Sakrete 60450027 User Manual

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Conforms to OSHA HazCom 2012 Standard
SAFETY DATA SHEET
1.1 PRODUCT IDENTIFIER
Product Name:
1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE
Use:
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET
Name/Address:
Sakrete Trowelable Crack Filler
Various.
Sakrete of North Carolina 8201 Arrowridge Blvd. Charlotte, NC
Telephone Number:
1.4 EMERGENCY TELEPHONE NUMBER
Emergency Telephone Number:
28273 866-725-7383
CHEMTREC 800-424-9300 INTERNATIONAL + 01-703-527-3887
Section 2: HAZARD(S) IDENTIFICATION
2.1 CLASSIFICATION OF THE CHEMICAL
Acute toxicity 4 (Oral) Skin sensitization 1 Carcinogenicity 1A Specific target organ toxicity - Repeated exposure 1
2.2 LABEL ELEMENTS
Hazard Pictogram:
Hazard class
Signal Word: Hazard Statement:
Danger Harmful if swallowed. May cause an allergic skin reaction. May
cause cancer. Causes damage to organs through prolonged or
Prevention:
repeated exposure. Wash hands thoroughly after handling. Do not eat, drink or smoke
when using this product. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe dust/fume/gas/mist/
Trade Name: Sakrete Trowelable Crack Filler Print date: 2014-07-17
vapors/spray.
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SAFETY DATA SHEET
Response:
If swallowed: Immediately call a poison center/doctor. Rinse mouth. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before
Storage: Disposal:
2.3 ADDITIONAL INFORMATION
reuse. If exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents and container in accordance with all local,
regional, national and international regulations.
Hazards not otherwise specified:
11.0 % of the mixture consists of ingredient(s) of unknown acute toxicity.
Not applicable.
Section 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 MIXTURES
Ingredient CAS No Wt. %
Silica, crystalline, quartz 14808-60-7 15 - 40 Asphalt 8052-42-4 15 - 40 Kaolin 1332-58-7 3 - 7 Mica 12001-26-2 1 - 5 Bentonite 1302-78-9 1 - 5 Aluminatesilicate 1327-36-2 1 - 5 Titanium dioxide 13463-67-7 0.1 - 1 Acetaldehyde 75-07-0 < 0.1 Ethyl acrylate 140-88-5 < 0.1
The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200.
Section 4: FIRST- AID MEASURES
4.1 DESCRIPTION OF THE FIRST AID MEASURE
Eye:
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get
Skin:
medical attention immediately. In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Wash clot hing before
Inhalation:
reuse. Call a physician if irritation develops and persists. If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing. Get medical advice/attention if
Ingestion:
you feel unwell. If swallowed, do NOT induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious person. Get medical advice/attention.
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED
Eye:
May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and
Skin:
Inhalation: Ingestion:
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED
Note to Physicians: Specific Treatments:
swelling. May cause skin irritation. Symptoms may include redness, drying,
defatting and cracking of the skin. May cause skin sensitization. May cause respiratory tract irritation. Harmful if swallowed. May cause stomach distress, nausea or vomiting.
Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice
immediately (show the label or SDS where possible).
Section 5: FIRE-FIGHTING MEASURES
5.1 EXTINGUISHING MEDIA
Suitable Extinguishing Media: Unsuitable Extinguishing Media:
5.2 SPECIAL HAZARDS ARISING FROM THE CHEMICAL
Products of Combustion:
5.3 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS
May include, and are not limited to: oxides of carbon.
Treat for surrounding material. Not available.
Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA).
Section 6: ACCIDENTAL RELEASE MEASURES
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES
Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP
Methods for Containment:
Contain spill, then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal
Methods for Cleaning-Up:
Protective Equipment (PPE). Scoop up material and place in a disposal container.
Section 7: HANDLING AND STORAGE
7.1 PRECAUTIONS FOR SAFE HANDLING
Handling:
Avoid contact with skin and eyes. Do not swallow. Avoid breathing vapour or mist. Handle and open container with care. When using do not eat or drink. Wash hands before eating, drinking, or smoking.
General Hygiene Advice:
(See section 8) Launder contaminated clothing before reuse. Wash hands before
eating, drinking, or smoking.
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SAFETY DATA SHEET
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES
Storage:
Keep out of the reach of children. Keep container tightly closed and in a well-ventilated place. (See section 10)
Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 CONTROL PARAMETERS
Exposure Guidelines
Occupational Exposure Limits
Ingredient OSHA-PEL ACGIH-TLV
)/(%SiO2+2) TWA (resp))
3
)/(%SiO2+2) TWA (total))
+5) mppcf TWA (resp)) 0.025 mg/m³
2
Silica, crystalline, quartz
((10 mg/m ((30 mg/m
((250)/(%SiO Asphalt 5 mg/m³ 0.5 mg/m³ (fume) Kaolin 15 mg/m3 2 mg/m3 Mica 20 mppcf 10 mg/m³ (total); 3 mg/m³ (resp) Bentonite Not available. Not available. Aluminatesilicate Not available. Not available. Titanium dioxide 15 mg/m3 (total dust) 10 mg/m³ Acetaldehyde 200 ppm Not available. Ethyl acrylate 5 ppm 5 ppm
8.2 EXPOSURE CONTROLS
Engineering Controls:
8.3 INDIVIDUAL PROTECTIVE MEASURES
Personal Protective Equipment:
Eye/Face Protection:
Skin Protection:
Hand Protection: Body Protection:
Respiratory Protection:
Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits.
Wear approved eye (properly fitted dust- or splash-proof chemical safety goggles) / face (face shield) protection.
Wear suitable waterproof gloves. Wear suitable waterproof protective clothing.
A NIOSH approved dust mask or filtering facepiece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a trained health and safety professional following requirements found in OSHA’s respirator standard (29 CFR 1910.134) and ANSI’s standard for
General Health and Safety Measures:
respiratory protection (Z88.2).
Handle according to established industrial hygiene and safety practices. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking.
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Color: Odor: Odor Threshold: Physical State: pH: Melting Point/Freezing Point: Initial Boiling Point and Boiling Range: Flash Point: Evaporation Rate: Flammability: Lower Flammability/Explosive Limit: Upper Flammability/Explosive Limit: Vapor Pressure: Vapor Density: Relative Density/Specific Gravity: Solubility: Partition coefficient: n-octanol/water: Auto-ignition Temperature: Decomposition Temperature: Viscosity:
Percent Volatile, wt. %: VOC content, wt. %:
Section 10: STABILITY AND REACTIVITY
10.1 REACTIVITY
No dangerous reaction known under conditions of normal use.
10.2 CHEMICAL STABILITY
Stable under normal storage conditions.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS
No dangerous reaction known under conditions of normal use.
10.4 CONDITIONS TO AVOID
Incompatible materials.
Paste. Not available. Not available. Not available. Paste. Not available. Not available. Not available. Not available. Not available. Not Flammable. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available. Not available.
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SAFETY DATA SHEET
10.5 INCOMPATIBLE MATERIALS
None known.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS
May include, and are not limited to: oxides of carbon.
Section 11: TOXICOLOGICAL INFORMATION
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS
Likely Routes of Exposure: Symptoms related to physical/chemical/toxicological characteristics:
Eye:
Skin:
Acute Toxicity:
Ingestion:
Inhalation:
Ingredient LC50 LD50
Skin contact, skin absorption, eye contact, inhalation, and ingestion.
May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness a nd swelling.
May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May cause skin sensitization.
Harmful if swallowed. May cause stomach distress, nausea or vomiting. May cause respiratory tract irritation.
Silica, crystalline, quartz Not available. Oral 500 mg/kg, rat Asphalt Not available.
Kaolin Not available. Not available. Mica Not available. Not available. Bentonite Not available. Oral >5000 mg/kg, rat Aluminatesilicate Not available. Not available.
Titanium dioxide Not available. Acetaldehyde Not available. Oral 1930 mg/kg, rat
Ethyl acrylate Inhalation 1414 ppm 4 h, rat
Calculated overall Chemical Acute Toxicity Values
LC50 (inhalation) LD50 (oral) LD50 (dermal)
23.3 mg/L 4 h, rat 1122.4 mg/kg, rat 4026.5 mg/kg, rabbit
Ingredient
Silica, crystalline, quartz G-A2, I-1, N-1, O, CP65 Asphalt G-A4, I-2B, N-1, O, CP65 Kaolin G-A4 Mica Not listed. Bentonite Not listed. Aluminatesilicate Not listed. Titanium dioxide G-A4, I-2B, O, CP65 Acetaldehyde G-A3, I-1, I-2B, N-2, CP65 Ethyl acrylate G-A4, I-2B, CP65
Oral >5000 mg/kg, rat
Dermal >2000 mg/kg, rabbit
Oral >10000 mg/kg, rat
Dermal >10000mg/kg, rabbit
Oral 800 mg/kg, rat
Dermal 500 µL/kg, rabbit
Chemical Listed as Carcinogen or
Potential Carcinogen
(NTP, IARC, OSHA, ACGIH, CP65)*
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SAFETY DATA SHEET
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11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE
Skin Corrosion/Irritation: Serious Eye Damage/Irritation:
Respiratory Sensitization: Skin Sensitization: STOT-Single Exposure: Chronic Health Effects:
Reproductive Toxicity:
Germ Cell Mutagenicity:
Carcinogenicity:
Developmental:
Fertility:
STOT-Repeated Exposure:
Aspiration Hazard:
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met. May cause an allergic skin reaction. Based on available data, the classification criteria are not met.
May cause cancer. This product is not classified as a mutagen.
Based on available data, the classification criteria are not met. Based on available data, the classification criteria are not met. Causes damage to organs through prolonged or repeated
exposure. Based on available data, the classification criteria are not met.
Toxicologically Synergistic Materials:
Other Information:
Not available. Not available.
Section 12: ECOLOGICAL INFORMATION
12.1 ECOTOXICITY
Acute/Chronic Toxicity:
No ecological consideration when used according to directions. Normal dilution of this product to drains, sewers, septic system s
12.2 PERSISTENCE AND DEGRADABILITY
Not available.
12.3 BIOACCUMULATIVE POTENTIAL
Bioaccumulation:
12.4 MOBILITY IN SOIL
Not available.
12.5 OTHER ADVERSE EFFECTS
Not available.
and treatment plants is not considered environmentally harmful.
Not available.
Section 13: DISPOSAL CONSIDERATIONS
13.1 WASTE TREATMENT METHODS
Disposal Method:
Other disposal recommendations:
This material must be disposed of in accordance with all local, state, provincial, and federal regulations.
Not available.
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SAFETY DATA SHEET
Conforms to OSHA HazCom 2012 Standard
Section 14: TRANSPORT INFORMATION
14.1 UN NUMBER
Not regulated.
14.2 UN PROPER SHIPPING NAME
Not applicable.
14.3 TRANSPORT HAZARD CLASS(ES)
Not applicable.
14.4 PACKING GROUP
Not applicable.
14.5 ENVIRONMENTAL HAZARDS
Not available.
14.6 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE
Not available.
14.7 SPECIAL PRECAUTIONS FOR USER
Do not handle until all safety precautions have been read and understood.
Section 15: REGULATORY INFORMATION
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE
CHEMICAL
MSDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012
SARA Title III
Ingredient Section 302 (EHS)
TPQ (lbs.)
Section 304
EHS RQ (lbs.)
CERCLA RQ (lbs.) Section 313
Silica, crystalline, quartz Not listed. Not listed. Not listed. Not listed. Asphalt Not listed. Not listed. Not listed. Not listed. Kaolin Not listed. Not listed. Not listed. Not listed. Mica Not listed. Not listed. Not listed. Not listed. Bentonite Not listed. Not listed. Not listed. Not listed. Aluminatesilicate Not listed. Not listed. Not listed. Not listed. Titanium dioxide Not listed. Not listed. Not listed. Not listed. Acetaldehyde Not listed. Not listed. 1,000 313 Ethyl acrylate Not listed. Not listed. 1,000 313
California Proposition 65:
This product contains chemicals known to the State of California to cause canc er.
Trade Name: Sakrete Trowelable Crack Filler Print date: 2014-07-17
State Regulations
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SAFETY DATA SHEET
Global Inventories: Ingredient USA
Silica, crystalline, quartz Yes. Asphalt Yes. Kaolin Yes. Mica No. Bentonite Yes. Aluminatesilicate Yes. Titanium dioxide Yes. Acetaldehyde Yes. Ethyl acrylate Yes.
NFPA-National Fire Protection Association:
Health: Fire: Reactivity:
Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme
SOURCE AGENCY CARCINOGEN CLASSIFICATIONS:
OSHA (O) Occupational Safety and Health Administration. ACGIH (G) American Conference of Governmental Industrial Hygienists.
A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen.
IARC (I) International Agency for Research on Cancer.
1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans.
4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans
NTP (N) National Toxicology Program.
1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens.
Section 16: OTHER INFORMATION
Date of Preparation: Version: Revision Date:
March 15, 2013
1.0 July 17, 2014
Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for the user’s own particular use.
TSCA
2 1 0
.
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Prepared by:
Prepared for:
Conforms to OSHA HazCom 2012 Standard
SAFETY DATA SHEET
Nexreg Compliance Inc. Phone: (519) 488-5126
www.nexreg.com
Sakrete of North America
End of Safety Data Sheet
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