Rust-Oleum 237531, 237532, 237452 User Manual

Revision Date: 7/22/2015

Rust-Oleum Multi Component Product Information Sheet

5494323 CPS 0.30CUFT CP-TURBOKRETE-KIT is a multi component product composed of the following individual chemical components:

237531 CPS 0.30CUFT CP TURBOKRETE-B

237532 CPS 0.30CUFT CP TURBOKRETE - A

237452 CPS 29.75 LB CP TurboKrete-Aggregate

SDSs for each component follow this cover sheet.

Transportation Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: 3066 3066 3066 3066

Proper Shipping Name:

Hazard Class: 8 8 8 8

Packing Group: II II II II

Lim ited Quantity: No No No No

Finished Good Schedule B Harmonized Tariff Code 3907.30.0000

Paint and Paint Related

Products

Paint and Paint Related

Products

Paint and Paint

GHS HAZARD STATEMENTS

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed. Acute Toxicity, Dermal, category 3 H311 Toxic in contact with skin. Skin Corrosion, category 1B H314 Causes severe skin burns and eye damage. Skin Sensitizer, category 1 H317 May cause an allergic skin reaction. STOT, single exposure, category 3, RTI H335 May cause respiratory irritation.

GHS LABEL PRECAUTIONARY STATEMENTS

P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with

water/shower.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

GHS SDS PRECAUTIONARY STATEMENTS

P270 Do no eat, drink or smoke when using this product.

Date Printed: 7/22/2015

112-24-3

80-05-7

111-40-0

P363 Wash contaminated clothing before reuse.

3. Composition/Information On Ingredients

HAZARDOUS SUBSTANCES

Chem ical Name CAS-No. Wt.%

Range

GHS Sym bols

Page 2 / 5

GHS Statem ents

Triethylenetetramine 4,4'-(1-Methylethylidene) Bisphenol Diethylenetriamine

50-75 25-50 25-50

GHS05-GHS06 GHS05-GHS07 GHS05-GHS06

H311-314-317 H317-318-335 H302-311-314-317

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical

attention. Do NOT allow rubbing of eyes or keeping eyes closed. If exposed to fumes or vapors, flush eyes with plenty of water for at least 15 minutes. Get medical attention.

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists. Remove contaminated clothing. Wash skin with soap and water. Get medical attention. Immediately flush skin with plenty of water for at least 15 minutes while removing clothing. Get medical attention immediately. Wash clothing separately before reuse. Destroy contaminated shoes. Wash contaminated clothing and decontaminate footwear before reuse.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: If swallowed, do not induce vomiting. If victim is conscious and alert, give 2 to 4 cupfuls of water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. Treat symptomatically and supportively. Do not induce vomiting unless advised by a physician. Call nearest Poison Control Center or Physician immediately.

5. Fire-fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. No unusual fire or explosion hazards noted.

SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent pressure buildup and possible

autoignition or explosion. Evacuate area and fight fire from a safe distance. Containers can rupture and release highly toxic material if exposed to heat. Substance is non-combustible but reacts with many metals to form explosive hydrogen gas. Use water spray to keep fire-exposed containers cool. Containers may explode when heated.

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Avoid runoff into sewers and waterways. Provide ventilation

and approach spill from upwind using proper personal protective equipment as indicated in Section 8. Carefully neutralize spill with sodium bicarbonate (NaHCO3). Contain spilled liquid with sand or earth. DO NOT use combustible materials such as sawdust. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Remove all sources of ignition, ventilate area and remove with inert absorbent and non-sparking tools. Dispose of according to local, state (provincial) and federal regulations. Do not incinerate closed containers.

7. Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.

Use only in a well-ventilated area. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.

STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep container closed when not in use.

Date Printed: 7/22/2015

8. Exposure Controls/Personal Protection

Page 3 / 5

Chem ical Name CAS-No.

Triethylenetetramine 112-24-3 55.0 N.E. N.E. N.E. N.E. Diethylenetriamine 111-40-0 30.0 1 ppm N.E. N.E. N.E. 4,4'-(1-Methylethylidene) Bisphenol

80-05-7 30.0 N.E. N.E. N.E. N.E.

Weight %

Less Than

ACGIH TLV-

TWA

ACGIH TLV-

STE L

OSHA PEL-TWA

OSHA PEL-

CEILING

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne

levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.

SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Use impervious gloves to prevent skin contact and absorption of this material through the skin. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of

personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.

9. Physical and Chemical Properties

Appearance: Odor: Relative Density: Freeze Point, °C: Solubility in Water: Decompostion Tem p., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:

Liquid Solvent Like

1.010 N.D. None N.D. 200 - 277 Does not Support Combustion Slower than Ether Heavier than Air

Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-

octanol/water:

Explosive Lim its, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:

Liquid N.E. N.D. N.D.

N.D.

1.1 - 6.5 94 N.D. N.D.

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid temperatures above 120°F (49°C). Avoid contact with strong acid and strong bases. Avoid

contact with metals.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Product slowly corrodes copper, aluminum, zinc, and galvanized surfaces.

HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes. Decomposition produces hydrogen chloride, chlorine and hydrogen gases.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

11. Toxicological information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Causes eye irritation. Substance causes severe eye irritation. Injury may be

permanent.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Causes skin irritation. Allergic reactions are possible. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Severely irritating; may cause permanent skin damage.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful

Date Printed: 7/22/2015

if inhaled. Avoid breathing fumes, spray, vapors, or mist. High vapor concentrations are irritating to the eyes, nose, throat and lungs. Prolonged or excessive inhalation may cause respiratory tract irritation.

EFFECTS OF OVEREXPOSURE - INGESTION: Corrosive and may cause severe and permanent damage to mouth, throat and stomach. Substance may be harmful if swallowed.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Prolonged or repeated overexposure may cause lung damage. Effects of overexposure may include irritation of the nose and throat, irritation of the digestive tract and signs of nervous system depression (e.g., headache, drowsiness, loss of coordination and fatigue). Repeated exposure to low concentrations of HCl vapor or mist may cause bleeding of nose and gums.

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

112-24-3 Triethylenetetramine 2500 mg/kg Rat 550 mg/kg Rabbit N.I. 80-05-7 4,4'-(1-Methylethylidene) Bisphenol 3200 mg/kg Rat 3577 mg/kg Rabbit N.I. 111-40-0 Diethylenetriamine 819 mg/kg Rat 672 mg/kg Rabbit N.I.

N.I. - No Information

Page 4 / 5

12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not

allow to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. 3066 3066 N.A.

Proper Shipping Name:

Hazard Class: N.A. 8 8 N.A.

Packing Group: N.A. II II N.A.

Lim ited Quantity: No Yes No No

Paint Products in

Limited Quantities

Paint and Paint Related

Products

Paint and Paint

GHS HAZARD STATEMENTS

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed. Acute Toxicity, Dermal, category 4 H312 Harmful in contact with skin. Skin Sensitizer, category 1 H317 May cause an allergic skin reaction. Eye Irritation, category 2 H319 Causes serious eye irritation. Acute Toxicity, Inhalation, category 2 H330 Fatal if inhaled. Carcinogenicity, category 2 H351 Suspected of causing cancer. Classified as Category 2 based on limited

evidence on human and/or animal studies. Mixtures with concentrations of suspected carcinogens ingredients at concentration present between 0.1% and 1.0% labelling the SDS will be optional depending on authorities. If Category 2 carcinogenic present at a concentration of 1% or above labelling the SDS will be expected. Routes of exposure are dependant on ingredient form.

STOT, repeated exposure, category 2 H373 May cause damage to organs through prolonged or repeated exposure.

GHS LABEL PRECAUTIONARY STATEMENTS

P201 Obtain special instructions before use. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection.

Date Printed: 7/22/2015

P281 Use personal protective equipment as required. P284 [In case of inadequate ventilation] wear respiratory protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

GHS SDS PRECAUTIONARY STATEMENTS

P270 Do no eat, drink or smoke when using this product. P363 Wash contaminated clothing before reuse.

Page 2 / 5

3. Composition/Information On Ingredients

HAZARDOUS SUBSTANCES

Chem ical Name CAS-No. Wt.%

Range

GHS Sym bols

GHS Statem ents

Bisphenol A Epoxy Resin Furfuryl Alcohol Hexanediol Diacrylate Titanium Dioxide

25085-99-8

98-00-0 13048-33-4 13463-67-7

50-75 10-25

2.5-10

1.0-2.5

No Information No Information GHS06-GHS08 H302-312-319-330-335-351-373 GHS07 H315-317-319 No Information No Information

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical

attention. Do NOT allow rubbing of eyes or keeping eyes closed.

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: If swallowed, rinse mouth with water. If feeling unwell, get medical attention. Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and get medical attention.

5. Fire-fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. FLASH POINT IS TESTED TO BE GREATER

THAN 200 DEGREES F. No unusual fire or explosion hazards noted.

SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. If water is used, fog nozzles are preferred.

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: If spilled, contain spilled material and remove with inert

absorbent. Dispose of contaminated absorbent, container, and unused contents in accordance with local, state, and federal regulations. Do not incinerate closed containers

7. Handling and Storage

Date Printed: 7/22/2015

Page 3 / 5

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse. Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.

STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use.

8. Exposure Controls/Personal Protection

Chem ical Name CAS-No.

Bisphenol A Epoxy Resin 25085-99-8 75.0 N.E. N.E. N.E. N.E. Furfuryl Alcohol 98-00-0 20.0 10 ppm 15 ppm 50 ppm N.E. Hexanediol Diacrylate 13048-33-4 10.0 N.E. N.E. N.E. N.E. Titanium Dioxide 13463-67-7 5.0 10 mg/m3 N.E. 15 mg/m3 N.E.

Weight %

Less Than

ACGIH TLV-

TWA

ACGIH TLV-

STE L

OSHA PEL-TWA

OSHA PEL-

CEILING

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne

levels below recommended exposure limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.

SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of

personal protective equipment and their applications.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.

9. Physical and Chemical Properties

Appearance: Odor: Relative Density: Freeze Point, °C:

Solubility in Water:

Decompostion Tem p., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:

Liquid Solvent Like

1.152 N.D. None N.D. 126 - 260 Does not Support Combustion Slower than Ether Heavier than Air

Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-

octanol/water:

Explosive Lim its, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:

Liquid N.E. N.A. N.D.

N.D.

1.8 - 16.3 94 N.D. N.D.

(See "Other information" Section for abbreviation legend)

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies.

HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

11. Toxicological information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, and may injure eye tissue if not removed promptly.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: May cause skin sensitization, an allergic reaction, which becomes evident

upon re-exposure to this material. Severely irritating; may cause permanent skin damage. May cause sensitization. May cause allergic reaction. Low hazard for usual industrial handling or commercial handling by trained personnel.

EFFECTS OF OVEREXPOSURE - INHALATION: High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid

Date Printed: 7/22/2015

breathing fumes, spray, vapors, or mist.

EFFECTS OF OVEREXPOSURE - INGESTION: Substance may be harmful if swallowed.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Contains Titanium Dioxide. Titanium Dioxide is listed as a Group

2B-"Possibly carcinogenic to humans" by IARC. No significant exposure to Titanium Dioxide is thought to occur during the use of products in which Titanium Dioxide is bound to other materials, such as in paints during brush application or drying. Risk of overexposure depends on duration and level of exposure to dust from repeated sanding of surfaces or spray mist and the actual concentration of Titanium Dioxide in the formula. (Ref: IARC Monograph, Vol. 93, 2010)

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No. Chemical Name Oral LD50 Dermal LD50 Vapor LC50

13463-67-7 Titanium Dioxide >10000 mg/kg Rat N.I. N.I.

N.I. - No Information

Page 4 / 5

12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not

allow to enter waterways, wastewater, soil, storm drains or sewer systems.

14. Transport Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. UN2874 UN2874 N.A.

Proper Shipping Name:

Hazard Class: N.A. 6.1 6.1 N.A.

Packing Group: N.A. III III N.A.

Lim ited Quantity: Yes Yes No Yes

Paint & related products

in limited quantities

Furfuryl alcohol mixture

Furfuryl alcohol

mixture

Paint & related

products in limited

quantities

15. Regulatory Information

U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:

Reactive Hazard, Acute Health Hazard, Chronic Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

No Sara 313 components exist in this product.

Toxic Substances Control Act:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:

No TSCA 12(b) components exist in this product.

Date Printed: 7/22/2015

16. Other Information

HMIS RATINGS

Health: 2* Flammability: 1 Physical Hazard: 1 Personal Protection: X

NFPA RATINGS

Health: 2 Flammability: 1 Instability 0

Page 5 / 5

VOLATILE ORGANIC COMPOUNDS, g/L:

SDS REVISION DATE: 7/22/2015

REASON FOR REVISION:

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

186

Date Printed: 7/22/2015

Safety Data Sheet

* Trusted Quality Since 1921 *

www.rustoleum.com

1. Identification

Product Name: CPS 29.75 LB CP TurboKrete-Aggregate Revision Date: 7/22/2015

Product Identifier: 237452 Supercedes Date: New SDS

Product Use/Class: Aggregate/TurboKrete Part C

Page 1 / 4

Supplier:

Preparer: Regulatory Department

Emergency Telephone:

Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA

24 Hour Hotline: 847-367-7700

2. Hazard Identification

Classification

Symbol(s) of Product

Signal Word

Warning

GHS HAZARD STATEMENTS

Acute Toxicity, Oral, category 4 H302 Harmful if swallowed.

GHS SDS PRECAUTIONARY STATEMENTS

P270 Do no eat, drink or smoke when using this product.

Manufacturer:

Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 USA

3. Composition/Information On Ingredients

HAZARDOUS SUBSTANCES

Chem ical Name CAS-No. Wt.%

Range

Crystalline Silica / Quartz

14808-60-7

75-100

GHS Sym bols

GHS07 H302

GHS Statem ents

4. First-aid Measures

FIRST AID - EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes holding eyelids open. Get medical

attention. Do NOT allow rubbing of eyes or keeping eyes closed.

Date Printed: 7/22/2015

FIRST AID - SKIN CONTACT: Wash skin with soap and water. Remove contaminated clothing. Get medical attention if irritation develops or persists.

FIRST AID - INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. Do NOT use mouth-to-mouth resuscitation. If you experience difficulty in breathing, leave the area to obtain fresh air. If continued difficulty is experienced, get medical assistance immediately.

FIRST AID - INGESTION: If swallowed, rinse mouth with water. If feeling unwell, get medical attention. Swallowing less than an ounce will not cause significant harm. For larger amounts, do not induce vomiting, but give one or two glasses of water to drink and get medical attention.

Page 2 / 4

5. Fire-fighting Measures

EXTINGUISHING MEDIA: Alcohol Film Forming Foam, Carbon Dioxide, Dry Chemical, Water Fog

UNUSUAL FIRE AND EXPLOSION HAZARDS: Keep containers tightly closed. FLASH POINT IS TESTED TO BE GREATER

THAN 200 DEGREES F. No unusual fire or explosion hazards noted.

SPECIAL FIREFIGHTING PROCEDURES: Water may be used to cool closed containers to prevent buildup of steam. If water is used, fog nozzles are preferred.

6. Accidental Release Measures

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Dispose of according to local, state (provincial) and federal

regulations. Do not incinerate closed containers. Sweep up gently to avoid dust cloud formation.

7. Handling and Storage

HANDLING: Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and launder before reuse.

Use only with adequate ventilation. Follow all MSDS/label precautions even after container is emptied because it may retain product residues. Avoid breathing fumes, vapors, or mist. Avoid contact with eyes, skin and clothing.

STORAGE: Store in a dry, well ventilated place. Keep container tightly closed when not in use. Keep container closed when not in use.

8. Exposure Controls/Personal Protection

Chem ical Name CAS-No.

Crystalline Silica / Quartz 14808-60-7 90.0 0.025 mg/m3 N.E. N.E. N.E.

PERSONAL PROTECTION

ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne

levels below recommended exposure limits. Provide general dilution of local exhaust ventilation in volume and pattern to keep TLV of hazardous ingredients below acceptable limits. Prevent build-up of vapors by opening all doors and windows to achieve crossventilation.

RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.

SKIN PROTECTION: Use gloves to prevent prolonged skin contact. Nitrile or Neoprene gloves may afford adequate skin protection.

EYE PROTECTION: Use safety eyewear designed to protect against splash of liquids. Wear safety glasses with side shields (or goggles) and a face shield.

OTHER PROTECTIVE EQUIPMENT: Refer to safety supervisor or industrial hygienist for further guidance regarding types of personal protective equipment and their applications. Refer to safety supervisor or industrial hygienist for further information regarding personal protective equipment and its application.

HYGIENIC PRACTICES: Wash thoroughly with soap and water before eating, drinking or smoking. Remove contaminated clothing immediately and launder before reuse.

Weight %

Less Than

ACGIH TLV-

TWA

ACGIH TLV-

STE L

OSHA PEL-TWA

OSHA PEL-

CEILING

Date Printed: 7/22/2015

9. Physical and Chemical Properties

Page 3 / 4

Appearance: Odor: Relative Density: Freeze Point, °C:

Solubility in Water:

Decompostion Tem p., °C: Boiling Range, °C: Flammability: Evaporation Rate: Vapor Density:

(See "Other information" Section for abbreviation legend)

Particulate Solid Solvent Like

2.646 N.D. None N.D. 999 - 2,230 Does not Support Combustion Slower than Ether Heavier than Air

Physical State: Odor Threshold: pH: Viscosity: Partition Coefficient, n-

octanol/water:

Explosive Lim its, vol%: Flash Point, °C: Auto-ignition Temp., °C: Vapor Pressure:

Solid N.E. N.A. N.D.

N.D.

N.A. - N.A. 537 N.D. N.D.

10. Stability and Reactivity

CONDITIONS TO AVOID: Avoid contact with strong acid and strong bases.

INCOMPATIBILITY: Incompatible with strong oxidizing agents, strong acids and strong alkalies. Not applicable for this product.

HAZARDOUS DECOMPOSITION: When heated to decomposition, it emits acrid smoke and irritating fumes. May produce

hazardous fumes when heated to decomposition as in welding. Fumes may contain: carbon monoxide, carbon dioxide, chlorine, hydrogen chloride, cyanide, and methylene diphenyl diisocyanate.

HAZARDOUS POLYMERIZATION: Will not occur under normal conditions.

STABILITY: This product is stable under normal storage conditions.

11. Toxicological information

EFFECTS OF OVEREXPOSURE - EYE CONTACT: Irritating, and may injure eye tissue if not removed promptly.

EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Low hazard for usual industrial handling or commercial handling by trained

personnel.

EFFECTS OF OVEREXPOSURE - INHALATION: Harmful if inhaled. High gas, vapor, mist or dust concentrations may be harmful if inhaled. Avoid breathing fumes, spray, vapors, or mist.

EFFECTS OF OVEREXPOSURE - INGESTION: Expected to be a low ingestion hazard.

EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: No Information

PRIMARY ROUTE(S) OF ENTRY: Eye Contact, Ingestion, Inhalation, Skin Absorption, Skin Contact

ACUTE TOXICITY VALUES The acute effects of this product have not been tested. Data on individual components are tabulated below:

CAS-No.

14808-60-7 Crystalline Silica / Quartz 500 mg/kg Rat N.I. N.I.

N.I. - No Information

Chem ical Name Oral LD50 Dermal LD50 Vapor LC50

12. Ecological Information

ECOLOGICAL INFORMATION: Product is a mixture of listed components.

13. Disposal Information

DISPOSAL INFORMATION: Dispose of material in accordance to local, state, and federal regulations and ordinances. Do not

allow to enter waterways, wastewater, soil, storm drains or sewer systems.

Date Printed: 7/22/2015

Page 4 / 4

14. Transport Information

Domestic (USDOT) International (IMDG) Air (IATA) TDG (Canada)

UN Number: N.A. N.A. N.A. N.A.

Proper Shipping Name: Not Regulated Not Regulated Not Regulated Not Regulated

Hazard Class: N.A. N.A. N.A. N.A.

Packing Group: N.A. N.A. N.A. N.A.

Lim ited Quantity: No No No No

15. Regulatory Information

U.S. Federal Regulations:

CERCLA - SARA Hazard Category

This product has been reviewed according to the EPA ‘Hazard Categories’ promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:

Acute Health Hazard, Chronic Health Hazard

Sara Section 313:

This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:

No Sara 313 components exist in this product.

Toxic Substances Control Act:

This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States:

No TSCA 12(b) components exist in this product.

16. Other Information

HMIS RATINGS

Health: 1* Flammability: 0 Physical Hazard: 0 Personal Protection: X

NFPA RATINGS

Health: 1 Flammability: 0 Instability 0

VOLATILE ORGANIC COMPOUNDS, g/L:

SDS REVISION DATE: 7/22/2015

REASON FOR REVISION:

Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined

Rust-Oleum Corporation believes, to the best of its knowledge, information and belief, the information contained herein to be accurate and reliable as of the date of this safety data sheet. However, because the conditions of handling, use, and storage of these materials are beyond our control, we assume no responsibility or liability for personal injury or property damage incurred by the use of these materials. Rust-Oleum Corporation makes no warranty, expressed or implied, regarding the accuracy or reliability of the data or results obtained from their use. All materials may present unknown hazards and should be used with caution. The information and recommendations in this material safety data sheet are offered for the users’ consideration and examination. It is the responsibility of the user to determine the final suitability of this information and to comply with all applicable international, federal, state, and local laws and regulations.

0

Rust-Oleum 237531, 237532, 237452 User Manual

Specifications and Main Features

Frequently Asked Questions

User Manual

GHS HAZARD STATEMENTS

GHS LABEL PRECAUTIONARY STATEMENTS

GHS SDS PRECAUTIONARY STATEMENTS

GHS HAZARD STATEMENTS

GHS LABEL PRECAUTIONARY STATEMENTS

GHS SDS PRECAUTIONARY STATEMENTS

GHS HAZARD STATEMENTS

GHS SDS PRECAUTIONARY STATEMENTS