Date Printed: 9/5/2014
Safety Data Sheet
1. Identification
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* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: 8494402 Supercedes Date: New SDS
Product Use/Class: Topcoat/Alkyd
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
ENAMEL 1-GL 2PK 8400 HI GLOSS DAIRY
WHT
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 9/5/2014
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if swallowed. Causes eye irritation. Vapors irritating to eyes and respiratory tract.
Combustible liquid and vapor. Harmful if inhaled. May affect the brain or nervous system causing dizziness, headache or nausea.
May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Flammable liquid and
vapor. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Vapor Harmful. Causes Eye, Skin,
Nose, and Throat Irritation.
Classification
Symbol(s) of Product
Signal Word
Danger
GHS HAZARD STATEMENTS
Flammable Liquid, category 2 H225 Highly flammable liquid and vapour.
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Eye Irritation, category 2B H320 Causes eye irritation.
GHS PRECAUTIONARY STATEMENTS
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
Date Printed: 9/5/2014
8052-41-3
13463-67-7
64742-88-7
68911-87-5
100-41-4
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P370+P378 In case of fire: Use … for extinction.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to …
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P220 Keep/Store away from clothing/…/combustible materials.
P410 Protect from sunlight.
P420 Store away from other materials.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
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The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Stoddard Solvents
Titanium Dioxide
Mineral Spirits
Organoclay
Ethylbenzene
25-50
10-25
10-25
1.0-2.5
0.1-1.0
4. First-aid Measures
GHS Symbols
GHS02
GHS06
GHS02-GHS07
GHS Statements
H224
H331
H225-332
Date Printed: 9/5/2014
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FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted. Closed
containers may explode when exposed to extreme heat due to buildup of steam. Isolate from heat, electrical equipment, sparks and
open flame.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool.
Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate
closed containers. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Ventilate
area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent, container, and unused contents
in accordance with local, state, and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Follow all MSDS/label precautions even after container is
emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes. Remove
contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Keep away from heat,
sparks, flame and sources of ignition. Keep container closed when not in use. Product should be stored in tightly sealed containers
and protected from heat, moisture, and foreign materials. Store in a dry, well ventilated place. Keep container tightly closed when not
in use. Avoid excess heat. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of
NFPA Class II combustible liquids.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Stoddard Solvents 8052-41-3 30.0 100 ppm N.E. 500 ppm N.E.
Titanium Dioxide 13463-67-7 20.0 10 mg/m3 N.E.
Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.
Organoclay 68911-87-5 5.0 N.E. N.E. N.E. N.E.
Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
Weight %
Less Than
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an
uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide
adequate protection.
SKIN PROTECTION: Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or
Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
Date Printed: 9/5/2014
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
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9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid
Solvent Like
1.069
N.D.
None
No Information
212 - 482
Supports Combustion
Slower than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.A.
N.D.
No Information
0.7 - 8.9
37
No Information
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid all possible sources of ignition. Avoid temperatures above 120 ° F. Avoid contact with strong acid
and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin irritation. Causes skin irritation. Allergic reactions are
possible.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. May cause headaches and dizziness. High vapor
concentrations are irritating to the eyes, nose, throat and lungs. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Aspiration hazard if swallowed; can enter lungs and cause damage. Harmful if
swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: IARC lists Ethylbenzene as a possible human carcinogen (group 2B).
Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system
damage. Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No
significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other
materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to
dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC
Monograph, Vol. 93, 2010)High concentrations may lead to central nervous system effects (drowsiness, dizziness, nausea,
headaches, paralysis, and blurred vision) and/or damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat
100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
N.I. - No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
Date Printed: 9/5/2014
Page 5 / 7
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name:
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: Yes Yes Yes Yes
Paint Products in
Limited Quantities
Paint Paint
Paint Products in
Limited Quantities
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Ethylbenzene 100-41-4
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
No TSCA components exist in this product.
Inventory Information
Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
Date Printed: 9/5/2014
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Titanium Dioxide
Chlorothalonil
Ethylbenzene
CAS-No.
13463-67-7
1897-45-6
100-41-4
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 3 Physical Hazard: 0 Personal Protection: X
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CANADIAN WHMIS CLASS: B2 D2A
NFPA RATINGS
Health: 2 Flammability: 3 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/5/2014
No Information
446
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.
H225 Highly flammable liquid and vapour.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
Date Printed: 9/5/2014
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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