Rust-Oleum 5494323 User Manual

Date Printed: 9/18/2014
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: CPS 0.30CUFT CP-TURBOKRETE-KIT Revision Date: 9/18/2014
Product Identifier: 5494323 Supercedes Date: 9/4/2014
Product Use/Class: Concrete Coating/TurboKrete Kit
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Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA
2. Hazard Identification
EMERGENCY OVERVIEW: May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if
inhaled. Harmful if swallowed. Causes severe skin and eye burns. Causes eye irritation. Vapors extremely irritating to eyes and respiratory tract. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Avoid contact with eyes, skin and clothing.
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
11% of the mixture consists of ingredient(s) of unknown acute toxicity

GHS HAZARD STATEMENTS

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed. Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin. Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 3 H331 Toxic if inhaled. Corrosive to Metals, category 1 H290 May be corrosive to metals. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage. Eye Irritation, category 2B H320 Causes eye irritation. Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage.

GHS PRECAUTIONARY STATEMENTS

P102 Keep out of reach of children. P103 Read label before use.
Date Printed: 9/18/2014
14808-60-7
25085-99-8
98-00-0
13463-67-7
P202 Do not handle until all safety precautions have been read and understood. P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P351 Rinse cautiously with water for several minutes. P360 Rinse immediately contaminated clothing and skin with plenty of water before removing
clothes. P361 Remove/Take off immediately all contaminated clothing. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P406 Store in corrosive resistant/… container with a resistant inner liner. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water. P501 Dispose of contents/container to … P322 Specific measures (see … on this label). P363 Wash contaminated clothing before reuse. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P321 Specific treatment (see … on this label). P352 Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P311 Call a POISON CENTER or doctor/physician. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P390 Absorb spillage to prevent material damage. P310 Immediately call a POISON CENTER or doctor/physician. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
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The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Crystalline Silica Bisphenol A Epoxy Resin Furfuryl Alcohol Titanium Dioxide
50-75
2.5-10
1.0-2.5
0.1-1.0
4. First-aid Measures
GHS Symbols
GHS07
GHS Statements
H302
Date Printed: 9/18/2014
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FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Containers can rupture and release highly toxic material if exposed to heat. Substance
is non-combustible but reacts with many metals to form explosive hydrogen gas. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid runoff into sewers and waterways. Provide ventilation
and approach spill from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with sodium bicarbonate (NaHCO3). Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Crystalline Silica 14808-60-7 75.0
Bisphenol A Epoxy Resin 25085-99-8 10.0 N.E. N.E. N.E. N.E. Furfuryl Alcohol 98-00-0 5.0 10 ppm (Skin) 15 ppm (Skin) 10 ppm (Skin) N.E.
Titanium Dioxide 13463-67-7 1.0 10 mg/m3 N.E.
Weight %
Less Than
ACGIH TLV-
TWA
0.025 mg/m3
[Respirable Dust]
ACGIH TLV-
STEL
N.E.
OSHA PEL-TWA
0.1 mg/m3
[Respirable Dust]
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
Date Printed: 9/18/2014
9. Physical and Chemical Properties
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Appearance: Odor: Relative Density: Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid Slight Amine
2.241 N.D. Negligible No Information 0 - 531 Supports Combustion Slower than Ether Heavier than Air
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
Liquid N.E. N.A. No Information
No Information
N.I. - N.I. 75 No Information No Information
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases. Avoid contact with metals.
INCOMPATIBILITY: Product slowly corrodes copper, aluminum,zinc, and galvanized surfacesIncompatible with strong oxidizing
agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: Decomposition produces hydrogen chloride, chlorine and hydrogen gases.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Substance causes severe eye irritation. Injury may be permanent.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Severely irritating; may cause permanent skin damage.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
EFFECTS OF OVEREXPOSURE - INGESTION: Corrosive and may cause severe and permanent damage to mouth, throat and stomach. Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Contains Titanium Dioxide. Titanium Dioxide is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)Repeated exposure to low concentrations of HCl vapor or mist may cause bleeding of nose and gums.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
14808-60-7 Crystalline Silica 500 mg/kg Rat N.I. N.I. 13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
Date Printed: 9/18/2014
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: 3066 3066 3066 3066
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Proper Shipping Name:
Hazard Class: 8 8 8 8
Packing Group: II II II II
Limited Quantity: No No No No
Paint and Paint Related
Products
Paint and Paint Related
Products
Paint and Paint
Related Products
Paint and Paint
Related Products
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Fire Hazard, Reactive Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:
No TSCA components exist in this product.
Inventory Information
Country Value
USA (TSCA) No Information Canada (DSL) No Information Mexico(INSQ) No Information Europe (EINECS) No Information Japan (ENCS) No Information Philippines (PICCS) No Information China (IECSC) No Information Australia (AICS) No Information Korea (KECI) No Information New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Crystalline Silica Titanium Dioxide
CAS-No.
14808-60-7 13463-67-7
Date Printed: 9/18/2014
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm.
Chemical Name
4,4'-(1-Methylethylidene) Bisphenol
CAS-No.
80-05-7
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B3 D2A E
NFPA RATINGS
Health: 2 Flammability: 2 Instability 0
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VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/18/2014
No Information
43
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H302 Harmful if swallowed.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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