust buildup by frequent cleaning and suitable
construction of the storage area. Do not store in an area equipped with emergency water
sprinklers.
Quartz (14808-60-7)
USA ACGIH
ACGIH TWA (mg/m³)
0.025 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m3)
(30)/(%SiO2 + 2) mg/m3 TWA, total du st
(10)/(%SiO2 + 2) mg/m3 TWA, respirable fraction
Cement, portland, chemicals (65997-15-1)
USA ACGIH
ACGIH TWA (mg/m³)
1 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m3)
5 mg/m³
Calcium sulfate (7778-18-9)
USA ACGIH
ACGIH TWA (mg/m³)
10 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m³)
5 mg/m³
Gypsum (Ca(SO4).2H2O) (13397-24-5)
USA ACGIH
ACGIH TWA (mg/m³)
10 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m³)
5 mg/m³
Limestone (1317-65-3)
USA ACGIH
ACGIH TWA (mg/m³)
10 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m3)
5 mg/m³
Calcium oxide (1305-78-8)
USA ACGIH
ACGIH TWA (mg/m³)
2 mg/m³
USA OSHA
OSHA PEL (TWA) (mg/m3)
5 mg/m³
Calcium hydroxide (1305-62-0)
USA ACGIH
ACGIH TWA (mg/m³)
5 mg/m³
5.3. Advice for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
6.2. Methods and material for containment and cleaning up
Use appropriate Personal Protective Equipment (PPE).
6.3. Reference to other sections
No additional information available.
SECTION 7: Handling and storage
7.1. Precautions for safe handling
not eat, drink or smoke.
7.2. Conditions for safe storage, including any incompatibilities
7.3. Specific end use(s)
Store in corrosive resistant container with a resistant inner liner.
No additional information available.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
(250)/(%SiO2 + 5) mppcf TWA, respirable fraction
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Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Safety Data Sheet
according to
Calcium hydroxide (1305-62-0)
USA OSHA
OSHA PEL (TWA) (mg/m³)
5 mg/m³
Appropriate engineering controls
:
Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below
recommended ex
Hand protection
:
Wear suitable waterproof gloves.
Eye protection
:
Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and
face protection (face shield).
Skin and body protection
:
Wear suitable waterproof protective cl othing.
Respiratory protection
:
A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areas or
when permissible exposure limits may be exceeded. Respirators should be selected by and used
under the d
OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for respiratory protection
(Z88.2).
Other information
:
Handle according to established industrial hygiene and safety practices. Do not eat, smoke or
drink where material is handled, processed or stored.
smoking.
Physical state
:
Solid
Appearance
:
Powder.
Colour
:
Various.
Odour
:
Characteristic.
Odour threshold
:
No data available.
pH : 10 - 13
Relative evaporation rate (butylacetate=1)
:
No data available.
Melting point
:
No data available.
Freezing point
:
No data available.
Boiling point
:
No data available.
Flash point
:
No data available.
Self ignition temperature
:
No data available.
Decomposition temperature
:
No data available.
Flammability (solid, gas)
:
Not Flammable.
Vapour pressure
:
No data available.
Relative vapour density at 20 °C
:
No data available.
Relative density
:
No data available.
Solubility
:
No data available.
Log Pow
:
No data available.
Log Kow
:
No data available.
Viscosity, kinematic
:
No data available.
Viscosity, dynamic
:
No data available.
Explosive properties
:
No data available.
Oxidising properties
:
No data available.
Explosive limits
:
No data available.
VOC content
:
0%, Not applicable; 0 wt, Not applicable.
8.2. Exposure controls
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
posure limits.
irection of a trained health and safety professional following requirements found in
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Wash hands carefully before eating or
9.2. Other information
SECTION 10: Stability and reactivity
10.1. Reactivity
No dangerous reaction known under conditions of normal use. Product slowly erodes aluminium.
10.2. Chemical stability
Stable under normal storage conditions. Keep dry in storage.
10.3. Possibility of hazardous reactions
No dangerous reaction known under conditions of normal use.
10.4. Conditions to avoid
Incompatible materials. Moisture.
01/20/2014 EN (English)
4/7
Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Safety Data Sheet
according to
Acute toxicity
:
Harmful if swallowed.
Quartz (14808-60-7)
LD50 oral rat
500 mg/kg
Calcium sulfate (7778-18-9)
LD50 oral rat
> 3000 mg/kg
Calcium oxide (1305-78-8)
LD50 oral rat
500 mg/kg
Calcium hydroxide (1305-62-0)
LD50 oral rat
7340 mg/kg
Sodium carbonate (497-19-8)
LD50 oral rat
4090 mg/kg
LC50 inhalation rat (mg/l)
2300 mg/m³ 2h
Aluminum sulfate (10043-01-3)
LD50 oral rat
1930 mg/kg
Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
ATE (oral)
590 - 720 mg/kg, rat
ATE (dermal)
>2000 mg/kg, rat
ATE (inhalation)
No data available.
Skin corrosion/irritation
:
Causes skin irritation.
Serious eye damage/irritation
:
Causes serious eye damage.
Respiratory or skin sensitisation
:
May cause an allergic skin reaction.
Germ cell mutagenicity
:
Based on available data, the classification criteria are not met.
Carcinogenicity
:
May cause cancer.
Quartz (14808-60-7)
IARC group
1
National Toxicity Program (NTP) Status
2
Reproductive toxicity
:
Based on available data, the classification criteria are not met.
Specific target organ toxicity (single exposure)
:
May cause respiratory irritation.
Specific target organ toxicity (repeated
:
Causes damage to lungs through prolonged or repeated exposure. (Respirable crystalline silic a
in
Agency for Research on Cancer (IARC) and National Toxicology Program (NTP) as a lung
carcinogen. Prolonged exposure to respirable crystalline silica has been known
silicosis, a lung disease, which may be disabling. While there may be a factor of individual
susceptibility to a given exposure to respirable silica dust, the risk of contracting silicosis and the
severity of the disease is clearly related to the
(usually years) of exposure.)
Aspiration hazard
:
Based on available data, the classification criteria are not met.
Symptoms/injuries after inhalation
:
May cause respiratory tract irritation.
Symptoms/injuries after skin contact
:
Causes skin irritation. May cause burns in the presence of moisture. Skin contact during
hydration may slowly develop sufficient heat that may cause severe burns possibly resulting in
permanent injury. Do not allow product to h
prolonged contact with skin. Handling can cause dry skin. May cause sensiti
contact.
Symptoms/injuries after eye contact
:
Causes serious eye damage. May cause burns in the presence of moisture. Symptoms may
include discomfort or pain, excess blinking and tear production, with possible redness and
swelling.
Symptoms/injuries after ingestion
:
Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Other information
:
Likely routes of exposure: ingestion, inhalation, skin and eye.
10.5. Incompatible ma terials
Wet cement is alkaline and incompatible with acid, ammonium salts and aluminum metal.
10.6. Hazardous decomposition products
May include, and are not limited to: oxides of carbon.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
exposure)
the form of quartz or cristobalite from occupational sources is listed by the International
to cause
amount of dust exposure and the length of time
arden around any body part or allow continuous,
01/20/2014 EN (English)
zation by skin
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Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Safety Data Sheet
according to
Ecology - general
:
No ecological consideration when used according to directions. Normal dilution of this product to
drains, sewers, septic systems an
Calcium sulfate (7778-18-9)
LC50 fishes 1
2980 mg/l (96 h: Lepomis macrochirus [static])
LC50 fish 2
> 1970 mg/l (96 h: Pimephales promelas [static])
Calcium oxide (1305-78-8)
LC50 fishes 1
1070 mg/l (96 h: Cyprinus carpio [static])
Sodium carbonate (497-19-8)
LC50 fishes 1
300 mg/l (96 h: Lepomis macrochirus [static])
EC50 Daphnia 1
265 mg/l (48 h: Daphnia magna)
LC50 fish 2
310 - 1220 mg/l (96 h: Pimephales promelas [static])
Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Persistence and degradability
No data available.
Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Bioaccumulative potential
No data available.
Calcium oxide (1305-78-8)
BCF fish 1
(no bioaccumulation)
Calcium hydroxide (1305-62-0)
BCF fish 1
(no bioaccumulation)
Sodium carbonate (497-19-8)
BCF fish 1
(no bioaccumulation)
Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Ecology - soil
No data available.
Other adverse effects
:
No data available.
Waste disposal recommendations
:
This material must be disposed of in accordance with all local, state, provincial, and federal
regulations.
Other information
:
No supplementary information available.
Quartz (14808-60-7)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Cement, portland, chemicals (65997-15-1)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Calcium sulfate (7778-18-9)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SECTION 12: Ecological information
12.1. Toxicity
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
12.2. Persistence and degradability
12.3. Bioaccumulative potential
d treatment plants is not considered environmentally harmful.
12.4. Mobility in soil
12.5. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SECTION 14: Transport information
In accordance with DOT.
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Additional information
SECTION 15: Regulatory information
15.1. US Federal regulations
01/20/2014 EN (English)
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Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
Safety Data Sheet
according to
Limestone (1317-65-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Calcium oxide (1305-78-8)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Calcium magnesium hydroxide (CaMg(OH)4) (39445-23-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Cement, alumina, chemicals (65997-16-2)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Calcium magnesium hydro x ide oxide (CaMg(OH)2O) (58398-71-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Calcium hydroxide (1305-62-0)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Sodium carbonate (497-19-8)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Aluminum sulfate (10043-01-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Sakrete Fast Setting Cement Patcher; Sakrete Leak Stopper Hydraulic Cement (Gray)
State or local regulations
This product contains Crystalline Silica, Quartz and may also contain trace amounts of
IARC (I)
International Agency for Research on Cancer.
1 - Carcinogenic to humans;
4 - Probably not carcinogenic to humans.
NTP (N)
National Toxicology Program.
1 - Evidence of Carcinogenicity;
5 - Twelfth Report - Items under consideration.
Data sources
:
SDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom
2012.
NFPA health hazard
:
3 - Short exposure could cause serious temporary or
residual injury even though prompt
was given.
NFPA fire hazard
:
1 - Must be preheated before ignition can occur.
NFPA reactivity
:
0 - Normally stable, even under fire exposure
conditions, and are not reactive with water.
15.2. US State regulations
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012.
other chemicals known to the State of California to cause cancer, birth defects or other
reproductive harm.
2A - Probably carcinogenic to humans;
2B - Possibly carcinogenic to humans;
3 - Not classifiable;
2 - Known Human Carcinogens;
3 - Reasonably anticipated to be Human Carcinogen;
4 - Substances delisted from report on Carcinogens;
SECTION 16: Other information
medical attention
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product
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