Date Printed: 9/2/2014
Safety Data Sheet
* Trusted Quality Since 1921 *
www.rustoleum.com
1. Identification
Product Name: SIE S39 1-GL BEYOND GLOSS NAVY GRAY Revision Date: 9/2/2014
Product Identifier: 238750 Supercedes Date: New SDS
Product Use/Class: Topcoat/Sierra S-39
Page 1 / 6
Supplier:
Preparer: Regulatory Department
Emergency Telephone:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
24 Hour Hotline: 847-367-7700
Manufacturer:
Rust-Oleum Corporation
11 Hawthorn Parkway
Vernon Hills, IL 60061
USA
2. Hazard Identification
EMERGENCY OVERVIEW: May cause eye, skin, or respiratory tract irritation. KEEP OUT OF REACH OF CHILDREN. Harmful if
inhaled. Causes eye irritation. Use ventilation necessary to keep exposures below recommended exposure limits, if any.
Classification
Symbol(s) of Product
Signal Word
Warning
GHS HAZARD STATEMENTS
Acute Toxicity, Dermal, category 5 H313 May be harmful in contact with skin.
Skin Irritation, category 2 H315 Causes skin irritation.
Aspiration Hazard, category 2 H305 May be harmful if swallowed and enters airways.
Skin Irritation, category 3 H316 Causes mild skin irritation.
Eye Irritation, category 2B H320 Causes eye irritation.
GHS PRECAUTIONARY STATEMENTS
P102 Keep out of reach of children.
P103 Read label before use.
P202 Do not handle until all safety precautions have been read and understood.
P234 Keep only in original container.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash … thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Date Printed: 9/2/2014
Proprietary
13463-67-7
1333-86-4
Proprietary
58253-49-9
P281 Use personal protective equipment as required.
P285 In case of inadequate ventilation wear respiratory protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P335 Brush off loose particles from skin.
P351 Rinse cautiously with water for several minutes.
P374 Fight fire with normal precautions from a reasonable distance.
P402 Store in a dry place.
P321 Specific treatment (see … on this label).
P352 Wash with plenty of soap and water.
P362 Take off contaminated clothing and wash before reuse.
P332+P313 If skin irritation occurs: Get medical advice/attention.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
3. Composition/Information On Ingredients
HAZARDOUS SUBSTANCES
Chemical Name CAS-No. Wt.%
Range
GHS Symbols
Page 2 / 6
GHS Statements
Acrylic Resin
Titanium Dioxide
Carbon Black
Surfactant
Polyoxyethylated oleyl amine
The text for GHS Hazard Statements shown above (if any) is given in the "16. Other Information" section.
2.5-10
2.5-10
0.1-1.0
0.1-1.0
<0.1
GHS07
GHS02
GHS07
H315-320
H251
H315-320
4. First-aid Measures
FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical
attention. Do NOT allow rubbing of eyes or keeping eyes closed.
FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation
develops or persists.
FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to
obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.
FIRST AID - INGESTION: Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce
vomiting, but give one or two glasses of water to drink and get medical attention. If swallowed, rinse mouth with water. If feeling
unwell, get medical attention.
5. Fire-fighting Measures
EXTINGUISHING MEDIA:
Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog
UNUSUAL FIRE AND EXPLOSION HAZARDS: FLASH POINT IS TESTED TO BE GREATER THAN 200 DEGREES F. No unusual
fire or explosion hazards noted. Keep containers tightly closed.
SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. If water is
used, fog nozzles are preferred.
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Dispose of according to local, state (provincial) and federal
regulations. Do not incinerate closed containers. If spilled, contain spilled material and remove with inert absorbent. Dispose of
contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. Do not incinerate
closed containers
6. Accidental Release Measures
7. Handling and Storage
Date Printed: 9/2/2014
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HANDLING: Avoid contact with eyes. Wash hands before eating. Wash thoroughly after handling. Remove contaminated clothing
and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied
because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.
STORAGE: Keep from freezing. Keep container closed when not in use. Store in a dry, well ventilated place. Keep container tightly
closed when not in use.
8. Exposure Controls/Personal Protection
Chemical Name CAS-No.
Acrylic Resin Proprietary 10.0 N.E. N.E. N.E. N.E.
Titanium Dioxide 13463-67-7 5.0 10 mg/m3 N.E.
Carbon Black 1333-86-4 1.0
Surfactant Proprietary 1.0 N.E. N.E. N.E. N.E.
Polyoxyethylated oleyl amine 58253-49-9 0.1 N.E. N.E. N.E. N.E.
Weight %
Less Than
ACGIH TLV-
TWA
3 mg/m3
(Inhalable Dust)
ACGIH TLV-
STEL
N.E. 3.5 mg/m3 N.E.
OSHA PEL-TWA
15 mg/m3 [Total
Dust]
OSHA PEL-
CEILING
N.E.
PERSONAL PROTECTION
ENGINEERING CONTROLS: Prevent build-up of vapors by opening all doors and windows to achieve cross-ventilation. Use
process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure
limits.
RESPIRATORY PROTECTION: A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be
permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. A respiratory
protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions
warrant a respirator's use.
SKIN PROTECTION: Nitrile or Neoprene gloves may afford adequate skin protection. Use gloves to prevent prolonged skin contact.
EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. Use ANSI Z87.1 approved safety eyewear.
OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further information regarding personal
protective equipment and its application. Refer to safety supervisor or industrial hygienist for further guidance regarding types of
personal protective equipment and their applications.
HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing
immediately and launder before reuse.
9. Physical and Chemical Properties
Appearance:
Odor:
Relative Density:
Freeze Point, °C:
Solubility in Water:
Decompostion Temp., °C:
Boiling Range, °C:
Flammability:
Evaporation Rate:
Vapor Density:
Liquid
Mild
1.074
ND
Miscible
No Information
115 - 770
Does not Support Combustion
Slower than Ether
Heavier than Air
(See "Other information" Section for abbreviation legend)
Physical State:
Odor Threshold:
pH:
Viscosity:
Partition Coefficient, n-octanol/
water:
Explosive Limits, vol%:
Flash Point, °C:
Auto-ignition Temp., °C:
Vapor Pressure:
Liquid
N.E.
N.D.
N.D.
No Information
16.0 - 25.0
>93
No Information
ND
10. Stability and Reactivity
CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases.
INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.
HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes. By open flame, carbon
monoxide and carbon dioxide.
HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.
STABILITY: This product is stable under normal storage conditions.
Date Printed: 9/2/2014
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11. Toxicological information
EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. Irritating, and may injure eye tissue if not removed
promptly.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Substance may cause slight skin irritation. Low hazard for usual industrial
handling or commercial handling by trained personnel.
EFFECTS OF OVEREXPOSURE - INHALATION: Low hazard for usual industrial handling or commercial handling by trained
personnel. Routine handling and application does not require use of respiratory protection; however, if air monitoring demonstrates
vapor, mist, or dust levels above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during
handling and application. Follow respirator manufacturer's directions for respirator use. High gas, vapor, mist or dust concentrations
may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist.
EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Contains Titanium Dioxide. Titanium Dioxide is listed as a Group
2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of
products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of
overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual
concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)Contains carbon black. Chronic inflammation,
lung fibrosis, and lung tumors have been observed in some rats experimentally exposed for long periods of time to excessive
concentrations of carbon black and several insoluble fine dust particles. Tumors have not been observed in other animal species
(i.e., mouse and hamster) under similar circumstances and study conditions. Epidemiological studies of North American workers
show no evidence of clinically significant adverse health effects due to occupational exposure to carbon black.
Carbon black is listed as a Group 2B-"Possibly carcinogenic to humans" by IARC and is proposed to be listed as A4- "not classified
as a human carcinogen" by the American Conference of Governmental Industrial Hygienists. Significant exposure is not anticipated
during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of
surfaces or spray mist and the actual concentration of carbon black in the formula.
PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact
ACUTE TOXICITY VALUES
The acute effects of this product have not been tested. Data on individual components are tabulated below:
CAS-No.
13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.
N.I. - No Information
Chemical Name Oral LD50 Dermal LD50 Vapor LC50
12. Ecological Information
ECOLOGICAL INFORMATION: Product is a mixture of listed components.
13. Disposal Information
DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not allow
to enter waterways, wastewater, soil, storm drains or sewer systems.
14. Transport Information
Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)
UN Number: N.A. N.A. N.A. N.A.
Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated
Hazard Class: N.A. N.A. N.A. N.A.
Packing Group: N.A. N.A. N.A. N.A.
Limited Quantity: No No No No
15. Regulatory Information
Date Printed: 9/2/2014
U.S. Federal Regulations:
CERCLA - SARA Hazard Category
This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to
meet the following categories:
Acute Health Hazard, Chronic Health Hazard
Sara Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the
Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Sara 313 components exist in this product.
Toxic Substances Control Act:
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from
the United States:
Chemical Name
Sodium Nitrite 7632-00-0
5-Chloro-2-Methyl-4-Isothiazolin-3-one 26172-55-4
Methyl-4-Isothiazolin-3-one 2682-20-4
Acetaldehyde 75-07-0
Inventory Information
CAS-No.
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Country Value
USA (TSCA) No Information
Canada (DSL) No Information
Mexico(INSQ) No Information
Europe (EINECS) No Information
Japan (ENCS) No Information
Philippines (PICCS) No Information
China (IECSC) No Information
Australia (AICS) No Information
Korea (KECI) No Information
New Zealand (NZIOC) No Information
No Information
CALIFORNIA PROPOSITION 65:
Warning: This products contains a substance known to the State of California to cause cancer.
Chemical Name
Titanium Dioxide
Carbon Black
CAS-No.
13463-67-7
1333-86-4
CALIFORNIA PROPOSITION 65 REPRODUCTIVE TOXINS
Warning: This product contains a substance known to the State of California to cause birth defects or other reproductive
harm.
No Proposition 65 Reproductive Toxins exist in this product.
International Regulations:
CANADIAN WHMIS:
This SDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16 headings.
Date Printed: 9/2/2014
16. Other Information
HMIS RATINGS
Health: 2* Flammability: 1 Physical Hazard: 0 Personal Protection: X
CANADIAN WHMIS CLASS: D2A
NFPA RATINGS
Health: 2 Flammability: 1 Instability 0
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VOLATILE ORGANIC COMPOUNDS, g/L:
MSDS REVISION DATE:
REASON FOR REVISION:
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
9/2/2014
No Information
0
Text for GHS Hazard Statements shown in Section 3 describing each ingredient:
H251 Self-heating: may catch fire.
H315 Causes skin irritation.
H320 Causes eye irritation.
Icons for GHS Pictograms shown in Section 3 describing each ingredient:
GHS02
GHS07
Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be
accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of
these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by
the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with
caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and
examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable
international, federal, state, and local laws and regulations.
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