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SAFETY DATA SHEET
5973
Safer Brand Critter Ridder Deer & Rabbit Repellent
Size
1 gal
Woodstream Corporation
(800) 424-9300
Regulatory Licenses
EPA Reg. No. 50932-15
Issuing Date
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The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and
all information in this SDS was provided by the supplier or was reproduced from publically available regulatory data sources. UL makes no representations
or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information
or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved.
_____________________________________________________________________________________________
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product identifier
Product Name
Other means of identification
Synonyms
Recommended use of the chemical and restrictions on use
Recommended Use
Uses advised against
Details of the supplier of the safety data sheet
Supplier Name
Supplier Address
Supplier Phone Number
Supplier Email
Emergency telephone number
None
Repellant, Pest, Non-Aerosol
It is a violation of Federal law to use this product in a manner inconsistent with its labeling.
Woodstream Corp.
69 North Locust St.
Lititz
PA
17543
US
Phone:(717) 626-2125
Fax:(717) 626-1912
Contact Phone(800) 800-1819
[email protected]
2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
GHS Label elements, including precautionary statements
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Emergency Overview
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Signal word Warning
Hazard Statements
Causes skin irritation
Causes serious eye irritation
Appearance Yellow
Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Wear eye/face protection
Precautionary Statements - Response
Specific treatment (see supplemental first aid instructions on this label)
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Skin
IF ON SKIN: Wash with plenty of soap and water
If skin irritation occurs: Get medical advice/attention
Take off contaminated clothing and wash before reuse
Precautionary Statements - Storage
None
Precautionary Statements - Disposal
None
Hazards not otherwise classified (HNOC)
Not applicable
Physical State Viscous liquid Liquid Odor Slight
Unknown Toxicity
42.15% of the mixture consists of ingredient(s) of unknown toxicity
Other information
No information available
Interactions with Other Chemicals
No information available.
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3. COMPOSITION/INFORMATION ON INGREDIENTS
.
Chemical Name CAS No Weight-% Trade Secret
Acetic acid 64-19-7
*The exact percentage (concentration) of composition has been withheld as a trade secret
1 - 5
*
4. FIRST AID MEASURES
First aid measures
General Advice
Eye Contact
Show this safety data sheet to the doctor in attendance.
Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Remove contact lenses, if present and
easy to do. Continue rinsing. Get medical attention if irritation develops and
persists. Do not rub affected area.
Skin Contact
Wash off immediately with soap and plenty of water for at least 15 minutes. Get
medical attention if irritation develops and persists.
Inhalation
Ingestion
Remove to fresh air. Get medical attention immediately if symptoms occur.
Rinse mouth immediately and drink plenty of water. Never give anything by mouth
to an unconscious person. Do NOT induce vomiting. Call a physician.
Self-protection of the first aider
Avoid contact with skin, eyes or clothing. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).
Most important symptoms and effects, both acute and delayed
Most Important Symptoms and
Burning sensation.
Effects
Indication of any immediate medical attention and special treatment needed
Notes to Physician
Treat symptomatically.
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5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from the Chemical
No information available.
Uniform Fire Code
Hazardous Combustion Products
Carbon oxides.
Explosion Data
Sensitivity to Mechanical Impact
Sensitivity to Static Discharge
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
Irritant: Liquid
Combustible Liquid: III-B
No.
No.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions
Other Information
Environmental Precautions
Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal
protective equipment as required.
Refer to protective measures listed in Sections 7 and 8.
Environmental Precautions
Methods and material for containment and cleaning up
Methods for Containment
Methods for cleaning up
Refer to protective measures listed in Sections 7 and 8. Prevent further leakage or spillage
if safe to do so.
Prevent further leakage or spillage if safe to do so.
Soak up with inert absorbent material. Pick up and transfer to properly labeled containers.
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STORAGE AND DISPOSAL
PESTICIDE STORAGE: Store only in a cool, dry area inaccessible to children and pets. Protect from freezing and heat. Keep
container tightly closed to prevent evaporation.
PESTICIDE DISPOSAL: Wastes resulting from use of this product may be disposed of on site or at an approved waste disposal
facility.
CONTAINER HANDLING: Non-refillable container. Do not reuse or refill this container. If Empty: Place in trash or offer for
recycling if available. If Partly Filled: Contact your local solid waste agency for disposal instructions. Never place unused product
down any indoor or outdoor drain.
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7. HANDLING AND STORAGE
Precautions for safe handling
Handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Do not eat, drink or smoke when using this product. Take off
contaminated clothing and wash before reuse.
Conditions for safe storage, including any incompatibilities
Storage
Incompatible Products
Keep containers tightly closed in a dry, cool and well-ventilated place.
Strong acids. Strong oxidizing agents. Strong bases.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Acetic acid
64-19-7
ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and Health
Administration - Permissible Exposure Limits Immediately Dangerous to Life or Health
Other Exposure Guidelines
Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962
(11th Cir., 1992) See section 15 for national exposure control parameters
STEL = 15 ppm
TWA: 10 ppm
TWA: 10 ppm
TWA: 25 mg/m
(vacated) TWA: 10 ppm
(vacated) TWA: 25 mg/m
3
IDLH: 50 ppm
TWA: 10 ppm
3
TWA: 25 mg/m
STEL: 15 ppm
STEL: 37 mg/m
3
3
Appropriate engineering controls
Engineering Measures
Showers
Eyewash stations
Ventilation systems
Individual protection measures, such as personal protective equipment
Eye/Face Protection
If splashes are likely to occur:. Wear safety glasses with side shields (or goggles). None
required for consumer use.
Skin and Body Protection
Respiratory Protection
Wear protective gloves and protective clothing. Long sleeved clothing. Impervious gloves.
No protective equipment is needed under normal use conditions. If exposure limits are
exceeded or irritation is experienced, ventilation and evacuation may be required.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with
skin, eyes or clothing. Wear suitable gloves and eye/face protection. Do not eat, drink or
smoke when using this product.
9. PHYSICAL AND CHEMICAL PROPERTIES
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Orange
1.029
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Physical and Chemical Properties
Physical State
Appearance
Color
Property
pH
Melting / freezing point
Boiling point / boiling range
Flash Point
Evaporation Rate
Flammability (solid, gas)
Flammability Limit in Air
Upper flammability limit
Lower flammability limit
Vapor pressure
Vapor density
Specific Gravity
Water Solubility
Solubility in other solvents
Partition coefficient: n-octanol/water
Autoignition temperature
Decomposition temperature
Kinematic viscosity
Dynamic viscosity
Explosive properties
Oxidizing Properties
Other Information
Viscous liquid, Liquid
Yellow
No information available
Values Remarks Method
4.6 None known
No data available None known
No data available None known
148 C / 298 F None known
No data available None known
No data available None known
No data available
No data available
No data available None known
No data available None known
No data available None known
Emulsifies None known
No data available None known
No data available None known
No data available None known
No data available None known
No data available None known
1158 None known
No data available
No data available
Odor
Odor Threshold
Slight
No information available
Softening Point
VOC Content (%)
Particle Size
Particle Size Distribution
No data available
No data available
No data available
10. STABILITY AND REACTIVITY
Reactivity
No data available.
Chemical stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization
Hazardous polymerization does not occur.
Conditions to avoid
None known based on information supplied.
Incompatible materials
Strong acids. Strong oxidizing agents. Strong bases.
Hazardous Decomposition Products
Carbon oxides.
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Inhalation
Eye Contact
Skin Contact
Ingestion
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Acetic acid
64-19-7
Information on toxicological effects
Symptoms
.
Specific test data for the substance or mixture is not available. May cause irritation of
respiratory tract.
Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. Irritating to eyes. May cause redness, itching, and pain. May cause
temporary eye irritation.
Specific test data for the substance or mixture is not available. Expected to be an irritant
based on components. Irritating to skin. Prolonged contact may cause redness and
irritation.
Specific test data for the substance or mixture is not available. Ingestion may cause
irritation to mucous membranes. Ingestion may cause gastrointestinal irritation, nausea,
vomiting and diarrhea.
= 3310 mg/kg ( Rat ) = 1060 µL/kg ( Rabbit ) = 11.4 mg/L ( Rat ) 4 h
Erythema (skin redness). May cause redness and tearing of the eyes.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization
Mutagenic Effects
Carcinogenicity
Reproductive Toxicity
STOT - single exposure
STOT - repeated exposure
Chronic Toxicity
Target Organ Effects
Aspiration Hazard
Numerical measures of toxicity Product Information
The following values are calculated based on chapter 3.1 of the GHS document
No information available.
No information available.
Contains no ingredient listed as a carcinogen.
No information available.
No information available.
No information available.
No known effect based on information supplied. Carcinogenic potential is unknown.
Respiratory system. Eyes. Skin. Teeth. Blood.
No information available.
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ATEmix (dermal)
44,794.35 mg/kg (ATE)
ATEmix (inhalation-dust/mist)
461.20 mg/l
12. ECOLOGICAL INFORMATION
Ecotoxicity
The environmental impact of this product has not been fully investigated.
Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to
Acetic acid
64-19-7
96h LC50: = 79 mg/L
(Pimephales promelas) 96h
LC50: = 75 mg/L (Lepomis
macrochirus)
EC50 = 8.8 mg/L 15 min
EC50 = 8.8 mg/L 25 min
EC50 = 8.8 mg/L 5 min
Persistence and Degradability
No information available.
Bioaccumulation
Chemical Name Log Pow
Acetic acid
64-19-7
Other adverse effects
No information available.
13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Disposal methods
This material, as supplied, is not a hazardous waste according to Federal regulations (40
CFR 261). This material could become a hazardous waste if it is mixed with or otherwise
comes in contact with a hazardous waste, if chemical additions are made to this material, or
if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether
the altered material is a hazardous waste. Consult the appropriate state, regional, or local
regulations for additional requirements.
Microorganisms
-0.31
Daphnia Magna (Water
Flea)
48h EC50: = 65 mg/L 24h
EC50: = 47 mg/L
Contaminated Packaging
Dispose of contents/containers in accordance with local regulations.
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name
Acetic acid
64-19-7
DOT
Proper Shipping Name
Hazard Class
NOT REGULATED
NON REGULATED
N/A
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California Hazardous Waste
Toxic
Corrosive
Ignitable
14. TRANSPORT INFORMATION
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TDG
MEX
ICAO
IATA
Proper Shipping Name
Hazard Class
IMDG/IMO
Hazard Class
RID
ADR
ADN
Not regulated
Not regulated
Not regulated
Not regulated
NON REGULATED
N/A
Not regulated
N/A
Not regulated
Not regulated
Not regulated
15. REGULATORY INFORMATION
International Inventories
TSCA Complies
DSL All components are listed either on the DSL or NDSL.
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
US Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden release of pressure hazard
Reactive Hazard
Yes
No
No
No
No
CWA (Clean Water Act)
This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21
and 40 CFR 122.42)
Chemical Name CWA - Reportable
Acetic acid
64-19-7
Quantities
5000 lb X
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
CERCLA
This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)
Chemical Name Hazardous Substances RQs Extremely Hazardous Substances
Acetic acid
64-19-7
5000 lb
RQs
RQ 2270 kg final RQ
RQ
RQ 5000 lb final RQ
US State Regulations
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This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements
under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data
sheets and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced
below. The pesticide label also includes other important information, including directions for use.
Pesticide label signal word: CAUTION
Precautionary Statements:
Causes moderate eye irritation. Avoid contact with skin, eyes, or clothing. Remove contaminated clothing and wash before reuse.
Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum or using tobacco. Prolonged or
frequently repeated skin contact may cause allergic reactions in some individuals.
Environmental Hazards:
For terrestrial uses: Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high
water mark. Do not contaminate water when disposing of equipment washwater or rinsate.
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California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
.
Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois
Acetic acid
64-19-7
X X X X
International Regulations
Mexico
National occupational exposure limits
Component Carcinogen Status Exposure Limits
Acetic acid
64-19-7 ( 1 - 5 )
Mexico - Occupational Exposure Limits - Carcinogens
Canada
WHMIS Hazard Class
D2B - Toxic materials
Mexico: TWA 10 ppm
Mexico: TWA 25 mg/m
Mexico: STEL 15 ppm
Mexico: STEL 37 mg/m
3
3
16. OTHER INFORMATION
NFPA Health Hazards 2 Flammability 1 Instability 0 Physical and
Chemical Hazards -
HMIS Health Hazards 2
Prepared By
Product Stewardship
Flammability 1
23 British American Blvd.
Latham, NY 12110
1-800-572-6501
Revision Date
Revision Note
27-Feb-2015
No information available
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text
End of Safety Data Sheet
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Physical Hazard 0 Personal Protection
X
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