Date Printed: 8/14/2014
Safety Data Sheet
1. Identification
Page 1 / 7
* Trusted Quality Since 1921 *
www.rustoleum.com
Product Name:
Product Identifier: 245403 Supercedes Date: New SDS
Product Use/Class: Topcoat/Alkyd
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
ROHPER 1-GL 2PK V7400 HIGH GLOSS
BLACK
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Revision Date: 8/14/2014
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: Harmful if inhaled. Harmful if swallowed. Causes eye irritation. Flammable liquid and vapor. Use
ventilation necessary to keep exposures below recommended exposure limits, if any. Harmful if inhaled. May affect the brain or
nervous system causing dizziness, headache or nausea. Vapor Harmful. Causes Eye, Skin, Nose, and Throat Irritation. May cause
eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN.
Classification
Symbol(s) of Product
Signal Word
Danger
Possible Hazards
37% of the mixture consists of ingredient(s) of unknown acute toxicity
GHS HAZARD STATEMENTS
Flammable Liquid, category 2 H225 Highly flammable liquid and vapour.
Organic Peroxide, categories C, D H242 Heating may cause a fire.
Acute Toxicity, Oral, category 2 H300 Fatal if swallowed.
Acute Toxicity, Oral, category 5 H303 May be harmful if swallowed.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Acute Toxicity, Dermal, category 1 H310 Fatal in contact with skin.
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Eye Irritation, category 2 H319 Causes serious eye irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
Acute Toxicity, Inhalation, category 4 H332 Harmful if inhaled.
STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.
STOT, single exposure, category 3, NE H336 May cause drowsiness or dizziness.
GHS PRECAUTIONARY STATEMENTS
Date Printed: 8/14/2014
Proprietary
98-56-6
8052-41-3
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P234 Keep only in original container.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting/…/ equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P321 Specific treatment (see … on this label).
P322 Specific measures (see … on this label).
P330 Rinse mouth.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of soap and water.
P361 Remove/Take off immediately all contaminated clothing.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use … for extinction.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P410 Protect from sunlight.
P411+P235 Store at temperatures not exceeding …°C/…°F. Keep cool.
P420 Store away from other materials.
P501 Dispose of contents/container to …
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3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
Polymers/Binder/Resin
1-Chloro-4(Trifluoromethyl)Benzene
Stoddard Solvents
10-25
10-25
10-25
GHS Symbols
GHS02-GHS06
GHS02
GHS Statements
H226-300-310
H224
Date Printed: 8/14/2014
64742-88-7
556-67-2
1333-86-4
100-41-4
Mineral Spirits
Octamethylcyclotetrasiloxane
Carbon Black
Ethylbenzene
10-25
2.5-10
1.0-2.5
0.1-1.0
GHS06
GHS02-GHS06
GHS02
GHS02-GHS07
H331
H226-311
H251
H225-332
Page 3 / 7
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Aspiration hazard: Do not induce vomiting or give anything by mouth because this material can enter the
lungs and cause severe lung damage. Get immediate medical attention. If swallowed, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Dry Sand, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode when exposed to extreme heat due to buildup of
steam. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks and open flame. No unusual fire or explosion
hazards noted.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible
autoignition or explosion. Evacuate area and fight fire from a safe distance. Use water spray to keep fire-exposed containers cool.
Containers may explode when heated.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Remove all sources of ignition, ventilate area and remove with
inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate
closed containers. Ventilate area, isolate spilled material, and remove with inert absorbent. Dispose of contaminated absorbent,
container, and unused contents in accordance with local, state, and federal regulations.
7. Handling and Storage
HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.
Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product
residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep containers tightly closed.
Isolate from heat, electrical equipment, sparks and open flame. Do not store above 120 ° F. Store large quantities in buildings
designed and protected for storage of NFPA Class II combustible liquids. Keep away from heat, sparks, flame and sources of
ignition. Avoid excess heat. Product should be stored in tightly sealed containers and protected from heat, moisture, and foreign
materials.
PERSONAL PROTECTION
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Polymers/Binder/Resin Proprietary 25.0 N.E. N.E. N.E. N.E.
1-Chloro-4(Trifluoromethyl)
Benzene
Stoddard Solvents 8052-41-3 15.0 100 ppm N.E. 500 ppm N.E.
Mineral Spirits 64742-88-7 15.0 100 ppm N.E. 100 ppm N.E.
Octamethylcyclotetrasiloxane 556-67-2 10.0 N.E. N.E. N.E. N.E.
Carbon Black 1333-86-4 5.0
Ethylbenzene 100-41-4 1.0 20 ppm 125 ppm 100 ppm N.E.
98-56-6 25.0 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
3 mg/m3
(Inhalable Dust)
ACGIH TLV-
STEL
N.E. 3.5 mg/m3 N.E.
OSHA PEL-TWA
OSHA PEL-
CEILING
Date Printed: 8/14/2014
ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.
RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be
followed whenever workplace conditions warrant a respirator's use. A NIOSH/MSHA approved air purifying respirator with an organic
vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed
exposure limits.
Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an
uncontrolled release, exposure levels are not known, or in any other circumstances where air purifying respirators may not provide
adequate protection.
SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
Page 4 / 7
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
(See "Other information" Section for abbreviation legend)
Liquid
Solvent Like
1.022
N.D.
Negligible
No Information
277 - 500
Supports Combustion
Slower than Ether
Heavier than Air
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.A.
N.D.
No Information
0.7 - 8.9
37
No Information
N.D.
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid temperatures above 120 ° F. Avoid contact with strong acid and strong bases. Avoid all possible
sources of ignition.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: By open flame, carbon monoxide and carbon dioxide. When heated to decomposition, it emits
acrid smoke and irritating fumes. Contains solvents which may form carbon monoxide, carbon dioxide, and formaldehyde.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes Serious Eye Irritation
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Allergic reactions are possible.
EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if
inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs.
Prolonged or excessive inhalation may cause respiratory tract irritation.
EFFECTS OF OVEREXPOSURE - INGESTION: Harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: High concentrations may lead to central nervous system effects
(drowsiness, dizziness, nausea, headaches, paralysis, and blurred vision) and/or damage. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Contains carbon black.
Chronic inflammation, lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of
time to excessive concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other
animal species (i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North
American workers show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified
Date Printed: 8/14/2014
as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated
during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of
surfaces or spray mist and the actual concentration of carbon black in the formula. IARC lists Ethylbenzene as a possible human
carcinogen (group 2B).
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50
98-56-6 1-Chloro-4(Trifluoromethyl)Benzene 13 g/kg Rat >2 mL/kg Rabbit 33 mg/L Rat
64742-88-7 Mineral Spirits >5000 mg/kg Rat 3000 mg/kg Rabbit >5.28 mg/L Rat
556-67-2 Octamethylcyclotetrasiloxane N.I. 794 µL/kg Rabbit N.I.
100-41-4 Ethylbenzene 3500 mg/kg Rat 15354 mg/kg Rabbit 17.2 mg/L Rat
N.I. - No Information
Page 5 / 7
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. 1263 1263 N.A.
Proper Shipping Name:
Hazard Class: N.A. 3 3 N.A.
Packing Group: N.A. III III N.A.
Limited Quantity: Yes Yes Yes Yes
Paint Products in
Limited Quantities
Paint Paint
Paint Products in
Limited Quantities
15. Regulatory Information
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Fire Hazard, Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name
1-Chloro-4(Trifluoromethyl)Benzene 98-56-6
Ethylbenzene 100-41-4
CAS-No.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Date Printed: 8/14/2014
No TSCA components exist in this product.
Inventory Information
Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Carbon Black
Ethylbenzene
CAS-No.
1333-86-4
100-41-4
Page 6 / 7
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 3 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: B2 D2A
NFPA RATINGS
Health: 2 Flammability: 3 Instability 0
VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
8/14/2014
No Information
337
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
Date Printed: 8/14/2014
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H224 Extremely flammable liquid and vapour.
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H251 Self-heating: may catch fire.
H300 Fatal if swallowed.
H310 Fatal in contact with skin.
H311 Toxic in contact with skin.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS06
GHS07
Page 7 / 7
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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