Sakrete B650911 User Manual

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Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
1.1 PRODUCT IDENTIFIER
Product Name: Product Code:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
Sakrete All Weather Blacktop Patch Not available.
Coating.
Sakrete of North America 8201 Arrowridge Blvd.
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone Number:
28273 Charlotte, NC - USA 866-725-7383
CHEMTREC 800-424-9300 INTERNATIONAL + 01-703-527-3887
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL ACCORDING TO OSHA HAZCOM 2012
Carcinogenicity 1A Specific target organ toxicity - Repeated exposure 1
2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012
Hazard Pictogram:
Hazard class
Signal Word: Hazard Statement:
Prevention:
Danger May cause cancer. Causes damage to lungs through prolonged or
repeated exposure. Obtain special instructions before use. Do not handle until all safety
precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands thoroughly
Response: Storage: Disposal:
after handling. Do not eat, drink or smoke when using this product. If exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents and container in accordance with all local,
regional, national and international regulations.
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2.3 ADDITIONAL INFORMATION
Hazards not otherwise classified:
Conforms to OSHA HazCom 2012 & CPR Standards
WHMIS Classification(s):
Class D2A - Carcinogenicity Class D2A - Chronic Toxic Effect s Class D2B - Skin Irritant
WHMIS Hazard Symbols:
SAFETY DATA SHEET
Not applicable.
WHMIS Signal Word:
3.1 MIXTURES
CAUTION
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS No Wt. %
Calcium carbonate 1317-65-3 60 - 100 Asphalt 8052-42-4 5 - 10 Fuel oil, no. -2 68476-30-2 1 - 5 Silica, crystalline, quartz 14808-60-7 1 - 5
The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Call a
Skin:
physician if irritation develops and persists. In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Wash clot hing before
Inhalation:
reuse. Call a physician if irritation develops and persists. If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical advice/attention if
Ingestion:
you feel unwell. If swallowed, do NOT induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
Skin:
person. Get medical advice/attention if you feel unwell.
May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling.
May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin.
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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SAFETY DATA SHEET
Inhalation: Ingestion:
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians: Specific Treatments:
May cause respiratory tract irritation. May be harmful if swallowed. May cause stomach distress, nausea or
vomiting.
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Section 5: FIRE-FIGHTING MEASURES
5.1 FLAMMABILITY
Flammability:
5.2 EXTINGUISHING MEDIA
Suitable Extinguishing Media: Unsuitable Extinguishing Media:
5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion: Explosion Data:
Sensitivity to Mechanical Impact: Not available. Sensitivity to Static Discharge: Not available.
5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Not flammable by WHMIS/OSHA criteria.
Powder, water spray, foam, carbon dioxide. Not available.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Methods for Cleaning-Up:
Protective Equipment (PPE). Scoop up material and place in a disposal container.
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Do not breathe dust/gas/fumes /vapor/spray. Handle and open container with care. When using do not eat, drink or smoke. (See section 8)
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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Conforms to OSHA HazCom 2012 & CPR Standards
SAFETY DATA SHEET
General Hygiene Advice:
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking.
Keep out of the reach of children. Keep container tightly closed. (See section 10)
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
15 mg/m³ (total);
Calcium carbonate
5 mg/m³ (resp) 10 mg/m³ Asphalt Not available. 0.5 mg/m³ (fume) Fuel oil, no. -2 Not available. 100 mg/m3
((10 mg/m ((30 mg/m
Silica, crystalline, quartz
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection: Body Protection:
Respiratory Protection:
((250)/(%SiO
Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits.
Wear eye protection.
Wear suitable gloves. Wear suitable protective clothing.
In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the
General Health and Safety Measures:
selected respirator.
Handle according to established industrial hygiene and safety practices. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Color: Odor: Odor Threshold:
)/(%SiO2+2) (resp));
3
)/(%SiO2+2) (total));
+5) mppcf (resp)) 0.025 mg/m³
2
Coated stone. Black. Petroleum odor. Not available.
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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SAFETY DATA SHEET
Physical State: pH: Melting Point/Freezing Point: Initial Boiling Point and Boiling Range: Flash Point: Evaporation Rate: Flammability: Lower Flammability/Explosive Limit: Upper Flammability/Explosive Limit: Vapor Pressure: Vapor Density: Relative Density/Specific Gravity: Solubility: Partition coefficient: n-octanol/water: Auto-ignition Temperature: Decomposition Temperature: Viscosity: Explosive Properties: Oxidizing Properties:
VOC content, wt. %:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
10.2 CHEMICAL STABILITY
Stable under normal storage conditions.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Incompatible materials.
10.5 INCOMPATIBLE MATERIALS
Strong acids. Strong oxidizers.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon.
Solid. Not available. Not available. Not available. > 93.3 °C (> 200 °F) < 1 (Ether = 1) Not flammable. Not available. Not available. Not available. > 1 (Air = 1) > 1 (Water = 1) Negligible. Not available. Not available. Not available. Not available. Not available. Not available. Not available.
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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SAFETY DATA SHEET
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure: Symptoms related to physical/chemical/toxicological characteristics:
Eye:
Skin:
Acute Toxicity:
Ingestion:
Inhalation:
Ingredient LC50 LD50
Skin contact, eye contact, inhalation, and ingestion.
May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness a nd swelling.
May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin.
May be harmful if swallowed. May cause stomach distress, nausea or vomiting. May cause respiratory tract irritation.
Calcium carbonate Not available. Oral 6450 mg/kg, rat Asphalt Not available. Fuel oil, no. -2
Silica, crysta lline, quartz Not available. Oral 500 mg/kg, rat
Inhalation 4.1 mg/L 4 h, rat
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
Not available.
> 2000 mg/kg, rat > 2000 mg/kg, rabbit
Chemical Listed as Carcinogen or Potential Carcinogen
Ingredient
Calcium carbonate Not listed. Asphalt G-A4, I-2B, CP65
Fuel oil, no. -2 Silica, crystalline, quartz G-A2, I-1, N-1, CP65
* See Section 15 for more information.
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation: Serious Eye Damage/Irritation:
Respiratory Sensitization: Skin Sensitization: STOT-Single Exposure:
May cause skin irritation. Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Causes damage to lungs through prolonged or repeated exposure.
Oral >5000 mg/kg, rat
Dermal >2000 mg/kg, rabbit
Oral 12 g/kg, rat
Dermal 4720 µL/kg, rabbit
(NTP, IARC, OSHA, ACGIH, CP65)*
G-A3, I-2B [Fuel oils, residual (heavy)],
I-3 [Fuel oils, distillate (light)]
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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SAFETY DATA SHEET
Chronic Health Effects:
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
Teratogenicity:
STOT-Repeated Exposure: Aspiration Hazard:
Embryotoxicity:
Fertility:
Toxicologically Synergistic Materials:
Other Information:
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
Section 13: DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Disposal Method:
Respirable crystalline silica in the form of quartz or cristobalite from occupational sources is listed by the International Agency for Research on Cancer (IARC) and National Toxicology Program (NTP) as a lung carcinogen. Prolonged exposure to respirable crystalline silica has been known to cause silicosis, a lung disease, which may be disabling. While there may be a factor of individual susceptibility to a given exposure to respirable silica dust, the risk of contracting silicosis and the severity of the disease is clearly related to the amount of dust
exposure and the length of time (usually years) of exposure. May cause cancer. Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
Not available. Not available.
Section 12: ECOLOGICAL INFORMATION
No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic system s and treatment plants is not considered environmentally harmful.
Not available.
This material must be disposed of in accordance with all local, state, provincial, and federal regulations.
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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SAFETY DATA SHEET
Other disposal recommendations:
Section 14: TRANSPORT INFORMATION
14.1 UN NUMBER
14.2 UN PROPER SHIPPING NAME
14.3 TRANSPORT HAZARD CLASS (ES)
14.4 PACKING GROUP
14.5 ENVIRONMENTAL HAZARDS
Not available.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
DOT TDG
Not regulated. Not regulated.
DOT TDG
Not applicable. Not applicable.
DOT TDG
Not applicable. Not applicable.
DOT TDG
Not applicable. Not applicable.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE CHEMICAL
Canada: This product has been classified in accordance with the hazard criteria of the
Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations.
US: SDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012
Not available.
SARA Title III
Ingredient Section 302
(EHS) TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA RQ (lbs.)
Section
313
Calcium carbonate Not listed. Not listed. Not listed. Not listed. Asphalt Not listed. Not listed. Not listed. Not listed. Fuel oil, no. -2 Not listed. Not listed. Not listed. Not listed. Silica, crystalline, quartz Not listed. Not listed. Not listed. Not listed.
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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SAFETY DATA SHEET
California Proposition 65:
State Regulations
This product contains Crystalline Silica, Quartz and may also contain other chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.
Global Inventories: Ingredient
Calcium carbonate NDSL Yes. Asphalt DSL Yes. Fuel oil, no. -2 DSL Yes. Silica, crystalline, quartz DSL Yes.
NFPA National Fire Protection Association:
Health: Fire: Reactivity:
HMIS-Hazardous Materials Identification System
Health: Fire: Physical Hazard:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
CP65 California Proposition 65 OSHA (O) Occupational Safety and Health Administration. ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen.
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens.
Section 16: OTHER INFORMATION
Date of Preparation: Expiry Date: Version: Revision Date:
August 18, 2014 August 18, 2017
1.0
August 18, 2014
Canada
DSL/NDSL
USA
TSCA
1 1 0
1*
1 0
.
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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SAFETY DATA SHEET
Disclaimer: We believe the statements, technical information and recommendations contained herein
are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.
Prepared by:
Nexreg Compliance Inc. Phone: (519) 488-5126
Prepared for:
www.nexreg.com
Sakrete of North America
End of Safety Data Sheet
Trade Name: Sakrete All Weather Blacktop Patch Print date: 2014-08-18
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