Rust-Oleum 257395B User Manual

Date Printed: 3/24/2015

Safety Data Sheet

1. Identification

Page 1 / 7

* Trusted Quality Since 1921 *

www.rustoleum.com

Product Name:

Product Identifier: 257395B Supercedes Date: New SDS

Product Use/Class: CONCRETE REPAIR/TurboKrete Part B

Supplier:

Preparer: Regulatory Department

Emergency Telephone:

CONSAV TUBE TURBOKRETE CONCRETE
REPAIR Part B

Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA

24 Hour Hotline: [phone]

Revision Date: 3/24/2015

Manufacturer:

Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA

2. Hazard Identification

EMERGENCY OVERVIEW: May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if

inhaled. Harmful if swallowed. Causes severe skin and eye burns. Causes eye irritation. Vapors extremely irritating to eyes and
respiratory tract. Use ventilation necessary to keep exposures below recommended exposure limits, if any. Avoid contact with
eyes, skin and clothing.

Classification

Symbol(s) of Product

Signal Word

Danger

Possible Hazards

27% of the mixture consists of ingredient(s) of unknown acute toxicity

GHS HAZARD STATEMENTS

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed.
Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Acute Toxicity, Inhalation, category 3 H331 Toxic if inhaled.
Corrosive to Metals, category 1 H290 May be corrosive to metals.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage.
Eye Irritation, category 2B H320 Causes eye irritation.
Reproductive Toxicity, category 2 H361 Suspected of damaging fertility or the unborn child. Classifed Category 2

suspected human reproductive toxicant irreversible effects such as structural
malfunctions, embryo/foetal lethality, post natal functional deficiencies.

Date Printed: 3/24/2015

Acute Toxicity, Dermal, category 2 H310 Fatal in contact with skin.
Skin Corrosion, category 1 H314 Causes severe skin burns and eye damage.
Skin Sensitizer, category 1 H317 May cause an allergic skin reaction.

GHS PRECAUTIONARY STATEMENTS

P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P351 Rinse cautiously with water for several minutes.
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing

clothes.
P361 Remove/Take off immediately all contaminated clothing.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P406 Store in corrosive resistant/… container with a resistant inner liner.
P501 Dispose of contents/container to …
P322 Specific measures (see … on this label).
P363 Wash contaminated clothing before reuse.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/attention.
P311 Call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P390 Absorb spillage to prevent material damage.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin

with water/shower.
P201 Obtain special instructions before use.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P272 Contaminated work clothing should not be allowed out of the workplace.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

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3. Composition/Information On Ingredients

Date Printed: 3/24/2015

140-31-8

1317-65-3

107-21-1

100-51-6

14808-60-7

HAZARDOUS SUBSTANCES

Chem ical Name CAS-No. Wt.%

Range

GHS Sym bols

Page 3 / 7

GHS Statements

1-(2-Aminoethyl) piperazine
Limestone
4-nonylphenol, branched

Ethylene Glycol
Benzyl Alcohol
Crystalline Silica / Quartz

84852-15-3

10-25
10-25

10-25

2.5-10

1.0-2.5

0.1-1.0

GHS05-GHS06

GHS05-GHS07­GHS08

GHS06
GHS07

H227-311-314-317

H302-361-314

H302-310-331
H302

The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical

attention. Do NOT allow rubbing of eyes or keeping eyes closed.

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical
attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the
area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk.
Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat
symptomatically and supportively. Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or
Physician immediately.

5. Fire-fighting Measures

EXTINGUISHING MEDIA:

UNUSUAL FIRE AND EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. Keep containers tightly closed.

SPECIAL FIREFIGHTING PROCEDURES: Containers can rupture and release highly toxic material if exposed to heat. Substance

is non-combustible but reacts with many metals to form explosive hydrogen gas. Use water spray to keep fire-exposed containers
cool. Containers may explode when heated.

Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid runoff into sewers and waterways. Provide ventilation

and approach spill from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with
sodium bicarbonate (NaHCO3). Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed
containers. Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust.

7. Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.

Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.

STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use.

8. Exposure Controls/Personal Protection

Chem ical Name CAS-No.

1-(2-Aminoethyl) piperazine 140-31-8 25.0 N.E. N.E. N.E. N.E.

Limestone 1317-65-3 25.0

4-nonylphenol, branched 84852-15-3 25.0 N.E. N.E. N.E. N.E.

Weight %

Less Than

ACGIH TLV-

TWA

15 mg/m3 (Total

Dust, OSHA)

ACGIH TLV-

STE L

N.E.

OSHA PEL-TWA

5 mg/m3

(Respirable Dust)

OSHA PEL-

CEILING

N.E.

Date Printed: 3/24/2015

Ethylene Glycol 107-21-1 5.0 N.E. 39 ppm N.E. N.E.

Benzyl Alcohol 100-51-6 5.0

Crystalline Silica / Quartz 14808-60-7 1.0

10 ppm (AIHA

WEEL)

0.025 mg/m3

[Respirable Dust]

N.E. N.E. N.E.

N.E.

0.1 mg/m3

[Respirable Dust]

Page 4 / 7

N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne

levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV
of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use.

SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption
of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of

personal protective equipment and their applications.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.

9. Physical and Chemical Properties

Appearance:
Odor:
Relative Density:
Freeze Point, °C:

Solubility in Water:

Decompostion Temp., °C:
Boiling Range, °C:
Flamm ability:
Evaporation Rate:
Vapor Density:

Gel/Paste
Slight Amine

1.350
N.D.
None
No Information
0 - 4046
Does not Support Combustion
Slower than Ether
Heavier than Air

Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-

octanol/water:

Explosive Lim its, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:

Liquid
N.E.
N.A.
N.D.

No Information

N.I. - N.I.
>93
No Information
N.D.

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases. Avoid contact with metals.

INCOMPATIBILITY: Product slowly corrodes copper, aluminum,zinc, and galvanized surfacesIncompatible with strong oxidizing

agents, strong acids and strong alkalies.

HAZARDOUS DECOMPOSITION: Decomposition produces hydrogen chloride, chlorine and hydrogen gases.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

11. Toxicological information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Substance causes severe eye irritation. Injury may be permanent.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Severely irritating; may cause permanent skin damage.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful

if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and
lungs.

EFFECTS OF OVEREXPOSURE - INGESTION: Corrosive and may cause severe and permanent damage to mouth, throat and
stomach. Substance may be harmful if swallowed.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated exposure to low concentrations of HCl vapor or mist may
cause bleeding of nose and gums.

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

Date Printed: 3/24/2015

ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Derm al LD50 Vapor LC50

140-31-8 1-(2-Aminoethyl) piperazine 2140 mg/kg Rat 880 µL/kg Rabbit N.I.
84852-15-3 4-nonylphenol, branched 580 mg/kg Rat 2031 mg/kg Rabbit N.I.
107-21-1 Ethylene Glycol 4000 mg/kg Rat N.I. N.I.
100-51-6 Benzyl Alcohol 1230 mg/kg Rat 2 g/kg Rabbit 8.8 mg/L Rat
14808-60-7 Crystalline Silica / Quartz 500 mg/kg Rat N.I. N.I.

N.I. - No Information

Page 5 / 7

12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not

allow to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. 1759 1759 N.A.

Proper Shipping Name:

Hazard Class: N.A. 8 8 N.A.

Packing Group: N.A. III III N.A.

Lim ited Quantity: Yes Yes No Yes

Paint Products in

Limited Quantities

Corrosive Solids, NOS

(aminoethylpiperazine,

nonylphenol)

Corrosive Solids, NOS

(aminoethylpiperazine,

nonylphenol)

Paint Products in

Limited Quantities

15. Regulatory Information

U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:

Chronic Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

Chemical Name

Ethylene Glycol 107-21-1

CAS-No.

Toxic Substances Control Act:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported
from the United States:

No TSCA components exist in this product.

Date Printed: 3/24/2015

CALIFORNIA PROPOSITION 65:

WARNING: This product contains a substance known to the State of California to cause cancer.

Chemical Name

Crystalline Silica / Quartz

CAS-No.

14808-60-7

CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS

WARNING: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.

No Proposition 65 Reproductive Toxins exist in this product.

International Regulations:

CANADIAN WHMIS:

This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.

16. Other Information

HMIS RATINGS

Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X

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CANADIAN WHMIS CLASS: D2A E

NFPA RATINGS

Health: 2 Flammability: 1 Instability 0

VOLATILE ORGANIC COMPOUNDS, g/L:

MSDS REVISION DATE:

REASON FOR REVISION:

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

3/24/2015

No Information

262

Text for GHS Hazard Statements shown in Section 3 describing each ingredient:

H227 Combustible liquid
H302 Harmful if swallowed.
H310 Fatal in contact with skin.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H361 Suspected of damaging fertility or the unborn child. Classifed Category 2 suspected human reproductive

toxicant irreversible effects such as structural malfunctions, embryo/foetal lethality, post natal functional
deficiencies.

Icons for GHS Pictograms shown in Section 3 describing each ingredient:

GHS05

Date Printed: 3/24/2015

Page 7 / 7

GHS06

GHS07

GHS08

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred
by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all
applicable international, federal, state, and local laws and regulations.