Date Printed: 2/27/2019
Safety Data Sheet
1. Identification
Page 1 / 6
* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: 249061 Supercedes Date: 11/7/2018
Recommended Use: Topcoat/Aerosol
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
PTOUCH 2X +SSPR 6PK SEMI-GLOSS
BLACK
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 2/27/2019
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
35% of the mixture consists of ingredient(s) of unknown acute toxicity.
GHS HAZARD STATEMENTS
Carcinogenicity, category 1B H350 May cause cancer.
Compressed Gas H280 Contains gas under pressure; may explode if heated.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Flammable Aerosol, category 1 H222 Extremely flammable aerosol.
Germ Cell Mutagenicity, category 1B H340 May cause genetic defects.
STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS LABEL PRECAUTIONARY STATEMENTS
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Date Printed: 2/27/2019
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P337+P313 If eye irritation persists: Get medical advice/attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F.
P501 Dispose of contents/container in accordance with local, regional and national regulations.
Page 2 / 6
3. Composition / Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Acetone 67-64-1 25-50 GHS02-GHS07 H225-319-332-336
Propane 74-98-6 10-25 GHS04 H280
Naphtha, Petroleum, Hydrotreated Light 64742-49-0 10-25 GHS08 H304
n-Butane 106-97-8 2.5-10 GHS04 H280
GHS Symbols
GHS Statements
Xylenes (o-, m-, p- isomers) 1330-20-7 2.5-10 GHS02-GHS07 H226-315-319-332
Hydrotreated Light Distillate 64742-47-8 2.5-10 GHS08 H304
Barium Sulfate 7727-43-7 2.5-10 GHS07 H332
Hydrous Magnesium Silicate 14807-96-6 1.0-2.5 Not Available Not Available
Ethylbenzene 100-41-4 1.0-2.5
n-Butyl Acetate 123-86-4 0.1-1.0 GHS02-GHS07 H226-336
Aliphatic Hydrocarbon 64742-89-8 0.1-1.0 GHS08 H304-340-350
Carbon Black 1333-86-4 0.1-1.0 Not Available Not Available
Octane 111-65-9 0.1-1.0
GHS02-GHS07GHS08
GHS02-GHS07GHS08
H225-304-332-351-373
H225-304-315-336
4. First-Aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-Fighting Measures
EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
Date Printed: 2/27/2019
Page 3 / 6
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS LESS THAN 20°F. EXTREMELY FLAMMABLE LIQUID AND
VAPOR!Water spray may be ineffective. Closed containers may explode when exposed to extreme heat due to buildup of steam.
Closed containers may explode when exposed to extreme heat. Vapors may form explosive mixtures with air. Vapors can travel to a
source of ignition and flash back. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame.
Perforation of the pressurized container may cause bursting of the can. No unusual fire or explosion hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Full protective equipment including self-contained breathing apparatus should be used. Evacuate area and
fight fire from a safe distance. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.
Special Fire and Explosion Hazard (Combustible Dust): No Information
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Contain spilled liquid with sand or earth. DO NOT use
combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove
all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state
(provincial) and federal regulations. Do not incinerate closed containers. Ventilate area, isolate spilled material, and remove with
inert absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal
regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only in a well-ventilated area. Use only with adequate ventilation. Follow all SDS and label precautions even after container is
emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks and open flame. Contents under pressure. Do not store above 120 ° F. Store large
quantities in buildings designed and protected for storage of flammable aerosols. Keep away from heat, sparks, flame and sources of
ignition. Contents under pressure. Do not expose to heat or store above 120 ° F. Avoid excess heat. Product should be stored in
tightly sealed containers and protected from heat, moisture, and foreign materials.
Advice on Safe Handling of Combustible Dust: No Information
8. Exposure Controls / Personal Protection
Chemical Name CAS-No.
Acetone 67-64-1 30.0 250 ppm 500 ppm 1000 ppm N.E.
Propane 74-98-6 20.0 N.E. N.E. 1000 ppm N.E.
Naphtha, Petroleum,
Hydrotreated Light
n-Butane 106-97-8 10.0 N.E. 1000 ppm N.E. N.E.
Xylenes (o-, m-, p- isomers) 1330-20-7 5.0 100 ppm 150 ppm 100 ppm N.E.
Hydrotreated Light Distillate 64742-47-8 5.0 N.E. N.E. N.E. N.E.
Barium Sulfate 7727-43-7 5.0 5 mg/m3 N.E. 15 mg/m3 N.E.
Hydrous Magnesium Silicate 14807-96-6 5.0 2 mg/m3 N.E. N.E. N.E.
Ethylbenzene 100-41-4 5.0 20 ppm N.E. 100 ppm N.E.
n-Butyl Acetate 123-86-4 1.0 50 ppm 150 ppm 150 ppm N.E.
Aliphatic Hydrocarbon 64742-89-8 1.0 N.E. N.E. N.E. N.E.
Carbon Black 1333-86-4 1.0 3 mg/m3 N.E. 3.5 mg/m3 N.E.
Octane 111-65-9 1.0 300 ppm N.E. 500 ppm N.E.
64742-49-0 20.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
PERSONAL PROTECTION
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Use explosion-proof ventilation equipment. Provide general dilution of local exhaust
ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by
opening all doors and windows to achieve cross-ventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of
this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
ACGIH TLV-
TWA
ACGIH TLV-
STEL
OSHA PEL-TWA
OSHA PEL-
CEILING
Date Printed: 2/27/2019
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information
regarding personal protective equipment and its application.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Engineering Measures for Combustible Dust: No Information
Page 4 / 6
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
(See "Other information" Section for abbreviation legend)
Aerosolized Mist
Solvent Like
0.750
N.D.
Slight
N.D.
-37 - 537
Supports Combustion
Faster than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.D.
N.D.
N.D.
0.9 - 13.0
-96
N.D.
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid all possible sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological Information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. May cause skin irritation. Allergic
reactions are possible. Prolonged or repeated contact may cause skin irritation.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: May cause central nervous system disorder (e.g., narcosis involving a
loss of coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage. High concentrations may lead to
central nervous system effects (drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports
have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.
Overexposure to xylene in laboratory animals has been associated with liver abnormalities, kidney, lung, spleen, eye and blood
damage as well as reproductive disorders. Effects in humans, due to chronic overexposure, have included liver, cardiac
abnormalities and nervous system damage. Contains carbon black. Chronic inflammation, lung fibrosis, and lung tumors have been
observed in some rats experimentally exposed for long periods of time to excessive concentrations of carbon black and several
insoluble fine dust particles. Tumors have not been observed in other animal species (i.e., mouse and hamster) under similar
circumstances and study conditions. Epidemiological studies of North American workers show no evidence of clinically significant
adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified
as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated
during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of
surfaces or spray mist and the actual concentration of carbon black in the formula. IARC lists Ethylbenzene as a possible human
carcinogen (group 2B).
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
Date Printed: 2/27/2019
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
67-64-1 Acetone 5800 mg/kg Rat >15700 mg/kg Rabbit 50.1 mg/L Rat
64742-49-0 Naphtha, Petroleum, Hydrotreated Light >5000 mg/kg Rat >3160 mg/kg Rabbit >4951 mg/L Rat
106-97-8 n-Butane N.E. N.E. 658 mg/L Rat
1330-20-7 Xylenes (o-, m-, p- isomers) 3500 mg/kg Rat >4350 mg/kg Rabbit 29.08 mg/L Rat
64742-47-8 Hydrotreated Light Distillate >5000 mg/kg Rat >2000 mg/kg Rabbit >5000 mg/L Rat
7727-43-7 Barium Sulfate 307000 mg/kg Rat N.E. N.E.
14807-96-6 Hydrous Magnesium Silicate 6000 N.E. 30
100-41-4 Ethylbenzene 3500 mg/kg Rat 15400 mg/kg Rabbit 17.4 mg/L Rat
123-86-4 n-Butyl Acetate 10768 mg/kg Rat >17600 mg/kg Rabbit > 21 mg/L Rat
64742-89-8 Aliphatic Hydrocarbon N.E. 3000 mg/kg Rabbit N.E.
1333-86-4 Carbon Black >15400 mg/kg Rat N.E. N.E.
111-65-9 Octane N.E. N.E. >23.36 mg/L Rat
N.E. - Not Established
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
Page 5 / 6
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components. Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Do not incinerate closed containers. Dispose of material in accordance to local, state, and federal
regulations and ordinances. Do not allow to enter waterways, wastewater, soil, storm drains or sewer systems. This product as
supplied is a USEPA defined ignitable hazardous waste. Dispose of unusable product as a hazardous waste (D001) in accordance
with local, state, and federal regulation.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1950 1950 N.A.
Proper Shipping Name:
Hazard Class: N.A. 2 2.1 N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: Yes Yes Yes Yes
Paint and Related Spray
Products in Ltd Qty
Aerosols Aerosols, flammable Aerosols
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Gas under pressure, Carcinogenicity, Serious eye damage or eye irritation, Specific target organ toxicity (single or repeated
exposure), Germ cell mutagenicity
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
Xylenes (o-, m-, p- isomers) 1330-20-7
Ethylbenzene 100-41-4
CAS-No.
Date Printed: 2/27/2019
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from
the United States:
No TSCA 12(b) components exist in this product.
U.S. State Regulations:
California Proposition 65:
WARNING: Cancer and Reproductive Harm - www.P65Warnings.ca.gov.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 4 Physical Hazard: 0 Personal Protection: X
NFPA RATINGS
Health: 2 Flammability: 4 Instability 0
Maximum Incremental Reactivity 0.93
SDS REVISION DATE: 2/27/2019
REASON FOR REVISION: Product Composition Changed
Substance and/or Product Properties Changed in Section(s):
01 - Identification
02 - Hazard Identification
Revision Statement(s) Changed
Page 6 / 6
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
Loading...