Date Printed: 8/13/2014
Safety Data Sheet
1. Identification
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* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: 904402 Supercedes Date: New SDS
Product Use/Class: Topcoat/Alkyd
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
ENAMEL 1-GL 2PK GLOSS MACHINE TOOL
GRAY
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 8/13/2014
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. Causes eye irritation. Combustible liquid and vapor. Use ventilation necessary to
keep exposures below recommended exposure limits, if any. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF
REACH OF CHILDREN.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Flammable liquid, category 4 H227 Combustible liquid
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS PRECAUTIONARY STATEMENTS
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P234 Keep only in original container.
Date Printed: 8/13/2014
8052-41-3
64742-88-7
1317-80-2
13463-67-7
100-41-4
1333-86-4
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see … on this label).
P332+P313 If skin irritation occurs: Get medical advice/attention.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P420 Store away from other materials.
P501 Dispose of contents/container to …
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Stoddard Solvents
Mineral Spirits
Titanium Dioxide
Titanium Dioxide
Ethylbenzene
Carbon Black
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
25-50
2.5-10
1.0-2.5
1.0-2.5
0.1-1.0
0.1-1.0
GHS Symbols
GHS02
GHS06
GHS02-GHS07
GHS02
GHS Statements
H224
H331
H225-332
H251
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, get medical attention.
EXTINGUISHING MEDIA:
5. Fire-fighting Measures
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
Date Printed: 8/13/2014
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UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of
steam. Keep containers tightly closed. Combustible liquid and vapor. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed
containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition, ventilate area and remove with
inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate
closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings
designed and protected for storage of NFPA Class II combustible liquids. Avoid excess heat.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Stoddard Solvents 8052-41-3 40.0 100 ppm N.E. 500 ppm N.E.
Mineral Spirits 64742-88-7 10.0 100 ppm N.E. 100 ppm N.E.
Titanium Dioxide 1317-80-2 5.0 10 mg/m3 N.E.
Titanium Dioxide 13463-67-7 5.0 10 mg/m3 N.E.
Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
Carbon Black 1333-86-4 1.0 3 mg/m3 N.E. 3.5 mg/m3 N.E.
Weight %
Less Than
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
15 mg/m3 (Total
Dust)
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
Liquid
Solvent Like
0.932
N.D.
Negligible
No Information
212 - 415
Supports Combustion
Slower than Ether
Heavier than Air
(See "Other information" Section for abbreviation legend)
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.A.
N.D.
No Information
0.7 - 8.9
38
No Information
N.D.
Date Printed: 8/13/2014
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10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents
which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Substance causes moderate eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid
breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or
excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to the nose, throat and respiratory tract. Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Reports have associated repeated and prolonged occupational
overexposure to solvents with permanent brain and nervous system damage. Contains carbon black. Chronic inflammation, lung
fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive
concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species
(i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers
show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified
as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated
during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of
surfaces or spray mist and the actual concentration of carbon black in the formula. IARC lists Ethylbenzene as a possible human
carcinogen (group 2B). Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by
IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound
to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of
exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula.
(Ref: IARC Monograph, Vol. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
Date Printed: 8/13/2014
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14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name: Not Regulated Paint Paint Not Regulated
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: No Yes, >5L No Yes, >5L No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Ethylbenzene 100-41-4
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA components exist in this product.
Inventory Information
Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Titanium Dioxide
Titanium Dioxide
Ethylbenzene
Carbon Black
CAS-No.
1317-80-2
13463-67-7
100-41-4
1333-86-4
Date Printed: 8/13/2014
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B3 D2A
NFPA RATINGS
Health: 2 Flammability: 3 Instability 0
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VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
8/13/2014
No Information
448
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.
H225 Highly flammable liquid and vapour.
H251 Self-heating: may catch fire.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Date Printed: 8/13/2014
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Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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