Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye burns. Causes skin irritation. May cause allergic skin reaction. May
cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Causes severe skin and
eye burns. Causes eye irritation. Vapors extremely irritating to eyes and respiratory tract. Use ventilation necessary to keep
exposures below recommended exposure limits, if any. Avoid contact with eyes, skin and clothing.
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
34% of the mixture consists of ingredient(s) of unknown acute toxicity
GHS HAZARD STATEMENTS
Acute Toxicity, Oral, category 4H302Harmful if swallowed.
Acute Toxicity, Dermal, category 4H312Harmful in contact with skin.
Acute Toxicity, Dermal, category 5H313May be harmful in contact with skin.
Skin Irritation, category 2H315Causes skin irritation.
Eye Irritation, category 2H319Causes serious eye irritation.
Acute Toxicity, Inhalation, category 3H331Toxic if inhaled.
Corrosive to Metals, category 1H290May be corrosive to metals.
Aspiration Hazard, category 2H305May be harmful if swallowed and enters airways.
Skin Corrosion, category 1H314Causes severe skin burns and eye damage.
Eye Irritation, category 2BH320Causes eye irritation.
Acute Toxicity, Dermal, category 1H310Fatal in contact with skin.
Acute Toxicity, Inhalation, category 4H332Harmful if inhaled.
Skin Corrosion, category 1H314Causes severe skin burns and eye damage.
GHS PRECAUTIONARY STATEMENTS
Date Printed: 9/12/2014
100-51-6
1761-71-3
P102Keep out of reach of children.
P103Read label before use.
P202Do not handle until all safety precautions have been read and understood.
P234Keep only in original container.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P262Do not get in eyes, on skin, or on clothing.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P281Use personal protective equipment as required.
P285In case of inadequate ventilation wear respiratory protection.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P351Rinse cautiously with water for several minutes.
P360Rinse immediately contaminated clothing and skin with plenty of water before removing
clothes.
P361Remove/Take off immediately all contaminated clothing.
P374Fight fire with normal precautions from a reasonable distance.
P402Store in a dry place.
P406Store in corrosive resistant/… container with a resistant inner liner.
P501Dispose of contents/container to …
P322Specific measures (see … on this label).
P363Wash contaminated clothing before reuse.
P301+P312IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352IF ON SKIN: Wash with plenty of soap and water.
P321Specific treatment (see … on this label).
P352Wash with plenty of soap and water.
P362Take off contaminated clothing and wash before reuse.
P332+P313If skin irritation occurs: Get medical advice/attention.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313If eye irritation persists: Get medical advice/attention.
P311Call a POISON CENTER or doctor/physician.
P304+P340IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P405Store locked up.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P390Absorb spillage to prevent material damage.
P310Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P302+P350IF ON SKIN: Gently wash with plenty of soap and water.
Page 2 / 6
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical NameCAS-No.Wt.%
Range
Benzyl Alcohol
4,4'-Methylene-bis-Cyclohexylamine
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
25-50
25-50
GHS Symbols
GHS06
GHS07
4. First-aid Measures
GHS Statements
H302-310-331
H302
Date Printed: 9/12/2014
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Remove contaminated clothing. Wash skin with soap and water. Get medical attention. Wash skin
with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. Immediately flush skin
with plenty of water for at least 15 minutes while removing clothing. Get medical attention immediately. Wash clothing separately
before reuse. Destroy contaminated shoes.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk.
Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat
symptomatically and supportively. Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or
Physician immediately.
Page 3 / 6
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustion generates toxic fumes of carbon monoxide, carbon dioxide and other
gases. No unusual fire or explosion hazards noted. Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. Containers can rupture and release
highly toxic material if exposed to heat. Substance is non-combustible but reacts with many metals to form explosive hydrogen gas.
Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Avoid
runoff into sewers and waterways. Provide ventilation and approach spill from upwind using proper personal protective equipment as
indicated in Section 8. Carefully neutralize spill with sodium bicarbonate (NaHCO3). Dispose of according to local, state (provincial)
and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Use only with adequate ventilation. Avoid prolonged or repeated contact with skin.
Wash hands before eating. Remove contaminated clothing and launder before reuse. Follow all MSDS/label precautions even after
container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin
and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Store in a dry, well
ventilated place. Keep container tightly closed when not in use.
8. Exposure Controls/Personal Protection
Chemical NameCAS-No.
Benzyl Alcohol100-51-645.0
4,4'-Methylene-bisCyclohexylamine
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below
acceptable limits.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or
Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
1761-71-335.0N.E.N.E.N.E.N.E.
Weight %
Less Than
ACGIH TLV-
TWA
10 ppm (AIHA
WEEL)
ACGIH TLV-
STEL
N.E.N.E.N.E.
OSHA PEL-TWA
OSHA PEL-
CEILING
Date Printed: 9/12/2014
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Page 4 / 6
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
CONDITIONS TO AVOID: Avoid all possible sources of ignition. Avoid contact with strong acid and strong bases. Avoid contact with
metals.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Product slowly corrodes copper,
aluminum,zinc, and galvanized surfaces
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Decomposition produces hydrogen chloride, chlorine and hydrogen gases.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye burns. Substance causes severe eye irritation. Injury may be
permanent.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Contact causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material. Severely irritating; may cause permanent skin damage.
EFFECTS OF OVEREXPOSURE - INHALATION: High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or
mist.
EFFECTS OF OVEREXPOSURE - INGESTION: Can burn mouth, throat and stomach. Aspiration hazard if swallowed; can enter
lungs and cause damage. Corrosive and may cause severe and permanent damage to mouth, throat and stomach. Substance may
be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: High concentrations may lead to central nervous system effects
(drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Repeated exposure to low concentrations
of HCl vapor or mist may cause bleeding of nose and gums.
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Reactive Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA components exist in this product.
Inventory Information
CountryValue
USA (TSCA)No Information
Canada (DSL)No Information
Mexico(INSQ)No Information
Europe (EINECS)No Information
Japan (ENCS)No Information
Philippines (PICCS)No Information
China (IECSC)No Information
Australia (AICS)No Information
Korea (KECI)No Information
New Zealand (NZIOC)No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
No Proposition 65 Carcinogens exist in this product.
Date Printed: 9/12/2014
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/12/2014
No Information
330
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302Harmful if swallowed.
H310Fatal in contact with skin.
H331Toxic if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS06
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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