Date Printed: 3/24/2015
Safety Data Sheet
1. Identification
Page 1 / 7
* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: V2116838 Supercedes Date: New SDS
Product Use/Class: Topcoat/Aerosol
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
ROHPER LSPR 6PK GLOSS HIGH TMP
ALUMINUM
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 3/24/2015
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Extremely flammable liquid and vapor. Vapors may cause flash fire or explosion. Harmful if inhaled.
May affect the brain or nervous system causing dizziness, headache or nausea. Contents Under Pressure. May cause eye, skin,
or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Harmful if swallowed. Causes eye
irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye,
Skin, Nose, and Throat Irritation.
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
81% of the mixture consists of ingredient(s) of unknown acute toxicity
GHS HAZARD STATEMENTS
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Flammable Liquid, category 1 H224 Extremely flammable liquid and vapour.
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Eye Irritation, category 2B H320 Causes eye irritation.
Flammable Aerosol, category 1 H280 Contains gas under pressure; may explode if heated
Date Printed: 3/24/2015
Page 2 / 7
Germ Cell Mutagenicity, category 1B H340 May cause genetic defects. Classified as mutagenic Category 1 if one
ingredient is present at or above 0.1%. Applies to liquids, solids (w/w units)
and gases (v/v). The substance may also have its own exposure limit.
Routes of exposure are dependent on ingredient form.
Carcinogenicity, category 1A H350 May cause cancer. Classified as carcinogenic Category 1 on the basis of
epidemiological and/or animal data. Mixtures are classified as carcinogenic
when at least 1 ingredient has been classified as carcinogenic and is present
at 0.1% or above Routes of exposure are dependant on ingredient form.May
cause cancer <state route of exposure if it is conclusively proven that no
other routes of exposure cause the hazard>.
GHS PRECAUTIONARY STATEMENTS
P211 Do not spray on an open flame or other ignition source.
P220 Keep/Store away from clothing/…/combustible materials.
P235 Keep cool.
P251 Pressurized container: Do not pierce or burn, even after use.
P375 Fight fire remotely due to the risk of explosion.
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to …
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P201 Obtain special instructions before use.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
Date Printed: 3/24/2015
100-41-4
7429-90-5
108-67-8
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chem ical Name CAS-No. Wt.%
Range
GHS Sym bols
Page 3 / 7
GHS Statements
Acetone
Liquefied Petroleum Gas
Xylene (mixed isomers)
Solvent Naphtha, Light Aromatic
1,2,4-Trimethylbenzene
Hydrous Magnesium Silicate
Ethylbenzene
Aluminum Flake
1,3,5-Trimethylbenzene
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
67-64-1
68476-86-8
1330-20-7
64742-95-6
95-63-6
25-50
25-50
2.5-10
2.5-10
2.5-10
2.5-1014807-96-6
1.0-2.5
1.0-2.5
1.0-2.5
GHS02-GHS07 H225-336-319
GHS08 H340-350
GHS02-GHS07 H226-312-332-315
GHS08 H340-350
GHS02-GHS07 H226-335-332-315-319
GHS02-GHS07
GHS02
GHS02-GHS07
H225-332
H228-261
H226-335
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the
area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20 °. F. - EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam.
Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to
a source of ignition and flash back. Isolate from heat, electrical equipment, sparks and open flame. Perforation of the pressurized
container may cause bursting of the can. No unusual fire or explosion hazards noted. Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Full protective equipment including self-contained breathing apparatus should be used.
Evacuate area and fight fire from a safe distance. Water may be used to cool closed containers to prevent pressure buildup and
possible autoignition or explosion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel.
Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to
local, state (provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and
remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state,
and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
Date Printed: 3/24/2015
Page 4 / 7
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Contents under
pressure. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class I
flammable liquids. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign materials.
Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep away from heat, sparks, flame and sources
of ignition. Avoid excess heat.
8. Exposure Controls/Personal Protection
Chem ical Name CAS-No.
Acetone 67-64-1 50.0 500 ppm 750 ppm 1000 ppm N.E.
Liquefied Petroleum Gas 68476-86-8 30.0 N.E. N.E. N.E. N.E.
Xylene (mixed isomers) 1330-20-7 10.0 100 ppm 150 ppm 100 ppm N.E.
Solvent Naphtha, Light Aromatic 64742-95-6 5.0 N.E. N.E. N.E. N.E.
1,2,4-Trimethylbenzene 95-63-6 5.0
Hydrous Magnesium Silicate 14807-96-6 5.0
Ethylbenzene 100-41-4 5.0 20 ppm 125 ppm 100 ppm N.E.
Aluminum Flake 7429-90-5 5.0 1 mg/m3 N.E.
1,3,5-Trimethylbenzene 108-67-8 5.0 25 ppm N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
25 ppm (NIOSH
REL)
2 mg/m3
(Respirable Dust)
ACGIH TLV-
STE L
N.E. N.E. N.E.
N.E.
OSHA PEL-TWA
20 mppcf (Mineral
Dust <1% Quartz)
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use explosion-proof ventilation equipment. Provide general dilution of local exhaust ventilation in
volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors
and windows to achieve cross-ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control
airborne levels below recommended exposure limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with
organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to
exceed exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin
protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flamm ability:
Evaporation Rate:
Vapor Density:
Aerosolized Mist
Solvent Like
0.750
N.D.
Slight
No Information
-34 - 999
Does not Support Combustion
Faster than Ether
Heavier than Air
(See "Other information" Section for abbreviation legend)
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-
octanol/water:
Explosive Lim its, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.A.
N.D.
No Information
0.9 - 13.0
>93
No Information
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Flammable hydrogen gas will evolve when product comes in contact with water or damp air. Heat will be
generated. The amount of heat generated will depend upon the volume of material in contact. Avoid temperatures above 120 ° F.
Avoid contact with strong acid and strong bases. Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
Date Printed: 3/24/2015
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
Page 5 / 7
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. High
vapor concentrations are irritating to the eyes, nose, throat and lungs. Harmful if inhaled. Avoid breathing fumes, spray, vapors, or
mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. May cause central nervous system disorder (e.g., narcosis involving a loss of
coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage. High concentrations may lead
to central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Derm al LD50 Vapor LC50
1330-20-7 Xylene (mixed isomers) 4300 mg/kg Rat N.I. 47635 mg/L Rat
64742-95-6 Solvent Naphtha, Light Aromatic N.I. >2000 mg/kg Rabbit N.I.
95-63-6 1,2,4-Trimethylbenzene 3280 mg/kg Rat >3160 mg/kg Rabbit N.I.
100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not
allow to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name:
Hazard Class: N.A. 2.1 2.1 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Lim ited Quantity: Yes Yes Yes Yes
Paint Products in
Limited Quantities
Aerosols Aerosols
Paint Products in
Limited Quantities
15. Regulatory Information
Date Printed: 3/24/2015
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Pressure Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Page 6 / 7
Chemical Name
Xylene (mixed isomers) 1330-20-7
1,2,4-Trimethylbenzene 95-63-6
Ethylbenzene 100-41-4
Aluminum Flake 7429-90-5
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:
No TSCA components exist in this product.
CALIFORNIA PROPOSITION 65:
WARNING: This product contains a substance known to the State of California to cause cancer.
Chemical Name
Ethylbenzene
CAS-No.
100-41-4
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
WARNING: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
Chemical Name
Toluene
CAS-No.
108-88-3
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Date Printed: 3/24/2015
16. Other Information
HMIS RATINGS
Health: 2* Flamm ability: 4 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: AB5 D2A
NFPA RATINGS
Health: 2 Flammability: 4 Instability 0
Page 7 / 7
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
3/24/2015
No Information
578
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H228 Flammable solid.
H261 In contact with water releases flammable gases.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H340 May cause genetic defects <state route of exposure if it is conclusively proven that no other routes of
exposure cause the hazard>.
H350 May cause cancer <state route of exposure if it is conclusively proven that no other routes of exposure
cause the hazard>.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS07
GHS08
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred
by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all
applicable international, federal, state, and local laws and regulations.
Loading...