Product Name:
Sakrete All Purpose Gravel
Sakrete Tube Sand
Product Code:
Not available.
Use:
Various.
Name/Address:
Sakrete of North America
28273
Telephone Number:
866-275-7383
Emergency Telephone
Number:
CHEMTREC 800-424-9300
INTERNATIONAL + 01-703-527-3887
Date of Preparation:
March 6, 2013 Rev October 15, 2015
Version #: 1.1
Hazard class
Specific target organ toxicity - Repeated expos ure 1
Acute toxicity 4 (Oral)
Hazard Pictogram:
Signal Word:
Danger
SAFETY DATA SHEET
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
Section 1: IDENTIFICATION
1.1 PRODUCT IDENTIFIER
Sakrete Commercial Sand Med
Sakrete Fine Plaster Sand
Sakrete Leveling Sand
Sakrete Mason Sand
Sakrete Multi Purpose Sand
Sakrete Natural Play Sand
Sakrete Paver Base
Sakrete Pool Filter Sand
Sakrete Traction Sand
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
1.4 EMERGENCY TELEPHONE NUMBER
2.1 CLASSIFICATION OF THE CHEMICAL
Carcinogenicity 1A
2.2 LABEL ELEMENTS
8201 Arrowridge Blvd.
Charlotte, NC
Section 2: HAZARD(S) IDENTIFICATION
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 1 of 10
Hazard Statement:
Causes damage to organs through prolonged or repeated
exposure. May cause cancer. Harmful if swallowed.
Prevention:
Do not breathe dust/fume/gas/mist/vapors/spray. Wash hands
protective gloves/protective clothing/eye protection/face protection.
Response:
If exposed or concerned: Get medical advice/attention. If
Get medical advice/attention if you feel unwell.
Storage:
Store locked up.
Disposal:
Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Hazards not otherwise
classified:
Not applicable.
This product is a hazardous chemical as defined by NOM-018-STPS-2000.
Ingredient
UN #
H / F/ R / *
CAS No
Wt. %
Silica, crystalline, quartz
Not available.
Not available.
14808-60-7
60 - 100
The exact percentage (concentration) of chemicals has been withheld as a trade secret in accordance
with paragraph (i) of §1910.1200.
* Per NOM-018-STPS-2000
Eye:
In case of contact, immediately flush eyes with plenty of water for at
medical attention immediately.
Skin:
In case of contact, immediately flush skin with plenty of water.
reuse. Call a physician if irritation develops and persists.
Inhalation:
If breathing is difficult, remove victim to fresh air and keep at rest in a
you feel unwell.
Ingestion:
If swallowed, do NOT induce vomiting unless directed to do so by
person. Get medical advice/attention.
2.3 ADDITIONAL INFORMATION
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 MIXTURES
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
SAFETY DATA SHEET
thoroughly after handling. Do not eat, drink or smoke when using
this product. Obtain special instructions before use. Do not handle
until all safety precautions have been read and understood. Wear
swallowed: Immediately call a poison center/doctor. Rinse mouth.
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
least 15 minutes. If easy to do, remove contact lenses, if worn. Get
Remove contaminated clothing and shoes. Wash clothing before
position comfortable for breathing. Get medical advice/attention if
medical personnel. Never give anything by mouth to an unconscious
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 2 of 10
Eye:
May cause eye irritation. Symptoms may include discomfort or pain,
swelling.
Skin:
May cause skin irritation. Symptoms may include redness, edema,
drying, defatting and cracking of the skin. Handling can cause dry skin.
Inhalation:
May cause respiratory tract irritation.
Ingestion:
Harmful if swallowed. May cause stomach distress, nausea or
vomiting.
Note to Physicians:
Symptoms may not appear immediately.
Specific Treatments:
In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Flammability:
Not flammable by WHMIS/OSHA criteria.
Suitable Extinguishing Media:
Treat for surrounding material.
Unsuitable Extinguishing Media:
Not available.
Products of Combustion:
May include, and are not limited to: oxides of carbon.
Explosion Data:
Sensitivity to Mechanical Impact: Not available.
Sensitivity to Static Discharge: Not available.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection
(SCBA).
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to
unnecessary and unprotected personnel.
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to
Protective Equipment (PPE).
Methods for Cleaning-Up:
Vacuum or sweep material and place in a disposal container.
SAFETY DATA SHEET
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
excess blinking and tear production, with possible redness and
4.3 INDICATION OF ANY IMMEDIATE ME DI CAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Section 5: FIRE-FIGHTING MEASURES
5.1 FLAMMABILITY
5.2 EXTINGUISHING MEDIA
5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
sewer or allow to enter waterways. Use appropriate Personal
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 3 of 10
Handling:
Avoid contact with skin and eyes. Do not swallow. Good
section 8)
General Hygiene Advice:
Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
Storage:
Keep out of the reach of children. Store in dust-tight, dry, labeled
sprinklers. (See section 10)
Occupational Exposure Limits
Ingredient
OSHA-PEL
ACGIH-TLV
Silica, crystalline, quartz
((10 mg/m3)/(%SiO2+2) TWA (resp))
((250)/(%SiO2+5) mppcf TWA (resp))
0.025 mg/m³
Engineering Controls:
Use ventilation adequate to keep exposures (airborne levels of dust,
fume, vapor, etc.) below recommended exposure limits.
Personal Protective Equipment:
Eye/Face Protection:
Wear approved eye (properly fitted dust- or splash-proof chemical safety
goggles) / face (face shield) protection.
Skin Protection:
Hand Protection:
Wear suitable waterproof gloves.
Body Protection:
Wear suitable waterproof protective clothing.
Respiratory Protection:
A NIOSH approved dust mask or filtering facepiece is recommended in
requirements found in OSHA’s respirator standard (29 CFR 1910.134)
SAFETY DATA SHEET
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
housekeeping is important to prevent accumulation of dust. Avoid
generating and breathing dust. The use of compressed air for
cleaning clothing, equipment, etc, is not recommended. Handle and
open container with care. When using do not eat or drink. (See
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
containers. Keep container s closed wh en not in use. A vo id an y dust
buildup by frequent cleaning and suitable construction of the storage
area. Do not store in an area equipped with emergency water
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
((30 mg/m3)/(%SiO2+2) TWA (total))
8.2 EXPOSURE CONTROLS
8.3 INDIVIDUAL PROTECTIVE MEASSURES
poorly ventilated areas or when permissible exposure limits may be
exceeded. Respirators should be selected by and used under the
direction of a trained health and safety professional following
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 4 of 10
and ANSI’s standard for respiratory protection (Z88.2).
General Health and
Handle according to established industrial hygiene and safety practices.
stored. Wash hands carefully before eating or smoking.
Appearance:
Powder, Granular, Pebble
Color:
Not available.
Odor:
Not available.
Odor Threshold:
Not available.
Physical State:
Solid.
pH:
Not available.
Melting Point/Freezing Point:
Not available.
Initial Boiling Point and Boiling Range:
Not available.
Flash Point:
Not available.
Evaporation Rate:
Not available.
Flammability:
Not Flammable.
Lower Flammability/Explosive Limit:
Not available.
Upper Flammability/Explosive Limit:
Not available.
Vapor Pressure:
Not available.
Vapor Density:
Not available.
Relative Density/Specific Gravity:
Not available.
Solubility:
Not available.
Partition coefficient: n-octanol/water:
Not available.
Auto-ignition Temperature:
Not available.
Decomposition Temperature:
Not available.
Viscosity:
Not available.
Percent Volatile, wt. %:
Not available.
VOC content, wt. %:
0%, Not applicable; 0 wt, Not applicable.
No dangerous reaction known under conditions of normal use.
SAFETY DATA SHEET
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
Safety Measures:
Do not eat, smoke or drink where material is handled, processed or
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 5 of 10
Stable under normal storage conditions. Keep dry in storage.
No dangerous reaction known under conditions of normal use.
Incompatible materials. Moisture.
Wet cement is alkaline and incompatible with acid, ammonium salts and aluminum metal.
May include, and are not limited to: oxides of carbon.
Likely Routes of Exposure:
Skin contact, skin absorption, eye contact, inhalation, and ingestion.
Symptoms related to physical/chemical/toxicological characteristics:
Eye:
May cause eye irritation. Symptoms may include discomfort or pain, excess
blinking and tear production, with possible redness and swelling.
Skin:
May cause skin irritation. Symptoms may include redness, edema, drying,
defatting and cracking of the skin. Handling can cause dry skin.
Ingestion:
Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Inhalation:
May cause respiratory tract irritation.
Acute Toxicity:
Ingredient
IDLH
LC50
LD50
Silica, crystalline, quartz
Ca [25 mg/m3 (cristobali te, t ridymite);
50 mg/m3 (quartz, t ri poli ) ]
Not available.
Oral 500 mg/kg, rat
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation)
LD50 (oral)
LD50 (dermal)
Not available.
500 mg/kg, rat
Not available.
Ingredient
Chemical Listed as Carcinogen or Potential Carcinogen
(NTP, IARC, OSHA, ACGIH, CP65)*
Silica, crystalline, quartz
G-A2, I-1, N-1, O, CP65
Skin Corrosion/Irritation:
Based on available data, the classification criteria are not met.
Serious Eye Damage/Irritation:
Based on available data, the classification criteria are not met.
Respiratory Sensitization:
Based on available data, the classification criteria are not met.
Skin Sensitization:
Based on available data, the classification criteria are not met.
STOT-Single Exposure:
Based on available data, the classification criteria are not met.
SAFETY DATA SHEET
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
10.2 CHEMICAL STABILITY
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
10.4 CONDITIONS TO AVOID
10.5 INCOMPATIBLE MATERIALS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 6 of 10
Chronic Health Effects:
Respirable crystalline silica in the form of quartz or cristobalite
exposure and the length of time (usually years) of exposure.
Carcinogenicity:
May cause cancer.
Germ Cell Mutagenicity:
Based on available data, the classification criteria are not met.
Reproductive Toxicity:
Developmental:
Based on available data, the classific ati on crit eria ar e not m et.
Teratogenicity:
Not hazardous by WHMIS/OSHA criteria.
Embryotoxicity:
Not hazardous by WHMIS/OSHA criteria.
Fertility:
Based on available data, the classific ati on crit eria ar e not m et.
STOT-Repeated Exposure:
Causes damage to organs through prolonged or repeated
exposure.
Aspiration Hazard:
Based on available data, the classific ati on crit eria ar e not met.
Toxicologically Synergistic
Materials:
Not available.
Other Information:
Not available.
Acute/Chronic Toxicity:
No ecological consideration when used according to directions.
and treatment plants is not considered environmentally harmful.
Not available.
Bioaccumulation:
Not available.
Not available.
Not available.
SAFETY DATA SHEET
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
from occupational sources is listed by the International Agency
for Research on Cancer (IARC) and National Toxicology
Program (NTP) as a lung carcinogen. Prolonged expo s ure to
respirable crystalline silica has been known to cause silicosis, a
lung disease, which may be disabling. While there may be a
factor of individual susceptibility to a given exposure to
respirable silica dust, the risk of contracting silicosis and the
severity of the disease is clearly related to the amount of dust
Section 12: ECOLOGICAL INFORMATION
12.1 ECOTOXICITY
Normal dilution of this product to drains, sewers, septic systems
12.2 PERSISTENCE AND DEGRADABILITY
12.3 BIOACCUMULATIVE POTENTIAL
12.4 MOBILITY IN SOIL
12.5 OTHER ADVERSE EFFECTS
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 7 of 10
Disposal Method:
This material must be disposed of in accordance with all
local, state, provincial, and federal regulations.
Other disposal recommendations:
Not available.
DOT
TDG
NOM-004-SCT2-1994
Not regulated.
Not regulated.
Not regulated.
DOT
TDG
NOM-004-SCT2-1994
Not applicable.
Not applicable.
Not applicable.
DOT
TDG
NOM-004-SCT2-1994
Not applicable.
Not applicable.
Not applicable.
DOT
TDG
NOM-004-SCT2-1994
Not applicable.
Not applicable.
Not applicable.
Not available.
Not available.
Do not handle until all safety precautions have been read and understood.
Canada: This product has been classified in accordance with the hazard criteria of the
Controlled Products Regula tions .
US: MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom
2012
Mexico: MSDS prepared pursuant to NOM-018-STPS-2000.
SAFETY DATA SHEET
Section 13: DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Section 14: TRANSPORT INFORMATION
14.1 UN NUMBER
14.2 UN PROPER SHIPPING NAME
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
14.3 TRANSPORT HAZARD CLASS (ES)
14.4 PACKING GROUP
14.5 ENVIRONMENTAL HAZARDS
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
14.7 SPECIAL PRECAUTIONS FOR USER
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICLA
Controlled Products Regulations and the MSDS contains all the information required by the
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 8 of 10
SARA Title III
Ingredient
Section 302
(EHS) TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA
RQ (lbs.)
Section 313
Silica, crystalline, quartz
Not listed.
Not listed.
Not listed.
Not listed.
State Regulations
California Proposition 65:
This product contains Crystalline Silica, Quartz and may also contain trace amounts of other
chemicals known to the State of California to cause cancer, birth defects or other reproductive harm.
Global Inventories
Ingredient
Canada
DSL/NDSL
USA
TSCA
Silica, crystalline, quartz
DSL
Yes.
NFPA - National Fire Protection Association:
Health:
2
Fire:
0
Reactivity:
0
HMIS - Hazardous Materials Identification System
Health:
2*
Fire:
0
Reactivity:
0
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
WHMIS Classification(s):
Class D2A – Carcinogenicity
Class D2A - Chronic Toxic Effects
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
SAFETY DATA SHEET
WHMIS Hazard Symbols:
Mexico Classification:
Blue = Health Red = Flammability Yellow = Reactivity White = Special
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 9 of 10
CP65
California Proposition 65
OSHA (O)
Occupational Safety and Health Administration.
ACGIH (G)
American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen.
A5 - Not suspected as a human carcinogen.
IARC (I)
International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans.
NTP (N)
National Toxicology Program.
1 - Known to be carcinogens.
2 - Reasonably anticipated to be carcinogens.
Date of Preparation:
October 15, 2015
Expiry Date:
October 15, 2018
Version:
1.1
Revision Date:
October 15, 2015
Disclaimer: We believe the statements, technical information and recommendations contained herein
and completeness of this information for the user’s own particular use.
Prepared by:
Nexreg Compliance Inc.
www.nexreg.com
Prepared for:
Sakrete of North America
SAFETY DATA SHEET
Conf orm s t o OSHA HazCom 2012, CPR & NOM-018-STPS-2000 Standards
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
A2 - Suspected human carcinogen.
A3 - Animal carcinogen.
A4 - Not classifiable as a human carcinogen.
2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in
humans and sufficient evidence of carcinogenicity in experimental animals.
2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in
humans in the absence of sufficient evidence of carcinogenicity in experimental animals.
3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
Section 16: OTHER INFORMATION
are reliable, but they are given without warranty or guarantee of any kind. The information contained in
this document applies to this specific material as supplied. It may not be valid for this material if it is used
in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability
Phone: (519) 488-5126
End of Safety Data Sheet
Trade Name: Sakrete Sands & Gravel Print date: 2015-10-15
Page 10 of 10
Loading...