Rust-Oleum 254157 User Manual

Date Printed: 9/18/2014
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: ROHPER 1-GL 2PK EPOXY SC9100 WHITE Revision Date: 9/18/2014
Product Identifier: 254157 Supercedes Date: 8/14/2014
Product Use/Class: Topcoat/SC9100 Epoxy
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Supplier:
Preparer: Regulatory Department
Emergency Telephone:
24 Hour Hotline: 847-367-7700
Manufacturer:
2. Hazard Identification
EMERGENCY OVERVIEW: Causes eye irritation. Causes skin irritation. May cause allergic skin reaction. Combustible liquid and
vapor. May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if inhaled. Use ventilation necessary to keep exposures below recommended exposure limits, if any.
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
54% of the mixture consists of ingredient(s) of unknown acute toxicity

GHS HAZARD STATEMENTS

Flammable liquid, category 4 H227 Combustible liquid Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin. Skin Irritation, category 2 H315 Causes skin irritation. Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation. STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness. Organic Peroxide, categories C, D H242 Heating may cause a fire. Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways. Eye Irritation, category 2B H320 Causes eye irritation. Acute Toxicity, Oral, category 2 H300 Fatal if swallowed. Acute Toxicity, Dermal, category 1 H310 Fatal in contact with skin.

GHS PRECAUTIONARY STATEMENTS

P102 Keep out of reach of children. P103 Read label before use. P202 Do not handle until all safety precautions have been read and understood.
Date Printed: 9/18/2014
25085-99-8
13463-67-7
98-56-6
14807-96-6
1317-65-3
P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. P285 In case of inadequate ventilation wear respiratory protection. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P351 Rinse cautiously with water for several minutes. P374 Fight fire with normal precautions from a reasonable distance. P402 Store in a dry place. P410+P412 Protect from sunlight. Do no expose to temperatures exceeding 50°C/ 122°F. P321 Specific treatment (see … on this label). P352 Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. P405 Store locked up. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/container to … P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P220 Keep/Store away from clothing/…/combustible materials. P420 Store away from other materials. P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool. P330 Rinse mouth. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P310 Immediately call a POISON CENTER or doctor/physician. P322 Specific measures (see … on this label). P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Bisphenol A Epoxy Resin Titanium Dioxide 1-Chloro-4(Trifluoromethyl)Benzene Talc Limestone
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
25-50 10-25 10-25 10-25
1.0-2.5
GHS Symbols
GHS02-GHS06
GHS Statements
H226-300-310
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.
Date Printed: 9/18/2014
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FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Combustible liquid and vapor. No unusual fire or explosion hazards noted. Closed containers may explode when exposed to extreme heat due to buildup of steam. Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Isolate the hazard area and deny entry to unnecessary and
unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Use only in a well-ventilated area. Follow all MSDS/label precautions even after
container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid prolonged or repeated contact with skin. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Avoid contact with eyes, skin and clothing.
STORAGE: Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings designed and protected for storage of NFPA Class II combustible liquids. Store in a dry, well ventilated place. Keep container tightly closed when not in use. Avoid excess heat.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Bisphenol A Epoxy Resin 25085-99-8 40.0 N.E. N.E. N.E. N.E.
Titanium Dioxide 13463-67-7 25.0 10 mg/m3 N.E.
1-Chloro-4(Trifluoromethyl) Benzene
Talc 14807-96-6 15.0 2 mg/m3 N.E.
Limestone 1317-65-3 5.0
98-56-6 20.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
5 mg/m3 (NIOSH,
Respirable Dust)
ACGIH TLV-
STEL
N.E.
OSHA PEL-TWA
15 mg/m3 [Total
Dust]
0.1 mg/m3
[Respirable]
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
N.E.
N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve cross­ventilation.
RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
Date Printed: 9/18/2014
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.
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9. Physical and Chemical Properties
Appearance: Odor: Relative Density: Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid Solvent Like
1.652 N.D. Negligible No Information 277 - 500 Supports Combustion Slower than Ether Heavier than Air
Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:
Liquid N.E. N.A. N.D.
No Information
0.9 - 10.5 50 No Information N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Product slowly corrodes copper, aluminum,zinc, and galvanized surfacesIncompatible with strong oxidizing
agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Substance causes severe eye irritation. Injury may be permanent. Substance
causes moderate eye irritation.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Substance may cause slight skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: High vapor concentrations are irritating to the eyes, nose, throat and lungs. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist. Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Irritating to the nose, throat and respiratory tract. Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Contains Titanium Dioxide. Titanium Dioxide is listed as a Group
2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I. 98-56-6 1-Chloro-4(Trifluoromethyl)Benzene 13 g/kg Rat >2 mL/kg Rabbit 33 mg/L Rat
N.I. - No Information
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
Date Printed: 9/18/2014
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13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name: Not Regulated Paint Paint Not Regulated
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: No Yes, >5L No Yes, >5L No No
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
1-Chloro-4(Trifluoromethyl)Benzene 98-56-6
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:
No TSCA components exist in this product.
Inventory Information
Country Value
USA (TSCA) No Information Canada (DSL) No Information Mexico(INSQ) No Information Europe (EINECS) No Information Japan (ENCS) No Information Philippines (PICCS) No Information China (IECSC) No Information Australia (AICS) No Information Korea (KECI) No Information New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Date Printed: 9/18/2014
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Chemical Name
Titanium Dioxide
CAS-No.
13463-67-7
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 2 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B3 D2A
NFPA RATINGS
Health: 2 Flammability: 2 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/18/2014
No Information
22
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H226 Flammable liquid and vapour. H300 Fatal if swallowed. H310 Fatal in contact with skin.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.
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