Rust-Oleum AS6582425 User Manual

Date Printed: 9/12/2014
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: AS 6500 System Silver Gray Revision Date: 9/12/2014
Product Identifier: AS6582425 Supercedes Date: New SDS
Product Use/Class: Anti Slip Floor Coating/Epoxy
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Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
2. Hazard Identification
EMERGENCY OVERVIEW: May cause allergic skin reaction; effects may be permanent. KEEP OUT OF REACH OF CHILDREN.
Causes skin irritation. Harmful to aquatic life with long lasting effects. Causes Serious Eye Irritation. Harmful if inhaled. Causes eye irritation. May cause eye, skin, or respiratory tract irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any.
Classification
Symbol(s) of Product
Signal Word
Warning

GHS HAZARD STATEMENTS

Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Skin Irritation, category 3 H316 Causes mild skin irritation. Eye Irritation, category 2B H320 Causes eye irritation.

GHS PRECAUTIONARY STATEMENTS

P102 Keep out of reach of children. P103 Read label before use. P202 Do not handle until all safety precautions have been read and understood. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area.
Date Printed: 9/12/2014
1344-28-1
25068-38-6
14808-60-7
13463-67-7
P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P335 Brush off loose particles from skin. P351 Rinse cautiously with water for several minutes. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P321 Specific treatment (see … on this label). P352 Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
GHS Symbols
GHS Statements
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Aluminum Oxide Bisphenol A Epoxy Resin Crystalline Silica Titanium Dioxide
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
25-50 10-25 10-25
2.5-10
GHS07
H302
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
FIRST AID - INHALATION: If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately. Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation.
FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, rinse mouth with water. If feeling unwell, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of steam. Isolate from heat, electrical equipment, sparks and open flame. No unusual fire or explosion hazards noted. Keep containers tightly closed. FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F.
SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. Water may be used to cool closed containers to prevent buildup of steam. If water is used, fog nozzles are preferred.
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. Do not incinerate closed containers
6. Accidental Release Measures
Date Printed: 9/12/2014
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7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only in a well-ventilated area. Use only with adequate ventilation. Avoid prolonged or repeated contact with skin. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep container closed when not in use. Store in a dry, well ventilated place. Keep container tightly closed when not in use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Aluminum Oxide 1344-28-1 35.0
Bisphenol A Epoxy Resin 25068-38-6 20.0 N.E. N.E. N.E. N.E.
Crystalline Silica 14808-60-7 20.0
Titanium Dioxide 13463-67-7 5.0 10 mg/m3 N.E.
Weight %
Less Than
ACGIH TLV-
TWA
1 mg/m3
[Respirable]
0.025 mg/m3
[Respirable Dust]
ACGIH TLV-
STEL
N.E.
N.E.
OSHA PEL-TWA
5 mg/m3
[Respirable]
0.1 mg/m3
[Respirable Dust]
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
N.E.
N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation.
RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
9. Physical and Chemical Properties
Appearance: Odor: Relative Density: Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
Liquid None
2.245 N.D. Slight No Information 300 - 400 Does not Support Combustion Slower than Ether Heavier than Air
(See "Other information" Section for abbreviation legend)
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
Liquid N.E. N.A. N.D.
No Information
N.A. - N.A. >93 No Information ND
Date Printed: 9/12/2014
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits acrid smoke and irritating fumes.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
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11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. Irritating, and may injure eye tissue if not removed
promptly.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Allergic reactions are possible. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Low hazard for usual industrial handling or commercial handling by trained personnel.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Prolonged or excessive inhalation may cause respiratory tract irritation. Avoid breathing fumes, spray, vapors, or mist.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Contains Titanium Dioxide. Titanium Dioxide is listed as a Group
2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
1344-28-1 Aluminum Oxide >5000 mg/kg Rat N.I. N.I. 14808-60-7 Crystalline Silica 500 mg/kg Rat N.I. N.I. 13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
Date Printed: 9/12/2014
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
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Chemical Name
Aluminum Oxide 1344-28-1
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:
No TSCA components exist in this product.
Inventory Information
Country Value
USA (TSCA) No Information Canada (DSL) No Information Mexico(INSQ) No Information Europe (EINECS) No Information Japan (ENCS) No Information Philippines (PICCS) No Information China (IECSC) No Information Australia (AICS) No Information Korea (KECI) No Information New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Crystalline Silica Titanium Dioxide
CAS-No.
14808-60-7 13463-67-7
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Date Printed: 9/12/2014
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 1 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: D2A
NFPA RATINGS
Health: 2 Flammability: 1 Instability 0
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VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/12/2014
No Information
0
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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